- •Recovered Paper and Recycled Fibers
- •Isbn: 3-527-30999-3
- •Introduction
- •Isbn: 3-527-30999-3
- •Isbn: 3-527-30999-3
- •2006, Isbn 3-527-30997-7
- •Volume 1
- •Isbn: 3-527-30999-3
- •4.1 Introduction 109
- •4.2.5.1 Introduction 185
- •4.3.1 Introduction 392
- •5.1 Introduction 511
- •6.1 Introduction 561
- •6.2.1 Introduction 563
- •6.4.1 Introduction 579
- •Volume 2
- •7.3.1 Introduction 628
- •7.4.1 Introduction 734
- •7.5.1 Introduction 777
- •7.6.1 Introduction 849
- •7.10.1 Introduction 887
- •8.1 Introduction 933
- •1 Introduction 1071
- •5 Processing of Mechanical Pulp and Reject Handling: Screening and
- •1 Introduction 1149
- •Isbn: 3-527-30999-3
- •Isbn: 3-527-30999-3
- •Isbn: 3-527-30999-3
- •Isbn: 3-527-30999-3
- •Introduction
- •Introduction
- •Isbn: 3-527-30999-3
- •1 Introduction
- •1 Introduction
- •1 Introduction
- •1 Introduction
- •1 Introduction
- •1 Introduction
- •150.000 Annual Fiber Flow[kt]
- •1 Introduction
- •1 Introduction
- •Introduction
- •Isbn: 3-527-30999-3
- •Void volume
- •Void volume fraction
- •Xylan and Fiber Morphology
- •Initial bulk residual
- •4.2.5.1 Introduction
- •In (Ai) Model concept Reference
- •Initial value
- •Validation and Application of the Kinetic Model
- •Inititial
- •Viscosity
- •Influence on Bleachability
- •Impregnation
- •Impregnation
- •Impregnation
- •Impregnation
- •Impregnation
- •Impregnation
- •Impregnation
- •Impregnation
- •Impregnation
- •Impregnation
- •Introduction
- •International
- •Impregnation
- •Influence of Substituents on the Rate of Hydrolysis
- •140 116 Total so2
- •Xylonic
- •Viscosity Brightness
- •Xyl Man Glu Ara Furf hoAc XyLa
- •Initial NaOh charge [% of total charge]:
- •Introduction
- •Isbn: 3-527-30999-3
- •Introduction
- •Isbn: 3-527-30999-3
- •Introduction
- •Introduction
- •Isbn: 3-527-30999-3
- •In 1950, about 50% of the global paper production was produced. This proportion
- •4.0% Worldwide; 4.2% for the cepi countries; and 4.8% for Germany.
- •1150 1 Introduction
- •1 Introduction
- •1 Introduction
- •Virgin fibers
- •74.4 % Mixed grades
- •Indonesia
- •Virgin fibers
- •Inhomogeneous sample Homogeneous sample
- •Variance of sampling Variance of measurement
- •1.Quartile
- •3.Quartile
- •Insoluble
- •Insoluble
- •Insoluble
- •Integral
- •In Newtonion liquid
- •Velocity
- •Increasing dp
- •2Α filter
- •0 Reaction time
- •Increasing interaction of probe and cellulose
- •Increasing hydrodynamic size
- •Vessel cell of beech
- •Initial elastic range
- •Internal flow
- •Intact structure
- •Viscosity 457
- •Isbn: 3-527-30999-3
- •1292 Index
- •Visbatch® pulp 354
- •Index 1293
- •1294 Index
- •Impregnation 153
- •Viscosity–extinction 433
- •Index 1295
- •1296 Index
- •Index 1297
- •Inhibitor 789
- •1298 Index
- •Index 1299
- •Impregnation liquor 290–293
- •1300 Index
- •Industries
- •Index 1301
- •1302 Index
- •Index 1303
- •Xylose 463
- •1304 Index
- •Index 1305
- •1306 Index
- •Index 1307
- •1308 Index
- •In conventional kraft cooking 232
- •Visbatch® pulp 358
- •Index 1309
- •In prehydrolysis-kraft process 351
- •Visbatch® cook 349–350
- •1310 Index
- •Index 1311
- •1312 Index
- •Viscosity 456
- •Index 1313
- •Viscosity 459
- •Interactions 327
- •1314 Index
- •Index 1315
- •Viscosity 459
- •1316 Index
- •Index 1317
- •Xylose 461
- •Index 1319
- •Visbatch® pulp 355
- •Impregnation 151–158
- •1320 Index
- •Index 1321
- •1322 Index
- •Xylan water prehydrolysis 333
- •Index 1323
- •1324 Index
- •Viscosity 459
- •Index 1325
- •Xylose 940
- •1326 Index
- •Index 1327
- •In selected kinetics model 228–229
- •4OMeGlcA 940
- •1328 Index
- •Index 1329
- •Intermediate molecule 164–165
- •1330 Index
- •Viscosity 456
- •Index 1331
- •1332 Index
- •Impregnation liquor 290–293
- •Index 1333
- •1334 Index
- •Index 1335
- •1336 Index
- •Impregnation 153
- •Index 1337
- •1338 Index
- •Viscose process 7
- •Index 1339
- •Volumetric reject ratio 590
- •1340 Index
- •Index 1341
- •1342 Index
- •Index 1343
- •1344 Index
- •Index 1345
- •Initiator 788
- •Xylose 463
- •1346 Index
- •Index 1347
- •Vessel 385
- •Index 1349
- •1350 Index
- •Xylan 834
- •1352 Index
Impregnation
HOT
DISPLACEMENT
COOKING
COLD
DISPLACEMENT
PUMP
DISCHARGE
CL
CL
IL
IL
Fig. 4.135 Steps of the CBC cooking cycle [4].
4.2.8.2.7 Batch Cooking Schedule Management
In the displacement cooking plant, a number of batch digesters share a common
tank farm and common supply and discharge systems. In order to make optimum
use of these systems, the digester operation follows a strict program. At a given
production rate, this program must account for scheduling the exclusive use of
certain systems (e.g., of chip supply or pulp discharge systems), for the management
of tank levels in the tank farm, and for the pulp quality.
The cooking schedule for a simple four-digester system is shown in Fig. 4.136.
The chip fill in digester 2 is offset from the chip fill in digester 1, then follows
digester 3, and after digester 4 it is again time for digester 1. The schedule for a
particular application depends on the number of digesters, the total length of the
cooking cycle as well as on the duration of the individual steps.
0 60 120 180 240 300
1
2
3
4
Digester #
Time, minutes
Chip Fill Impregnation Hot displacement Heating and cooking Cold displacement Discharge Space time
Fig. 4.136 Example for cooking schedule of four-digester displacement cooking plant.
376 4 Chemical Pulping Processes
4.2.8.3 Continuous Cooking Technology and Equipment
4.2.8.3.1 Principles of Continuous Cooking
The basic idea of continuous cooking is to close the chain of continuous processes
in the fiber line. Based on the original process, technologies have developed over
time which employ in-digester washing and advanced alkali and temperature profiling.
The outline of a typical single-vessel continuous cooking system is illustrated in
Fig. 4.137. Vapor recovered from the extraction liquor is used to remove air from
the chips and to preheat them. The chips are then continuously transported to the
digester with the help of liquor circulated between the chip feeding system and
the digester top. A percentage of the cooking chemicals is charged with white
liquor to the top circulation, while the remainder of the white liquor goes to the
digester.
The continuous digester itself is a huge vessel of vertical cylindrical design.
Chips move from the top of the digester to the bottom by gravity. The vessel is
equipped with a top separator, which separates the circulation liquor from the
chips, and with a scraper and outlet device in the bottom. The digester has strainers
at different levels, which hold back wood and pulp when liquor is extracted
from the digester. Several liquor circulation loops are used to change the chemical
regime and/or to adjust the temperature in the different zones of the digester. A
central pipe discharge brings the circulation liquor back to the center of the digester
near the corresponding set of circulation screens. Steam is used for liquor
heating, preferably in indirect shell-and-tube heat exchangers.
Spent liquor which is not circulated back to the cooking process is extracted for
vapor recovery. The weak black liquor is then subjected to fiber separation and
cooling before being transferred to the evaporation plant.
Continuous cooking systems can be categorized into single-vessel and two-vessel
systems, with hydraulic or steam/liquor phase digesters. Two-vessel systems have a
separate vessel where the impregnation of chips takes place. In such a system, the
chips are fed to the top of the impregnation vessel and then transferred from the bottom
of the impregnation vessel to the digester top by a separate circulation loop.
CHIP STEAMING,
CHIP FEEDING
SYSTEM
VAPOR
RECOVERY
SYSTEM
Extraction liquor
Pulp
Chips Top
circulation
liquor
Chips and liquor
Wash filtrate
Weak black liquor
Vapor
DIGESTER
White liquor
Steam
Fig. 4.137 Outline of single-vessel continuous cooking system.
4.2 Kraft Pulping Processes 377
Hydraulic digesters are completely filled with liquor, whereas steam/liquor phase
digesters have a vapor phase at the top. In a steam/liquor phase digester, the chips
reach above the liquor level. They can be heated to cooking temperature with
direct steam, which in most cases requires prior impregnation and therefore
makes sense mainly in a two-vessel system.
4.2.8.3.2 Continuous Cooking Process Steps
While different continuous cooking technologies follow their individual concept,
the basic steps found in all these systems are chip steaming, chip feeding, impregnation,
cooking, washing, and pulp discharge. These steps are described in general
below, and are discussed later in connection with some special continuous
cooking techniques.
Chip Steaming
The continuous cooking process starts when the chips enter a steam environment.
The target of steaming is the elimination of air from the chips to a maximum
extent. As the chips are warmed up, the air is positively displaced from inside
them by the increasing partial pressure of wood moisture and by its own increasing
volume. The residual air removal must occur by counter-diffusion of water
vapor against air.
Adequate steaming of chips must be ensured at all times, because the buoyancy
of air entrapped in chips can critically influence chip column movement in the
digester. Other negative effects of poor air removal include pump cavitation, feed
line hammering, and inhomogeneous impregnation.
Traditionally, steaming was performed at elevated pressure in a steaming vessel
and/or near atmospheric pressure in the chip bin. Lately, it has been found that
pressurized steaming can be skipped when the duration of atmospheric steaming
is sufficiently long.
Chip Feeding
Once the air is removed from the chips, they must be brought to digester pressure,
which is done by a combination of rotary feeding devices and pumps. Liquor
is used as the transport medium for chips from the feeding system to the digester
top.