- •Contents
- •Foreword
- •Preface
- •1 Materials in the Lab
- •2 Measurement
- •3 Joints, Stopcocks, and Glass Tubing
- •4 Cleaning Glassware
- •5 Compressed Gases
- •6 High and Low Temperature
- •7 Vacuum Systems
- •8 The Gas-Oxygen Torch
- •APPENDIX
- •Appendix A Preparing Drawings for a Technician
- •Index
- •Foreword
- •Preface
- •For the Second Edition
- •Please note:
- •1 Materials in the Lab
- •1.1 Glass
- •1.1.1 Introduction
- •1.1.2 Structural Properties of Glass
- •1.1.3 Phase Separation
- •1.1.4 Devitrification
- •1.1.5 Different Types of Glass Used in the Lab
- •1.1.6 Grading Glass and Graded Seals
- •1.1.7 Separating Glass by Type
- •1.1.9 Stress in Glass
- •1.1.11 Tempered Glass
- •1.1.13 Limiting Broken Glass in the Lab
- •1.1.14 Storing Glass
- •1.1.15 Marking Glass
- •1.1.16 Consumer's Guide to Purchasing Laboratory Glassware
- •1.2 Flexible Tubing
- •1.2.1 Introduction
- •1.2.2 Physical Properties of Flexible Tubing
- •1.3 Corks, Rubber Stoppers, and Enclosures
- •1.3.1 Corks
- •1.3.2 Rubber Stoppers
- •1.3.3 Preholed Stoppers
- •1.3.4 Inserting Glass Tubing into Stoppers
- •1.3.5 Removing Glass from Stoppers and Flexible Tubing
- •1.3.6 Film Enclosures
- •1.4 O-Rings
- •1.4.2 Chemical Resistance of O-Ring Material
- •1.4.3 O-Ring Sizes
- •2 Measurement
- •2.1 Measurement: The Basics
- •2.1.1 Uniformity, Reliability, and Accuracy
- •2.1.2 History of the Metric System
- •2.1.3 The Base Units
- •2.1.4 The Use of Prefixes in the Metric System
- •2.1.5 Measurement Rules
- •2.2 Length
- •2.2.1 The Ruler
- •2.2.2 How to Measure Length
- •2.2.3 The Caliper
- •2.2.4 The Micrometer
- •2.3 Volume
- •2.3.1 The Concepts of Volume Measurement
- •2.3.2 Background of Volume Standards
- •2.3.4 Materials of Volumetric Construction #1 Plastic
- •2.3.5 Materials of Volumetric Construction #2 Glass
- •2.3.6 Reading Volumetric Ware
- •2.3.7 General Practices of Volumetric Ware Use
- •2.3.8 Calibrations, Calibration, and Accuracy
- •2.3.9 Correcting Volumetric Readings
- •2.3.10 Volumetric Flasks
- •2.3.11 Graduated Cylinders
- •2.3.12 Pipettes
- •2.3.13 Burettes
- •2.3.14 Types of Burettes
- •2.3.15 Care and Use of Burettes
- •2.4 Weight and Mass
- •2.4.1 Tools for Weighing
- •2.4.2 Weight Versus Mass Versus Density
- •2.4.3 Air Buoyancy
- •2.4.5 Balance Location
- •2.4.6 Balance Reading
- •2.4.7 The Spring Balance
- •2.4.8 The Lever Arm Balance
- •2.4.9 Beam Balances
- •2.4.10 Analytical Balances
- •2.4.11 The Top-Loading Balance
- •2.4.12 Balance Verification
- •2.4.13 Calibration Weights
- •2.5 Temperature
- •2.5.1 TheNature of Temperature Measurement
- •2.5.2 The Physics of Temperature-Taking
- •2.5.3 Expansion-Based Thermometers
- •2.5.4 Linear Expansion Thermometers
- •2.5.5 Volumetric Expansion Thermometers
- •2.5.7 Thermometer Calibration
- •2.5.8 Thermometer Lag
- •2.5.9 Air Bubbles in Liquid Columns
- •2.5.10 Pressure Expansion Thermometers
- •2.5.11 Thermocouples
- •2.5.12 Resistance Thermometers
- •3.1 Joints and Connections
- •3.1.1 Standard Taper Joints
- •3.1.2 Ball-and-Socket Joints
- •3.1.3 The O-Ring Joint
- •3.1.4 Hybrids and Alternative Joints
- •3.1.5 Special Connectors
- •3.2 Stopcocks and Valves
- •3.2.1 Glass Stopcocks
- •3.2.2 Teflon Stopcocks
- •3.2.3 Rotary Valves
- •3.2.4 Stopcock Design Variations
- •3.3.1 Storage and Use of Stopcocks and Joints
- •3.3.2 Preparation for Use
- •3.3.3 Types of Greases
- •3.3.4 The Teflon Sleeve
- •3.3.5 Applying Grease to Stopcocks and Joints
- •3.3.6 Preventing Glass Stopcocks and Joints from Sticking or Breaking on a Working System
- •3.3.7 Unsticking Joints and Stopcocks
- •3.3.8 Leaking Stopcocks and Joints
- •3.3.9 What to Do About Leaks in Stopcocks and Joints
- •3.3.10 General Tips
- •3.4 Glass Tubing
- •3.4.1 The Basics of Glass Tubing
- •3.4.2 Calculating the Inside Diameter (I.D.)
- •3.4.3 Sample Volume Calculations
- •4 Cleaning Glassware
- •4.1 The Clean Laboratory
- •4.1.1 Basic Cleaning Concepts
- •4.1.2 Safety
- •4.1.3 Removing Stopcock Grease
- •4.1.4 Soap and Water
- •4.1.5 Ultrasonic Cleaners
- •4.1.6 Organic Solvents
- •4.1.7 The Base Bath
- •4.1.8 Acids and Oxidizers
- •4.1.9 Chromic Acid
- •4.1.10 Hydrofluoric Acid
- •4.1.11 Extra Cleaning Tips
- •4.1.12 Additional Cleaning Problems and Solutions
- •4.1.13 Last Resort Cleaning Solutions
- •5 Compressed Gases
- •5.1 Compressed GasTanks
- •5.1.1 Types of Gases
- •5.1.2 The Dangers of Compressed Gas
- •5.1.3 CGA Fittings
- •5.1.4 Safety Aspects of Compressed Gas Tanks
- •5.1.5 Safety Practices Using Compressed Gases
- •5.1.6 In Case of Emergency
- •5.1.7 Gas Compatibility with Various Materials
- •5.2 The Regulator
- •5.2.1 The Parts of the Regulator
- •5.2.2 House Air Pressure System
- •5.2.4 How to Use Regulators Safely
- •5.2.6 How to Purchase a Regulator
- •6 High and Low Temperature
- •6.1 High Temperature
- •6.1.1 TheDynamics of Heat in the Lab
- •6.1.2 General Safety Precautions
- •6.1.3 Open Flames
- •6.1.4 Steam
- •6.1.5 Thermal Radiation
- •6.1.6 Transfer of Energy
- •6.1.7 Hot Air Guns
- •6.1.8 Electrical Resistance Heating
- •6.1.9 Alternatives to Heat
- •6.2 Low Temperature
- •6.2.1 TheDynamics of Cold in the Lab
- •6.2.2 Room Temperature Tap Water (=20°C)
- •6.2.8 Safety with Slush Baths
- •6.2.9 Containment of Cold Materials
- •6.2.10 Liquid (Cryogenic) Gas Tanks
- •7 Vacuum Systems
- •7.1 How to Destroy a Vacuum System
- •7.2.1 Preface
- •7.2.2 How to Use a Vacuum System
- •7.2.4 Pressure, Vacuum, and Force
- •7.2.5 Gases, Vapors, and the Gas Laws
- •7.2.6 Vapor Pressure
- •7.2.7 How to Make (and Maintain) a Vacuum
- •7.2.8 Gas Flow
- •7.2.9 Throughput and Pumping Speed
- •7.3 Pumps
- •7.3.1 The Purpose of Pumps
- •7.3.2 The Aspirator
- •7.3.3 Types and Features of Mechanical Pumps
- •7.3.4 Connection, Use, Maintenance, and Safety
- •7.3.5 Condensable Vapors
- •7.3.6 Traps for Pumps
- •7.3.7 Mechanical Pump Oils
- •7.3.8 The Various Mechanical Pump Oils
- •7.3.9 Storing Mechanical Pumps
- •7.3.11 Ultra-High Vacuum Levels Without Ultra-High
- •7.3.12 Diffusion Pumps
- •7.3.13 Attaching a Diffusion Pump to a Vacuum System
- •7.3.14 How to Use a Diffusion Pump
- •7.3.15 Diffusion Pump Limitations
- •7.3.17 Diffusion Pump Maintenance
- •7.3.18 Toepler Pumps
- •7.4 Traps
- •7.4.1 The Purpose and Functions of Traps
- •7.4.2 Types of Traps
- •7.4.3 Proper Use of Cold Traps
- •7.4.4 Maintenance of Cold Traps
- •7.4.5 Separation Traps
- •7.4.6 Liquid Traps
- •7.5 Vacuum Gauges
- •7.5.2 The Mechanical Gauge Family
- •7.5.4 The Liquid Gauge Family
- •7.5.5 The Manometer
- •7.5.6 The McLeod Gauge
- •7.5.7 How to Read a McLeod Gauge
- •7.5.8 Bringing a McLeod Gauge to Vacuum Conditions
- •7.5.10 The Tipping McLeod Gauge
- •7.5.11 Condensable Vapors and the McLeod Gauge
- •7.5.12 Mercury Contamination from McLeod Gauges
- •7.5.13 Cleaning a McLeod Gauge
- •7.5.14 Thermocouple and Pirani Gauges
- •7.5.15 The Pirani Gauge
- •7.5.16 Cleaning Pirani Gauges
- •7.5.17 The Thermocouple Gauge
- •7.5.18 Cleaning Thermocouple Gauges
- •7.5.19 The lonization Gauge Family
- •7.5.20 The Hot-Cathode Ion Gauge
- •7.5.21 Cleaning Hot-Cathode Ion Gauges
- •7.5.24 The Momentum Transfer Gauge (MTG)
- •7.6 Leak Detection and Location
- •7.6.1 AllAbout Leaks
- •7.6.3 False Leaks
- •7.6.4 Real Leaks
- •7.6.5 Isolation to Find Leaks
- •7.6.6 Probe Gases and Liquids
- •7.6.7 The Tesla Coil
- •7.6.8 Soap Bubbles
- •7.6.9 Pirani or Thermocouple Gauges
- •7.6.10 Helium Leak Detection
- •7.6.11 Helium Leak Detection Techniques
- •7.6.13 Repairing Leaks
- •7.7 More Vacuum System Information
- •7.7.1 The Designs of Things
- •8 The Gas-Oxygen Torch
- •8.1.2 How to Light a Gas-Oxygen Torch
- •8.1.3 How to Prevent a Premix Torch from Popping
- •8.2.2 How to Tip-Off a Sample
- •8.2.3 How to Fire-Polish the End of a Glass Tube
- •8.2.4 Brazing and Silver Soldering
- •Appendix
- •A.2 Suggestions for Glassware Requests
- •B.1 Introduction
- •B.2 Polyolefins
- •B.3 Engineering Resins
- •B.4 Fluorocarbons
- •B.5 Chemical Resistance Chart
- •C.1 Chapter 1
- •C.4 Chapter 4
- •C.5 Chapter 5 & Chapter 6
- •C.6 Chapter 7
- •C.7 Chapter 8
- •D.1 Laboratory Safety
- •D.2 Chemical Safety
- •D.3 Chapter 1
- •D.4 Chapter 2
- •D.5 Chapter 3
- •D.6 Chapter 4
- •D.7 Chapter 5 and the Second Half of Chapter 6
- •D.8 Chapter 7
- •D.9 Chapter 8
- •Index
Appendix
Appendix A
Preparing Drawings
for a Technician
A.1 The Problems with Requests to Glass Shops*
There are many brilliant men and women who are excellent teachers and scientists, can analyze the most complex data, and can draw the most complex molecules or mathematical equations. Yet, many of these same people cannot communicate the shapes of even simple items on a piece of paper. In addition to this complication, when an object is made of glass, new complications are created. These newproblems typically derive from thefact that working with glass is like working with no other material on earth. Thus, the average person will tryto rationalize construction with materials they are more familiar with, such as wood or metal. In addition, it is unlikely that this average person will have had the opportunity to learn theparameters andlimitations of glassware construction.
I am in no waytrying to belittle the problems that machine, wood, or electrical shops have with poorlymade or inadequate drawings. However, sawing, turning,
J l
Fig. A.1Examples of requests to a glass shop.
* As a glassblower, I am most familiar with the specific problems encountered with requests to a glass shop. Regardless, these frustrations are shared by all whorequest custom items for construction.
489
490 |
Preparing Drawings for a Technician |
gluing, soldering, drilling, and cutting are common terms that are understood by most people. The terminology of glass is different: Fire-polishing, fusing, blowing open a hole, and spinning a base are as foreign to the average person as the tools used. Because of misunderstandings of the tools and operations used with glass, what a person asks for is often not what they want. Over the years, I've had requests for "drilling a hole in a tube and sticking a tube over the hole in the tube so that material could go several ways" or "welding a flat glass plate on the end of a tube so that it could stand up." In these two examples, what the requestors wanted were a "T" seal and a base to a column, respectively (see Fig. A.I). If I had done exactly what was requested, the costs could have been phenomenal.
A.2 Suggestions for Glassware Requests
Whether you have a glass shop in your facility or send your glassware requests to an outside glass shop, you should limit your requests for what you want and not state how to do it, because this will save you time and money. By simply stating what is wanted, providing necessary dimensions and related construction materials, and avoiding discussions on how to make the item, much time and confusion can be avoided.
The Sketch. Prepare a reasonably accurate sketch. You do not have to be a draftsman or an artist. However, you are not a two-year-old child with a crayon. It is likely that the more time that the glassblower spends on trying to figure out what your drawing is trying to represent, the more you will be charged.
The Measurements. Measurements should preferably be given in centimeters (or millimeters). English measurements are not recommended, and tenths of English measurements are not acceptable.
Tubing Identification. Commercially available tubing is only available in metric sizes. These tubing sizes are shown in Chapter 3. American-made mediumand heavy-wall tubing is made to English measurement dimensions, but are now listed in metric equivalent sizes. For example, 1-in. tubing is listed as 25.4 mm. Commercially available sizes (both metric and English) of medium and heavy wall tubing are shown in Chapter 3.
fl
|
|
|
|
/ |
24/40 |
24/40 |
18/9 |
18/9 |
#12 |
inner |
outer |
ball |
socket |
O-ring |
Fig. A.2 Examples of complete joint identification.
Appendix |
491 |
V A
Correct Incorrect
Fig. A.3 Proper orientation and placement of hooks.
Demountable Joint Identification. Joints should be drawn and identified as being either an inner (male) or outer (female) section. Size should be identified as well (see Sec. A.2 and Sec. 3.1.1). Ball-and-socket joints should be equally identified (see Fig. A.2 and Sec. 3.1.2). Because O-ring joints do not have inner and outer sections, only their sizes are required (see Fig. A.2 and Sec. 3.1.3).
In addition, hooks always point away from joints and cannot be attached to joints (see Fig. A.3). The former is obvious because hooks are used to attach springs used to keep pieces together. If hooks are pointed the wrong way, they cannot function. The location of hooks is more subtle because problems can occur if a hook is placed on the outside of an outer joint or too close to ground glass. By placing a hook on or too close to the ground section, it is likely to warp the shape of the ground section, which will cause a poorly fitting, leaky joint.
"But You Never Told Me." Leave nothing understood or assumed unless you are willing to accept whatever is handed back to you. Therefore, leave your name and how (and where) the glassblower may get in touch with you if additional questions should develop. If you are working with (or for) someone else, leave a name and how to get in touch with that person, as well as your own information.
Provide the Right Measurements. Give measurements from specified areas that cannot vary. For example, see Fig. A.4(a), where the length of the cold trap's internal tube is ambiguous by the A measurement because C can vary extensively.
B
(a) |
(b) |
Fig. A.4 Where measurements are made is important.
492 |
Preparing Drawings for a Technician |
O.D.
Length
Item A Item B Required fit of
AandB
Fig. A.5 If your piece needs to fit within something, say so.
On the other hand, the measurement from the ground area of the joint to the end of the inside tube is specific. The B (or B') measurement is preferred.
Provide measurements when a change occurs, such as the seal of one size tubing to another [see Fig. A.4(b)]. The length of the internal tube of the cold trap is ambiguous with the A measurement because the location of B and C can vary extensively. Two preferred measurements would be either B and C, or " and D.
Do Not Make Your Primary Drawing in 3-D. Most of these types of drawings are incomprehensible or confusing, and it is difficult to place measurements on them. An extra sketch in 3-D can sometimes be helpful.
Accuracy. Most glasswork is done within an accuracy of ±1.5 mm (l/16th of an inch). If you require greater accuracy, say so. Similarly, if the glassware fits into some other device, or some other device fits into the glassware, say so. For an example, see Fig. A.5. If item A is ordered, and it is required to fit into item B, it is important to provide the following specifications of item A to the glassblower:
1)The maximum O.D. of the (lower) tube
2)The minimum length of the (lower) tube
3)The maximum O.D. of the ball
Whenever possible, provide item B to the glassblower so that he or she can test to see of the item fits before it is delivered.
Listen to Any Suggestions from the Glassblower. He or she knows what glass can do (and how to do it) and cannot do (and how to avoid it). In addition, he or she makes and often repairs items (perhaps similar to what you want) every day.