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Temperature 2.5

161

to use) thermometers. In addition, they are used to determine the temperatures of melting, boiling, and transformation points of various materials. Because of their limited use in the average laboratory, further discussion of pressure expansion thermometers is beyond the scope of this book.

2.5.11 Thermocouples

Thermocouples are robust and inexpensive. Reading the temperature from a thermocouple is invariably as easy as reading a controller's dial, liquid crystal, or LED. The following commentary is intended to provide a basic understanding of the operation of thermocouples and their limitations. If you have any questions about the final selection of a thermocouple, controller, lead, and extension for any specific type of job or desired use, contact a thermocouple manufacturing company because it will likely provide you with the best information on how to make your system work.

Table 2.33 Thermocouple Types and Characteristics

ANSI Symbol

Composition (pos. - neg. lead)

J

Iron - Constan-

 

tan (Cu-Ni)

Temperature

Range (°C)

Comments

(Thermocouple)

(Extension)

0 to 750

Recommended for reducing atmosphere. Displays

0 to 200

poor conformance characteristics due to poor iron

 

purity. Above 538°C, oxidation of Fe in air is rapid

 

so heavy-gauge wire is recommended for extended

 

use. Should not be used bare in sulfurous atmo-

 

spheres above 538°C.

T Copper - Con-

-200 to 350

Recommended for mildly oxidizing and reducing

stantan (Cu-

-60 to 100

atmospheres as well as moist environments. Per-

Ni)

 

forms very well at low temperatures and limits of

 

 

error are guaranteed in the subzero range, although

 

 

type E may be preferred due to higher emf. The cop-

 

 

per lead makes secondary compensation unneces-

 

 

sary.

K Chromel -

-200 to 1250

Alumel

0 to 200

Recommended for clean oxidizing atmospheres. They can be used in reducing atmospheres, but they should not be cycled from reducing to oxidizing and back repeatedly. The higher temperature ranges can only be achieved with heavy-gauge wires. They should not be used in vacuums and should not be bare in sulfurous atmospheres.

*LED stands for light emitting diode. These devices are the lighted numerals typically seen on digital clocks.

162

Measurement

Table 2.33 Thermocouple Types and Characteristics (continued)

ANSI Symbol

Composition (pos. - neg. lead)

E

Chromel - Con-

 

stantan (Cu-

 

Ni)

Temperature

Range (°C)

Comments

(Thermocouple)

(Extension)

-200 to 900

Recommended for vacuum use or for inert, mildly

0 to 200

oxidizing or reducing atmospheres. These thermo-

 

couples produce the greatest amount of emf and

 

therefore can detect small temperature changes.

S Platinum - Plati-

0 to 1450

num 10%,

0 to 150

Rhodium

 

Recommended for use in oxidizing or inert atmospheres to 1400°C, although it may be brought to 1480°C for a short time. Most stable, especially at high temperatures. Type S is used for standard calibration between the antimony point (630.74°C) and gold point (1064.43°C). Should only be used inside nonmetallic sheaths such as alumina due to metallic diffusion (from metal sheaths) contaminating the Pt.

R

Platinum - Plati-

0 to 1450

 

num 13%,

0 to 150

 

Rhodium

 

B

Platinum - Plati-

50 to 1700

 

num 30%,

0 to 100

 

Rhodium

 

Na

Omega-P™

-270 to 1300

 

"Nicrosil" (Ni-

0 to 200

 

Cr-Si) -

 

 

Omega-N™

 

 

"Nisil" (Ni-Si-

 

 

Mg)

 

Ga

Tungsten -

0 to 2320

 

Tungsten

0 to 260

 

26%, Rhodium

 

Ca

Tungsten 3%

0 to 2320

 

Rhodium -

0 to 870

 

Tungsten

 

 

26%, Rhodium

 

Da

Tungsten 3%

0 to 2320

 

Rhodium -

0 to 260

 

Tungsten

 

 

25%, Rhodium

 

Recommended for use in oxidizing or inert atmospheres to 1400°C. although it may be brought to 1480°C for a short time. Should only be used inside nonmetallic sheaths such as alumina.

These thermocouples are excellent for vacuum use. The output between 0 and 50°C is virtually flat and therefore is useless at these temperatures. The reference junction can be between 0° to 40°C. Should only be used inside nonmetallic sheaths such as alumina.

Similar to type K, but with improved oxidation resistance at higher temperatures.

Useful in reducing or vacuum environments at high temperature, but not for oxidizing atmospheres.

Useful in reducing or vacuum environments at high temperature, but not for oxidizing atmospheres.

Useful in reducing or vacuum environments at high temperature, but not for oxidizing atmospheres.

" Not ANSI designations.

Temperature 2.5

163

Junction 3

Junction 1

CM

.

C

Voltmeter I V

Junction 2

Fig. 2.31 A simple diagram of a copper-constantan thermocouple.This illustration is from The Temperature Handbook©1989 by Omega Engineering, Inc. All rights reserved. Reproduced with the permission of Omega Engineering, Inc., Stamford, CT 06907

In 1821 Thomas Seebeck discovered that when two different types of metal wires were joined at both ends and one of the ends was heated or cooled, a current was created within the closed loop (this current is now called the Seebeck effect). Specifically, heat energy was transformed into measurable electrical energy.

Unfortunately, there is not enough current produced to do any work, but there is enough to measure (1 to 7 millivolts). This rise in potential energy is called the emf or electromotive force.

By hooking the other end of joined dissimilar wires up to a voltmeter and measuring the emf (output), it is possible to determine temperature. Such a tempera- ture-measuring device is called a thermocouple.

There are seven common thermocouple types as identified by the American National Standards Institute (ANSI). They are identified by letter designation and are described in Table 2.33. There are four other thermocouple types that have letter designations; however, these four are not official ANSI code designations because one or both of their paired leads are proprietary alloys. They are included at the end of Table 2.33. Although Table 2.33 lists the standard commercially available thermocouples, there are technically countless other potential thermocouples because all that is required for a thermocouple is two dissimilar wires.

At a basic level, it seems that one should be able to take any thermocouple, attach it to a voltmeter, and determine the amount of electricity generated from the heat applied to the dissimilar junction. Then the user could look in some predetermined thermocouple calibration table* to determine the amount of heat that the amount of electricity from that specific type of joined wires produces.

One of the negative complications of thermocouples is that they do not have a linear response to heat. In addition, as temperature changes, thermocouples do not

'Thermocouple calibration tables have been compiled by the NIST and can be found in a variety of sources such as the Handbook of Chemistry and Physics by the Chemical Rubber Company, published yearly.

164 Measurement

produce a consistent emf change. Therefore, there must be individual thermocouple calibration tables for each type of thermocouple.

If you look at a thermocouple calibration table, you will see that it has a reference junction at 0°C. This reference point is used because of an interesting complication that arises when a thermocouple is hooked up to a voltmeter. To explain this phenomenon, first look at one specific type of thermocouple, a type T (cop- per-constantan design). Also, assume that the wires in the voltmeter are all copper. Once the thermocouple is hooked to the voltmeter, we end up having a total of three junctions (see Fig. 2.31):

Junction 1. The original thermocouple junction of copper and constantan.

Junction 2. The connection of the constantan thermocouple wire to the copper wire of the volt meter.

Junction 3. The connection of the copper thermocouple wire to the copper wire of the volt meter.

We are hoping to find the temperature of Junction 1, but it seems we now have two more junctions with which to be concerned. Fortunately, Junction 3 can be ignored because this connection is of similar, not dissimilar, metals. Therefore, no emf will be produced at this junction. Junction 2 presents a problem because it will produce an emf, but of an unknown temperature; this means that we have two unknowns in the same circuit, and we are unable to differentiate between the two. Any voltmeter reading taken at this point will be proportional to the temperature difference between the first and third junction.

If we take Junction 2 and place it in a known temperature, we can eliminate one of the two unknowns. This procedure is done by placing Junction 2 (now known as the reference junction) in an ice bath of 0°C (known as the reference temperature). Because the temperature (voltmeter) reading is based on an ice-bath reference temperature, the recording temperature is referenced to 0°C (see Fig. 2.32).

Junction 1

Junction 2 (Reference temperature)

Junction 4

\^.^mj - ^ ^

IC6 bath

Fig. 2.32 A thermocouple using an ice bath for a reference temperature.This illustration is from The Temperature Handbook©1989 by Omega Engineering, Inc. All rights reserved. Reproduced with the permission of Omega Engineering, Inc., Stamford, CT 06907

Temperature 2.5

165

References for voltmeter/thermocouple readings (found in such books as the CRC Handbook) will usually indicate that they are referenced to 0°C. Because Junctions 3 and 4 are of similar metals, they have no effect on the emf.

This example is limited because it is representative only of thermocouples with copper leads. In all other thermocouples, there are likely to be four dissimilar metal junctions and therefore up to four Seebeck effects. However, by extending the copper wires from the voltmeter and attaching them to an isothermal block, placing the same type of wire from one of the thermocouple leads to the part between the icebath and the isothermal block, and then attaching the thermocouple wires to the isothermal block (to eliminate thermal differences at these two junctions), it is possible to cancel out all but the desired Seebeck effect (see Fig. 2.33).

It is obvious that the use of an ice bath is inconvenient and impractical. Maintaining a constant 0.0°C temperature can be difficult, and there always is the possibility of the icebath tipping over. Fortunately there are two convenient techniques to circumvent the need for an actual ice bath for thermocouple measurements.

One approach requires measuring the equivalent voltage of the ice-bath reference junction and having a computer compensate for the equivalent effect. This technique, called software compensation, is the most robust and easiest to use. However, depending on the equipment used, the lag time involved for the compensation may be unacceptable.

Alternatively, it is possible to have hardware compensation by inserting an electric current (typically from a battery) to provide a voltage which electronically offsets the reference junction. This approach is called an electronic ice-point reference. This method has the simplicity of an ice bath, but is far more convenient to

 

Isothermal

Junction 3

Block

 

Junction 1

 

Fe

 

Junction 2

 

(Reference

 

temperature)

 

Ice

 

bath

Fig. 2.33 An iron-constantan thermocouple using an isothermal block and an ice bath. This illustration is from The Temperature Handbook©! 989 by Omega Engineering, Inc. All rights reserved. Reproduced with the permission of Omega Engineering, Inc., Stamford, CT 06907

166

 

Measurement

Table 2.34 American Wire Gauge

 

Size Comparison Chart

AWGa

Diameter

Diameter

(mils)

(mm)

 

8

128

3.3

10

102

2.6

12

81

2.1

14

64

1.6

16

51

1.3

18

40

1.0

20

32

0.8

22

25

0.6

24

20

0.5

26

16

0.4

28

13

0.3

1 American Wire Gauge.

 

use. The major disadvantage is that a different

electric circuit is required for each

type of thermocouple.

 

 

Ironically, the sophistication of modern controllers typically makes most of the concerns about how temperature is determined irrelevant. The greatest concern for the user is to select the right type and size of thermocouple for the specific job and environment, then to select the proper controller for that type of thermocouple.

Although there are many overlapping temperature ranges among various thermocouple types, all types of thermocouples perform better for some jobs than others. For example, Type K is significantly less expensive than Type R, although both thermocouples can read into the 1000°C range. This similarity would lead one to believe that either choice is adequate, however Type K is preferred because of its lower cost. If all you need are occasional readings of such temperatures, you could get by with Type K. However, if you expect to do repeated and constant cycling up to temperatures in the 1000°C range, Type K would soon fail and would need to be replaced. Unfortunately, you are not likely to notice failure developing until something has obviously gone wrong. Because the potential costs of failure are likely to be greater than the additional cost of the more expensive thermocouple, it may be more economical to obtain the more expensive type R at the outset.

Sample size should also be considered when selecting thermocouple size. If a large thermocouple (with a high heat capacitance) is used on a small sample (with a low heat capacitance), the sample's temperature could be changed. As stated before, the act of taking an object's temperature can change its temperature.

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