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118

Thermodynamics

 

 

5.7 Radiation processes

Radiometrya

Radiant energyb

Qe = Le cosθ dA dΩ dt J

(5.145)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

∂Qe

 

 

W

 

(5.146)

Radiant flux

Φe =

 

 

 

 

 

 

 

 

 

∂t

 

(“radiant power”)

= Le cosθ dA dΩ

(5.147)

Radiant energy

We =

 

∂Qe

 

 

Jm−3

 

(5.148)

densityc

 

∂V

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Me =

 

Φe

 

 

Wm−2

 

(5.149)

d

 

∂A

 

Radiant exitance

= Le cosθdΩ

 

(5.150)

 

Ee =

Φe

 

 

 

Wm−2

 

(5.151)

e

 

 

 

 

 

 

∂A

 

 

 

 

 

 

 

Irradiance

= Le cosθdΩ

 

(5.152)

 

Ie =

Φe

 

 

 

Wsr−1

 

(5.153)

 

 

Radiant intensity

=

 

Le cosθ dA

 

(5.154)

 

Le =

 

1

 

 

 

 

 

2Φe

Wm−2 sr−1

(5.155)

Radiance

cosθ

 

dAdΩ

 

 

 

 

1

 

 

 

 

 

∂Ie

 

 

 

=

 

 

 

 

 

 

 

(5.156)

 

cosθ

 

∂A

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Qe radiant energy

Le radiance (generally a function of position and direction)

θangle between dir. of dΩ and normal to dA

solid angle

Aarea

ttime

Φe radiant flux

We radiant energy density

dV di erential volume of propagation medium

Me radiant exitance

z

(normal)

θ

dΩ

 

 

dA x

φ y

Ee

irradiance

Ie

radiant intensity

aRadiometry is concerned with the treatment of light as energy.

bSometimes called “total energy.” Note that we assume opaque radiant surfaces, so that 0 ≤ θ π/2. cThe instantaneous amount of radiant energy contained in a unit volume of propagation medium. dPower per unit area leaving a surface. For a perfectly di using surface, Me = πLe.

ePower per unit area incident on a surface.

5.7 Radiation processes

119

 

 

Photometrya

Luminous energy

Qv = Lv cosθ dA dΩ dt lms

(5.157)

(“total light”)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Φv =

∂Qv

 

 

 

 

lumen (lm)

(5.158)

 

 

∂t

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Luminous flux

= Lv cosθ dA dΩ

(5.159)

Luminous

Wv =

∂Qv

 

 

 

 

lmsm−3

(5.160)

densityb

∂V

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Mv =

Φv

 

 

 

 

lx

 

(lmm−2)

(5.161)

Luminous

∂A

exitancec

= Lv cosθdΩ

 

(5.162)

 

Ev =

Φv

 

 

 

 

lmm−2

 

(5.163)

Illuminance

 

 

 

 

 

 

 

 

 

 

∂A

 

 

 

 

 

 

 

 

 

 

 

 

(“illumination”)d

= Lv cosθdΩ

 

(5.164)

 

Φv

 

 

 

cd

 

 

 

 

(5.165)

Luminous

Iv =

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

intensitye

=

Lv cosθ dA

 

(5.166)

Luminance

Lv =

 

 

1

 

 

 

 

 

 

2Φv

 

 

 

cdm−2

(5.167)

cosθ

 

 

dAdΩ

 

 

(“photometric

 

 

 

 

 

1

 

 

 

 

 

 

∂Iv

 

 

 

 

 

brightness”)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

(5.168)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

= cosθ ∂A

 

 

 

 

 

 

 

 

 

Luminous e cacy

K =

Φv

=

Lv

=

Iv

 

lmW−1

(5.169)

 

 

 

 

 

 

 

 

Φe

 

 

Le

Ie

 

 

Luminous

V (λ) =

 

K(λ)

 

 

 

 

(5.170)

e ciency

 

 

 

 

 

 

Kmax

 

 

 

 

Qv luminous energy

Lv luminance (generally a function of position and direction)

θangle between dir. of dΩ and normal to dA

solid angle

Aarea

ttime

Φv luminous flux

Wv luminous density

Vvolume

Mv luminous exitance

z

 

 

5

(normal)

θ

dΩ

 

 

 

dA x

φ y

Ev illuminance

Iv luminous intensity

Kluminous e cacy

Le

radiance

Φe

radiant flux

Ie

radiant intensity

Vluminous e ciency

λwavelength

Kmax spectral maximum of

K(λ)

aPhotometry is concerned with the treatment of light as seen by the human eye.

bThe instantaneous amount of luminous energy contained in a unit volume of propagating medium. cLuminous emitted flux per unit area.

dLuminous incident flux per unit area. The derived SI unit is the lux (lx). 1lx = 1lmm−2. eThe SI unit of luminous intensity is the candela (cd). 1cd = 1lmsr−1.

120

Thermodynamics

 

 

Radiative transfera

Flux density

Fν = Iν (θ,φ)cosθ dΩ Wm−2 Hz−1

 

(through a

 

plane)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

(5.171)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Mean intensityb

Jν =

1

 

 

Iν (θ,φ) dΩ

Wm−2 Hz−1

(5.172)

 

 

 

 

 

 

 

 

 

 

4π

Spectral energy

 

 

 

 

1

Iν (θ,φ) dΩ

Jm−3 Hz−1

 

densityc

uν =

 

 

 

(5.173)

 

c

Specific

 

 

 

 

ν

 

 

Wkg−1 Hz−1 sr−1

 

emission

jν =

 

(5.174)

 

 

 

ρ

 

coe cient

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Gas linear

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

absorption

αν = ν

 

=

 

1

 

m−1

 

(5.175)

coe cient

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

lν

 

 

(αν 1)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Opacityd

κν =

 

 

 

αν

 

 

kg−1 m2

 

(5.176)

 

 

 

ρ

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Optical depth

τν = κν ρ ds

 

(5.177)

 

 

1 dIν

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

= −κν Iν + jν

 

(5.178)

Transfer

ρ

ds

 

equatione

or

 

 

 

dIν

= −αν Iν + ν

 

(5.179)

 

 

 

 

ds

 

 

Kirchho ’s lawf

Sν

 

 

 

jν

 

 

ν

 

 

 

 

 

 

=

 

 

 

(5.180)

 

 

κν

αν

 

Emission from

Iν = Sν (1 − eτν )

 

 

a homogeneous

 

(5.181)

medium

 

z

 

dΩ

 

 

 

(normal)

θ

 

 

 

 

x

 

y

 

 

 

φ

 

Fν

flux density

 

Iν

specific intensity

 

(Wm−2 Hz−1 sr−1)

Jν

mean intensity

 

uν

spectral energy density

solid angle

θangle between normal and direction of Ω

jν

specific emission

 

coe cient

ν

emission coe cient

 

(Wm−3 Hz−1 sr−1)

ρdensity

αν linear absorption coe cient

nparticle number density

σν

particle cross section

lν

mean free path

κν

opacity

τν

optical depth, or

 

optical thickness

ds

line element

Sν

source function

aThe definitions of these quantities vary in the literature. Those presented here are common in meteorology and astrophysics. Note particularly that the ambiguous term specific is taken to mean “per unit frequency interval” in the case of specific intensity and “per unit mass per unit frequency interval” in the case of specific emission coe cient. bIn radio astronomy, flux density is usually taken as S = 4πJν .

cAssuming a refractive index of 1. dOr “mass absorption coe cient.” eOr “Schwarzschild’s equation.”

fUnder conditions of local thermal equilibrium (LTE), the source function, Sν , equals the Planck function, Bν (T ) [see Equation (5.182)].

5.7 Radiation processes

121

 

 

Blackbody radiation

1050

1010

)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

1010 K

)

 

1040

 

 

 

 

 

 

 

 

 

 

 

 

−1

 

 

 

 

 

 

 

 

 

 

 

 

 

 

−1

 

 

 

 

 

 

 

 

 

 

 

 

 

 

sr

 

νm(T ) = c/λm(T )

 

 

 

 

 

 

 

 

 

 

109 K

 

sr

 

 

 

10

10

K

 

λm(T )

 

 

 

 

 

 

−1

 

105

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

−1

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

108 K

 

 

 

 

10

30

 

109 K

 

 

 

 

 

 

 

 

 

 

Hz

 

1

 

 

 

 

 

 

 

 

 

 

 

 

 

m

 

 

 

108 K

 

 

 

 

 

 

 

 

 

 

−2

 

 

 

 

 

 

 

 

 

107 K

 

 

 

−2

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

mW/

10−5

 

 

 

 

 

106 K

 

 

 

 

 

/mW

 

1020

 

107 K

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

106 K

 

 

 

 

 

 

 

 

 

ν

 

 

 

 

 

105 K

 

 

 

 

 

 

 

 

λ

1010

 

 

105 K

 

 

 

 

 

 

 

 

 

(B

10−10

 

104 K

 

 

 

 

 

 

 

 

 

 

(B

 

10−10

 

 

104 K

2.7K

 

 

 

 

 

brightness

10−20

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

brightness

 

 

 

 

 

 

 

 

 

 

 

10−15

10

3

K

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

1

 

 

 

103 K

 

 

 

 

 

 

 

 

 

 

 

100K

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

100K

 

 

 

 

 

 

 

 

 

 

2.7K

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

10−20

 

10−12 10−10

10−8

10−6 10−4 10−2

 

 

 

 

 

 

106 108 1010

1012 1014

1016 1018

 

1020

1022

 

 

 

 

10−14

 

1

102

 

 

frequency (ν/Hz)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

wavelength (λ/m)

 

 

 

 

 

 

 

 

 

 

Bν (T ) =

23

 

 

exp

1

 

−1

 

 

 

(5.182)

Bν

surface brightness per

 

 

 

 

 

 

2

 

 

 

 

 

 

 

 

 

 

 

 

unit frequency

 

 

 

 

Planck

 

 

 

 

c

 

 

kT

 

 

 

 

 

 

 

(Wm

2 Hz

1 sr

1)

5

 

 

 

 

 

 

 

 

 

 

dν

 

 

 

 

 

 

 

 

 

 

 

Bλ

 

 

 

 

 

functiona

Bλ(T ) = Bν (T )

 

dλ

 

 

 

 

 

 

 

 

 

 

(5.183)

surface brightness per

 

 

 

 

 

 

 

 

 

 

 

 

 

unit wavelength

 

 

 

 

 

 

 

 

 

 

hc2

 

exp

hc

 

 

 

 

1

 

 

 

(Wm−2 m−1 sr−1)

 

 

 

 

 

 

= 2λ5

 

 

λkT − 1

 

 

 

(5.184)

h

Planck constant

 

 

 

Spectral energy

uν (T ) =

4π Bν (T )

Jm−3 Hz−1

 

 

 

 

 

(5.185)

c

speed of light

 

 

 

 

 

 

 

 

c

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

k

Boltzmann constant

 

density

uλ(T ) =

4π Bλ(T )

Jm−3 m−1

 

 

 

 

 

 

(5.186)

T

temperature

 

 

 

 

 

 

 

 

 

 

 

c

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

uν,λ

spectral energy density

Rayleigh–Jeans

Bν (T ) =

2kT

ν

2

=

2kT

 

 

 

 

 

 

 

 

(5.187)

 

 

 

 

 

 

 

 

 

 

law (hν kT )

 

c2

3

 

 

λ2

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Wien’s law

 

 

 

2

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Bν (T ) =

 

 

exp

 

 

 

 

 

 

(5.188)

 

 

 

 

 

 

 

 

 

 

(hν kT )

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

c2

 

 

 

 

 

kT

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Wien’s

 

 

 

 

5.1 10−3 mK

for Bν

 

 

 

 

λm

wavelength of

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

displacement

λmT = "2.9 × 10−3 mK

for Bλ

 

 

 

(5.189)

 

maximum brightness

 

law

 

 

 

 

×

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Stefan–

M = π

 

Bν (T ) dν

 

 

 

 

 

 

 

 

 

(5.190)

M

exitance

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Boltzmann

 

0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

σ

Stefan–Boltzmann

 

law

b

2π5k4

 

 

4

 

 

 

4

 

Wm

2

 

 

 

 

 

 

constant (

 

 

 

 

 

 

 

 

= 15c2h3 T

= σT

 

 

 

 

 

(5.191)

 

5.67 × 10

8

Wm

K

)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

2

4

 

Energy density

u(T ) =

4 σT 4

 

 

 

 

Jm−3

 

 

 

 

 

 

 

 

(5.192)

u

energy density

 

 

 

 

 

 

 

 

 

c

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Greybody

M = σT

4

= (1 − A)σT

4

 

 

 

 

 

 

 

(5.193)

 

mean emissivity

 

 

 

 

 

 

 

 

 

 

 

 

A

albedo

 

 

 

 

 

 

 

aWith respect to the projected area of the surface. Surface brightness is also known simply as “brightness.” “Specific intensity” is used for reception.

bSometimes “Stefan’s law.” Exitance is the total radiated energy from unit area of the body per unit time.