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- •Contents
- •Foreword to the English translation
- •Preface
- •1 Introduction
- •1.1 Historical review
- •1.2 The birth of the concept of crystal growth
- •1.3 Morphology, perfection, and homogeneity
- •1.4 Complicated and complex systems
- •References
- •Suggested reading
- •2 Crystal forms
- •2.1 Morphology of crystals – the problems
- •References
- •Suggested reading
- •3 Crystal growth
- •3.1 Equilibrium thermodynamics versus kinetic thermodynamics
- •3.2 Driving force
- •3.3 Heat and mass transfer
- •3.4 Examples of mass transfer
- •3.6 Nucleation
- •3.7 Lattice defects
- •3.8 Interfaces
- •3.9 Spiral growth
- •3.10 Growth mechanism and morphology of crystals
- •3.11 Morphological instability
- •3.12 Driving force and morphology of crystals
- •3.13 Morphodroms
- •3.14 Element partitioning
- •3.15 Inclusions
- •References
- •Suggested reading
- •4 Factors determining the morphology of polyhedral crystals
- •4.1 Forms of polyhedral crystals
- •4.2 Structural form
- •4.3 Equilibrium form
- •4.4 Growth forms
- •4.4.1 Logical route for analysis
- •4.4.2 Anisotropy involved in the ambient phase
- •4.4.3 Whiskers
- •MAJOR FACTORS
- •METHODOLOGY
- •IMPURITIES
- •AMBIENT PHASES AND SOLVENT COMPONENTS
- •4.4.7 Factors controlling growth forms
- •References
- •Suggested reading
- •5 Surface microtopography of crystal faces
- •5.1 The three types of crystal faces
- •5.2 Methods of observation
- •5.3 Spiral steps
- •5.4 Circular and polygonal spirals
- •5.5 Interlaced patterns
- •5.6 Step separation
- •5.7 Formation of hollow cores
- •5.8 Composite spirals
- •5.9 Bunching
- •5.10 Etching
- •References
- •Suggested reading
- •6 Perfection and homogeneity of single crystals
- •6.1 Imperfections and inhomogeneities seen in single crystals
- •6.2 Formation of growth banding and growth sectors
- •6.3 Origin and spatial distribution of dislocations
- •References
- •7 Regular intergrowth of crystals
- •7.1 Regular intergrowth relations
- •7.2 Twinning
- •7.2.1 Types of twinning
- •7.2.2 Energetic considerations
- •7.2.4 Penetration twins and contact twins
- •7.2.5 Transformation twin
- •7.2.6 Secondary twins
- •7.3 Parallel growth and other intergrowth
- •7.4 Epitaxy
- •7.5 Exsolution, precipitation, and spinodal decomposition
- •References
- •Suggested reading
- •8 Forms and textures of polycrystalline aggregates
- •8.1 Geometrical selection
- •8.2 Formation of banding
- •8.3 Spherulites
- •8.4 Framboidal polycrystalline aggregation
- •References
- •Suggested reading
- •9 Diamond
- •9.1 Structure, properties, and use
- •9.2 Growth versus dissolution
- •9.3 Single crystals and polycrystals
- •9.4 Morphology of single crystals
- •9.4.1 Structural form
- •9.4.2 Characteristics of {111}, {110}, and {100} faces
- •9.4.3 Textures seen inside a single crystal
- •9.4.4 Different solvents (synthetic diamond)
- •9.4.5 Twins
- •9.4.6 Coated diamond and cuboid form
- •9.4.7 Origin of seed crystals
- •9.4.8 Type II crystals showing irregular forms
- •References
- •Suggested reading
- •10 Rock-crystal (quartz)
- •10.1 Silica minerals
- •10.2 Structural form
- •10.3 Growth forms
- •10.4 Striated faces
- •10.5 Growth forms of single crystals
- •10.5.1 Seed crystals and forms
- •10.5.2 Effect of impurities
- •10.5.3 Tapered crystals
- •10.6 Twins
- •10.6.1 Types of twins
- •10.6.2 Japanese twins
- •10.6.3 Brazil twins
- •10.7 Scepter quartz
- •10.8 Thin platy crystals and curved crystals
- •10.9 Agate
- •References
- •11 Pyrite and calcite
- •11.1 Pyrite
- •11.1.2 Characteristics of surface microtopographs
- •11.1.4 Polycrystalline aggregates
- •11.2 Calcite
- •11.2.1 Habitus
- •11.2.2 Surface microtopography
- •References
- •12 Minerals formed by vapor growth
- •12.1 Crystal growth in pegmatite
- •12.3 Hematite and phlogopite in druses of volcanic rocks
- •References
- •13 Crystals formed by metasomatism and metamorphism
- •13.1 Kaolin group minerals formed by hydrothermal replacement (metasomatism)
- •13.2 Trapiche emerald and trapiche ruby
- •13.3 Muscovite formed by regional metamorphism
- •References
- •14 Crystals formed through biological activity
- •14.1 Crystal growth in living bodies
- •14.2 Inorganic crystals formed as indispensable components in biological activity
- •14.2.1 Hydroxyapatite
- •14.2.2 Polymorphic minerals of CaCO3
- •14.2.3 Magnetite
- •14.3 Crystals formed through excretion processes
- •14.4 Crystals acting as possible reservoirs for necessary components
- •14.5 Crystals whose functions are still unknown
- •References
- •Appendixes
- •A.1 Setting of crystallographic axes
- •A.2 The fourteen Bravais lattices and seven crystal systems
- •A.3 Indexing of crystal faces and zones
- •A.4 Symmetry elements and their symbols
- •Materials index
- •Subject index
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References 223
10 m
Figure 10.21. Scanning electron micrograph of Uruguay band.
The order of formation of the banding pattern is (1)→(4), and there can be cases that all four stages are present, or one part may be absent, or, in some cases, the cycle repeats.
From these observations of the texture, it is considered that agate precipitates from an aqueous solution containing SiO2, which intruded into a geode, and that in the aqueous solution clusters having right-handed and left-handed structures were already formed. When these clusters aggregate through electromigration due to the wall surface, the banding patterns discussed in (1) and (2) and large quartz crystals, (3), are formed. However, Uruguay banding is principally formed by gravitational settlement once the wall surface effect has diminished.
References
1R. Bechman and D. R. Hale, Electronic grade synthetic quartz, Brush Strokes, September, 1955, 1–7
2F. Iwasaki and H. Iwasaki, Industrialization of synthetic quartz in the States and Japan,
J. Japan. Assoc. Crystal Growth, 25, 1988, 247–50 (in Japanese with English abstract)
3F. Iwasaki, H. Iwasaki, and Y. Okabe, Growth rate anisotropy of synthetic quartz grown in Na2CO3 solution, J. Crystal Growth, 178, 1999, 648–52
4M. Hosaka, T. Miyata, and I. Sunagawa, Growth and morphology of quartz crystals synthesized above the transition temperature, J. Crystal Growth, 152, 1995, 300–6
5M. Hosaka and S. Taki, Hydrothermal growth of quartz crystals in NaCl solution,
J. Crystal Growth, 51, 1981, 589–600
224 Rock-crystal (quartz)
6 W. Zhong, Synthetic Quartz, 2nd edn, Beijing, Scientific Pub., 1994 (in Chinese)
7H. Iwasaki and F. Iwasaki, Morphological variations of quartz crystals as deduced from computer experiments, J. Crystal Growth, 151, 1995, 348–58
8 J. W. Mullin, A. Amatavivadhana, and M. Chakraborty, J. Appl. Chem., 20, 1970, 153
9 A. A. Chernov, L. N. Roshkovich, and M. M. Mkrtchan, J. Crystal Growth, 74, 1986, 101
10J. Owezarek and K. Sangwal, J. Crystal Growth, 102, 1990, 547
11Lu Taijing, R. B. Yallee, C. K. Ong, and I. Sunagawa, Formation mechanism of tapering of crystals: A comparative study between potassium dihydrogen phosphate crystals and natural quartz crystals, J. Crystal Growth, 151, 1995, 342–7
12C. Frondel, The System of Mineralogy, 7th edn, vol. 3, New York, John Wiley, 1962
13T. Yasuda and I. Sunagawa, X-ray topographic study of quartz crystals twinned according to Japan twin law, Phys. Chem. Min., 8, 1982, 121–7
14I. Sunagawa and T. Yasuda, Apparent re-entrant corner effect upon the morphologies of twinned crystals; A case study of quartz twinned according to Japanese twin law,
J. Crystal Growth, 65, 1983, 43–9
15I. Sunagawa, J. Takahashi, K. Aonuma, and M. Takahashi, Growth of quartz crystals twinned after Japan law, Phys. Chem. Min., 5, 1979, 53–63
16Lu Taijing and I. Sunagawa, Texture formation of agate in geode, Min. J., 17, 1994, 53–76
17Lu Taijing and I. Sunagawa, Structure of Brazil twin boundaries in amethyst showing Brewster fringes, Phys. Chem. Min., 17, 1990, 207–11
18T. Nishinaga, T. Nakano, and S. Zhang, Epitaxial lateral overgrowth of GaAs by LPE,
Jpn. J. Appl. Phys., 27, 1988, L964–7
19T. Nishinaga, Microchannel epitaxy: An overview, J. Crystal Growth, 237–9, 2002, 1410–17
20Y. Takahashi, H. Imai, M. Hosaka, and I. Sunagawa, Genesis of scepter quartz, Collected Abstracts, 2000 Annual Meeting of Miner. Soc. Japan, 2000, p. 97 (in Japanese)
21I. K. Bonev, Nature and origin of the twisted quartz crystals (“Gwindels”) and of quartz with white stripes (“Fadenquartz”), Collected Abstracts, IMA–17, Toronto, A84, 1998