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Statistical physics (2005)

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270

Solution of the Exercises and Problems

 

4

 

 

 

 

 

 

 

 

 

 

 

 

3

 

 

 

 

 

 

 

 

 

 

 

D(E)

2

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

1

 

 

 

 

 

 

 

 

 

 

 

 

0

0

1

2

3

4

5

6

7

8

9

10

 

1

 

 

 

 

 

 

 

E

 

 

 

 

 

Fig. 2: Densities of states D+/D0 (lower curve) and D/D0 (upper curve), plotted versus / 0.

II.3.

(a) For the branch = E(k),

E(k) = 2(k k0)2 0

2m

the variation of which is given in Fig.1. The spectrum of the permitted energies is [0, ∞].

– For 0 < ≤ 0, there are two possible wavevector moduli k for a given energy :

2m

k1,2 = k0 ± 2 ( + 0)

– For > 0, there is a single allowed wavevector modulus :

2m

k = k0 + 2 ( + 0)

(b) One then deduces, for > 0

Å … 0 ã

D( ) = D0( ) 1 +

+ 0

and for < 0 (adding both contributions corresponding for either sign in the k1,2 formula) :

0

D( ) = 2D0( )

+ 0

Problem 2002 : Physical Foundations of Spintronics

271

The corresponding curve is plotted in Fig. 2.

II.4.

(a)Assume that the electrons are accommodated one next to the other in the available energy levels. Since the temperature is taken to be zero, the first electron must be located on the fundamental level, the second one on the first excited level, and so forth. Thus the first levels to be

filled are those of the Ebranch, with k around k0, the Fermi energy F being a little larger than 0 for N small. When N increases, the energyF also increases. It reaches 0 when all the states of the Ebranch, of wave vectors ranging between 0 and 2k0, are filled. For larger numbers of electrons, both branches E± are filled.

(b)The E+ branch remains empty until F reaches the value F = 0. There are then

 

0

 

 

 

 

π 2

0

 

N = 0 D( )d =

 

 

 

 

 

 

2LxLym

 

electrons on the Ebranch.

 

 

 

 

 

E(k) < F , i.e.,

(c) In

the Ebranch, the filled

states

verify

k1

< k < k2 with :

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

k1,2 = k0 ±

 

2 ( F + 0)

 

 

 

 

 

 

2m

 

 

 

 

(see the dashed lines in Fig.1). The extremities of the corresponding k vectors are thus located inside a ring, limited by two Fermi “surfaces” consisting of the circles of respective radii k1 and k2.

II.5.

(a)When N is larger than N , one has to add the extra N − N electrons in both branches, up to the Fermi level. The situation is then given by

the dotted line in Fig.1. For either E± branch, the extremities of the

wave vectors k corresponding to the filled states are located inside the disk defined by E±(k) < F .

(b)For the E+ (resp. E) branch, the radius of the disk corresponding to the occupied states is determined by E+(kF+) = F (resp. E(kF) = F ), with :

kF± = k0

+

 

2 ( F + 0)

 

 

 

 

2m

 

In either branch, the Fermi “surface” is a circle for this two-dimensional problem.

(c) One finds :

N − N = 0

F

(D+( ) + D( )) d = π 2

F

 

 

 

LxLym

 

272

Solution of the Exercises and Problems

One then deduces the relation between the electrons number and the Fermi energy :

N =

LxLym

(2 0 + F )

π 2

 

 

II.6.

(a)The energies E±(B) in either branch only vary to second order in B, i.e., one has E±(B) = E±0 + O(B2). This implies that the Fermi energy too only varies to second order in B.

(b)The total magnetization at zero temperature is the sum of the average

ˆ

values of Sz in each filled quantum state, i.e.,

M =

 

 

(B) ˆ

(B)

 

(B)

ˆ

(B)

 

 

Ψk,+|Sz |Ψk,+ +

Ψk,−|Sz |Ψk,−

 

k<kF+

 

 

 

 

 

 

k<kF

 

 

 

 

 

 

 

 

=

 

k+

 

4αk

2π

kdk + 0

k

 

 

2π

kdk

0

 

 

 

4αk

 

 

F

γB LxLy

 

 

F γB LxLy

 

One thus finds :

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

M =

γB LxLy

(kF− kF+) =

LxLy

γBm

 

4α

 

 

2π

4π

 

II.7. One returns to the expression of question I.4, replacing a±(0) by a±(tn) and a±(t) by a±(tn+1). One averages over the angle φn, using the fact that this angle is not correlated to a±(tn) : a+(tn) a(tn) e−iφn = 0. One thus finds that the term in sin(2ωτ ) does not contribute and then gets the relation given in the text : s¯(tn+1) = cos(2ωτ ) s¯(tn).

II.8.

(a)If ωτ 1, then cos(2ωτ ) 1 2ω2τ 2. The change of s¯(t) in a time interval τ between two collisions is then weak.

(b) In the

time

interval

t τ ,

the

number

of

collisions

n = t/τ

1 takes place (the fact that t is not an exact multiple of

τ plays a negligible role). Consequently,

 

 

 

 

 

s¯(t) = s¯(0) (cos(2ωτ ))n = s¯(0) exp (n ln(cos(2ωτ )))

 

Using ln(cos(2ωτ ))

ln(1 2ω2τ 2)

 

2ω2τ 2,

one

obtains

s¯(t) = s¯(0) e−t/td

with td = 1/(2ω2τ ).

 

 

 

 

(c)The shorter τ , the longer td. Paradoxically, a poor conductor, in which the time interval between collisions is very short, leads to a longer spin relaxation time than a good conductor. This surprising result can be put together with the quantum Zenon e ect, in which one finds that a frequent observation of a system prevents its evolution.

Problem 2002 : Physical Foundations of Spintronics

273

(d)One finds ω = 7.6 × 109 sec1 and td = 8.7 × 109 sec. As announced in the introduction of the text, the spin relaxation time td can be much longer than the interval τ between collisions, corresponding to the relaxation time of the electron velocity.

II.9. Let us write the rate equation for the spins + and populations :

df+

= g+

f+

f+

+

f

 

df

= g

f

f

+

f+

dt

tr

td

td

 

dt

tr

td

td

In steady-state regime, one has df+/dt = df/dt = 0, which leads to

1

1

 

ã

1

 

 

 

 

1

1

 

ã

1

 

 

 

 

+

 

 

g+ +

 

 

g

 

 

 

 

 

 

 

 

+

 

 

g+

 

 

g+

f+ =

Å tr

t

t

 

 

 

=

 

Å

t

 

t

t

 

 

1d

2

 

 

d

 

f

 

 

r

 

1d

2

 

 

d

 

 

 

 

 

 

 

 

 

 

 

 

+

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

+

 

 

 

 

 

 

 

 

tr 2

tr td

 

 

 

 

 

 

 

 

 

 

 

tr 2

tr td

 

 

and thus

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

P =

g+ − g

 

1

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

g+ + g1 + 2

tr

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

td

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

To maintain a high polarization, at fixed injection rate, one must minimize the denominator, and thus select a material in which td is as large as possible, consequently in which collisions occur very frequently. Examples of these developments, together with references, may be found in the paper in Physics Today volume 52 (1999) p.33.

Index

adiabatic process, 63

band

allowed, 182 conduction, 189, 190 forbidden, 182 theory (elements), 182 valence, 190

band gap, 190 black body

definition, 210 radiation, 215 spectrum, 210 Bloch function, 183

Boltzmann Factor, 41 Bose-Einstein condensation, 203,

205

Bose-Einstein distribution, 137, 147 Bose-Einstein distribution of photons, 206, 212

Bose-Einstein statistics, 201 bosons, 120, 124

boundary conditions Born-Von Kármán, 141 periodical, 141 stationary, 140

Brillouin zone, 182, 186

chemical equilibrium, 98 potential, 49, 68 reactions, 95

reactions and statistical physics, 103

chemical bond, 126

classical statistics (validity), 83

collision, 80, 115 collision time, 80 collisions, 248

common limit of the Quantum Statistics, 149, 150

Compact Disk reader, 197 conductor, 189

cross section, 80 crystal

eigenstates, 182 energy bands, 182 finite, 185 hamiltonian, 176

infinite (periodic chain), 180

density of states in a crystal energy, 188 wavevector, 186

density of states of free particles energy, 145, 146 momentum, 144

wave vector, 144

density operator in Quantum Mechanics, 10, 27

diamond, 189 dispersion law, 182, 247 donor, 195

dopant, 195

double potential well, 177

e ective mass electron, 182, 188 hole, 193

electrical conductivity, 194 electrostatic screening, 233 emission

275

276

induced, 214 spontaneous, 214 stimulated, 214

energy, 186 band, 182

fixed average value, 42 fluctuations around its most

likely value, 37 energy states of a molecule

electronic, 106 rotation, 105 translation, 104 vibration, 106

energy states of an N -particle system, 32

ensemble

average, 12, 19 canonical, xvi, 40 grand canonical, xvi, 51 microcanonical, xvi, 35

ensemble average, xvi enthalpy, 100 entropy

and information (Shannon), 18

canonical ensemble, 45 grand canonical ensemble, 53 HC molecule, 236 statistical (Boltzmann defini-

tion), 13

statistical (Gibbs definition, 15

equilibrium, xv, 11 equilibrium conditions, xv

equilibrium conditions between two systems

exchanging energy, 36 exchanging energy and par-

ticles, 48 equipartition theorem, 87 equiprobability, 12

equivalence between statistical ensembles, 45

exchange energy, 122

Index

interaction, 122

Fermi

energy, 156 sphere, 158 surface, 158

Fermi-Dirac statistics, 155

Fermi-Dirac distribution, 137, 147, 155

fermions, 120, 124 free, 155

paramagnetism, 159 properties at non-zero tempe-

rature, 160

properties at zero temperature, 155

specific heat, 163 ferromagnetism, 115, 122, 126 Fock basis, 125

fossil radiation, 212 free energy, 70, 89, 96 free enthalpy, 73, 98 free particles, 34

number of microstates, 29 quantum states in a box, 138

GaAs, 197, 238 germanium, 190 Gibbs Paradox, 90

global climate change, 220

grand partition function factorization for indistinguishable particles, 134

grand potential, 71, 137, 202 greenhouse e ect, 218

Hückel model, 181 hamiltonian

N -particle, 32 Hartree method, 176 Hartree-Fock method, 176 heat, 63

elementary statistical definition, 63

Index

heat reservoir, 40 helium 4, 126

Bose-Einstein condensation, 203 hole, 192

e ective mass, 193

ideal gas

canonical partition function, 85

canonical statistical treatment, 85

limit of the Quantum Statistics, 150

independent-electron approximation, 177

insulator, 190

Joule-Gay-Lussac expansion, 13, 64

Kirchho law, 218

Lagrange multipliers, 57 Lambert law, 217

laser e ect, 214 law of mass action

in statistical physics, 110 in thermodynamics, 98

Le Châtelier principle, 101

linear combination of atomic orbitals, 183

Liouville Theorem, 21 luminance, 216

macrostate, xvi, 11 magnetic susceptibility

fermions, 160

quasi-1D Conductor, 234 Matthiessen law, 191 Maxwell-Boltzmann statistics, 85 mean field treatment, 34

mean free path, 80 metal, 189

methods in statistical physics, 31, 223

microstate, xvi, 11

277

number for free particles, 29 molecular beam epitaxy, 197

Nernst law, 66

non-radiative recombination, 243

occupation numbers, 125

paramagnetism Curie, 160 Pauli, 160

quasi-1D conductor, 235 parameters, xv

extensive, xvi external, xv intensive, xvi internal, xv

particles distinguishable, 114 free, 34

indistinguishable, 114, 116 partition function

canonical, 44

grand canonical, 50, 52 rotation, 109 translation, 108 vibration, 109

Pauli paramagnetisme, 159 Pauli principle, 119

periodic classification of the elements, 126

phase space, 2 phase transition, 205 phonon, 208

photoconductivity, 196 photocopier, 196 photons

density of states, 208 spectral density in energy, 209 states, 206

statistics, 207 Planck law, 209

postulates of Statistical Physics, 13

postulates of the Statistical Physics, 13

278

pressure kinetic calculation, 81 probability density (classical), 8 process, xvi

quantum boxes, 237 quantum statistics, 131

classical limit, 149, 150

radiation pressure, 210 radiative

balance, 217, 219 lifetime, 242 recombination, 242 yield, 244

resistance, 184

variation with temperature (metal), 191

variation with temperature (semiconductor), 194

semiconductor, 194 n-type, 195 p-type, 195

p − n junction, 196 quantum well, 197 doped, 195 intrinsic, 193 pure, 193 statistics, 192

silicon, 190

singlet state of two spins, 122 Slater determinant, 124 solar cell, 196, 218 Sommerfeld development, 171 specific heat

Einstein model, 47 Debye model, 48 electrons, 163 ideal gas, 88 lattice, 47

spin relaxation time, 249 spin-statistics connection, 120 spintronics, 245

statistics Bose-Einstein, 201

Index

classical, 83 Fermi-Dirac, 155 Maxwell-Boltzmann, 85 quantum, 131

Stefan-Boltzmann law, 215 superconductivity, 126, 205 system, xi, xv

isolated, xv, 35

temperature, 40, 65 thermal

de Broglie wavelength, 84 equilibrium, xi, xv radiation, 210

thermionic emission, 165 thermodynamical potentials, 67 thermodynamics

first law, 60 second law, 64 third law, 66 zeroth law, 60

thermostat, 40

tight-binding approximation, 183 time average, 11 transformation

infinitesimal, xvi irreversible, xvi of Legendre, 72 quasi-static, xvi reversible, xvi

triplet state of two spins, 122

valence band, 190

white dwarfs, 162 Wien law, 211

with temperature, 191 work, 61

(elementary) statistical definition, 62