- •Preface
- •Acronyms
- •Introduction
- •Background and objectives
- •Content, format and presentation
- •Radioactive waste management in context
- •Waste sources and classification
- •Introduction
- •Radioactive waste
- •Waste classification
- •Origins of radioactive waste
- •Nuclear fuel cycle
- •Mining
- •Fuel production
- •Reactor operation
- •Reprocessing
- •Reactor decommissioning
- •Medicine, industry and research
- •Medicine
- •Industry
- •Research
- •Military wastes
- •Conditioning of radioactive wastes
- •Treatment
- •Compaction
- •Incineration
- •Conditioning
- •Cementation
- •Bituminisation
- •Resin
- •Vitrification
- •Spent fuel
- •Process qualification/product quality
- •Volumes of waste
- •Inventories
- •Inventory types
- •Types of data recorded
- •Radiological data
- •Chemical data
- •Physical data
- •Secondary data
- •Radionuclides occurring in the nuclear fuel cycle
- •Simplifying the number of waste types
- •Radionuclide inventory priorities
- •Material priorities
- •Inventory evolution
- •Assumptions
- •Errors
- •Uncertainties
- •Conclusions
- •Acknowledgements
- •References
- •Development of geological disposal concepts
- •Introduction
- •Historical evolution of geological disposal concepts
- •Geological disposal
- •Definitions and comparison with near-surface disposal
- •Development of geological disposal concepts
- •Roles of the geosphere in disposal options
- •Physical stability
- •Hydrogeology
- •Geochemistry
- •Overview
- •Alternatives to geological disposal
- •Introduction
- •Politically blocked options: sub-seabed and Antarctic icecap disposal
- •Sea dumping and sub-seabed disposal
- •Antarctic icesheet disposal
- •Technically impractical options; partitioning and transmutation, space disposal and icesheet disposal
- •Partitioning and Transmutation
- •Space disposal
- •Icesheets and permafrost
- •Non-options; long-term surface storage
- •Alternatives to conventional repositories
- •Introduction
- •Alternative geological disposal concepts
- •Utilising existing underground facilities
- •Extended storage options (CARE)
- •Injection into deep aquifers and caverns
- •Deep boreholes
- •Rock melting
- •The international option: technical aspects
- •Alternative concepts: fitting the management option to future boundary conditions
- •Conclusions
- •References
- •Site selection and characterisation
- •Introduction
- •Prescriptive/geologically led
- •Sophisticated/advocacy led
- •Pragmatic/technically led
- •Centralised/geologically led
- •Conclusions to be drawn
- •Lessons to be learned (see Table 4.2)
- •Site characterisation
- •Can we define the natural environment sufficiently thoroughly?
- •Sedimentary environments
- •Hydrogeology
- •The regional hydrogeological model
- •More local hydrogeological model(s)
- •Crystalline rock environments
- •Lithology and structure
- •Hydrogeology
- •Hydrogeochemistry
- •Any geological environment
- •References
- •Repository design
- •Introduction: general framework of the design process
- •Identification of design requirements/constraints
- •Concept development
- •Major components of the disposal system and safety functions
- •A structured approach for concept development
- •Detailed design/specifications of subsystems
- •Near-field processes and design issues
- •Design approach and methodologies
- •Design confirmation and demonstration
- •Interaction with PA/SA
- •Demonstration and QA
- •Repository management
- •Future perspectives
- •References
- •Assessment of the safety and performance of a radioactive waste repository
- •Introduction
- •The role of SA and the safety case in decision-making
- •SA tasks
- •System description
- •Identification of scenarios and cases for analysis
- •Consequence analysis
- •Timescales for evaluation
- •Constructing and presenting a safety case
- •References
- •Repository implementation
- •Legal and regulatory framework; organisational structures
- •Waste management strategies
- •The need for a clear policy and strategy
- •Timetables vary widely
- •Activities in development of a geological repository
- •Concept development
- •Siting
- •Repository design
- •Licensing
- •Construction
- •Operation
- •Monitoring
- •Research and development
- •The staging process
- •Attributes of adaptive staging
- •The decision-making process
- •Status of geological disposal programmes
- •Overview
- •Status of geological disposal projects in selected countries
- •International repositories
- •Costs and financing
- •Cost estimates
- •Financing
- •Conclusions
- •Acknowledgements
- •References
- •Research and development infrastructure
- •Introduction: Management of research and development
- •Drivers for research and development
- •Organisation of R&D
- •R&D in specialised (nuclear) facilities
- •Introduction
- •Inventory
- •Release of radionuclides from waste forms
- •Solubility and sorption
- •Waste form dissolution
- •Colloids
- •Organic degradation products
- •Gas generation
- •Conventional R&D
- •Engineered barriers
- •Corrosion
- •Buffer and backfill materials
- •Container fabrication
- •Natural barriers
- •Geochemistry and groundwater flow
- •Gas transport and two-phase flow
- •Biosphere
- •Radionuclide concentration and dispersion in the biosphere
- •Climate change
- •Landscape change
- •Underground rock laboratories
- •URLs in sediments
- •Nature’s laboratories: studies of the natural environment
- •General
- •Corrosion
- •Cement
- •Clay materials
- •Degradation of organic materials
- •Glass corrosion
- •Radionuclide migration
- •Model and database development
- •Conclusions
- •References
- •Building confidence in the safe disposal of radioactive waste
- •Growing nuclear concerns
- •Communication systems in waste management programmes
- •The Swiss programme
- •The Japanese programme
- •Examples of communication styles in other countries
- •Finland
- •Sweden
- •France
- •United Kingdom
- •Comparisons between communication styles in Finland, France, Sweden and the United Kingdom
- •Lessons for the future
- •What is the way forward?
- •Acknowledgements
- •References
- •A look to the future
- •Introduction
- •Current trends in repository programmes
- •Priorities for future efforts
- •Waste characterisation
- •Operational safety
- •Emplacement technologies
- •Knowledge management
- •Alternative designs and optimisation processes
- •Materials technology
- •Novel construction/immobilisation materials: the example of low pH cement
- •Future SA code development
- •Implications for environmental protection: disposal of other wastes
- •Conclusions
- •References
- •Index
Waste sources and classification |
23 |
|
Lead |
|
Neutron |
π |
γ |
Proton |
|
Fig. 2.12. Accelerator facilities at the Paul Scherrer Institute (PSI), Switzerland (image courtesy of PSI).
However, it should be noted that the concentration of radioactivity is more evenly distributed in the case of such an accelerator facility.
2.4.3. Military wastes
Military wastes arise from processes leading to the manufacture of nuclear weapons, depleted uranium weapons and armour, as well as other more mundane items such as thorium mantles used in gas lamps (the military have a tendency to stockpile, which leads to an accumulation of materials that cannot be disposed of in the same manner as household refuse).
Military wastes are physically no different to those arising from the nuclear fuel cycle, in that to produce nuclear weapons uranium must be mined to produce feed stock for enrichment to very high levels of uranium-235, or to produce fuel for reactors which provide the spent fuel from which plutonium is then extracted by reprocessing. This leads to reactor operational and decommissioning wastes, as well as reprocessing wastes of broadly similar types to those arising in the civilian programme. What is different is the spectrum of radioactivity associated with these wastes. For example, the operational wastes from the handling of plutonium consist of the same types of protective clothing used in the civilian programme for the manufacture of MOX, e.g., rubber gloves, overalls, overshoes, glove boxes etc., the difference being that the associated radioactivity consists of a different spectrum of plutonium isotopes and, of course, the volumes of these types of wastes are significantly higher in the case of military applications.
Information concerning the types of military wastes that arose within the British programme can be found in the UK inventory (Nirex, 2002).
2.5. Conditioning of radioactive wastes
Treatment and conditioning processes are used to convert radioactive waste materials into a form that is suitable for subsequent management, such as transportation, storage and final disposal.