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green synthesis
Ms. Murugiah Krishani is a research scholar in the Department
of Chemical and Process Engineering under the Faculty of
Integrated Technologies, Universiti Brunei Darussalam. She
obtained her B.Tech in Biotechnology (2015) and M.Tech in
Biotechnology (2017) from Anna University, India. Later in
2017, Krishani joined in PABCET as an Assistant Professor and
worked for three years. Her major area of research is Bone Tissue
Engineering and she published several articles in Bone Tissue
Engineering and Machine Learning Techniques in the field of
Biomedical applications.
252 M. Krishani et al.
Dr. Nonni Soraya Sambudi is a Faculty Member at the Depart-
ment of Chemical Engineering, Universitas Pertamina. She earned
her Ph.D. in Chemical and Biomolecular Engineering from Korea
Advanced Institute of Science and Technology (KAIST).
Dr. Sambudi has over 10 years of experience in the field of
material science, with a particular focus on nanotechnology. Her
works on the synthesis of carbon quantum dots for various
applications such as photocatalytic process, drug delivery, heavy
metals detection and removal have been published in several
prestigious journals. She has collaborated with many institutions
globally and has been a keynote speaker at numerous international
conferences. Dr. Sambudi’s current projects include developing
advanced nanomaterials and composite as electrodes for
photoelectrochemical process and drug delivery vehicles.
Dr. Hazwani Suhaimi obtained her BEng in Chemical Engi-
neering (2009), MSc in Advanced Chemical Engineering with IT
and Management (2010), and PhD in Chemical Engineering
(2015) from Loughborough University. In January 2016, Hazwani
joined Universiti Brunei Darussalam as a lecturer in Chemical and
Process Engineering, and was promoted to Assistant Professor in
December 2021. She has been the Programme Leader of the
Chemical and Process Engineering since August 2016. Her
major research is on the nutrient diffusion in tissue engineering
membranes and scaffolds. Over the years, she has expanded her
research activities and interests including in the area of
biomaterials, ankle injury, rehabilitation, waste management, and
membrane science.
Utilisation of Plant Extracts for Green Synthesis of Metallic Nanoparticles
S. Giridhar Reddy
Abstract
This chapter focuses on making metal nanoparticles in an environmentally friendly
way using plant materials. It talks about how different plants have special
chemicals that can help reduce and stabilize these nanoparticles when they’re
being made. The mechanisms, influencing factors, and characterisation techniques
are discussed in detail. Additionally, the chapter examines the environmental
impact and potential applications of these green-synthesized nanoparticles across
diverse fields. Overall, it provides a concise and insightful overview, emphasising
the importance of sustainable practices in contemporary nanotechnology.
Keywords
10
Plant extracts · Green synthesis · Metallic nanoparticles · Nanoparticle green
chemistry synthesis
10.1 Introduction
Plant-derived substances have garnered attention as environmentally friendly and
sustainable options for creating nanoparticles (NPs). Many plants contain active
compounds capable of both reducing and encasing NPs, aiding in their formation.
These extracts are abundant in phytochemicals like flavonoids, phenols, terpenoids,
and alkaloids,which are essentialfor reducing metal ions and stabilizing NPs. Utilizing
plant extracts for nanoparticle synthesis brings several benefits, including being
S. G. Reddy (✉)
Department of Physical Sciences, Amrita School of Engineering, Bengaluru, Amrita Vishwa
Vidyapeetham, Bengaluru, Karnataka, India
e-mail: s_giri@blr.amrita.edu
#
The Author(s), under exclusive license to Springer Nature Switzerland AG 2025
R. Malviya, S. Sundram (eds.), Sustainable Green Biomaterials As Drug Delivery
Systems, Biomaterials, Bioengineering and Sustainability 1,
https://doi.org/10.1007/978-3-031-79062-1_10
253
254 S. G. Reddy
eco-friendly, cost-effective, easily scalable, and compatible with biological systems.
Furthermore, the vast diversity of plant species offers a wide range of phytochemical
compositions, enabling the creation of NPs tailored to specificproperties for
applications in medicine, catalysis, sensing, and environmental clean-up.
In recent years, the interest has been garnered by the eco-friendly nature of plant
products for the synthesis of metallic NPs, owing to their sustainable approach. This
method leverages phytochemicals natural reducing and stabilising properties in
different plant extracts to create metallic NPs tailored for various applications
(Shankar et al. 2003a).
Plants are rich reservoirs of bioactive compounds like flavonoids, phenols,
terpenoids, and alkaloids, which act as effective agents in reducing and capping
metallic NPs (Iravani 2011). The green synthesis process involves the gentle reduction of metal ions by these phytochemicals in plant extracts, avoiding harsh
chemicals and high temperatures comm on in traditional synthesis methods (Mittal
and Chisti
2013).
The appeal of plant extract-based nanoparticle synthesis lies in its sustainability,
affordability, scalability, and compatibility with living organisms. By embracing the
principles of green chemistry, researchers can reduce the environmental impact of
NP production while exploring novel applications in nanotechnology (Khan et al.
2018). This chapter will explore the mechanisms behind green synthesis utilizing
plant extracts, emphasizing the contribution of phytochemicals in the formation and
stability of NPs (Siddiqi and Husen 2018; Sathishkumar et al. 2009). Additionally,
we will explore the wide range of metallic NPs produced through this method and
their applications in medicine, catalysis, sensing, and environmental clean-up
(Prasad and Elumalai 2011) (Fig. 10.1).
Through our exploration of plant extract-mediated synthesis, we acknowledge the
significant potential of this approach in advancing sustainable nanotechnology and
addressing global challenges in science, technology, and environmental conservation.
Plants excel at synthesizing NPs compared to other biological methods because
they offer abundant resources, are non-toxic, and naturally provide capping agents.
Also, using plant extracts is cheaper than isolating and culturing microorganisms,
making NPs synthesis more cost-effective (Sharma et al. 2009; Singhal et al. 2011).
The ease of access, safety, and diverse range of secondary metabolites make plants a
favourable choice for NPs synthesis. Many plants are currently under investigation
for their NPs synthesis potential (Prasad 2014).
10.1.1 Silver Oxide Nanoparticles
Different plants, like leaves, fruit, stems, and root extracts are used for green
synthesis, chosen based on availability, phytochemical content, and ease of extraction. After cleaning, the plant material is processed to make an extract using methods
such as grinding, blending, or maceration in solvents like water, ethanol, or methanol. In a distinct phase, a solution containing silver salt, typically silver nitrate
(AgNO₃), is combined with the plant extract, which influences the size and shape