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Файл:Биотехнология = Biotechnology. Учебное пособие по английскому языку
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Video 5
I mentioned in the last video that 99 % of the aromatic compounds that
you'll see in an organic chemistry class is either going to be benzene or molecule derived from benzene or a molecule derived from benzene. So what I want
to do in this video is just familiarize you with some of these molecules and how
to name them so you know what you're looking at or I guess so you could name
what you're looking at. So you've seen this multiple times benzene just looks
like this. It's a six-carbon ring with three double bonds. These three double
bonds like that and that's it's not the only configuration. Sometimes it's shown
to be in resonance with this form right here. So the double bonds all flip around
the circle like that or sometimes it's simply drawn like this. And I just talked
about this in the last video just to show that really neither of these configurations is exactly right, that these PI electrons are just circular eight. They're just
moving around the entire ring and sometimes you'll just have the hexagon with
a circle on the inside to show that the PI electrons just floating around the entire
ring. Now if I were to add something to the benzene ring it's pretty straightforward to name it. So say I have this molecule right here, this molecule right here,
let's say I have that benzene but let's say this carbon over here, it has one, two,
three bonds. If I didn't draw anything else, you just assume that there's also
a hydrogen here. But maybe there's no hydrogen there. Let me do this in a different color. Maybe you have a chlorine there. Well this is just chlorobenzene.
If that was a bromine it would be bromobenzene. Let me change it a little bit.
Let's see how to chloro there and let's say you had a oh I don't know let's say
you had a bromo over here. Let's say you have a bromo over there. Draw
the bromo bromo so you could just start numbering, you could actually start
numbering in either place.
Let's start with the bromine. It's just alphabetically in front so this would
be one bromo-two chloro-benzene. Now it gets a little bit more involved
the IUPAC which we know is kind of the group that named most things. They
tend to everything else we've seen. So far they came up with a separate naming
mechanism from the common names but benzene it's so ingrained in the organic
chemistry computing community that all of the benzene or benzene derivative
molecules they just kind of said: “Well you know what we'll just going to use
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the names that everyone uses”. So here's a couple of common benzene derivatives so if you have this molecule right here, if you have this molecule right
here, I would actually draw the PI electrons as a circle. Actually, I'll draw it
with the double bonds. So let's say you have this molecule right here and over
here you have noh8 right there this is called a phenol. This is called a phenol, so
it's not called benzene anymore and if you had a molecule that look like this,
just like a phenol, so it's essentially it is a phenol. But let's say you have a bromine right there, what you do is you start numbering at the group, that's making
this a phenol. So you start numbering there. One and then you get to the two. So
this is two bromophenol and unfortunately this is one of those things you just
kind of have to memorize. That a phenol is really just a benzene ring with an
OH group. Another one that is probably a good idea to memorize. I mean at
least for me and organic chemistry the most confusing thing is when someone
says the name of a molecule that it sounds like they expect you to understand
but you don't understand it. So it's I guess a good idea to understand as many
names as possible. So if you just have a benzene ring and then you just have
a methyl group attached to that benzene ring this is called toluene. And once
again if you had a fluorine right over there this would be one, two, three, four
O2 toluene. Now a couple of other ones that you will see and once again as you
know if you watched many Khan Academy videos, I hate memorizing things,
but these are just names and these aren't systematically derived. The chemistry
community just uses them because that's the way they name them. So it is one
of those things you kind of have to memorize. So if you have a benzene ring
where the functional group, that's kind of defining the benzene ring, it's essentially becoming a mean. We haven't actually covered videos on means yet, and
I'll do that in a future video but it's essentially, it's replaced one of the hydrogen's in ammonia. Ammonia has three hydrogens and one lone pair here
we've replaced one of the hydrogens. Actually, there's two hydrogens here
we've replaced one of the hydrogens with a benzene ring. This type of thing you
call it aniline. If I put a fluoro here, this would be two fluoro and allene. So you
use whatever the base molecule is and then you just name it really the way
we've named a lot of things before and I'll just introduce you to two more.
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So we have a benzene ring and then you have a carboxyl group and we'll
talk more about carboxyl groups in the future but it creates carboxylic acid this
thing right here, this hydrogen it can actually be released quite easily and we'll
talk about that in the future this right here is called benzoic acid. Benzoic acid
and this name, there is a little bit more logic to this. You have the bends part for
the benzene. So let me make this in different colors. The benzene part that gives
us the bends right there and then in general whenever you have a carboxyl
group like this, it becomes a carboxylic acid and you tend to add the acid to
the end. So this actually has some logical naming to it. Now the last one I'll introduce you to is very similar to this. Here we just have a hydrogen and it
would be an aldehyde. So let me draw that and you could almost imagine what
that's going to be called. It's benzaldehyde. You have your benzene ring and
then instead of this carboxyl group you have an aldehyde group. There's implicitly a carbon here.
Let me make that just in case it's the first time you're seeing it. You have
a carbon instead of an OH group. You have just a hydrogen. And so once again
you have a benzene. It actually makes sense to put the bends over there and
then you have the aldehyde group and then you have an aldehyde group right
over here. This is called a benzaldehyde or this molecule is called benzaldehyde
bends. Aldehyde and we'll study a means and aldehydes and carboxylic acids in
much more detail in future videos and actually see reactions that involve them.
But I just wanted to expose you to this and when you see these kinds of names
you don't you know become intimidated.
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Учебное издание
Винникова Татьяна Александровна,
Трифонова Елена Николаевна
Булгакова Ирина Юрьевна
БИОТЕХНОЛОГИЯ
BIOTECHNOLOGY
Учебное пособие
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Редактор Е. В. Осикина
Компьютерная верстка О. Г. Белименко
Для дизайна обложки использованы материалы
из открытых интернет-источников
Сводный темплан 2019 г.
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Издательство ОмГТУ. 644050, г. Омск, пр. Мира, 11; т. 23-02-12.
Типография ОмГТУ.
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