Учебное пособие 800637
.pdf
|
|
, |
|
|
|
700 |
|
|
|
|
, |
|
|
|
|
|
|
Ni-AlZrO |
NiO-AlZrO. |
|
|
||
|
: |
|
|
, |
|
|
, |
|
|
|
, |
|
. |
|
|
|
|
|
|
|
|
|
|
|
|
|
Ni-AlZrO |
|
|
- |
|
|
|
||
|
: |
|
. |
|
|
|
AlZrO |
|
|
- |
|
|
|
|
|
|
|
|
|
|
|
||
|
Ni. |
|
|
|
|
|
|
|
|
|
|
|
Ni (4-6 |
). |
|
|
|
|
( |
) |
|
|
Ni- |
AlZrO |
|
|
|
( |
|
|
|
5-70 |
.% Ni) |
||
|
1000-1200 . |
|
, |
|
|
|
, |
|
|
|
|
|
AlZrO. |
|
|
|
|
|
700 |
|
|
- |
|
(ZrO2), |
, |
, |
|
|
|
|
|
, |
|
|
|
|
|
|
|
|
|
|
|
||||
( |
.1) |
|
|
|
|
|
|
|
. |
|
|
|
|
2000 |
|
|
|
|
|
|
|
|
|
|
а |
1500 |
|
|
|
|
|
|
|
|
|
|
.К |
|
|
|
|
|
|
|
|
|
|
|
, |
1000 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
k |
|
|
|
|
|
|
|
|
|
|
|
H |
|
|
|
|
|
|
|
|
|
|
|
|
500 |
|
|
|
|
|
|
|
|
|
|
|
0 |
|
|
|
|
|
|
|
|
|
|
|
0 |
20 |
|
40 |
60 |
80 |
|
|
|
|
|
|
|
К |
ц |
ация Ni, а .% |
|
|
|
|
|
|
|
. |
|
|
Ni-AlZrO |
|
|
|
(○) |
|
|
|
|
|
700 ( ) – |
, ( ) – |
|
|
|
|
|
|||
|
|
700 ° |
|
|
|
|
(ZrO2). |
|
, |
||
|
|
, |
|
|
|
|
|
- |
|||
|
|
|
|
|
|
|
|
, |
|
||
|
, |
|
|
|
|
|
|
|
. |
|
|
|
, |
|
|
|
|
|
|
|
|
|
- |
|
|
|
|
|
|
. |
|
|
, |
|
- |
|
Ni |
|
(10-30 |
, |
|
|
|
|
Ni). |
||
|
|
|
|
|
|
NiO |
|
|
|
|
10-30 |
|
, |
. |
|
|
|
|
|
|
|
( |
- |
|
|
|
) |
|
|
|
|
|
|
|
- |
|
- |
|
. |
|
Hk |
|
|
|
NiO |
|
- |
|
– |
|
|
|
|
|
|
|
|
- |
|
|
. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
160 |
|
|
|
|
|
|
53.092 |
|
|
|
|
|
Cd3As2+44.7 |
.% MnAs |
|
|
|
|
|
|
|
|
||
. . |
|
|
1, |
. . |
|
2, . . |
3 |
|
1 |
. |
.- . |
, |
|
, luizasa11@mail.ru |
|
|
|
|
|
|
|
|||||
2 - |
|
.- . |
|
, |
, maggadji@rambler.ru |
|
||
|
|
3 |
|
, a.abdulabek@gmail.com |
|
|
||
|
|
|
|
|
|
|||
|
|
|
. |
. . |
|
, |
, |
|
Cd3As2+MnAs (MnAs – 44.7%). |
, |
30-33 |
, |
|||||
|
|
|
|
|
|
|
. |
|
|
|
|
|
|
|
|
|
|
: |
|
, |
|
, |
|
|
, |
. |
. 1 |
|
|
|
|
|
, |
|
- |
15 |
|
50 |
. |
|
|
15 24 |
- |
|
. |
|
|
|
33 |
, |
|
. |
|
, |
|
|
|
|
|
MnAs, |
|
|
Cd3As2 + MnAs (52.7 |
|
. % MnAs), |
|
|
|
|||
|
|
|
, |
- |
||||
|
|
|
|
|
|
|
||
|
|
|
|
|
|
|
|
. |
|
15 |
|
50 |
|
, |
, |
|
|
|
|
|
|
|
Cd3As2, |
|
|
|
|
|
|
|
|
|
Cd3As2 |
50 GPa [1]. |
- |
, |
|
|
|
30-33 |
|
|
|
- |
|
|
|
, |
|
|
|
||
|
|
|
. |
|
|
|
- |
|
|
|
|
|
|
|
|
||
|
|
|
|
|
|
: |
|
- |
.2 |
|
|
|
|
, |
R(t)=A1e-t/t1+A2e-t/t2. |
|
|
|
|
|
|
|
, |
|
||
, |
|
|
|
|
|
Cd3As2+MnAs (MnAs–44.7%). |
|
. 1.
161
. 2. |
1- |
(Cd3As2)0.653(MnAs)0.44: |
, – |
2- |
|
|
33 |
- |
. |
|
- |
|
|
. |
. 3. |
|
tmin=min{t1,t2}, |
R(t)=A1e- |
t/t1+A2e-t/t2 (1), |
t0, |
|
S(t)=Ae-t/t0(2) |
1. Lanpo He. Pressureinduced superconductivity in the three-dimensional topological Dirac semimetal Cd3As2/ YatingJia, Sijia Zhang, Xiaochen Hong, ChangqingJin and Shiyan Li// npj Quantum Materials.-2016.- 1.- p. 16014.
162
|
|
|
|
|
VI. |
|
|
|
|
|
|
537.9 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
CuO, |
|
|
|
|
|
- |
|
|
|
|
. . |
1, . . |
2, . . |
|
3 |
|
|
|||
|
|
|
1 |
|
, Dima.P.S@yandex.ru |
|
|
|
|||
|
|
|
|
|
|
|
|
||||
|
|
2 - |
.- . |
, |
, rembeza@yandex.ru |
|
|
||||
|
3 |
. |
, |
.- . |
, menshikova.vrn@mail.ru |
|
|
||||
|
|
|
|
||||||||
|
|
« |
|
|
|
|
|
|
|
» |
|
500˚ . |
|
|
|
|
|
CuO, |
|
|
|
400 |
|
|
|
, |
|
|
. |
|
- |
440 |
|||
|
|
|
|
|
|
|
|
|
|||
. |
. |
|
, |
|
|
|
|
, |
|
, |
|
|
: |
, |
|
|
, |
|
|
, |
|
, |
|
|
|
- |
|
|
|
||||||
|
|
, |
, |
|
|
. |
|
|
|
|
|
CuO – |
|
|
|
|
|
|
|
|
|
- |
|
p- |
, |
|
|
|
|
|
|
|
|
|
- |
|
1,4-2,9 |
[1]. |
|
|
|
|
|
[3]. |
CuO |
. |
|
|
|
|
|
|
|
|
|
|
|
||
|
|
|
|
[2], |
- |
|
[3], |
|
[4], |
- |
|
|
|
[5] |
. . |
|
|
|
|
|
|
|
- |
, |
|
, |
|
|
|
. |
|
[1] |
|
- |
|
|
CuO |
|
|
|
|
|
|
|
- |
||
|
|
|
- |
|
|
|
|
|
|||
, |
|
|
. |
|
|
|
|
|
|
|
- |
|
|
400 |
500 . |
|
|
|
|
|
|
|
- |
|
|
, |
|
|
|
400 . |
, |
500 |
. |
|
|
|
|
|
|
|
|
|
|
|
. |
|
|
CuO |
400 500˚ |
|
. |
|
|
|
CuO. |
- |
|
|
|
|
||
, |
250 |
|
|
, |
|
|
|
|
|
CuO (1,1,0) 31,7˚. |
- |
|
400 |
500 |
|
|
- |
: |
(1,1,0) 31,7˚, (-1,1,1) |
35,5˚, |
(1,1,1) |
38,8˚, |
CuO. |
|
440 |
. |
|
350 |
|
20 |
∙ |
|
. |
|
45% |
|
|
4∙105 1/ |
300 |
1100 |
|
2,65 . |
, |
163
CuO. |
|
- |
CuO |
, |
- |
. |
|
|
1. Y. Yang, D. Xu, Cu2O/CuO Bilayered Composite as a High-Efficiency Photocathode for Photoelectrochemical Hydrogen Evolution ReactionS-cientific Reports, Oct 17 [Online] Available:
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5066255/#b62
2. F. Z. CHAFIand B. Fares, “2015 3rd International Renewable and Sus-tainable Energy
Conference (IRSEC)” Fe-doped CuO deposited by spray pyrolysis technique, DOI
10.1109/IRSEC.2015.7455109, pp. 1–5, Dec. 2015.
3. Ş. Baturay, “n-Type conductivity of CuO thin films by metal doping”, Applied Surface
Science, DOI 10.1016/j.apsusc.2017.12.004, V 477, pp. 91-95, May. 2019.
4. L. JianBo, “Single phase CuO thin films prepared by thermal oxidation in air with water vapor” Advanced Materials Research, DOI: 10.4028/www.scientific.net/AMR.1109.544 V 1109 pp.
544-548 Jun. 2015
5. V. Ramya; “CuO Thin Film Prepared by Chemical Bath Deposition Technique: A Review”
International Journal of NanoScience and Nano-technology V 8, n 1, pp. 11-15 Jun 2017
538.975
ZnO
|
. . |
1, . . |
2 |
|
|
|
1 |
, belykh.maks@yandex.ru |
|
||
|
|
|
|
|
|
2 - |
.- . |
, |
|
, rembeza@yandex.ru |
|
« |
|
|
|
|
» |
, |
|
|
|
. |
- |
- |
|
|
|
||
: |
|
, |
- |
, |
, |
. |
|
|
|
|
|
|
ZnO |
|
|
|
. |
, |
|
|
|
|
- |
, |
|
|
|
|
ZnO [1]. ZnO |
|
n- |
, |
|
|
- |
Al3+ |
. 1 , 1 . |
|
. |
|
Zn2+ |
|
|
|
|
) |
|
|
) |
|
. 1. |
|
Al3 + |
: – |
Zn2 + |
ё |
Al3 +; – |
Al |
|
|
|
|
|
, |
- |
|
|
|
|
, |
. 1 |
. |
, |
, |
- |
Al ZnO [2]. |
|
|
|
|
|
|
|
|
164
|
, |
|
- |
- |
|
, |
550 º 30 |
. |
|
|
550 º |
|
|
|
60 |
. |
|
|
- |
|
. |
|
. 1. |
|
|
8U |
5A |
4T |
, |
% |
0,5 % |
0,75 % |
1 % |
|
|
|
|
|
|
|
4,88 |
3,353 |
0,686 |
30 |
|
|
|
|
|
|
9,06 |
4,86 |
2,688 |
60 |
|
|
|
|
|
|
|
|
( |
. 2). |
. 2. |
|
|
|
. 1 |
. 2 |
, |
- |
|
, |
|
- |
. |
|
|
. |
1.Lee J. -H. Electrical and op-tical properties of ZnO transparent conducting films by the solgel method./ J. –H. Lee, K. –H. Ko, and B.-O. Park // Journal of Crystal Growth. – 2003. – V. 247. –
№1 – 2. – P.119 – 125.
2.Serier H. Al-doped ZnO powdered materials: Al solubility limit and IR absorption properties / H. Serier, M. Gaudon, and M. Mntrier // Solid State Sciences. – 2009. – V. 11. -№ 7. – P. 1192 – 1197, 2009.
538.975 |
|
|
|
|
|
|
|
|
|
|
, |
|
– |
|
|
|
. . |
|
1, . . |
2 |
|
|
1 |
, polkovnikov.vova.net@yandex.ru |
|||
|
|
|
||||
2 |
- |
|
.- . |
, |
, rembeza@yandex.ru |
|
|
« |
|
|
|
|
» |
(II) |
– |
|
. |
|
|
(II) |
|
|
|
|
|
|
. |
165
|
|
|
|
|
: |
– |
|
, |
|
|
|
|
|
, |
(II), |
|
|
|
|
|
. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
(II) p- |
[1] |
|
|
- |
|
|
|
|
, |
|
|
|
|
|
|
|
: |
, |
|
, |
- |
|
|
, |
|
|
|
|
|
|
|
. |
|
- |
|
||
|
|
- |
|
|
|
|
|
|
- |
|
|
1,3 – 1,7 |
[2]. |
||
uO |
|
|
|
|
|
|
|
|
|
|
|
|
|
||
|
|
|
|
|
CuO p- |
|
|
|
|
|
|
|
|
||
CuCl2 |
2H2O |
|
|
200 |
, |
|
|
|
|
|
|
|
|
- |
|
|
. |
|
|
|
|
|
10 |
. |
0,1 |
/ |
- |
||||
|
|
|
|
|
|
|
|
|
|
|
300 |
|
. |
|
|
|
|
|
|
|
|
|
: |
|
|
|
|
1,5 |
, |
- |
|
|
|
|
|
( |
|
) 80 |
, |
|
|
|
6 |
|
7 |
/ . |
- |
|
|
|
4 |
|
. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
, |
||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
.1,2. |
|
|
|
|
|
1,8 |
|
|
- |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
CuO_520_3h |
|
|
21 1 |
|
|
|
|
|
||
|
|
|
|
1000 |
|
|
01 |
1 |
|
|
|
|
|
||
|
|
|
|
|
|
1 |
|
|
|
|
|
||||
|
|
|
|
|
|
|
|
|
|
|
|
|
|||
|
|
|
|
|
|
|
|
0 |
|
|
|
|
|
||
|
|
|
|
|
|
|
|
O; |
|
|
|
|
|
||
|
|
|
|
|
|
|
|
0 |
|
|
|
|
|
||
|
|
|
|
|
|
|
|
Cu O; 1 10 |
CuCuO;O;10- |
2 |
Cu O; -1 1 2 Cu O; -202 Cu O; 1 1 2 Cu O; 0 2 0 |
|
|
|
|
|
|
|
|
|
|
|
|
Cu |
|
|
|
||||
|
|
|
|
500 |
|
|
|
Cu O; |
2 1 O; 2 0 2 |
|
|||||
|
|
|
|
|
|
|
0 |
|
|||||||
|
|
|
|
|
|
|
|
Cu |
|
||||||
|
|
|
|
|
|
|
|
CuO; |
|
||||||
|
|
|
|
0 |
20 |
|
30 |
|
|
40 |
|
50 |
|
60 |
|
|
|
|
|
|
|
|
|
|
|
|
|||||
|
|
|
.1 |
|
|
|
|
|
|
|
(II) |
|
|
520 |
|
.2 |
uO |
|
|
300 |
|
|
|
, |
|
(II) |
|
|
520 |
300 . |
, |
|
, |
|
|
|
|
|
|
|
|
|
|
520 . |
|
|
|
2 |
|
- |
|
|
|
|
|
|
|
|
33 |
. |
.3 |
|
- |
|
|
|
|
|
520 . |
|
166
.3
1.Yang Y. Cu2O/CuO Bilayered Composite as a High-Efficiency Photocathode for Photoelectrochemical Hydrogen Evolution Reaction / Y. Yang, D. Xu // S-cientific Reports. – 2016. - V. 6: 35158.
2.Chafi F. Z. Characterization techniques of Fe-doped CuO thin films deposited by the Spray
Pyrolysis method/ F. Z. Chafi , L. Bahmad , N. Hassanain , B. Fares , L. Laanab, A. Mzerd //Faculty of ScienceBP. 1014Av. Ibn Batouta Rabat, Morocco – Jul 2018.
537.9
|
|
|
|
|
PbTe |
|
|
|
|
. . |
1, . . |
2 |
|
|
|
|
|
1 |
, threeroad@mail.ru |
|
|
|
|
|
|
|
|
|
|
|
|
2 |
- |
.- . |
, |
, kalinin48@mail.ru |
|
|
|
|
« |
|
|
|
|
» |
|
|
|
|
|
|
|
|
- |
. |
PbTe, |
|
|
|
|
|
- |
|
|
|
|
|
|
|
|
: |
|
|
|
|
, |
|
- |
. |
|
|
|
|
|
|
|
|
, |
|
, |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
. |
|
|
|
- |
|
|
|
|
|
|
|
- |
|
, |
|
|
|
500 |
900 . |
- |
, |
|
|
|
|
- |
|
: |
, |
|
|
, |
- |
, |
|
|
. |
|
, |
|
|
|
PbTe. |
|
|
|
|
0,023 |
.% PbI2. |
|
|
|
|
|
|
: |
|
|
||
|
|
|
|
|
|
|
|
, |
|
. |
PbI2, |
— |
. |
|
- |
3,5×10-3 |
|
|
|
|
|
||
|
|
( |
1 |
|
- |
), |
- |
|
|
|
1270 . |
|
|
|
|
|
|
|
900 |
|
|
|
- |
. |
|
|
1270 . |
|
|
|
- |
|
|
65 |
, |
|
|
3 |
- |
167
|
|
10 |
, |
. |
|
|
|
|
|
|
1 |
, |
0,064 |
. |
- |
|
3 / |
2; |
34×18 |
5 / |
|
. |
||
2 |
|
10 |
||
|
|
|
|
|
300 — 800 . |
- |
- |
||
|
|
|||
850 |
|
|
6 |
, |
1 |
|
ZT |
bTe, |
|
|
|
. |
ZT |
|
initial – |
,
004.942:681.586.2
-
|
. |
- |
|
|
|
|
. |
|
2 |
: |
- |
|
|
|
|
700 |
|
|
10×10×2 3. |
- |
Netzsch LFA 467, |
- |
|
|
Netzsch SBA 458 |
- |
|
|
- |
|
|
. |
|
. |
- |
|
|
|
|
|
PbTe, |
|
; heat treated – |
|
850 |
||
6 |
|
|
|
|
|
850 |
6 |
- |
|
|
|
, |
. |
|
( |
№ 19-48-360010). |
|||
|
. . |
1, . . |
|
2, |
. . |
3, . . |
4, . . |
5 |
|
1 - |
.- |
. |
, |
, vmfmm@mail.ru |
|
|
|
2 |
. |
.- |
. |
, . . ., vmfmm@mail.ru |
|
|
|
|
|
|
||||
|
3 |
. |
. |
, |
, vmfmm@mail.ru |
|
|
|
|
|
|
||||
|
4 |
. |
. |
, |
, vmfmm@mail.ru |
|
|
|
|
|
|
||||
|
|
|
5 |
, vmfmm@mail.ru |
|
|
|
|
« |
|
|
|
» |
||
|
|
|
|
|
|
||
|
|
ё |
|
|
c |
|
. |
|
|
|
|
|
|
.
168
|
|
: |
|
|
|
, |
|
, |
- |
|
|
, |
|
, |
. |
|
|
|
|
|
|
|
|
|
|
|
|
|
- |
( |
) |
|
|
, |
|
|
|
|
- |
ё |
|
, |
|
ё |
|
[1]. |
, |
, |
- |
[2] |
|
|
|
|
|
- |
|||
|
, |
|
|
|
. |
|
|
||
|
|
|
|
|
|
|
|
||
|
|
|
|
|
|
- |
|
|
- |
|
|
|
c |
ё |
|
. |
|
|
|
|
|
|
|
|
ё |
- |
|||
|
|
|
|
|
|
|
|
||
|
|
|
|
|
, |
|
|
Innalabs |
|
(Ireland) [3]. |
|
, |
|
|
|
|
|
|
|
, |
|
PZT |
. |
ё |
|
|
|
|
|
|
|
|
|
|
|
||||
|
|
|
|
|
. |
|
|
|
|
|
|
|
|
|
( |
|
|
|
) |
|
|
|
- |
|
|
|
[4]. |
ё |
- |
|
, |
|
|
|
|
. |
|
|
|
|
|
|
|
|
|
|
|
||
|
, |
|
|
|
|
|
|
|
- |
|
|
, |
|
|
, |
|
. |
|
- |
|
|
|
|
|
|
|
|
- |
|
|
|
|
|
|
|
|
|
|
|
|
. |
|
. |
|
|
|
|
|
|
|
|
|
|
ё |
|
|
|
|
|
|
|
|
|
|
|
|
|
- |
|
|
|
|
|
|
|
|
|
|
|
- |
|
|
|
[5]. |
|
|
|
|
|
1. |
|
|
|
|
|
|
|
|
- |
/ |
. . |
, |
. . |
, . . |
. // |
|
|
|
- |
|
|
|
. – 2015. – № 3 (87). – |
. 84-96. |
|
|
|
- |
|
2. |
|
|
|
|
|
|
|
|
|
|
|
/ . . |
, . . |
, . |
. |
. // |
|
. . . |
|
. |
. « |
|
». – 2015. – № 2. – |
. 28-39. |
|
|
|
|
3.A Set of High Accuracy Low Cost Metallic Resonator CVG / V. V. Chikovani, I. M. Okon, A. S. Barabashov, P. Tewksbury // Proceedings of IEEE/ION PLANS 2008, Monterey, CA, May
2008, pp. 238-243. |
, . . |
|
|
|
|
|
/ . . |
- |
4. |
|
- |
|
|
|
|||
, . . |
. – |
- - |
: |
, 2015. – 178 . |
|
|
|
|
5. |
|
|
|
|
- |
|
|
|
|
|
/ . . |
|
, . . |
, . . |
|
. // |
- |
2018. . 162-166. |
|
|
: |
XIX |
. |
. |
: |
, |
|
|
|
|
|
|
|
|
169