
Новые достижения в химии и химической технологии растительного сырья. Материалы II всероссийской конференции [2005]
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248

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C |
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K2CO3 |
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CH2O |
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O (I I a)- (I I c) |
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N O (I I I a)- (I I I c)
CH2O OH
C CH3
NO
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(a) X=Cl; (() X=NO2; (1) X=COOH
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2.J:$4$1.8 -.J., ;(:0=.8 ;.*., K(0&9($8 K.K., C9/58()(9.8 C.C, M&$107- E.8 G.M. // K0=07 #'0'./16) ".$/01$102. 1990. C. 513.
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B&=('&1, /3.& ,!!#+.()&'+#+7 0(-&6&2(, 8'( 0/, 6&1+;+2,, )(.(- /(.& 0/, &'(1+ &6('& 0,0+/,.,2()(4( -(#$9& &2&=&6,2& 2& -,#$2?+ /&.,-? 0/(,!5(.,' !2,C+2,+ '(-!,82(!', , 0(3)#+2,+ 2()(7 =,(#(- 4,8+!-(7 &-',)2(!',.
D <'(7 '(8-, 6/+2,3 0/+.!'&)#3+'!3 ,2'+/+!2?1 !,2'+6 N--,#– 6&1+;+22?5 0/(,6)(.2?5 &2&=&6,2& , #"0,2,2&:
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N |
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N |
N |
CH2CH2CH2 NCS |
N |
H + CH2 |
CH CH2 NCS |
CH2OCH2CH2CH2NCS |
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CH2OH |
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N |
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D,2'+6 )?*+"-&6&22?5 !(+.,2+2,7 (!";+!')#3#, /&62?1, -(#,- 8+!')&1, #,#/(.&2,.& ) 0/,!"'!'),, -&',6&'(/& (20%, NaOH, KOH) , /&!')(/,'+#+7 0/, 2&4/+)&2,, , =+6 2&4/+)&2,,. E(/(*,+ )?- 5(.? =?#, 0(#"8+2? 0/, -,038+2,, &2&=&6,2& , #"0,2,2& ! ,6=?'-(1 #,#/(.&2,.& ) FGH ) 0/,!"'!'),, 40%-2(4( KOH.
I?5(. 9+#+)?5 0/(."-'() – 47–72%.
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251
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2.B$*A%( F.C. G)3)9 /!./!%)+%( $/0&*')= EEEI. J., 1965. E. 46.
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252

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NH2NH2.H2O |
+ |
+ |
+ |
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CH3OH,52o,2.8! |
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ONO2 |
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OCH3 |
OH |
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I |
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II |
III |
IV |
+ |
+ |
+ |
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(1) |
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ONO2 |
ONO2 |
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V |
VI |
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VII |
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@A%$3A $. .($,(."'()*$5$ 6 ,-)'(.( /- 100%-/A+ I )$).-6"!" 3!2
II – 26%, III –10%, IV – 29%, V – 14%, VI (#$,/"!/".,-.) – 17%, VII
(!-:(/%"!/".,-.) – 3%. D$(3"/(/"( I 6 1,$34*.-% $.)4.).64(., - /".- ,-.A VI " VII 1(,(%$32., 1$ *,-+/(+ &(,( '-)."'/$, "> ")%$3/$+ 6 *$- /('/4< )&()8.
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253

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3.!"#$"%&$ '.(., )&*+",-." /.(., =&.> ).0. - 3*. // 4'*5. 1996. 6. 32.
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255

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O 1. MgCl |
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2. H+ |
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[Zr] |
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Mg |
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1 |
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[Ni] HCO2Me |
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256