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3.Muzzarelli R.A., Tanfani F., Scarpini G. Chelating film-forming, and coagulating abiility of chitosan-glucan complex from Aspergillus niger industriawasts // Biotech. and Bioeng. 1980. V. 22. P. 885–896.
4.Muzzarelli R.A.A.Niatural chelating polymers. Pergamonpress, 1973. V. 309.
5.Rudall K.M., Kenchington W. The chitin system // Biolog. Rev. 1973. P. 597–636.
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1. |
CoCl2·6H2O |
2 : 1 |
64,1 |
10,39 |
2,71 |
0,00298 |
|
2. |
>$>l2·6E2M |
4 : 1 |
75,29 |
6,76 |
3,15 |
0,0024 |
|
3. |
>$>l2·6E2M |
8 : 1 |
82,01 |
3,14 |
2,96 |
0,0011 |
|
4. |
>u>l2 2E2M |
4 : 1 |
69,73 |
6,3 |
4,79 |
0,0014 |
|
5. |
>u>l2 2E2M |
2 : 1 |
56,75 |
11,2 |
5,86 |
0,0023 |
|
6. |
>u>l2 2E2M |
8 : 1 |
73,61 |
3,39 |
3,29 |
0,0096 |
|
7. |
NiCl2 6E2M |
4 : 1 |
79,20 |
6,76 |
3,25 |
0,0018 |
|
8. |
NiCl2 6E2M |
2 : 1 |
73,65 |
10,39 |
6,88 |
0,0019 |
|
9. |
NiCl2 6E2M |
8 : 1 |
91,55 |
3,14 |
2,74 |
0,0099 |
|
10. |
MnCl2 4H2O |
8 : 1 |
83,80 |
2,92 |
1,71 |
0,0087 |
|
11. |
MnCl2 4H2O |
4 : 1 |
74,86 |
5,49 |
3,50 |
0,0020 |
|
12. |
MnCl2 4H2O |
2 : 1 |
68,86 |
9,75 |
2,83 |
0,0017 |
|
214
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