Новые достижения в химии и химической технологии растительного сырья. Материалы II всероссийской конференции [2005]
.pdf!"#$#%"&'()" *)+",-.' ,'/'(+,* )#0. 1'0',2', 3,#4-.3 5#0#1
%.5. %67896:;1, '.5. )<=>87?2, ".,. @>A=B??7;9C>2
1!"#$ «%&'()*+,'-. '*/0'1-233+&415*(&+,362. 2 7)1&6('-. 2'3(2(/( +&3182920&361. 7)19-:+&''13(2», ;13615361& :133&, 85, <. <15=1)14, 603079 (>1332?)
2<2@&=1)14362. =13/4*)3(5&''-. *)82(&6(/)'1- 3()12(&+,'-. /'25&)32(&(, /+. A+,2'36*?, 65, <. <15=1)14, 603000 (>1332?) E-mail: irinamaslen@yandex.ru
! "#$%&'()) *+),' "#-./0#)%$' 1&*23)""24 5"%)+)$ 6 -5&.&75- 8)$65 #6%5*"2, *)()$%*#, 59 +#$%5%).:"&7& $2+:', ;*).585*#)%$' 5< 1&%+)-.)"5) * =).'< &90&+&*.)"5' ./0)4 5 >5*&%"2<. ?#$35+')%$'
#$$&+%5,)"% -5&.&758)$65 #6%5*"2< 0&-#*&6, *)0;%$' 1&5$65 "&*&7& $2+:' 0.' 5< 1&.;8)"5'.
@)+$1)6%5*"2, 5$%&8"56&, AB! '*.')%$' 6&+# 0)+)*:)* <*&4"2< 1&+&0, 6&%&+#' '*.')%$' ")5$1&.:9;),&4 8#$%:/ -5&,#$$2 0)+)*# 1+5 1)+)+#-&%6) 0+)*)$5"2. C&,1.)6$"#' 1)+)+#-&%6# 6&+2 D6$%+#6%5*"2, 1;%), 1&9*&.')% 59*.)8: 0;-5.:"2) *)()$%*# (&% 6 0& 15%), 1)6%5"&*2) *)()$%*# (0& 3%), .51502 (&% 1,5 0& 3%). E$%#%6&, 1&$.) D6$%+#6=55 '*.'/%$' =)../.&9# 5 .57"5". F%5 *)()$%*# "#<&0'% 35+&6&) 1+5,)")- "5) * +#9.58"2< &%+#$.'< 1+&59*&0$%* (15()*&4 1+&,23.)""&$%5, ,)- 05=5"), G#+,#6&.&755, 6&$,)%&.&755, 6&>)*)""&, 1+&59*&0$%*)).
H#,5 59;8#)%$' 1+&=)$$ *20).)"5' 1)6%5"&*2< *)()$%*. @)6%5" -2. 1&.;8)" 59 $&$"&*&4 6&+2 65$.&%"2, 750+&.59&,. I9;8)"& *.5'- "5) %)<"&.&758)$65< 1#+#,)%+&* (<#+#6%)+# 750+&.59;/()7& #7)"%#, )7& 6&"=)"%+#=55, 750+&,&0;.', %),1)+#%;+2, $%)1)"5 59,).:8)"5' ,#%)+5#.#, 1+&0&.>5%).:"&$%5 1+&=)$$# 750+&.59–D6$%+#75+&*#"5)) "# *2<&0 5 6#8)$%*)""2) 1&6#9#%).5 1)6%5"#.
I$$.)0&*#"5' 1&6#9#.5, 8%& $ *&9+#$%#"5), 6&"=)"%+#=55 750+&-
.59;/()7& #7)"%# ;,)":3#)%$' *2<&0 1)6%5"#, *$.)0$%*5) +#9+;3)"5' 1)6%5"&*&4 ,&.)6;.2 * $+)0) $ *2$&65, 9"#8)"5), pH. I$1&.:9&*#"5) * 6#8)$%*) 750+&.59;/()7& #7)"%# &+7#"58)$6&4 65$.&%2 $&1+&*&>0#- )%$' *20).)"5), -&.:3&7& 6&.58)$%*# -#..#$%"2< *)()$%*, 8), 1+5 5$1&.:9&*#"55 ,5")+#.:"&4 65$.&%2. F%& &-J'$"')%$' ")0&$%#%&8"&
358
!"#"$ %& "'()''&*$++% '%,-.*.$/01 1"/"%23$2.3.&%*. 4 &.("/ 23"3%-- +0/ "'&%#+"(./ %&+%'"&'5 " &%36. 7.2.-+.5 8"9"3: '#"&.$&'5 './0/ %;- 3%/+0/ "'&%#+"(%/ &%36%%93.,%*.+"5, 2!%<.-" &%365+01 9%!%& -%'&"- ;.=& 42% %& &$33"&%3"" *'$> ?%''"" (32 /!+ ;.).
@9<"$ &%365+0$ 3$')3'0 A%/'(%> %9!.'&" 23$-'&.*!$+0 1340 &%365+0/" /$'&%3%B-$+"5/". C!%<.-: /$'&%3%B-$+"> * ;3.+"D.1 23%/0E!$++%> ,.!$B" &%36. '%'&.*!5$& 7,72 /!+ ;., . ,.2.'0 &%36. – 29,34 /!3- &%++.
F &%36$ +."9%!$$ *03.B$+% 23"')&'&*"$ /%!$()! ;)/"+%*01 ("'!%&, +.1%-5<"1'5 +. 3.,+01 '&.-"51 1"/"#$'(%> ,3$!%'&" " "/$=<"1 3.,+)= /%!$()!53+)= '&3)(&)3). G)/"+%*0$ ("'!%&0 5*!5=&'5 %'+%*+0/" *$<$- '&*./", %23$-$!5=<"/" '*%>'&*. &%365+01 '"'&$/.
H$!: +.E$> 3.9%&0 – *0-$!$+"$ ;)/"+%*%;% (%/2!$('. 2% /$&%-) I.I. J./9.!%*. " ",)#$+"$ $;% 9"%!%;"#$'(%> .(&"*+%'&".
K.&$3".!%/ +.E$;% "''!$-%*.+"5 '!)B"! &%36 /$'&%3%B-$+"5 A$/- +%$ A%/'(%> %9!.'&". A%36 -.++%;% /$'&%3%B-$+"5 23$-'&.*!5$& '%9%> 2!%&+)= &$/+%-9)3)= /.'') ' 1.3.(&$3+0/ 9%!%&+0/ ,.2.1%/, '% '&$2$- +:= 3.,!%B$+"5 35%, '%-$3B.+"$/ ,%!0 8,3%.
F (.#$'&*$ 6.3/.(%!%;"#$'("1 &$'&%* -!5 %23$-$!$+"5 9"%!%;"#$'(%>
.(&"*+%'&" +./" 90!. %23$-$!$+. .+&";3"9(%*.5 .(&"*+%'&: " *!"5+"$ ;)- /"+%*%;% (%/2!$('. +. 23%D$''0 3$2.3.&"*+%> 3$;$+$3.D"" (%B".
@23$-$!$+"$ .+&";3"9(%*%> .(&"*+%'&" 2%!)#$++%;% (%/2!$('. 23%*%-"!" * )'!%*"51 in vitro /$&%-%/ -*)1(3.&+01 '$3">+01 3.,*$-$- +"> * B"-(%> 2"&.&$!:+%> '3$-$ 8.9)3%. F (.#$'&*$ &$'&- /"(3%%3;.+",/%* "'2%!:,%*.!"': E&.//0 Trichophiton rubrum –
248/700, Trichophiton mentagrophytes var intergitale F4CG – 268,
Microsporium canis F4CG – 326/316, 2%!)#$++0$ * %&-$!$ /"(%!%;"" D$+&3.!:+%;% (%B+%-*$+$3%!%;"#$'(%;% "+'&"&)&. K"+"'&$3'&*. ,-3.- *%%13.+$+"5 ?%''"" (;. K%'(*.) " *% F'$3%''">'(%/ D$+&3$ 2% ;!)9%("/ /"(%,./ " /"(%;$++0/ .!!$3;"5/ (8.+(&-C$&$39)3;).
7. (3"&$3"> .+&";3"9(%*%> .(&"*+%'&" 23"+"/.!" 6)+;"'&"#$- '("> &"&3, (%&%30> %D$+"*.!" * *$'%*01 $-"+"D.1 (/"(3%;3.//.1 +. 1 /"!!"!"&3 2"&.&$!:+%> '3$-0). 7. 6)+;"'&"#$'("> &"&3 23"+"/.!" 23$-$!:+)= (%+D$+&3.D"= 23$2.3.&. * '3$-$, 23" (%&%3%> %&')&'&*)$& *"-"/0> 3%'& ()!:&)30 * )'!%*"51 %2&"/.!:+%> &$/2$3.&)30 " ,.-.+- +%> /"(3%9+%> +.;3),(%>. L,)#$+"$ .+&";3"9(%*%> .(&"*+%'&" 2%(.- ,.!% '!$-)=<"$ 3$,)!:&.&0 (&.9!.)
360
!"#"$%&'"( &)&*+, -'&*.+'*), /+0+12"'+ ,31)/"&*2)4) FILIPENDULA ULMARIA L. MAXIM
&.&. '5678976, '.+. :;<=9, ,.,. !6>6?97, 4./. .;@976
!"#$%&' ("$)*+,$-./001' )0&./,$&-/-, 2,. 3/0&0+, 36,
!"#$%, 634050 (4"$$&5) E-mail: serga01net@yahoo.com
!"#$%&'% ()*+),-.-/'$%0,'1 02-3042 *)04'4%.5&-/- 06*57, 0-- 8*-2-9:)%+-% '00.%:-2)&'%+ %/- 1'+'$%0,-/- 0-04)2) – -0&-2&-3 ;4)8 8-'0,) ' *)"*)<-4,' &-261 ;((%,4'2&61 8*%8)*)4-2 *)04'4%.5&-/- 8*-'01-9:%&'7. =%05+) 0.-9&63 '1 0-04)2 ")4*#:&7%4 '"#$%&'% *)04'- 4%.5&61 -<>%,4-2. ?)'<-.%% 8-:1-:7@'+ +%4-:-+ )&).'") 72.7%407 1*-+)4--+)00-08%,4*-+%4*'7 (AB/CD). = &)04-7@%3 *)<-4% )24-*6 '"#$).' 1'+'$%0,'3 0-04)2 08'*4-2-3 26479,' '" ,-*&%3 ' .'045%2
.)<)"&',) 27"-.'04&-/-. D*)2&%&'% ,-+8-&%&4-2 ;,04*),4-2 :- ' 8-0.% /':*-.'") :)%4 <-.%% 8-.E '&(-*+)F'E - 0-04)2%.
?)04-3,# $)04%3 .)<)"&',) 27"-.'04&-/- 8-.#$).' +%4-:-+ +)F%- *)F'' 2 0--4&-G%&'' 1 : 10 ('"2.%,)4%.5 – 40%-&63 ;4)&-.) 2 0--42%4- 042'' 0 4*%<-2)&'7+' AH XI.
D8'*4-26% ;,04*),46 $)04%3 .)<)"&',) 8-:2%*/).' 268)*'2)&'E :.7 #:).%&'7 08'*4). I4 8-.#$%&&-/- -<*)"F) -4<'*).' $)045, ,-4-*#E 8-:2%*/).' /':*-.'"# (HCl, 30 +'&, 100 ºD). J-.#$%&&6% *)042-*6 -1-
.)9:).' ' 2+%04% 0 -<*)"F)+' <%" /':*-.'") -04)2.7.' &) 0#4,' 2 1-.-- :'.5&',% 8*' 4 ºD, 268)2G'% -0):,' -4:%.7.', ) ('.54*)46 ;,04*)/'*-- 2).' 1.-*-(-*+-+, 8-0.% $%/- 2-:&)7 ()") 260#G'2).)05 8-: 2),##+-+ ' 0#1-3 -04)4-, -<*)<)462).07 ;4'.)F%4)4-+. =6479,' 1.-*-(-*+-+ ' ;4'.)F%4)4-+ -<>%:'&7.' 8%*%: )&).'"-+ AB/CD. K'0.-4&63 /':*-.'" 8*'2-:'4 , *)"*#G%&'E /.',-"':-2 ' 2602-<-9:%&'E )/.',-&-2, '" ,-4-*61 .%4#$'%, +-/#4 <645 8*-)&).'"'*-2)&6 AB/CD. L),'+ -<*)"-+, 8-.#$).' 8- :2) -<*)"F) '" ,)9:-3 $)04' *)04'4%.5&-/- 06*57 – 26479- ,' '" &)4'2&-/- 08'*4-2-/- ;,04*),4) (-<*)"%F I) ' 26479,' '" 8-:2%*/- -/- /':*-.'"# 08'*4-2-/- ;,04*),4) (-<*)"%F II).
A>B97CD 6?6BCE6 4!/#&. M&).'" 8*-2-:'.' &) 8*'<-*% Agilent ?N 6890 Plus, 0&)<9%&&-+ +)00-08%,4*).5&6+ :%4%,4-*-+ MSD 5973N (DOM). P0.-2'7 1*-+)4-/*)('$%0,-/- *)":%.%&'7: ,-.-&,) ,)8'..7*- &)7 DB-5ms (5% :'(%&'. ' 95% :'+%4'.8-.'0'.-,0)&, 4-.@'&) ()"6 0,25 +,+) *)"+%*-+ 30 + ! 0,25 ++, 8*-/*)++'*-2)&'% 4%+8%*)4#*6 -4
362
!"#$#%&'()' *+,%)-.
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
16 |
1445 |
4-!"#$%&'(")*$+),- %'- |
1,21 |
1,85 |
96 |
– |
– |
– |
|
|
&.$#, |
|
|
|
|
|
|
17 |
1463 |
4-/'01$%&'-3- |
0,05 |
– |
95 |
– |
– |
– |
|
|
!"#$%&'(")*,.20"/'0 |
|
|
|
|
|
|
18 |
1559 |
5,6,7,7,-#"#1,/'01$-4,4,7,- |
1,03 |
0,37 |
96 |
– |
– |
– |
|
|
#1'!"#'.-2-(")*$341,)$) |
|
|
|
|
|
|
19 |
1567 |
5$0"%,)$6,- %'&.$#, |
0,16 |
– |
95 |
– |
– |
– |
20 |
1603 |
N,N-0'7#'.-3- |
1,04 |
0,67 |
96 |
– |
– |
– |
|
|
!"#'.(")*,!'0 |
|
|
|
|
|
|
21 |
1632 |
3-/'01$%&'-("##,- |
0,15 |
0,49 |
78 |
– |
– |
– |
|
|
0,!,&%$) |
|
|
|
|
|
|
22 |
1764 |
8"#1,0"%,)$6,- %'&.$#, |
0,31 |
0,15 |
98 |
– |
– |
– |
23 |
1788 |
9")*'.(")*$,# |
0,28 |
0,13 |
90 |
– |
– |
– |
24 |
1796 |
5,6,7,7,-#"#1,/'01$-6- |
3,01 |
2,77 |
98 |
– |
– |
– |
|
|
/'01$%&'-4,4,7,-#1'!"#'.- |
|
|
|
|
|
|
|
|
(")*$341,)$)-2 (.$.'$- |
|
|
|
|
|
|
|
|
.'0) |
|
|
|
|
|
|
25 |
1843 |
6,10,14- |
0,31 |
– |
97 |
– |
– |
– |
|
|
#1'!"#'.:")#,0"%,)$)-2 |
|
|
|
|
|
|
26 |
1857 |
:")#,0"%,)$6,- %'&.$#, |
0,05 |
– |
95 |
– |
– |
– |
27 |
1884 |
1-)$),0";") |
– |
0,67 |
98 |
0,38 |
– |
98 |
28 |
1969 |
<"%&,0"%,)$6,- (:,.2!'- |
5,44 |
5,28 |
99 |
0,55 |
0,02 |
99 |
|
|
#')$6,-) %'&.$#, |
|
|
|
|
|
|
29 |
1979 |
=#'.$6>+ 73'1 /"%&,0"%,- |
0,08 |
– |
95 |
– |
– |
– |
|
|
)$6$+ %'&.$#> |
|
|
|
|
|
|
30 |
2016 |
1,2,3,4,4a,9,10,10a- |
– |
– |
– |
0,28 |
– |
97 |
|
|
$%#,/'01$-1,4-0'!"#'.-7- |
|
|
|
|
|
|
|
|
'*$:1$:'.3"),)#1") |
|
|
|
|
|
|
31 |
2064 |
<":#,0"%,)$6,- (!,1/,1'- |
0,05 |
– |
95 |
– |
– |
– |
|
|
)$6,-) %'&.$#, |
|
|
|
|
|
|
32 |
2088 |
1-$%#,0"%,)$. |
0,36 |
0,41 |
99 |
0,11 |
– |
90 |
33 |
2147 |
9,12-$%#,0"%,0'")$6,- |
0,93 |
2,11 |
96 |
– |
– |
– |
|
|
%'&.$#, |
|
|
|
|
|
|
34 |
2163 |
?%#,0"%,)$6,- (",1')$- |
0,83 |
0,77 |
99 |
– |
– |
– |
|
|
6,-) %'&.$#, |
|
|
|
|
|
|
35 |
2379 |
5"/'01$,('"#')$6,- %'- |
– |
– |
– |
1,81 |
– |
99 |
|
|
&.$#, |
|
|
|
|
|
|
36 |
2485 |
1,2,3,4,4a,9,10,10a- |
– |
– |
– |
1,00 |
– |
98 |
|
|
$%#,/'01$-1,4-0'!"#'.-7- |
|
|
|
|
|
|
|
|
'*$:1$:'.3"),)#1")- |
|
|
|
|
|
|
|
|
%,1($)$6,- %'&.$#, |
|
|
|
|
|
|
364
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
.#'5 "/$1*"+1-(.2 "'1,!1 + $.*90<#1#. 4(,$"0(*1. C 93.#"2 &1$1!#.$1 )$"5+05.2"; 8!'#$1!#12( ?1$21!"0"4(3.'!"; 1!#(+-"'#( '0.,9.# )$.,)"0"B(#<, 3#" "#+.#'#+.--% *1 8#" -. #"0<!" ?01+"-"(,%, -" ( '10(@(01#%, +%'=(. !1$/"-"+%. !('0"#%, ')($#% ( '#.$"(,%.
!"#!$#%& '(!)!*(+&",( -,.($#%& $&/&".$- '(!0-""% )(0!##(,- ,(.-1",!*!
(.$. ,234356
!"#$%&'"$()* +&$,-#"$./0%%1* .&"+&/&-2(&%&3)40$()* )%$.).,., ,5. 6. 7",8)%$(&*, 2, !"#$%&'"$(, 660075 (9&$$)') E-mail: nauka@mail.kgtei.kts.ru
G(2"--(! !(#1;'!(; Schizandra chinensis Bail. – ",-" (* (-#.$.'- -.;=(& ( ",-"+$.2.--" 210"(*93.--%& $1'#.-(; ?0"$% C(/($( ( H10<-.4" D"'#"!1. I4" )0",% (*,1+-1 )$(2.-57# + -1$",-"; 2.,(@(-. !1! '#(290($97:.. ( #"-(*($97:.. '$.,'#+" )$( ?(*(3.'!"2 ( 92'#- +.--"2 ).$.9#"20.-((. 6'-"+-". ?1$21!"0"4(3.'!". ,.;'#+(. 0(2"-- -(!1 *1!0731.#'5 + '#(2905@(( ,%&1#.0<-"4" @.-#$1 ( )"+%=.-(( $.1!#(+-"'#( @.-#$10<-"; -.$+-"; '('#.2%, $.4905@(( /("0"4(3.'!(&
366