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1.6.5.1.4. Flash and ultra-rapid pyrolysis

Flash pyrolysis is the process in which the reaction time is of only several seconds or even less. The heating rate is very high. This requires special reactor configuration in which biomass residence times are only of few seconds. Two of appropriate designs are entrained flow reactor and the fluidized bed reactor. Flash pyrolysis of any kind of biomass requires rapid heating and therefore the particle size should be fairly small, i.e., approximately 105–250 µm [5].

Flash pyrolysis is of the following types:

  • flash hydro-pyrolysis: Hydro-pyrolysis is flash pyrolysis done in hydrogen atmosphere at a pressure up to 20 MPa;

  • rapid thermal process: It is a particular heat transfer process with very short heat residence times (between 30 ms and 1.5 s). It is done at temperatures between 400 and 950 oC. Rapid de-polymerization and cracking of feed stocks takes place. Rapid heating eliminates the side reactions whereby giving products with comparable viscosity to diesel oil;

  • solar flash pyrolysis: Concentrated solar radiation can be used to perform flash pyrolysis. The solar energy can be obtained through devices like solar towers, dish connectors, solar furnaces, etc.;

  • vacuum flash pyrolysis: In this process, pyrolysis is done under vacuum. It limits the secondary decomposition reactions, which in its turn gives high oil yield and low gas yield.

The vacuum facilitates the removal of the condensable products from the hot reaction

zone. This prevents further cracking and further re-condensation reactions [5].

Table 4. Product yield with temperature from flash pyrolysis of mixed wood waste [11]

Temperature (oC)

Char (wt%)

Liquid (wt%)

Gases (wt%)

400

24.1

65.5

10.2

450

21.4

65.7

11.1

500

18.9

66.0

14.6

550

17.3

67.0

14.9

550

16.7

67.8

15.7

550

17.1

66.2

15.2

Table 4 reports temperature influence in the range of 400 to 550 oC on products yield from flash pyrolysis of mixed wood waste in a fluidized bed reactor. It is seen that liquid increased marginally where as significant increase in gas yield was observed. Char quantity decreased, as the temperature is increased.

A summary of experimental data presented in [5] evidences that there is a temperature optimum around 500 oC corresponding to maximum liquid yield from flash pyrolysis of all studied biomass.

Ultra-rapid pyrolysis involves extremely fast mixing of biomass with a heat carrier solid, resulting in a very high heat-transfer and hence heating rate. A rapid quenching of the primary product follows the pyrolysis, occurring in its reactor. A gas–solid separator separates the hot heat-carrier solids from the non-condensable gases and primary product vapours, and returns them to the mixer. They are then heated in a separate combustor. Then a non-oxidizing gas transports the hot solids to the mixer (see Figure 13a). A precisely controlled short uniform residence time is an important feature of ultra-rapid pyrolysis. To maximize the product yield of gas, the pyrolysis temperature is around 1000 °C for gas and around 650 °C for liquid [4].

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