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Basic Semiconductor and Metal-Oxide-Semiconductor (MOS) Physics

93

Accumulation

p

EFM

G

 

eV

+

++

M O S

FIGURE 2.27

EC

Ei

EF

EV

Carrier Density

p0

n0

n

Z

W

Energy band diagram for ideal MOS capacitor under the application of applied voltage.

is the applied voltage. The difference between the Fermi level in the metal and the semiconductor is the applied bias.

Because Φm and ΦS do not change with applied voltage, but EFm moves up relative to EFS, causing a tilt in the oxide conduction band, the energy bands of the semiconductor bend near the interface (the valence bands are bent to come closer to the Fermi level) accommodating the accumulation of holes at the interface as in Figure 2.27. The effect of depositing a negative charge in the gate of a MOS transistor causes hole accumulation.

An increase in surface hole concentration implies an increase in Ei EF at the surface. Because the Fermi level within the semiconductor remains unchanged as no current flows though the MOS structure with increasing (Ei EF), Ei must move up in the energy near the surface. This results in band bending near the surface. From Figure 2.27 it is clear that near the surface the Fermi level lies closer to the valence band, creating a larger hole concentration than that arising from the doping of the p-type semiconductor.

2.14.2  Depletion

When a positive bias is applied to the metal, positive charges are deposited on the metal and a corresponding net negative charge accumulates at the semiconductor surface. Such a negative charge in the p-type material is due to depletion of holes from the surface, leaving behind the uncompensated ionized acceptors. Thus the hole concentration decreases, moving Ei closer to EF, bending the band down near the semiconductor surface as in Figure 2.28. If the positive voltage is increased, the band bends down more

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Technology Computer Aided Design: Simulation for VLSI MOSFET

Depletion

Electric field E

VG > 0

qVG

EFM

M O S

EC

Ei

EF EV

Na

Carrier Density

p0

p

n

n0

Z

W

FIGURE 2.28

Effect of applied electric field on the interface charge density in the ideal MOS capacitor: positive gate voltage (VG) creates a depletion region.

strongly, resulting in inversion that occurs for the higher positive applied positive gate bias [39].

2.14.3  Inversion

If the positive bias on the metal side is increased further, the bands at the semiconductor surface bend down more strongly as shown in Figure 2.29. A large positive voltage can bend Ei below EF . Thus the conduction band at the oxidesemiconductor region comes close to the Fermi level in the semiconductor. This reverses the mobile charges from holes to electrons at the interface and the electron density increases. If the positive bias is increased until EC comes close to the electron quasi-Fermi level near the interface, the electron density increases and the semiconductor near the interface has electrical properties of an n-type semiconductor. This n-type surface layer is formed not by doping, but by inversion of the original p-type semiconductor due to the applied bias. This inverted layer is separated by the underlying p-type material by a depletion region.

2.14.4 Surface Potential

Figure 2.30 shows the band bending of the semiconductor on the onset of strong inversion [37–39]. It is described by the quantity Φ (x) , which measures the position of the intrinsic Fermi level with respect to the bulk intrinsic Fermi level. The band bending at the oxide-semiconductor interface is described in terms of the potential ΦS as in Figure 2.30. We notice that ΦS = 0 is the flat band condition for the MOS (Figure 2.26). When ΦS < 0 , the

Basic Semiconductor and Metal-Oxide-Semiconductor (MOS) Physics

95

Electric field E

VG >> 0

qVG

EFM

Inversion

Na

EC

Density

Ei

Carrier

 

EF

 

Ev

 

n(interface) ≥ p0

p0

p

n

n0

W Z

FIGURE 2.29

Band bending with increase of positive bias on the metal side of MOSFET.

At inversion

ΦS = 2ΦF

EC

Ei

F

Surface

potential qΦs EF

EV

F = EF Ei Positive for p-substrate Negative for n-substrate

Oxide Semiconductor

Z

FIGURE 2.30

Band bending of the semiconductor in the inversion mode.

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Technology Computer Aided Design: Simulation for VLSI MOSFET

bands bend up at the surface and holes accumulate. Similarly when ΦS > 0, depletion takes place, and finally when ΦS > 0 and greater than ΦF , the bands bend in such a way that Ei lies below EF, resulting in inversion.

The onset of inversion is a gradual process and is a function of gate bias. The strong inversion occurs when the electron concentration at the interface is equal to the bulk p-type concentration. Strong inversion means the surface will be as strongly n-type as p-type. So the intrinsic level Ei is at a position ΦF below the Fermi level at the interface. The surface band bending is given in (2.91) as

ΦS(inv) = 2ΦF

(2.91)

For an n-MOSFET, the substrate is p-type and ΦF

is positive, and a positive

ΦS is required for inversion. For a p-MOSFET the substrate is n-type and ΦF is negative, causing inversion.

The charge density of the metal Qm is balanced by the channel depletion charge Qd and the inversion charge Qn. We are interested in calculating the threshold voltage (i.e., the gate voltage needed to cause inversion in the channel).

The total surface charge density is related to the surface field by Gauss’s law. This charge QS is the total surface charge density at the semiconductoroxide interface region and includes the induced free charge in inversion and the background ionic charge. The charge QS is zero when the bands are flat.

For a larger positive gate voltage the surface potential increases. The hole concentration near the surface decreases while the electron concentration increases, according to the following relationships:

p

= N

a

exp qΦS

(x=0)

 

 

 

 

 

 

 

kT

 

 

 

 

 

 

 

 

 

 

 

 

 

and

 

 

 

 

 

 

 

 

 

 

 

n

=

ni2

 

exp

 

qΦS

 

 

 

 

 

(x=0)

 

 

Na

 

 

 

 

 

 

 

 

kT

since

 

 

 

 

 

 

 

 

 

 

 

n = ni

 

 

 

 

 

EF Ei

 

 

exp

 

 

 

 

 

kT

 

 

 

 

 

 

 

 

 

 

p = ni

 

 

 

 

 

Ei EFi

 

 

exp

kT

 

 

 

 

 

 

 

 

 

 

 

(2.92)

(2.93)

(2.94)

(2.95)

np = ni2

(2.96)

Basic Semiconductor and Metal-Oxide-Semiconductor (MOS) Physics

97

The electron surface concentration is equal to that of hole (n(0) = p(0) = ni), when Ei coincides with EF at x = 0. This happens when

ΦS = ΦF =

kT

 

Na

(2.97)

q

ln

 

 

 

ni

 

as shown in Figure 2.31.

With further increase in the gate voltage, the electron surface concentration increases up to a point where n(x = 0) becomes equal to ppo = Na which is the original hole concentration in the substrate. This is because the band curvature at the surface (x = 0) places Ei at an energy qΦF below EF. In other words, the band curvature is equal to 2(Ei EF) or ΦS = 2ΦF.

When this condition is met, the semiconductor surface is said to be in strong inversion.

For ΦF ≤ ΦS 2ΦF, the electron concentration is larger than the hole concentration, and the surface is in weak inversion, while for ΦS 2ΦF it is in strong inversion as shown in Figure 2.32. The inversion layer is rich in electrons and hence is a good conductor. The MOS capacitor consists of two conducting electrodes (the metal gate and the inversion layer at the silicon surface). As in the case of accumulation, the capacitance of the MOS structure is again

equal to Cox.

When an inversion layer is formed, electrons are the local majority carriers at the surface. Any subsequent increase in gate voltage increases the electron concentration in the inversion layer and produces a larger inversion charge Qinv. However, the thickness of the inversion layer remains very small. Its actual thickness is similar to that of an accumulation layer.

Concentration in Log Scale

concentr

Na

Hole

ro

atio

n

n

concentration

 

ct

 

Ele

ΦF

ΦS

F

FIGURE 2.31

Hole and electron concentration as a function of surface potential.

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Technology Computer Aided Design: Simulation for VLSI MOSFET

 

 

EC

 

 

Ei

Surface

qΦF

 

 

EF

potential

 

ΦS = 2ΦF

qΦF

EV

 

–2qΦF

 

Metal Oxide

Semiconductor

Z

FIGURE 2.32

Band bending under strong inversion at the surface.

The electron charge in an inversion layer can be thought of as a surface charge [40]. As in the case of an accumulation layer, the inversion charge depends exponentially on the surface potential:

Q α exp qΦS

inv (2.98)

kT

When the gate voltage is increased beyond inversion, the surface potential ΦS increases very slightly above 2ΦF and one can assume that ΦS = 2ΦF when an inversion layer is present. Because the semiconductor is p-type, the electrons in the inversion layer are produced by a slow process called thermal generation at room temperature. They can also be produced by external generation (if a light source is present). If the semiconductor is in the dark and at cryogenic temperature, the inversion layer may never form.

In summary the following rules will be used to describe the relationships between the charge on the metal gate and the charge in the accumulation, depletion, and inversion layers as shown in Figure 2.33.

QG = Qacc   (accumulation)

(2.99)

QG = Qd

(depletion)

(2.100)

QG = Qd + Qinv

  (inversion)

(2.101)

QG = charge at the back-side contact of the sample (dielectric mode)

Basic Semiconductor and Metal-Oxide-Semiconductor (MOS) Physics

99

 

Oxide

 

 

 

Metal

Silicon

 

Qacc

 

 

 

 

 

 

x

QG

x

 

 

x = 0

 

 

 

 

 

 

 

(a)

 

(b)

 

QG

Qd

QG

Qd

 

 

 

 

 

x

 

x

 

 

xd

 

xdmax

 

 

(c)

 

Qinv

 

 

 

(d)

 

FIGURE 2.33

Charges in the MOS structure: (a) flat band, (b) accumulation, (c) depletion, and (d) inversion.

2.15  Flat-Band Voltage: Effect of Real Surfaces

2.15.1  Equalization of the Fermi Levels

The Fermi level of the metal gate and the silicon are so far considered equal. However, in practice this is not the case. In modern devices the gate material is not actually a metal, but heavily doped polysilicon. The doping concentration for that material is so high (≈1020 cm–3) that it can be considered as a metal. Let us first consider the metal and the semiconductor separately. The energy needed to extract an electron with an energy EFM from the metal is called the work function qΦm. The work function in the semiconductor is denoted by qΦsc . The potential work function difference is Φms = Φm − Φs. It is to be noted that Φms is negative for both n+ poly-silicon gate and n-type Si substrate and n+ poly-silicon gate and p-type Si substrate.

When a MOS structure is formed, the Fermi levels align, and the charge transfer causes a tilt in the oxide conduction band [40,41]. The bands bend down near the semiconductor surface to accommodate work function difference as shown in Figures 2.34(a),(b),(c). To go back to a flat-band condition a voltage must be applied to the gate. This voltage called work function difference is denoted by Φms :

Φms = Φm − Φsc =

EF EFM

(2.102)

 

q

 

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Technology Computer Aided Design: Simulation for VLSI MOSFET

qΦm

EFM

Metal Gate oxide

(a)

EFM

Metal Gate oxide

(c)

Vaccum

qΦsc

 

 

EC

EC

EFM

 

 

 

 

EF

EF

 

 

EV

EV

Metal

Gate

 

Semiconductor

Semiconductor

oxide

 

 

 

 

 

(b)

 

EC

qΦMS EF

EV

Semiconductor

FIGURE 2.34

Energy band diagram of MOSFET when (a) the metal and the semiconductor are taken separately, (b) no bias is applied, and (c) a bias equal to Φms is applied to the gate.

2.15.2 Oxide Charges

Oxides grown on silicon contain positive charges due to the presence of contaminating metallic ions or imperfect Si-oxide bonds [40]. These charges can either be fixed or mobile in the oxide. However, for simplicity only the case of fixed charges is considered.

Let us consider an elementary real positive charge Q(Coulomb m–2) at a depth x in the oxide. Let x = 0 be defined at the metal/oxide interface as shown in Figure 2.35(a). Negative charges will appear in the metal and the silicon. The sum of these three charges is equal to zero. The charge in the silicon can be removed when an appropriate negative bias is applied to the gate as in Figure 2.35(b). If the charge is closer to the semiconductor, a larger compensation gate bias is required to remove it. In an actual device, charges

Basic Semiconductor and Metal-Oxide-Semiconductor (MOS) Physics

101

ρ

 

 

ρ

 

 

 

 

Q

 

 

 

Q

 

 

tOX

 

 

tOX

 

 

 

x

 

 

x

 

 

 

 

x

 

 

x

 

 

x = 0

 

 

x = 0

 

 

Metal

Oxide

Semiconductor

Metal

Oxide

Semi

 

 

 

conductor

 

 

 

 

 

 

 

 

(a)

 

 

(b)

 

 

FIGURE 2.35

Single charge in an oxide for (a) VG = 0 and (b) an applied gate voltage.

are distributed throughout the oxide. The compensating voltage is obtained as equal to

VQ =

QOX

(2.103)

 

COX

 

2.15.3  Interface Traps

A set of charges arise from the interface states at the Si-SiO2 interface. They are created by the sudden termination of the semiconductor crystal lattice at the oxide interface. In the oxidation process, Si reacts with oxygen forming a SiO2 layer. When the oxidation process is suddenly stopped, some ionic Si left near the interface causes perturbation to the periodic crystal structure of the semiconductor and hence some Si-Si bonds are unfulfilled or dangling. As a result there are energy states in the band gap at the silicon surface. These states called interface states or interface traps can be charged positively or negatively, and depending on their nature and their energy with respect to the Fermi level will affect the surface potential.

2.15.4  Flat-Band Voltage

Flat-band voltage is defined as the voltage that must be applied to the gate to bring the semiconductor energy bands to a flat level. It can also be defined as the voltage applied to the gate such that there is no band bending in the

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Technology Computer Aided Design: Simulation for VLSI MOSFET

semiconductor. Flat-band is achieved by applying a gate voltage that compensates for the following:

The differences in work functions of the semiconductor and the gate electrode

The presence of charges in the oxide

The interface traps

VFB = VQ + Φms + Vi = Φms QOX +

Qi

(2.104)

 

COX

COX

 

For simplicity the various oxide and interface charges are included in an effective positive charge Qit (C/cm2) at the interface. Qit includes both Qi and QOX. This charge will introduce an effective negative charge in the semiconductor. To compensate for these charges, a bias Vit = CQOXit must be applied to the gate. Flat band voltage can be given as

VFB = Vit + Φms = Φms

Qit

(2.105)

COX

 

 

2.16  Expression of Threshold Voltage

The threshold voltage of a MOSFET is defined as the voltage that must be applied to the gate to form an inversion layer. In a MOS transistor, the gate voltage is equal to the sum of the potential drops in the semiconductor and the oxide given as

VG = ΦS +

QG

(2.106)

COX

 

 

where QG is equal to the positive charge on the gate electrode. An equal amount of negative charge also exists in the semiconductor, composed of ionized impurities in the depletion region, and the free electrons at the oxide/silicon interface at the inversion. If the charge due to the free electrons is assumed to be much smaller than that due to ionized impurities when the inversion layer starts to form, the above equation can be written as

VG = 2ΦF

Qd

= VTHO

(2.107)

 

 

COX

 

VTH0 is called the ideal threshold voltage, and it is measured with respect to the source [40].