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1.2.3 Biaxial Crystals

Physical Properties of Biaxial Crystalline Materials

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

Al2(MoO4)3

3.495

Insoluble

Al2(WO4)3

5.079

(010)-p

Insoluble

Al2Ge2O7

4.06

Insoluble

Al2SiO4F2

3.57

8 (Mohs)

(001)-p

Insoluble

Al2SiO5-andalusite

3.13

6.5 (Mohs)

(110)

Insoluble

Al2SiO5-kyanite

3.6

4–7.5 (Mohs)

(100)-p

Insoluble

Al2SiO5-sillimanite

3.25

6.5 (Mohs)

(010)-p

Insoluble

Al4B2O9

2.904

Al6Ge2O13

3.662

Insoluble

Al6Si2O13

3.19

1750

(010)-i

Insoluble

AlHfTaO6

8.33

Insoluble

AlNb11O29

4.46

Insoluble

AlNbO4

4.673

Insoluble

AlTaO4

6.86

Insoluble

As2S3

3.49

1.5 (Mohs)

(010)-p

Insoluble

AsS

3.56

1.5 (Mohs)

(010)-i

Insoluble

AsSbS3

3.92

1.5 (Mohs)

(001)-p

Insoluble

Ba2CaMgAl2F14

4.204

3.5 (Mohs)

(001)-p

 

Ba2CdMgAl2F14

4.735

Ba2LiNb5O15

Insoluble

Ba2NaNb5O15

5.41

Insoluble

Ba2Zn3F10

5.26

Ba2ZnAlF9

4.909

Ba2ZnGaF9

5.169

Ba3Al2F12

4.37

Ba3TiAl10O20

4.13

BaAl2B2O7

3.559

BaAl2Ge2O8

Insoluble

BaAl2Si2O8

3.96

6–6.5 (Mohs)

(001)-p

Insoluble

BaBe2Si2O7

4.00

7 (Mohs)

(001)(100)-p

Insoluble

BaCa2Mg(SiO4)2

3.974

Insoluble

BaCa2Si3O9

3.73

3.5 (Mohs)

(011)(010)-p

Insoluble

BaCdAlF7

5.04

BaCdGaF7

5.406

BaCO3

4.31

3.5 (Mohs)

(010)-i

Very slightly soluble

BaGaF5

5.104

BaGe2O5

5.85

Insoluble

BaGeAl6O12

4.031

BaGeGa6O12

5.201

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

BaGeO3

5.072

Insoluble

BaMgF4

4.538

BaNb2O6

Insoluble

BaSO4

4.50

3 (Mohs)

(001)-p

Insoluble

BaTa2O6

7.824

Insoluble

BaTi4O9

4.52

Insoluble

BaTiAl6O12

3.791

BaTiGa6O12

4.981

BaY2F8

5.047

250–350

BaY2O4

5.806

BaZnF4

5.178

β-BaSi2O5

3.77

5 (Mohs)

(001)

Insoluble

β-Ca2SiO4

3.31

6 (Mohs)

(100)-i

Insoluble

Be2BO3F

2.37

7.5 (Mohs)

(010)-p

Insoluble

BeAl2O4

3.75

1600–2300 (V)

None

Insoluble

BeAl6O10

3.75

β-Ga2O3

5.95

(010)-p

Insoluble

Bi2Al4O9

6.229

Bi2GeO5

Insoluble

Bi2Mo2O9

6.518

Insoluble

Bi2Mo3O12

6.196

(100)-p

Insoluble

Bi2O3

9.37

Very slightly soluble

Bi2SiO5

Insoluble

Bi2WO6

7.35

3.5 (Mohs)

Bi3TiNbO9

Insoluble

Bi4B2O9

8.185

Bi4Ti3O12

8.045

313

Insoluble

γ-Bi2MoO6

7.068

BiB3O6

5.03

5–5.5 (Mohs)

Insoluble

BiNbO4

Insoluble

BiSbO4

8.48

Insoluble

BiTaO4

8.958

Insoluble

BiVO4-clinobisvanite

6.95

BiVO4-pucherite

6.63

4 (Mohs)

(001)-p

Ca(IO3)2

4.48

3.5 (Mohs)

(011)-i

Ca2(AsO4)Cl

(010)-p

Ca2(PO4)Cl

(010)-p

Ca2(PO4)F

(010)-p

Insoluble

Ca2(VO4)Cl

3.075

(010)-p

Ca2Al2O5

3.73

Ca2B6O11

2.85

Ca2BO3Cl

2.766

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

Ca2Nb2O7

Insoluble

Ca2Sb2O7

5.204

Insoluble

Ca2V2O7

3.36

5.5 (Mohs)

(110)-p

Ca3(VO4)2

3.16

(110)(001)-p

Ca3Al2O6

3.017

Ca3Ga4O9

4.208

Ca3MgSi2O8

3.31

6 (Mohs)

None

Insoluble

Ca3Si2O7

2.96

5.5 (Mohs)

Insoluble

Ca5Al6O14

3.03

(001)-p

Ca5Ga6O14

4.18

5 (Mohs)

CaAl2F8

2.89

4.5 (Mohs)

(111)-p

Insoluble

CaAl2O4

2.942

CaAl2Si2O8

2.76

6–6.5 (Mohs)

(001)-p

Insoluble

CaAl4O7

2.894

8.5 (Mohs)

CaAlB3O7

3.44

7.5 (Mohs)

None

Insoluble

CaAlBO4

2.60

CaB2O4

2.702

CaB2Si2O8

3.00

7 (Mohs)

None

Insoluble

CaB3O5F

2.729

Insoluble

CaB4O7

2.69

CaBa(CO3)2

3.67

4 (Mohs)

(110)-i

Very slightly soluble

CaBe(PO4)F

2.95

5 (Mohs)

(110)-i

Insoluble

CaBe2(PO4)2

2.89

6 (Mohs)

None

Insoluble

CaCO3-aragonite

2.93

3.5–4 (Mohs)

(010)-i

Very slightly soluble

CaGa2O4

4.333

CaGe2O5

4.868

Insoluble

CaIn2O4

6.15

CaMg(PO4)F

Insoluble

CaMgAsO4F

3.77

5 (Mohs)

(101)-i

Very slightly soluble

CaMgB2O5

3.02

4.5 (Mohs)

(010)-p

Very slightly soluble

CaMgGe2O6

4.265

Insoluble

CaMgSi2O6

3.26

6.5 (Mohs)

(110)-i

Insoluble

CaMgSiO4

3.06

5.5 (Mohs)

(010)-i

Insoluble

CaNb2O6

4.78

5.5 (Mohs)

None

Insoluble

CaSc2O4

3.897

Insoluble

CaSiO3

2.9

5 (Mohs)

(100)-p

Insoluble

CaSnO3

5.759

Insoluble

CaSnSiO5

4.56

4 (Mohs)

Insoluble

CaSO4

2.96

3.5 (Mohs)

(010)(100)

Very slightly soluble

CaTa2O6

Insoluble

CaTiO3

4.04

Insoluble

CaTiSiO5

3.53

5.5 (Mohs)

(110)-i

Insoluble

CaV2O6

3.59

(100)(001)-p

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

CaYBO4

3.783

CaZnGe2O6

4.807

Insoluble

CaZnSiO4

4.25

5 (Mohs)

(010)(100)

Insoluble

CaZrSi2O7

3.63

Insoluble

CaZrTi2O7

4.407

Insoluble

Cd2B2O5

5.24

Cd2GeO4

6.313

Insoluble

CdB4O7

3.51

CdWO4

8.005

Cs2BeF4

4.128

Cs2CdBr4

4.069

Cs2HgI4

4.357

Cs2MgCl4

2.952

Cs2ZnBr4

4.034

Cs2ZnCl4

3.357

CsB3O5

3.39

Soluble

CsGd(MoO4)2

(100)-p

CsLiBeF4

3.411

CsLiSO4

3.455

Very soluble

CsNbB2O6

(001)-p

Insoluble

CsLiSO4

3.455

Very soluble

CsNbB2O6

(001)-p

Insoluble

CsTiOAsO4

4.511

None

Insoluble

CsZnAlF6

4.04

Ga2(WO4)3

(010)-p

Ga2GeO5

4.97

Insoluble

GaNbO4

5.01

Insoluble

Gd(BO2)3

4.84

Gd2(MoO4)3

4.65

Gd2(WO4)3

7.475

Gd2GeO5

Insoluble

Gd2MoO6

7.068

Gd2O2SO4

6.483

Gd2O3

8.33

Gd2SiO5

6.77

6 (Mohs)

(100)-p

Insoluble

Gd2Sr3(BO3)4

5.266

Gd2WO6

8.339

Gd3NbO7

7.459

Insoluble

Gd3TaO7

8.414

Insoluble

Gd4Al2O9

6.467

α-Ga4GeO8

5.65

Insoluble

GdAlGe2O7

Insoluble

GdAlO3

7.437

Insoluble

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

GdGaGe2O7

6.08

Insoluble

GdMgB5O10

4.309

GdNbO4

Insoluble

GdP5O14

3.55

Insoluble

GdPO4

5.986

470

Insoluble

GdScO3

6.642

Insoluble

HfO2

10.11

Insoluble

HgCl2

5.490

HgO

11.14

1.5–2.0 (Mohs)

(010)-p

HIO3

4.637

In2(MoO4)3

3.92

In2(WO4)3

5.619

(010)-p

InCaBO4

4.536

InGaO3

6.447

InNbO4

6.27

(010)-p

Insoluble

InPO4

4.830

Insoluble

InTaO4

8.296

(010)-p

Insoluble

InVO4

4.50

Insoluble

K2CaSiO4

2.865

Insoluble

K3Gd(VO4)2

3.15

Slightly soluble

K3La(PO4)2

5.293

Insoluble

K3Lu(VO4)2

3.15

Slightly soluble

K3Y(VO4)2

3.15

Slightly soluble

KAlSi3O8

2.57

6 (Mohs)

(001)-p

Insoluble

KAl3Si3O10(OH)2

2.78

Insoluble

KBF4

2.51

Slightly soluble

KB5O84H2O

1.740

2.5 (Mohs)

(010)-p

KGaSi3O8

2.887

Insoluble

KIn(MoO4)2

4.17

KLaP4O12

Insoluble

KLu(WO4)2

7.759

KNbB2O6

3.151

(001)-p

Insoluble

KNbO3

4.617

Insoluble

KNO3

2.11

2 (Mohs)

(011)-p

Soluble

KPb2Cl5

4.78

2.5 (Mohs)

Insoluble

KTaB2O6

4.262

(001)-p

Insoluble

KTaO3

5.996 ?

Insoluble

KTi3NbO9

3.88

Insoluble

KTiNbO5

3.82

Insoluble

KTiOAsO4

3.454

None

Insoluble

KTiOPO4

3.024

702

None

Insoluble

KVO3

2.879

(010)-p

KY(MoO4)2

5.40

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

KY(WO4)2

6.56

LaB3O6

4.216

(010)-p

La2(WO4)3

6.626

La2Ba3(BO3)4

5.353

La2Be2O5

6.061

900(100)

(010)-i

Insoluble

La2Ca3(BO3)4

4.157

La2O2SO4

5.467

La2SiO5

Insoluble

La2Sr3(BO3)4

4.783

La2Ti2O7

5.782

648

(010)-p

Insoluble

La2TiO5

5.5

Insoluble

La3NbO7

6.25

Insoluble

La3SbO7

6.558

Insoluble

La3TaO7

7.139

Insoluble

LaAlGe2O7

5.18

Insoluble

LaBMoO6

5.293

LaBO3

5.304

LaBWO6

6.185

LaGaGe2O7

Insoluble

LaGaO3

7.21

Insoluble

LaInO3

LaMgB5O10

3.923

LaNb5O15

6.264

Insoluble

LaNbO4

5.914

Insoluble

LaP5O14

3.290

Insoluble

LaPO4

5.067

5.5 (Mohs)

(100)-i

Insoluble

LaSbO4

6.30

Insoluble

LaScO3

5.79

Insoluble

LaVO4

Insoluble

LaY(WO4)3

6.53

Li2BeSiO4

2.69

7 (Mohs)

(010)-i

Insoluble

Li2CO3

2.097

Slightly soluble

Li2GeO3

3.489

Insoluble

Li2MgGeO4

3.31

Insoluble

Li2SiO3

2.527

Insoluble

Li3La2(BO3)3

4.50

Li3PO4

2.48

4 (Mohs)

(010)-p

Insoluble

Li3VO4

2.645

Insoluble

Li3Y2(BO3)3

3.50

Li5AlO4

2.251

Li6Al2(BO3)4

2.58

Li6Lu(BO3)3

3.538

Li6Y(BO3)3

2.76

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

LiAl(MoO4)2

3.95

LiAl(PO4)F

3.10

5.5 (Mohs)

(100)(110)-p

Insoluble

LiAlGe2O6

4.354

Insoluble

LiAlSi2O6

3.1

7 (Mohs)

(010)-p

Insoluble

LiAlSi4O10

2.40

6.5 (Mohs)

(001)-p

Insoluble

LiBaAlF6

4.114

LiBaGaF6

4.526

LiBO2

2.883

LiB3O5

2.474

7 (Mohs)

None

Insoluble

LiGa(WO4)2

7.44

LiGaGe2O6

4.783

Insoluble

LiGaO2

4.175

Insoluble

LiGaSi2O6

Insoluble

LiGdO2

6.246

LiGdP4O12

Insoluble

LiIn(MoO4)2

4.149

LiIn(WO4)2

7.47

LiInGe2O6

5.041

Insoluble

LiInSi2O6

4.071

Insoluble

LiInSiO4

4.160

Insoluble

LiLa(MoO4)2

4.551

LiLaO2

6.18

Soluble

LiLaP4O12

Insoluble

LiLu(WO4)2

8.02

LiLuGeO4

5.98

Insoluble

LiLuP4O12

Insoluble

LiLuSiO4

5.46

Insoluble

LiSc(WO4)2

6.716

LiScGe2O6

4.157

Insoluble

LiScGeO4

3.928

Insoluble

LiScSi2O6

3.090

Insoluble

LiScSiO4

3.183

Insoluble

LiVO3

2.971

(100)-p

Insoluble

LiY(WO4)2

6.83

LiYGeO4

4.365

Insoluble

LiYO2

6.258

LiYSiO4

3.746

Insoluble

LiZnBO3

3.64

Lu2MoO6

8.167

Lu2O2SO4

7.854

Lu2SiO5

5.892

6.5 (Mohs)

None

Insoluble

Lu2WO6

9.718

LuCaBO4

6.036

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

LuP5O14

3.72

Insoluble

LuTaO4

9.761

Insoluble

Mg2(PO4)F

3.15

5 (Mohs)

(100)-i

Insoluble

Mg2B2O5

2.910

5.5 (Mohs)

(hk0)-p

Insoluble

Mg2BO3F

2.784

Insoluble

Mg2GeO4

4.028

Insoluble

Mg2SiO4

3.22

7 (Mohs)

(010)-i

Insoluble

Mg3(PO4)2

2.76

(100)(010)

Insoluble

Mg3B2O6

3.04

6.5 (Mohs)

(110)-p

Insoluble

Mg3B7O13Cl

2.95

7 (Mohs)

None

Slightly soluble

Mg3TiB2O8

3.35

3.5 (Mohs)

(100)-p

Insoluble

Mg4Al8Si2O20

3.489

7.5 (Mohs)

(010)(001)-i

Insoluble

Mg4Ga8Ge2O20

Insoluble

Mg5(BO3)3F

3.112

Insoluble

MgAl3BSiO9

2.98

7.5 (Mohs)

(100)-p

Insoluble

MgAlBO4

3.45

7 (Mohs)

None

Insoluble

MgGaBO4

4.285

Insoluble

MgGeO3

4.282

Insoluble

MgMoO4

3.809

MgSiO3

3.21

5–6 (Mohs)

(110)-i

Insoluble

MgTi(SO4)3

2.82

MgTi2O5

3.649

Insoluble

MgWO4

6.893

Na(Sr,Ba)PO4

2.919

Insoluble

Na2BaTi2Si4O14

3.43

6 (Mohs)

(100)-i

Insoluble

Na2BeF4

2.482

Na2BeSi2O6

2.70

6 (Mohs)

(100)-i

Insoluble

Na2Ca(PO4)F

2.88

Insoluble

Na2CaMg(PO4)2

3.10

4.5 (Mohs)

Insoluble

Na2GeO3

3.319

Insoluble

Na2KTiNbSi4O14

2.968

6.5 (Mohs)

Insoluble

Na2LiAlF6

2.98

(001)-p

Slightly soluble

Na2LiYSi6O15

2.76

Insoluble

Na2MgAlF7

2.97

3.5 (Mohs)

(110)-i

Slightly soluble

Na2MgGaF7

3.359

Na2MgInF7

3.627

Na2MgScF7

2.853

Na2MgSiO4

2.75

Insoluble

Na2Si2O5

(100)-p

Slightly soluble

Na2SiO3

2.64

Insoluble

Na2Ti2Si2O9

3.44

6 (Mohs)

(010)-i

Insoluble

Na2ZnCl4

2.382

Na3AlF6

2.90

2.5 (Mohs)

(001)-p

Slightly soluble

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

Na3GdSi3O9

3.439

Insoluble

Na3La(BO3)2

3.49

Na3La2(BO3)3

4.19

Na3ScSi2O7

2.861

Insoluble

Na3YSi3O9

2.962

Insoluble

NaAl(AsO4)F

3.64

5 (Mohs)

(110)-i

Slightly soluble

NaAl(PO4)F

3.126

4.5 (Mohs)

(111)-i

Insoluble

NaAlGeO4

3.337

(010)-p

Insoluble

NaAlSi3O8

2.63

6–6.5 (Mohs)

(001)-p

Insoluble

NaBePO4

2.81

5.5 (Mohs)

(010)-p

Insoluble

NaBF4

2.53

3 (Mohs)

(100)(010)

Soluble

NaCaPO4

3.117

3 (Mohs)

NaCdPO4

4.10

NaGaGe2O6

4.864

Insoluble

NaGaGeO4

4.028

(010)-p

Insoluble

NaGaSiO4

3.336

(010)-p

Insoluble

NaGdGeO4

5.366

Insoluble

NaGdP2O7

4.287

Insoluble

NaGdP4O12

3.45

Insoluble

NaGdSiO4

Insoluble

NaIn(MoO4)2

4.02

NaLaP2O7

3.803

Insoluble

NaLaP4O12

3.4

Insoluble

NaLiV2O6

2.962

NaLuGeO4

6.025

Insoluble

NaLuP2O7

4.114

Insoluble

NaLuSiO4

5.435

Insoluble

NaMgF3

3.06

NaNbO3

4.57

5.5 (Mohs)

Insoluble

NaScGeO4

3.39

Insoluble

NaScSi2O6

3.22

Insoluble

NaSr3Al3F16

3.51

4 (Mohs)

None

Slightly soluble

NaTaO3

7.123

Insoluble

NaVO3

2.91

(110)-p

0.8

NaYGeO4

4.302

Insoluble

NaYO2

4.382

Slightly soluble

NaYSiO4

4.083

Insoluble

NaZnF3

4.105

NH4B5O84H2O

1.57

2.5 (Mohs)

(100)-p

Pb2KNb5O15

6.143

(001)

Insoluble

Pb2NaNb5O15

Insoluble

Pb2V2O7

6.46

3 (Mohs)

-

Pb3(PO4)2

7.456

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

Pb3(VO4)2

7.44

Pb3GeO5

Insoluble

Pb3MgNb2O9

Insoluble

Pb3ZnNb2O9

Insoluble

PbBi2Nb2O9

6.684

Insoluble

PbBr2

6.693

(001)-p

PbCl2

5.85

31

(001)-p

0.99 (20)

PbCO3

6.55

3 (Mohs)

(110)(021)-i

Very slightly soluble

PbGeO3

6.968

Insoluble

PbO (massicot)

9.642

 

(100)-p

PbNb2O6

Insoluble

PbSeO3

7.12

3.5 (Mohs)

(001)-p

PbSeO4

7.08

3.5 (Mohs)

None

PbSiO3

6.32

4.5 (Mohs)

(010)-p

Insoluble

PbSO4

6.32

3.5 (Mohs)

(001)(210)

Insoluble

PbTa2O6

7.65

Insoluble

PbTiP2O8

Insoluble

PbZnSiO4

6.13

3 (Mohs)

(120)-i

Insoluble

RbAlSiO4

Insoluble

RbB5O84H2O

1.946

2.5 (Mohs)

Rb2BeF4

3.749

RbBi(MoO4)2

5.52

RbGd2Br7

4.79

Slightly soluble

RbLa(WO4)2

6.88

RbNbB2O6

3.584

(001)-p

Insoluble

RbTaB2O6

4.65

(001)-p

Insoluble

RbTiOAsO4

4.018

None

Insoluble

RbTiOPO4

3.647

None

Insoluble

Sb2O3

5.83

2.5–3 (Mohs)

(110)-p

Insoluble

SbNbO4

5.68

5.5 (Mohs)

(010)-i

Insoluble

SbTaO4

7.53

5–5.5 (Mohs)

(010)-i

Insoluble

Sc(PO3)3

2.736

Insoluble

Sc2(MoO4)3

3.102

Sc2(WO4)3

4.566

(010)-p

Slightly soluble

Sc2Si2O7

Insoluble

(Sc,Y)2Si2O7

3.39

6.5 (Mohs)

(110)-i

Insoluble

Sc2SiO5

3.49

Insoluble

Sc2TiO5

3.611

Insoluble

ScAlBeO4

None

Insoluble

ScCaBO4

3.319

ScGaO3

5.10

(010)-p

Insoluble

ScGe2O5

5.286

Insoluble

ScMgBO4

3.287

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

ScNbO4

4.843

(010)-p

Insoluble

ScTaO4

6.90

(010)-p

Insoluble

Sr2(AsO4)Cl

(010)-p

Sr2(VO4)Br

4.342

Sr2(VO4)Cl

3.883

(010)-p

Sr2KNb5O15

Insoluble

Sr2KTa5O15

Insoluble

Sr2NaNb5O15

5.19

Insoluble

Sr2Nb2O7

5.204

Insoluble

Sr2Ta2O7

7.074

Insoluble

SrAl2Ge2O8

3.714

Insoluble

SrAl2O4

3.554

SrAl2Si2O8

3.13

Insoluble

SrAl4O7

3.266

SrB2O4

3.350

SrCO3

3.79

3.5 (Mohs)

(010)-i

Very slightly soluble

SrGa2O4

4.85

SrGa2Si2O8

3.797

Insoluble

SrGd2O4

7.287

Insoluble

SrIn2O4

6.854

SrLu2O4

8.496

Insoluble

SrNb2O6

Insoluble

SrSc2O4

Insoluble

SrSiO3

3.66

Insoluble

SrSO4

3.97

3 (Mohs)

(001)-p

Insoluble

SrTa2O6

Insoluble

SrY2O4

5.344

SrZnGe2O6

Insoluble

TeO2

6.00

2 (Mohs)

(010)-p

Very slightly soluble

TlNbB2O6

(001)-p

Insoluble

TlTaB2O6

(001)-p

Insoluble

V2O5

3.37

Y2(MoO4)3

3.3

Very soluble

Y2(WO4)3

(010)-p

Very soluble

Y2BeO4

4.582

Insoluble

Y2GdSbO7

6.443

Insoluble

Y2GdTaO7

7.102

Insoluble

Y2GeO5

Insoluble

Y2MgBe2Si2O10

4.152

6.5 (Mohs)

None

Insoluble

Y2MoO6

5.366

Y2O2SO4

4.813

Y2Si2O7

4.3

6 (Mohs)

None

Insoluble

Y2SiO5

4.543

6.5 (Mohs)

None

Insoluble

© 2003 by CRC Press LLC

Physical Properties of Biaxial Crystalline Materials—continued

Biaxial

Density

Hardness

Cleavage

Solubility (ºC)

material

(g/cm3)

(kg/mm2)

plane

(g/100 g H2O)

Y2Ti2SiO9

Insoluble

Y2WO6

6.818

Y3SbO7

5.699

Insoluble

Y3TaO7

6.413

Insoluble

Y4Al2O9

4.518

Insoluble

YAlO3

5.35

1030–1450

(110)-p

Insoluble

YCa4O(BO3)3

6–6.5 (Mohs)

None

Insoluble

YCaGaBe2Si2O10

4.107

6.5 (Mohs)

None

Insoluble

YF3

5.056

YGd2Nb2O9

6.802

Insoluble

YHfTaO6

8.13

Insoluble

YNbO4

5.58

Insoluble

YP5O14

Insoluble

YScO3

4.94

Insoluble

YTaO4

7.579

Insoluble

YTiTaO6

6.51

Insoluble

Zn3(AsO3)2

4.27

5 (Mohs)

(110)-i

Insoluble

Zn3(BO3)2

4.12

ZnB4O7

3.07

ZnWO4

7.87

ZrO2

5.82

6.5 (Mohs)

(001)-p

Insoluble

© 2003 by CRC Press LLC

1.3 Optical Properties*

The optical properties of crystals in this section are grouped into three tables: isotropic crystals, uniaxial crystals, and biaxial crystals. Materials are listed alphabetically in order of the chemical formulas. The following properties are included:

Transmission Range: Electronic and lattice absorption edges are given in terms of the wavelengths between which the transmission of a 1-mm-thick sample at 300 K is 10%. The values cited are approximate and are intended to as a general guide because many factors such as impurities, imperfections, temperature, crystallographic orientations, and compositional variations can affect the values.

Band Gap: Band gap data for transitions at room temperature unless noted otherwise. The energy gap depends on the structure of the material and varies with direction in anisotropic crystals. Optical transition: (D) – direct, (I) – indirect.

Refraction Index (n): For isotropic crystals, there is only one refractive index. Uniaxial crystals with tetragonal, hexagonal, and trigonal (or rhombohedral) symmetry exhibit a unique index of refraction (symbolized as e or ε) when light vibrates parallel to the c-axis (the extraordinary ray). For light vibrating at 90° to the c-axis (the ordinary ray), the refractive indices are the same (symbolized as o or ω) in all 360° directions. Biaxial crystals with orthorhombic, monoclinic, and triclinic symmetry possess three significant indices of refraction, commonly symbolized as x, y, z or α, β, γ in the order from smallest to largest.

Unless specified, the refraction indices are the average values for standard daylight or are the values measured at 632.8 nm at room temperature (the differences in the daylight and He-Ne values are within 0.1%). In a few instances, e.g., tellurides, these materials are opaque to visible light so that the refractive indices are measured with an infrared light source. In these cases, the wavelength used is listed with parentheses.

Birefringence (n): Birefringence of anisotropic materials is a measure of the maximum difference of the refractive indices within a crystal for a given wavelength.

Dispersion formulas: Refractive indices at specific wavelengths within specified ranges can be derived from dispersion formulas given in Section 1.3.4. Note that several different functional forms have been used to represent the dispersion of the refractive index.

Thermooptic coefficients (dn/dt): Thermooptic coefficients of optical crystals at various wavelengths are given in Section 1.3.5.

* This section was adapted from “Optical crystals” by B. H. T. Chai, Handbook of Laser Science and Technology, Suppl. 2, Optical Materials (CRC Press, Boca Raton, FL, 1995), p. 3 ff (with additions).

© 2003 by CRC Press LLC