- •Preface
- •The Author
- •Contributors
- •Table of Contents
- •1.1 Introduction*
- •1.2.1 Isotropic Crystals
- •1.2.2 Uniaxial Crystals
- •1.2.3 Biaxial Crystals
- •1.3.1 Isotropic Crystals
- •1.3.2 Uniaxial Crystals
- •1.3.3 Biaxial Crystals
- •1.3.4 Dispersion Formulas for Refractive Indices
- •1.3.5 Thermooptic Coefficients
- •1.4 Mechanical Properties
- •1.4.1 Elastic Constants
- •1.4.2 Elastic Moduli
- •1.4.3 Engineering Data
- •1.5 Thermal Properties
- •1.5.1 Melting Point, Heat Capacity, Thermal Expansion, and Thermal Conductivity
- •1.5.2 Temperature Dependence of Heat Capacity for Selected Solids
- •1.5.3 Debye Temperature
- •1.6 Magnetooptic Properties
- •1.6.1 Diamagnetic Materials
- •1.6.2 Paramagnetic Materials
- •1.6.3 Ferromagnetic, Antiferromagnetic, and Ferrimagnetic Materials
- •1.7 Electrooptic Properties
- •1.7.1 Linear Electrooptic Coefficients
- •1.7.2 Quadratic Electrooptic Materials
- •1.8 Elastooptic Properties
- •1.8.1 Elastooptic Coefficients
- •1.8.2 Acoustooptic Materials
- •1.9 Nonlinear Optical Properties
- •1.9.1 Nonlinear Refractive Index*
- •1.9.2 Two-Photon Absorption*
- •1.9.3 Second Harmonic Generation Coefficients
- •1.9.4 Third-Order Nonlinear Optical Coefficients
- •1.9.5 Optical Phase Conjugation Materials*
- •2.1 Introduction
- •2.2 Commercial Optical Glasses
- •2.2.1 Optical Properties
- •2.2.3 Mechanical Properties
- •2.2.4 Thermal Properties
- •2.3 Specialty Optical Glasses
- •2.3.1 Optical Properties
- •2.3.2 Mechanical Properties
- •2.3.3 Thermal Properties
- •2.4 Fused (Vitreous) Silica*
- •2.5 Fluoride Glasses
- •2.5.1 Fluorozirconate Glasses
- •2.5.2 Fluorohafnate Glasses
- •2.5.3 Other Fluoride Glasses
- •2.6 Chalcogenide Glasses
- •2.7 Magnetooptic Properties
- •2.7.1 Diamagnetic Glasses
- •2.7.2 Paramagnetic Glasses
- •2.8 Electrooptic Properties
- •2.9 Elastooptic Properties
- •2.10 Nonlinear Optical Properties
- •2.10.1 Nonlinear Refractive Index*
- •2.10.2 Two-Photon Absorption
- •2.10.3 Third-Order Nonlinear Optical Coefficients
- •2.10.4 Brillouin Phase Conjugation
- •2.11 Special Glasses
- •2.11.1 Filter Glasses
- •2.11.2 Laser Glasses
- •2.11.3 Faraday Rotator Glasses
- •2.11.4 Gradient-Index Glasses
- •2.11.5 Mirror Substrate Glasses
- •2.11.6 Athermal Glasses
- •2.11.7 Acoustooptic Glasses
- •2.11.8 Abnormal Dispersion Glass
- •3.1 Optical Plastics
- •3.2 Index of Refraction
- •3.3 Nonlinear Optical Properties
- •3.4 Thermal Properties
- •3.5 Engineering Data
- •4.1 Physical Properties of Selected Metals
- •4.2 Optical Properties
- •4.3 Mechanical Properties
- •4.4 Thermal Properties
- •4.5 Mirror Substrate Materials
- •5.1 Introduction
- •5.2 Water
- •5.2.1 Physical Properties
- •5.2.2 Absorption
- •5.2.3 Index of Refraction
- •5.3 Physical Properties of Selected Liquids
- •5.3.1 Thermal conductivity
- •5.3.2 Viscosity
- •5.3.3 Surface Tension
- •5.3.4 Absorption
- •5.4 Index of Refraction
- •5.4.1 Organic Liquids
- •5.4.2 Inorganic Liquids
- •5.4.3 Calibration Liquids
- •5.4.4 Abnormal Dispersion Liquids
- •5.5 Nonlinear Optical Properties
- •5.5.1 Two-Photon Absorption Cross Sections
- •5.5.2 Nonlinear Refraction
- •5.5.3 Kerr Constants
- •5.5.4 Third-Order Nonlinear Optical Coefficients
- •5.5.5 Stimulated Raman Scattering
- •5.5.6 Stimulated Brillouin Scattering
- •5.6 Magnetooptic Properties
- •5.6.1 Verdet Constants of Inorganic Liquids
- •5.6.2 Verdet Constants of OrganicLiquids
- •5.6.3 Dispersion of the Verdet Constants
- •5.7 Commercial Optical Liquids
- •6.1 Introduction
- •6.2 Physical Properties of Selected Gases
- •6.3 Index of Refraction
- •6.4 Nonlinear Optical Properties
- •6.4.2 Two-Photon Absorption
- •6.5 Magnetooptic Properties
- •6.6 Atomic Resonance Filters
- •Appendices
- •Safe Handling of Optical Materials
- •Fundamental Physical Constants
- •Units and Conversion Factors
5.DeShazer, L. G.,Rand, S. C., and Wechsler, B. A., Laser crystals, Handbook of Laser Science and Technology,Vol. V: Optical Materials, Part 3 (CRC Press, Boca Raton, FL, 2000), p. 595.
6.Wechsler, B. A. and Sumida, D. S., Laser crystals, Handbook of Laser Science and Technology, Suppl. 2: Optical Materials (CRC Press, Boca Raton, FL, 2000), p. 595.
7.Browder, J. S., Ballard, S. S., and Klocek, P., Physical property comparisons of infrared optical materials, Handbook of Infrared Optical Materials (Marcel Dekker, New York, 1991).
1.5.2 Temperature Dependence of Heat Capacity for Selected Solids
Temperature dependence of the molar heat capacity at constant pressure for representative crystalline solids and semiconductors in the range 200 to 600 K.
Molar Heat Capacity Cp in J/mol K
Name |
200 K |
250 K |
300 K |
400 K |
500 K |
600 K |
|
Al2O3 |
51.12 |
67.05 |
79.45 |
88.91 |
106.17 |
112.55 |
|
66.50 |
75.66 |
83.82 |
91.51 |
104.52 |
109.86 |
||
CaCO3 |
|||||||
|
|
|
|
|
|
||
CaO |
33.64 |
38.59 |
42.18 |
45.07 |
49.33 |
50.72 |
|
CsCl |
50.13 |
51.34 |
52.48 |
53.58 |
56.90 |
59.10 |
|
Cu2O |
34.80 |
— |
42.41 |
44.95 |
49.19 |
50.83 |
|
77.01 |
89.25 |
99.25 |
107.65 |
127.19 |
136.31 |
||
CuSO4 |
|||||||
|
|
|
|
|
|
||
Ge |
— |
— |
23.25 |
23.85 |
24.96 |
25.45 |
|
KCl |
48.44 |
50.10 |
51.37 |
52.31 |
54.71 |
56.35 |
|
LiCl |
43.35 |
46.08 |
48.10 |
49.66 |
53.34 |
55.59 |
|
MgO |
— |
— |
37.38 |
40.59 |
45.56 |
47.30 |
|
NaCl |
46.89 |
48.85 |
50.21 |
51.25 |
53.96 |
55.81 |
|
Si |
15.64 |
18.22 |
20.04 |
21.28 |
23.33 |
24.15 |
|
SiO2 |
32.64 |
39.21 |
44.77 |
49.47 |
59.64 |
64.42 |
|
|
|
|
|
|
|
||
|
|
|
|
|
|
|
References:
Chase, M. W., et al., JANAF Thermochemical Tables, 3rd ed., J. Phys. Chem. Ref. Data, 14, (1985). Garvin, D., Parker, V. B., and White, H. J., CODATA Thermodynamic Tables (Hemisphere Press, New York, 1987).
DIPPR Database of Pure Compound Properties, Design Institute for Physical Properties Data, (American Institute of Chemical Engineers, New York, 1987).
1.5.3 Debye Temperature
References:
1.Tropf, W. J., Thomas, M. F., and Harris, T. J., Properties of crystals and glasses, Handbook of Optics, Vol. II (McGraw-Hill, New York, 1995), p. 33.51.
2.Physics, 82nd edition, Lide, D. R., Ed. (CRC Press, Boca Raton, FL, 2001), p. 12-87.
© 2003 by CRC Press LLC
|
Debye |
|
Material |
temperature (K) |
Ref. |
AgBr |
145 |
1 |
AgCl |
162 |
1 |
AgGaS2 |
255 |
1 |
AgGaSe2 |
156 |
1 |
AgGaTe2 |
212 |
2 |
β-AgI |
116 |
1 |
Al2O3 |
1030 |
1 |
AlAs |
417 |
2 |
AlN |
950 |
1 |
AlP |
588 |
2 |
AlSb |
292 |
2 |
BaF2 |
283 |
1 |
BeO |
1280 |
1 |
BN |
1900 |
1 |
BP |
985 |
1 |
C (diamond) |
2240 |
1 |
CaF2 |
510 |
1 |
CdGeS2 |
253 |
1 |
CdS |
215 |
1 |
CdSe |
181 |
1 |
CdSiP2 |
282 |
2 |
CdSnP2 |
195 |
2 |
CdTe |
160 |
1 |
CsBr |
145 |
1 |
CsCl |
175 |
1 |
CsI |
124 |
1 |
Cu2GeS3 |
254 |
2 |
Cu2GeSe3 |
168 |
2 |
Cu2SnS3 |
214 |
2 |
Cu2SnSe3 |
148 |
2 |
Cu3AsSe4 |
169 |
2 |
Cu3SbSe4 |
212 |
2 |
CuCl |
179 |
1 |
CuGaS2 |
356 |
1 |
CuInTe2 |
195 |
2 |
GaAs |
344 |
1 |
GaP |
460 |
1 |
GaSb |
320 |
2 |
Ge |
380 |
1 |
HgTe |
242 |
2 |
InP |
321 |
2 |
InAs |
249 |
2 |
|
Debye |
|
Material |
temperature (K) |
Ref. |
InSb |
144 |
2 |
KBr |
174 |
1 |
KCl |
235 |
1 |
KF |
336 |
1 |
KI |
132 |
1 |
KTaO3 |
311 |
1 |
LaF3 |
392 |
1 |
LiF |
735 |
1 |
LiNbO3 |
560 |
1 |
MgAl2O4 |
850 |
1 |
MgF2 |
535 |
1 |
MgO |
950 |
1 |
NaBr |
225 |
1 |
NaCl |
321 |
1 |
NaF |
492 |
1 |
NaI |
164 |
1 |
PbF2 |
225 |
1 |
PbS |
227 |
1 |
PbSe |
138 |
1 |
PbTe |
125 |
1 |
Se |
151 |
1 |
Si |
645 |
1 |
β-SiC |
1000 |
1 |
SiO2, α-quartz |
271 |
1 |
SrF2 |
378 |
1 |
Te |
152 |
1 |
TiO2 |
760 |
1 |
Tl[Br,Cl], KRS-6 |
120 |
1 |
Tl[Br,I] KRS-5 |
110 |
1 |
TlBr |
116 |
1 |
TlCl |
126 |
1 |
Y2O3 |
465 |
1 |
Y3Al5O12 |
754 |
1 |
ZnGeAs2 |
271 |
2 |
ZnGeP2 |
428 |
1 |
ZnO |
416 |
1 |
α-ZnS |
351 |
1 |
β-ZnS |
340 |
1 |
ZnSe |
270 |
1 |
ZnTe |
225 |
1 |
ZrO2:12%Y2O3 |
563 |
1 |
© 2003 by CRC Press LLC
