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1.4.2 Elastic Moduli

The mechanical response of a material to an applied force is described by various moduli. Young’s modulus E (extension in tension) and the modulus of rigidity or shear G are related to Poisson’s ratio (ratio of lateral to longitudinal strain under unilateral stress) by = E/2G) – 1. The bulk modulus B (1/isothermal compressibility) is related to the above moduli by B = E/3(1 – ).

Elastic Moduli

 

 

 

Moduli

 

 

Poisson’s

Young’s

Rigidity

Bulk

Material

ratio

E (GPa)

G (GPa)

B (GPa)

Ag3AsS3

0.38

28

10

37

AgBr

0.39

24.7

8.8

40.5

AgCl

0.41

22.9

8.1

44.0

AgGaS2

0.37

52

19

67

β–AgI

0.4

12

4.4

24

AlAs

0.27

108

42.4

77.2

AlN

0.26

294

117

202

Al2O3

0.23

400

162

250

ALON

0.24

317

128

203

BaB2O4

0.41

30

11

60.6

BaF2

0.31

65.8

25.1

57.6

BaTiO3

0.36

145

53

174

BeAl2O4

469

BeO

0.23

395

162

240

Bi12GeO20

0.28

82

32

63.3

Bi12SiO20

0.28

84

33

63.1

BN

0.11

833

375

358

BP

0.19

324

136

172

C (diamond)

0.10

1100

500

460

CaCO3

0.31

83

32

73.2

CaF2

0.29

110

42.5

85.7

CaLa2S4

0.25

96

38.4

64

CaMoO4

0.29

103

40

80

CaWO4

0.29

96

37

78

CdGeS2

0.32

74

28

70

CdS

0.38

42

15

59

CdSe

0.37

42

15.3

53

CdTe

0.35

8.4

14.2

42.9

CsBr

0.27

22

8.8

15.8

CsCl

0.27

25

10.0

18.2

CsI

0.26

18

7.3

12.6

CuCl

0.30

24.8

8.9

39.3

GaAs

0.24

116

46.6

75.0

GaN

0.25

294

118

195

GaP

0.24

140

56.5

89.3

© 2003 by CRC Press LLC

Elastic Moduli—continued

 

 

 

Moduli

 

 

Poisson’s

Young’s

Rigidity

Bulk

Material

ratio

E (GPa)

G (GPa)

B (GPa)

Ge

0.20

132

54.8

75.0

InAs

0.30

74

28

61

InP

0.30

89

34

72.7

KBr

0.30

18

7.2

15.2

KCl

0.29

22

8.5

18.4

KF

0.28

41

16

31.8

KH2PO4

0.26

38

15

28

KI

0.30

14

5.5

11.9

KNbO3

0.22

250

71

95

KTaO3

0.27

316

124

230

LaF3

0.32

120

46

100

LiF

0.22

110

45

65.0

LiIO3

0.23

55

22.4

33.5

LiNbO3

0.25

170

68

112

LiSrAlF6

0.3

109

LiYF4

0.32

85

32

81

MgAl2O4

0.26

276

109

198

MgF2

0.26

137

53.9

99.1

MgO

0.18

310

131

163

NaBr

0.26

29

11.6

19.9

NaCl

0.26

37

14.5

25.3

NaF

0.24

76

30.7

48.5

NaI

0.28

22

8.4

16.1

[NH4] 2CO

0.41

~9

~3

17

NH4H2PO4

0.32

29

11

27.9

PbF2

0.33

59.8

22.4

60.5

PbMoO4

0.35

66

24

72

PbS

0.28

70.2

27.5

52.8

PbSe

0.28

64.8

25.4

48.5

PbTe

0.26

56.9

22.6

39.8

Se

0.27

24

9

17

Si

0.22

162

66.2

97.7

α–SiC

0.16

455

197

221

β–SiC

0.17

447

191

224

β–SiC (CVD)

0.21

466

SiO2, α–quartz

0.08

95

44

38

SrF2

0.29

89

34.6

71.3

SrMoO4

0.30

87

33

73

SrTiO3

0.23

283

115

174

Te

0.25

35

14

24

TeO2

0.33

45

17

46

TiO2

0.27

293

115

215

© 2003 by CRC Press LLC

Elastic Moduli—continued

 

 

 

Moduli

 

 

Poisson’s

Young’s

Rigidity

Bulk

Material

ratio

E (GPa)

G (GPa)

B (GPa)

TlBr

0.32

24

8.9

22.4

Tl[Br,I] KRS-5

0.34

19.6

7.3

20.4

TlCl

0.33

25

9.3

23.8

Tl[Br,Cl], KRS-6

0.33

24

9.0

32.2

Y3Al5O12

0.24

280

113

180

Y3Fe5O12

0.29

200

Y2O3

0.30

173

67

145

ZnO

0.35

127

47

144

α-ZnS

0.30

87

33

74

β-ZnS

0.32

82.5

31.2

76.6

β-ZnS (CVD)

0.29

74.5

ZnSe

0.30

75.4

29.1

61.8

ZnSe (CVD)

0.28

70.3

 

 

ZnTe

0.30

61.1

23.5

51.0

ZrO2: 12%Y2O3

0.31

233

88.6

205

The above table was adapted from Tropf, W. J., Thomas, M. F., and Harris, T. J., Properties of crystals and glasses, Handbook of Optics, Vol. II (McGraw-Hill, New York, 1995), p. 33.48.

1.4.3 Engineering Data

The following engineering properties can depend on the production method and exhibit sample–to–sample variations. Material strength may also depend on subsurface damage resulting from grinding and polishing. Therefore, the data should be considered only as a guide.

Engineering Data

 

Flexure

Fracture

Volume

 

 

strength

toughness

compressibility

 

Material

(MPa)

(MPa m1/2)

(Tpa–1)

Ref.

AgCl

26

 

 

1

AgSb

 

 

57.1

4

Al2O3

1200

3

1.36 || c

1

 

 

 

1.22 || a

1

AlN

225

3

 

1

Al23O27N5

310

1.4

 

1

α-AgI

 

 

41

4

BaB2O4

 

1.5

 

1

BaF2

27

 

 

1

Be3Al2Si6O18

 

 

6.65

2

BeO

275

 

 

1

C (diamond)

2940

2.0

 

1

© 2003 by CRC Press LLC

Engineering Data—continued

 

Flexure

Fracture

Volume

 

 

strength

toughness

compressibility

 

Material

(MPa)

(MPa m1/2)

(TPa–1)

Ref.

Ca5(PO4)3F

 

 

 

13.2

 

2

CaF2

90

0.5

 

11.64

1,2

CaLa2S4

81

0.68

 

 

 

1

CaMoO4

 

 

 

12.5

 

2

CaWO4

 

 

 

13.3

 

2

CdS

28

 

 

 

 

1

CdSe

21

 

 

 

 

1

CdSiAs2S4

 

 

 

4.3

 

4

CdTe

26

 

 

 

 

1

CsBr

8.4

 

 

 

 

1

CsI

5.6

 

 

 

 

1

GaAs

55

 

 

77.1

 

1,4

GaN

70

 

 

 

 

1

GaP

100

0.9

 

11.0

 

1,4

GaSbs

 

 

 

45.7

 

4

Gd2(MoO4)3

 

 

 

27.2

 

2

Gd3Ga5O12

 

 

 

5.88

2

Gd3Sc2Ga3O12

 

1.2

 

 

 

3

Ge

100

0.66

 

 

 

1

InAs

 

 

 

54.9

 

4

InP

 

 

 

73.5

 

4

InSb

 

 

 

44.2

 

4

KBr

11

 

 

 

 

1

KCl

10

 

 

 

 

1

KMgO3

 

 

 

14.4

 

2

LaB3O6

 

1.9 (111)

 

 

 

 

 

0.38 (10–1)

 

 

 

LaF3

33

 

 

 

 

1

LiB3O5

 

2.0

 

 

 

 

LiCaAlF6

 

0.18 ||

c

 

 

3

 

 

0.37 c

 

 

3

LiF

27

 

 

15.05

1,2

LiNbO3

 

 

 

8.8

 

2

LiSrAlF6

 

0.40 ||

c

 

 

3

LiYF4

35

 

 

 

 

1

Lu3Al5O12

 

1.1

 

 

 

3

MgAl2O4

170

1.5

 

 

 

1

MgF2

100

 

 

10.1

 

1

MgO

130

1.0

 

6.2

 

1

MnF2

 

 

 

4.3

|| a

2

 

 

 

 

2.0

c

2

© 2003 by CRC Press LLC

Engineering Data—continued

 

Flexure

Fracture

Volume

 

 

strength

toughness

compressibility

 

Material

(MPa)

(MPa m1/2)

(TPa–1)

Ref.

NaCl

9.6

 

 

 

 

1

Si

130

0.95

 

 

 

1

β-SiC

250

 

 

 

 

1

β-SiC (CVD)

 

3.3

 

 

 

 

Sr5(PO4)3F

 

0.51

 

 

 

3

Sr5(VO4)3F

 

0.36

||

c

 

3

Te

11

 

 

 

 

1

Tl[Br,Cl], KRS-6

21

 

 

 

 

1

Tl[Br,I] KRS-5

26

 

 

 

 

1

Y2.25Yb0.75Al5O12

 

1.3

 

 

 

3

Y2O3

150

0.7

 

 

 

1

Y2SiO5

 

0.54

||

a

 

3

 

 

0.70

||

b

 

3

 

 

0.78

||

c

 

3

Y3Al5O12

 

1.0, 1.4

 

3

Y3Al5O12

 

 

 

 

5.34

2

Y3Fe5O12

 

 

 

 

6.15

2

Y3Ga5O12

 

 

 

 

5.73

2

α-ZnS

69

 

 

 

 

1

β-ZnS (CVD)

60

0.8

 

 

 

1

ZnSe

55

0.32

 

 

 

1

ZnSe (CVD)

52

1

 

 

 

 

ZnTe

24

 

 

 

 

1

ZrO2: 12%Y2O3

200

2.0

 

 

 

1

 

 

 

 

 

 

 

References:

1.Tropf, W. J., Thomas, M. F., and Harris, T. J., Properties of crystals and glasses, Handbook of Optics, Vol. II 2 (McGraw–Hill, New York, 1995), p. 33.48.

2.DeShazer, L. G., Rand, S. C., and Wechsler, B. A., Laser crystals, Handbook of Laser Science and Technology,Vol. IV: Optical Materials, Part 3 (CRC Press, Boca Raton, FL, 1987), p. 595.

3.Wechsler, B. A. and Sumida, D. S., Laser crystals, Handbook of Laser Science and Technology, Suppl. 2: Optical Materials (CRC Press, Boca Raton, FL, 1995), p. 595.

4.Berger, L. I. and Pamplin, B. R., Properties of semiconductors, CRC Handbook of Chemistry and Physics, 82nd edition, Lide, D. R., Ed. (CRC Press, Boca Raton, FL, 2001), p. 12–87.

© 2003 by CRC Press LLC