Варианты заданий к самостоятельной работе №2 Задача №2
Таблица 2
№ |
Реакция |
n |
ko |
Ea, кДж/ моль |
T1 |
T2 |
% |
исх. конц моль |
1 |
HI + C2H5I ® С2H6 + I2 |
2 |
5,0.1013 |
124 |
250 |
400 |
30 |
2 |
2 |
C6H5ONa + C3H7I® C6H5OC3H7 + NaI |
2 |
3,5 .1011 |
93,6 |
300 |
500 |
50 |
2 |
3 |
HI + CH3I ® CH4 + I2 |
2 |
2,0.1014 |
140 |
300 |
600 |
60 |
1 |
4 |
2N2O5 ® 2N2O4 + O2 |
1 |
4,6.1013 |
103,5 |
450 |
650 |
10 |
1 |
5 |
2O3 ® 2O2 |
2 |
6,3.1018 |
117,9 |
300 |
500 |
70 |
1 |
6 |
(CH3CO)2O+C2H5OH® СH3COOC2H5+ CH3COOH |
2 |
4,1.105 |
56,0 |
300 |
500 |
30 |
1 |
7 |
C2H5ONa + CH3I ® C2H5OCH3 + NaI |
2 |
2,4.1011 |
81,5 |
300 |
450 |
40 |
2 |
8 |
H2 + I2 ® 2HI |
2 |
1,6.1014 |
165,5 |
400 |
600 |
60 |
1 |
9 |
2HI ® H2 + I2 |
2 |
9,2.1013 |
186,4 |
500 |
300 |
40 |
1 |
10 |
C2H5Cl ® C2H4 + HCl |
1 |
4,0.104 |
248 |
300 |
500 |
20 |
2 |
11 |
H2 + C2H4 ® C2H6 |
2 |
4,0.1013 |
180,5 |
300 |
600 |
50 |
1 |
12 |
NO + Cl2 ® NOCl + Cl |
2 |
4,0.1012 |
85 |
500 |
300 |
80 |
2 |
13 |
C2H5Br ® C2H4 + HBr |
1 |
7,2.1012 |
218 |
300 |
400 |
50 |
1 |
14 |
CO2 + OH- ® HCO3- |
2 |
1,5.1013 |
38,2 |
300 |
350 |
60 |
1 |
15 |
2NO2 ® 2NO + O2 |
2 |
9,4.1012 |
112,6 |
400 |
600 |
50 |
1 |
16 |
C2H4 + H2 ® C2H6 |
2 |
4,0.1013 |
180 |
150 |
200 |
50 |
2 |
17 |
H2 + BrCl ® HBr + HCl |
2 |
2,0.1014 |
50 |
300 |
400 |
40 |
1 |
18 |
NO· + Br2 ® NOBr + Br· |
2 |
4,0.1012 |
95 |
200 |
350 |
70 |
2 |
19 |
2N2O5 ® 2N2O4 + O2 |
1 |
4,6.1013 |
103,5 |
400 |
600 |
30 |
3 |
20 |
(C2H5)3N + C2H5Br ® (C2H5)4NBr |
2 |
2,8.1012 |
46,8 |
300 |
450 |
60 |
1 |
21 |
N2O4 ® 2NO2 |
1 |
1,1.106 |
54,4 |
400 |
500 |
20 |
2 |
22 |
C6H5CH2ONa + C4H9I ® C6H5CH2OC4H9 + NaI |
2 |
2,9.1011 |
90,1 |
300 |
450 |
40 |
1 |
23 |
OH· + H2 ® H2O + H· |
2 |
1,6.1015 |
41,8 |
900 |
1200 |
50 |
1 |
24 |
C2H5Br ® C2H4 + HBr |
1 |
7,2.1012 |
218 |
300 |
400 |
60 |
2 |
25 |
H2 + ICl ® HI + HCl |
2 |
1,6.1015 |
41,8 |
500 |
650 |
70 |
1 |
26 |
C2H5Cl ® C2H4 + HCl |
1 |
4,0.1014 |
247,5 |
400 |
500 |
50 |
2 |
27 |
2N2O5 ® 2N2O4 + O2 |
1 |
4,6.1013 |
103,5 |
400 |
300 |
450 |
1 |
28 |
HI + CH3I ® CH4 + I2 |
2 |
2,0.1014 |
140 |
400 |
700 |
70 |
2 |
29 |
N2O4 ® 2NO2 |
1 |
1,1.106 |
54,4 |
350 |
600 |
40 |
2 |
30 |
SO2(г) + H2 ® S(к) + 2H2O(г) |
2 |
4.1012 |
98,2 |
300 |
500 |
20 |
4 |