Organic Reaction Mechanisms 1997
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Organic Reaction Mechanisms, 1997 An Annual Survey Covering the Literature Dated December 1996 to November 1997 Edited by A.C. Knipe and W.E. Watts Copyright © 2001 John Wiley & Sons, Ltd
ISBNs: 0-471-89935-6 (Hardback); 0-470-84580-5 (Electronic)
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M
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J
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K J
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Me Me
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R2 |
5 |
R |
3 |
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R1 |
N |
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N |
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Ph |
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O |
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(1) |
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(2) |
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S 2 |
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3 |
X |
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6 |
O |
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X = NH, O, S |
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(3) |
(4) |
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Br |
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(6) |
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R1 |
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H |
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OMe |
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X |
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But |
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R2 |
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Y |
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(7) |
(8) a; X = O, S; Y = S |
(9) |
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+ |
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b; X = O, S; Y = SBr |
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J
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O |
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Me Me |
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O2N |
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R |
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R HO3S |
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H |
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Me Me |
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H |
N |
HO3S |
N |
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NO2 |
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H |
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(10) |
(11) |
(12) |
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(13) |
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R = H, Me, Br |
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J
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R
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N |
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N |
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3 |
N |
N NH2 |
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(14) |
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(15) |
R = OR1, NHR1
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# #
# #
# #
M
$
Me
ClCH2 C CH2Br
ClCH2 |
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C |
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CH2Br |
X |
X |
Ph |
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Me |
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CHPh2 |
+ |
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(16) |
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(17) |
(18) |
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M K
K
M M #
$
$ $
M
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OC12H25
OC12H25
C12H25O |
C12H25O |
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(25) |
(26) |
! " ! "
M
! "
O
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* |
CO2H |
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N |
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Cl(CH3)2SiCPh2Me |
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H |
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(27) |
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(28) |
eecan be >95%
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M
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K K
! "
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OMe |
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OMe |
Cl3C |
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Me |
OMe |
Me |
OMe |
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O |
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O |
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H |
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HO2C |
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O |
Br |
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(29) |
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O |
H |
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(30) |
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O |
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H |
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(31) |
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OH |
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N |
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O |
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MeO N |
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O |
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N |
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MeO |
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N |
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(32) |
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(33) |
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– |
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SO3SO3H |
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H SO3SO3 |
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+ |
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Me |
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Me |
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(34) |
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(35) |
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J
J
Me
O SO2
Me
Me |
Me |
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(36) |
(37) |
K M