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2.26

 

SECTION 2

 

 

 

TABLE 2.6 Abbreviations and Standard Letter Symbols

 

 

 

 

 

 

 

 

 

 

 

Abampere

abamp

 

Angular momentum

 

 

Absolute

abs

 

Angular momentum terms

j, J, l, L, N

Absolute activity

 

 

Angular velocity

6

 

Absorbance (decaidic)

A

 

Anhydrous

anhyd

 

 

Absorbance (napierian)

B

 

Approximate (circa)

ca.

 

 

Absorptance

 

 

Aqueous solution

aq

 

 

Absorption coefficient, linear

a, K

 

Aqueous solution at infinite

aq,

 

decaidic

 

 

dilution

 

 

 

Absorption coefficient, linear

 

 

Are, unit of area

a

 

 

napierian

 

 

Area

A, S

Absorption coefficient, molar

, "

 

Area per molecule

a ,

decaidic

 

 

Astronomical unit

AU

 

 

Absorption coefficient, molar

 

 

Asymmetry parameter

 

 

 

napierian

 

 

Atmosphere, unit of pressure

atm

 

 

Absorption index

k

 

Atomic mass

m

a

 

Acceleration

a

 

Atomic mass constant

m

u

 

Acceleration due to gravity

g, gn

 

Atomic mass unit

amu

 

 

Acetyl

Ac

 

Atomic number

Z

 

 

Acoustic absorption factor

a

 

Atomic percent

at.%

 

 

Acoustic dissipation factor

 

 

Atomic weight

at. wt.

Acoustic reflection factor

 

 

Average

av

 

 

Acoustic transmission factor

(

 

Average linear gas velocity

 

 

Activation energy

E a

 

Avogadro constant

L, NA

Activity (referenced to

a

 

Axial angular momentum

, 1, 5

Raoult’s law)

 

 

Axial spin angular momen-

,

Activity (referenced to

 

 

tum

 

 

 

Henry’s law):

 

 

Bandwidth (10%) of a spec-

0.1

Concentration basis

a c

 

tral filter

 

 

 

Molality basis

a m

 

Band variance

2

 

Mole fraction basis

a x

 

Bar, unit of pressure

bar

 

 

Activity (radioactive)

A

 

Barn, unit of area

b

 

 

Activity coefficient (refer-

f

 

Barrel

bbl

 

enced to Raoult’s law)

 

 

Base of natural logarithms

e

 

 

Activity coefficient (refer-

 

 

Becquerel

Bq

 

 

enced to Henry’s law):

 

 

Bed volume

V

g

 

Concentration basis

c

 

Beta particle

 

 

 

Molality basis

m

 

Bloch function

u k (r )

Mole fraction basis

x

 

Body-centered cubic

bcc

 

 

Adjusted retention time

tR

 

Bohr

b

 

Adjusted retention volume

V R

 

Bohr magneton

B

 

Admittance

Y

 

Bohr radius

a 0

 

Affinity of reaction

A

 

Boiling point

bp

 

 

Alcohol

alc

 

Boltzmann constant

k ,

k B

Alfve ´n number

Al

 

Bragg angle

 

 

 

Alkaline

alk

 

Breadth

b

 

Alpha particle

 

 

British thermal unit

Btu

 

 

Alternating current

ac

 

Bulk modulus

K

 

 

Amorphous

am

 

Bulk strain

 

 

 

Amount concentration

c

 

Burgers vector

b

 

 

Amount of substance

n

 

Butyl

Bu

 

 

Ampere

A

 

Calorie, unit of energy

cal

 

 

Amplification factor

 

 

Calorie, international steam

cal

IT

Angle of optical rotation

 

 

table

 

 

 

Angstrom

A ˚, A

 

Candela

cd

 

 

Angular dispersion

d /d

 

Capacitance

C

 

 

 

 

 

 

 

 

 

GENERAL INFORMATION, CONVERSION TABLES, AND MATHEMATICS

 

 

 

2.27

TABLE 2.6 Abbreviations and Standard Letter Symbols (

Continued

)

 

 

 

 

 

 

 

Capacity, volume

Q V

Concentration of solute in

C

S

Capacity, weight

Q W

stationary phase

 

 

Cartesian space coordi-

x, y, z

Condensed phase (solid or

cd

 

nates

 

 

liquid)

 

 

 

Celsius temperature

t,

Conductance

 

G

 

Centimeter-gram-second

cgs

Conductivity

 

,

system

 

 

Conductivity cell constant

K

cell

Centrifugal distortion con-

 

 

Conductivity tensor

ik

stants:

 

 

Contact angle

 

 

 

A reduction

,

Coordinate, position vector

r

 

S reduction

D, d

 

Coulomb

 

C

 

Charge density of electrons

 

 

Counts per minute

cpm, c/m

 

Charge number of electro-

n

 

Coupling constant, direct di-

D

AB

chemical reaction

 

 

polar

 

 

 

Charge number of an ion

z

 

Critical density

 

d c

 

Chemically pure

C

P

Critical temperature

tc

 

Chemical potential

 

Cross section

 

 

 

Chemical shift

 

 

Crystalline

 

cr, cryst

Circa (approximate)

ca.

 

Cubic

 

cub

 

Circular frequency

6

Cubic expansion coefficient

, v,

Circular wave vector:

 

 

Curie

 

Ci

 

For particles

k

 

Cycles per second

 

Hz

 

For phonons

q

 

Curie temperature

T c

Circumference divided by

 

Dalton (atomic mass unit)

Da

 

the diameter

 

 

Day

 

d

 

Citrate

Cit

Debye, unit of electric dipole

D

 

Coefficient of heat transfer

h

 

Debye circular frequency

6D

Collision cross section

 

Debye circular wave-number

q D

 

Collision diameter

d

 

Debye-Waller factor

D,

B

Collision frequency

Z

 

Decay constant (radioactive)

 

 

Collision frequency factor

z

 

Decibel

 

dB

 

Collision number

Z

 

Decompose

 

dec

 

Column volume

V col

Degeneracy, statistical

d, g,

Compare (confer)

cf.

 

weight

 

 

 

Complex refractive index

 

Degree of dissociation

 

 

Component of angular mo-

k, K, m, M

Degrees Baume

 

Be

mentum

 

 

Degrees Celsius

 

C

 

Compressibility:

 

 

Degrees Fahrenheit

F

 

Isentropic

S

Density (mass)

 

,

Isothermal

T

Density, critical

 

d c

 

Compression factor

Z

 

Density, relative

d

 

Compression modulus

K

 

Density of liquid phase

L

 

Compton wavelength of elec-

c

Density of states

 

N E ,

tron

 

 

Density of vibrational modes

N 6

Compton wavelength of neu-

c,n

(spectral)

 

 

 

tron

 

 

Detect, determine (d)

det(d)

 

Compton wavelength of

c,p

Determination

 

detn

 

proton

 

 

Deuteron

 

d

 

Concentration (amount of

c

 

Diamagnetic shielding factor

1

 

substance)

 

 

Diameter

 

d

 

Concentration (mass)

 

 

Dielectric polarization

P

 

Concentration at peak

C

max

Differential thermal analysis

DTA

 

maximum

 

 

Diffusion coefficient

D

 

Concentration of solute in

C

M

Diffusion coefficient, liquid

D

f

mobile phase

 

 

film

 

 

 

 

 

 

 

 

 

 

2.28

 

 

 

SECTION 2

 

 

 

 

TABLE 2.6 Abbreviations and Standard Letter Symbols (

 

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Diffusion coefficient, mobile

D

 

M

 

Electron magnetic moment

 

e

phase

 

 

 

 

Electron paramagnetic reso-

 

EPR

Diffusion coefficient, station-

D

 

S

 

nance

 

 

 

 

ary phase

 

 

 

 

Electron radius

 

 

re

 

Diffusion current

id

 

 

 

Electron rest mass

 

m

e

Diffusion length

L

 

Electron spin resonance

ESR

 

 

Diffusion rate constant, mass

k d

 

 

Electronvolt

 

 

eV

 

transfer coefficient

 

 

 

 

Electrostatic unit

 

esu

 

Dilute

dil

 

 

 

Elementary charge

 

e

 

Dirac delta function

 

 

 

 

Elution volume, exclusion

 

V

e

Direct current

dc

 

 

 

chromatography

 

 

 

Direct dipolar coupling con-

D

 

AB

 

Emittance

 

 

"

 

stant

 

 

 

 

By blackbody

 

 

M

bb

Disintegration energy

Q

 

 

Energy

 

 

E

 

Disintegrations per minute

dpm

 

 

 

Energy density

 

 

w

,

Displacement vector of an

u

 

 

 

Energy per electron hole

 

"

 

ion

 

 

 

 

pair of ion pair in detector

 

 

 

Dissociation energy

D, E d

 

Enthalpy

 

 

H

 

From ground state

D

 

0

 

Entropy

 

 

S

 

From the potential mini-

D

 

e

 

Entropy unit

 

 

e.u.

mum

 

 

 

 

Equilibrium constant

 

K, K 0

Distribution ratio

D

 

 

 

Concentration basis

 

K

c

Donor ionization energy

E d

 

Molality basis

 

 

K

m

Dropping mercury electrode

dme

 

 

 

Pressure basis

 

K

p

Dyne, unit of force

dyn

 

 

 

Equilibrium position vector

 

R

0

Einstein transition probabili-

A, B

 

of an ion

 

 

 

 

ties

 

 

 

 

Equivalent weight

 

equiv wt

Spontaneous emission

A

 

nm

 

Erg, unit of energy

 

erg

 

Stimulated absorption

B

 

mn

 

Especially

 

 

esp.

 

Stimulated emission

B

 

nm

 

et alii (and others)

 

et al.

Electric charge

Q

 

 

et cetera (and so forth)

 

etc.

Electric current

I

 

 

Ethyl

 

 

Et

 

Electric current density

j, J

 

Ethylenediamine

 

en

 

 

Electric dipole moment of a

p,

 

 

Ethylenediamine-

N,N,N ,N -

EDTA

molecule

 

 

 

 

tetraacetic acid

 

 

 

Electric displacement

D

 

 

 

Euler number

 

 

Eu

Electric field gradient

q

 

 

 

Exempli gratia (for example)

e.g.

 

Electric field strength

E

 

 

 

Expansion coefficient

 

 

 

Electric flux

 

 

Exponential

 

 

exp

 

Electric mobility

u ,

 

Extent of reaction

 

 

 

Electric polarizability of a

 

 

 

Fano factor

 

 

F

 

molecule

 

 

 

 

Farad

 

 

F

 

Electric potential

V ,

 

Faraday constant

 

 

F

 

Electric potential difference

U, V

 

Fermi, unit of length

f

 

 

Electric susceptibility

0e

 

Fermi energy

 

 

E F

Electrical conductivity

 

 

 

Film tension

 

 

f

Electrical conductance

G

 

 

 

Film thickness

 

 

h,

t

Electrical resistance

R

 

 

 

Fine structure constant

 

 

 

Electrochemical transfer co-

 

 

 

Finite change

 

 

 

efficient

 

 

 

 

First radiation constant

 

c 1

Electrokinetic potential

%

 

 

 

Flow rate

 

 

q

 

Electromagnetic unit

emu

 

 

 

Flow rate, column chroma-

 

F c

Electromotive force

E , emf

 

tography

 

 

 

 

Electron

e

 

 

Fluid phase (gas or liquid)

 

 

 

,e

 

 

 

Electron affinity

E ea

 

Fluidity

 

 

 

GENERAL INFORMATION, CONVERSION TABLES, AND MATHEMATICS

 

 

2.29

TABLE 2.6 Abbreviations and Standard Letter Symbols (

Continued

)

 

 

 

 

 

 

Fluorescent efficiency

F

Helmholtz energy

 

A

Fluorescent power

P

F

Henry

 

H

Flux

F, J

Hertz

 

Hz

Focal length

f

 

Hexagonal

 

hex

Foot

ft

 

Horsepower

 

hp

For example (exempli gratia)

e.g.

 

Hour

 

h

Force

F

 

Hygroscopic

 

hygr

Force constant (vibrational

k

 

Hyperfine coupling constant

a, A

levels)

 

 

Hyperfine coupling tensor

T

Formal concentration

F

 

ibidem (in the same place)

ibid.

Fourier number

Fo

id est (that is)

 

i.e.

Franklin, unit of electric

Fr

Ignition

 

ign

charge

 

 

Impedance

 

Z

Freezing point

fp

 

Inch

 

in

Frequency

f, v

Indices of a family of crys-

hkl

Friction coefficient

f,

 

tallographic planes

 

Froude number

Fr

Indirect spin-spin coupling

J AB

Fugacity

f

 

constant

 

 

Fugacity coefficient

 

Inductance

 

L

Gallon

gal

 

Inertial defect

 

 

Galvani potential difference

 

Infinitesimal change

 

Gamma, unit of mass

 

 

Infrared

 

ir

Gamma radiation

 

 

Inner column volume

V i

Gap energy (solid state)

E g

Inner electric potential

 

Gas (physical state)

g

 

Inner electrode potential

 

Gas constant

R

 

Inorganic

 

inorg

Gauss

G

 

Inside diameter

 

i.d.

gfactor

g

Insoluble

 

insol

Gibbs energy

G

 

Interatomic distances:

 

Grade

grad

Equilibrium distance

re

Grain, unit of mass

gr

 

Ground-state distance

r0

Gram

g

 

Substitution structure dis-

rs

Grand partition function

 

tance

 

 

Grashof number

Gr

Zero-point average

rz

Gravimetric

grav

distance

 

 

Gravitational constant

G

 

Internal energy

U

Gray

Gy

 

Interstitial (outer) volume

V o

Gru¨neisen parameter

,

In the place cited (loco ci-

loc. cit.

Half-life

t1/2

tato)

 

 

Half-wave potential

E 1/2

In the same place

 

ibid.

Hall coefficient

A

H , R H

In the work cited

op. cit.

Hamilton function

H

 

Ionic conductivity

, 1

Harmonic vibration wave-

6

Ionic strength

 

I

number

 

 

Concentration basis

Ic

Hartmann number

Ha

 

Molality basis

 

Im

Hartree energy

E h

Ionization energy

E i

Heat

q, Q

Irradiance

 

E

Heat capacity

C

 

Joule

 

J

At constant pressure

C

p

Joule-Thomson coefficient

, JT

At constant volume

C

v

Kelvin

 

K

Heat flow rate

 

Kilocalorie

 

kcal

Heat flux

J

 

Kilogram

 

kg

Hectare, unit of area

ha

 

Kilogram-force

 

kgf

Height

h

 

Kilowatt-hour

 

kWh

Helion

h

 

Kinematic viscosity

v,

 

 

 

 

 

 

2.30

 

 

 

 

SECTION 2

 

 

 

 

TABLE 2.6

Abbreviations and Standard Letter Symbols (

 

Continued

)

 

 

 

 

 

 

 

 

 

 

 

 

Kinetic energy

 

K, T, E k

 

Mass number

 

A

 

 

Knudsen number

 

Kn

 

 

 

Mass of atom

 

m,

m

a

Kovats retention indices

RI

 

 

 

Mass transfer coefficient

k d

 

 

Lagrange function

 

L

 

 

Matrix volume

 

V g

 

Lambda, unit of volume

 

 

 

 

Maximum

 

max

 

 

Lande ´g-factor

 

g, ge

 

Maxwell, unit of magnetic

Mx

 

Larmor circular frequency

6L

 

 

flux

 

 

 

 

Larmor frequency

 

vL

 

 

Mean ionic activity

a

 

Lattice plane spacing

d

 

 

 

Mean ionic activity coeffi-

 

 

Lattice vector

 

R,

R

0

 

cient

 

 

 

 

Lattice vectors

 

a,

b,

c

 

Mean ionic mobility

 

W

 

 

Length

 

l, L

 

Melting point

 

mp

 

 

Length of arc

 

s

 

 

 

Metallic

 

met

 

 

Lewis number

 

Le

 

 

Metastable

 

m

 

 

Light year

 

l.y.

 

 

Metastable peaks

 

m

*

 

Limit (mathematics)

 

lim

 

 

 

Meter

 

m

 

 

Linear expansion coefficient

1

 

 

Methyl

 

Me

 

 

Linear reciprocal dispersion

D

1, d /dx

 

Micrometer

 

m

 

Linear strain

 

e , "

 

 

Micron

 

 

 

Liquid

 

l, lq

 

 

Mile

 

mi

 

 

Liquid crystal

 

lc

 

 

 

Miller indices

 

h, l, k

Liter

 

L, 1

 

 

Milliequivalent

 

meq

 

 

loco citato (in the place

loc. cit.

 

Millimeters of mercury, unit

mmHg

 

cited)

 

 

 

 

 

of pressure

 

 

 

 

Logarithm, common

 

log

 

 

 

Millimole

 

mM

 

 

Logarithm, base

e

ln

 

 

 

Minimum

 

min

 

 

Longitudinal relaxation time

T

1

 

 

Minute

 

m, min

 

 

Lorenz coefficient

 

L

 

 

Mixture

 

mixt

 

Loss angle

 

 

 

 

 

Mobility

 

 

 

Lumen

 

lm

 

 

 

Mobility ratio

 

b

 

Luminous intensity

 

I

 

 

 

Modulus of elasticity

E

 

 

Lux

 

lx

 

 

 

Molal

 

m

 

 

Mach number

 

Ma

 

 

Molality

 

b

 

Madelung constant

 

 

 

 

Molar

 

M,

M

Magnetic dipole moment of

m,

 

 

Molar (decadic) absorption

"

 

 

a molecule

 

 

 

 

 

coefficient

 

 

 

 

Magnetic field strength

H

 

 

 

Molar ionic conductivity

, 1

Magnetic flux

 

 

 

 

Molar magnetic suscepti-

0m

 

Magnetic flux density

 

B

 

 

 

bility

 

 

 

 

Magnetic moment of protons

p / B

 

Molar mass

 

M

 

 

in water

 

 

 

 

 

Molar quantity

X

X

m

 

Magnetic quantum number

M

j

 

 

Molar refraction

R, R

m

Magnetic Reynolds number

Rm

 

 

 

Molar volume

 

V

m

 

Magnetic susceptibility

, 0

 

Mole

 

mol

 

 

Magnetic vector potential

A

 

 

 

Mole fraction, condensed

x

 

 

Magnetizability

 

 

 

 

 

phase

 

 

 

 

Magnetization

 

M

 

 

 

Gaseous mixtures

y

 

 

Magnetogyric ratio

 

 

 

 

Mole percent

 

mol %

 

 

Mass

 

m

 

 

 

Molecular weight

mol wt

 

 

Mass absorption coefficient

/ , m

 

Moment of inertia

I, J

 

Mass concentration

 

,

 

 

Momentum

 

p

 

 

Mass density

 

 

 

 

 

Monoclinic

 

mn

 

 

Mass flow rate

 

q m

 

 

Monomeric form

 

mon

 

 

Mass fraction

 

w

 

 

 

Muon, negative

 

 

 

Massieu function

 

J

 

 

 

Muon, positive

 

 

 

 

 

 

 

 

 

 

 

 

 

 

GENERAL

INFORMATION, CONVERSION TABLES, AND MATHEMATICS

 

 

 

2.31

TABLE 2.6 Abbreviations and Standard Letter Symbols (

Continued

)

 

 

 

 

 

 

 

 

 

Mutual inductance

M, L

 

 

Outer diameter

 

o.d.

Napierian absorbance

B

 

 

 

Outer electric potential

3

Napierian base

e

 

 

 

Overall order of reaction

n

 

Napierian molar absorption

 

 

 

 

Overpotential

 

 

coefficient

 

 

 

 

Oxalate

 

Ox

 

Neel temperature

T

N

 

 

Oxidant

 

ox

 

Net retention volume

V

N

 

 

Packing uniformity factor

 

Neutrino

ve

 

 

Page(s)

 

p. (pp.)

Neutron

n

 

 

 

Parsec, unit of length

pc

 

Neutron magnetic moment

N

 

 

Partial molar quantity

X

 

Neutron number

N

 

 

 

Partial order of reaction

n B

Neutron rest mass

m

n

 

 

Particle diameter

d p

Newton

N

 

 

 

Particle position vector:

 

 

Normal concentration

N

 

 

 

Electron

 

r

 

Normal stress

 

 

 

Ion position

 

R

j

Nuclear magnetic resonance

NMR

 

 

 

Partition coefficient

K

 

Nuclear magneton

N

 

 

Partition function

q, Q, z, Z, 5

Nuclear spin angular mo-

I

 

 

 

Partition ratio

k

mentum

 

 

 

 

Parts per billion, volume

ng/mL

 

Nucleon number

A

 

 

 

Parts per billion, weight

ng/g

 

Number concentration

C

 

 

 

Parts per million, volume

g/mL

Number density

n

 

 

 

Parts per million, weight

/g

Number of entities

N

 

 

 

Pascal

 

Pa

 

Numerical aperture

NA

 

 

 

Path length (absorbing)

l

 

Nusselt number

Nu

 

 

Peak asymmetry factor

AF

Obstruction factor

 

 

 

 

Peak resolution

 

Rs

Oersted, unit of magnetic

Oe

 

 

 

Pe ´clet number

 

Pe

 

field

 

 

 

 

Peltier coefficient

 

Ohm

5

 

 

Percent

 

%

 

opere citato (in the work

op. cit.

 

 

Period of time

 

T

 

cited)

 

 

 

 

Permeability

 

 

Optical speed

f/number

 

 

Permeability of vacuum

0

Orbital angular momentum:

 

 

 

 

Permittivity

 

"

 

Quantum number

L 0, 1, 2, 3,

. .

.Permittivity of vacuum

"0

Series symbol

 

S, P, D, F,

. .

.pH, expressed in activity

p

a H

Orbital angular momentum

 

 

 

 

Expressed in molarity

pH

 

(molecules):

 

 

 

 

Phenyl

 

Ph,

 

Quantum number

1 0, 1, 2, . . .

 

Phosphorescent efficiency

-P

Symbol

 

, , , . . . Phosphorescent power

P

P

Orbital angular momenta of

l

0, 1, 2, 3,

. . . Photochemical yield

 

 

individual electrons

 

s, p, d, f, . . .

Photoluminescence power

P

 

Order of Bragg reflection

n

 

 

 

Photon

 

 

Order of reaction

n

 

 

 

Pion

 

 

Order of reflection

n

 

 

 

Planck constant

 

h

 

Order parameters (solid

s

 

 

 

Planck constant/2

 

 

state), long range

 

 

 

 

Planck function

 

Y

 

Short range

 

 

 

Plane angle

 

, , , ,

Organic

org

 

 

Plate height

 

H

 

Orthorhombic

o-rh

 

 

 

Plate number, effective

N eff

Osmotic coefficient

 

 

 

Poise

 

P

 

Molality basis

m

 

 

Polymeric form

 

pol

 

Mole fraction basis

x

 

 

Porosity, column

 

"

 

Osmotic pressure (ideal di-

 

 

 

Positron

 

 

lute solution)

 

 

 

 

Potential energy

 

V , -, E P

Ounce

oz

 

 

 

Pound

 

lb

 

 

 

 

 

 

 

 

 

 

2.32

SECTION 2

 

TABLE 2.6 Abbreviations and Standard Letter Symbols (

Continued

)

Pounds per square inch

 

psi

 

Powder

 

pwd

 

Power

 

p

 

Poynting vector

 

S

 

Prandtl number

 

Pr

 

Pressure (partial)

 

p

 

Pressure (total)

 

p, P

 

Pressure coefficient

 

 

 

Pressure, column inlet

 

p i

 

Pressure, column outlet

 

p o

 

Pressure, critical

 

p c

 

Pressure drop

 

P

 

Pressure-gradient correction

j

 

Principal moments of inertia

 

IA ;IB ;IC

Principal quantum number

 

n

 

Probability

 

P

 

Probability density

 

P

 

Product sign

 

 

 

Propyl

 

Pr

 

Proton

 

p

 

Proton magnetic resonance

 

pmr

 

Proton magnetrogyric ratio

 

p

 

Proton number

 

Z

 

Proton rest mass

 

m p

 

Pyridine

 

py

 

Quadrupole interaction en-

 

 

 

ergy tensor

 

 

 

Quadrupole moment of a

 

Q, )

molecule

 

 

 

Quantity of electricity, elec-

 

Q

 

tric charge

 

 

 

Quantum of energy

 

hv

 

Quantum yield

 

 

 

Rad, unit of radiation dose

 

rad

 

Radian

 

rad

 

Radiant energy

 

Q, W

Radiant energy density

 

, w

Radiant energy flux

 

dQ

/dt

Radiant exitance

 

M

 

Radiant flux received

 

E

 

Radiant intensity

 

I

 

Radiant intensity at time

t

I(t)

after termination of excita-

 

 

 

tion

 

 

 

Radiant power

 

-

 

Radiant power incident on

 

P 0

 

sample

 

 

 

Radiofrequency

 

rf

 

Radius

 

r

 

Rate of concentration change

 

r

 

Rate constant

 

k

 

Rate of reaction

 

v

 

Ratio of heat capacities

 

 

 

Reactance

 

X

 

Reciprocal lattice

 

a *,

b *, c *

Reciprocal lattice vector (cir-

G

 

 

 

cular)

 

 

 

 

 

Vectors for

 

a *;

b *,

c *

Reciprocal radius of ionic at-

 

 

 

 

 

mosphere

 

 

 

 

 

Reciprocal temperature pa-

 

 

 

 

 

rameter, 1/ kT

 

 

 

 

 

Reciprocal thickness of dou-

 

 

 

 

 

ble layer

 

 

 

 

 

Reduced column length

 

 

 

 

 

Reduced mass

 

 

 

 

Reduced plate height

 

h

 

 

 

Reduced velocity

 

v

 

 

 

Reductant

 

red

 

 

 

Reference

 

ref

 

 

 

Reflectance

 

 

 

 

 

Reflection plane

 

 

 

 

 

Refractive index

 

n

 

 

 

Relative permeability

 

r

 

 

Relative permittivity (dielec-

 

"r

 

 

tric constant)

 

 

 

 

 

Relative pressure coefficient

 

p

 

 

Relative retention ratio

 

 

 

 

 

Relaxation time

 

(

 

 

 

Rem, unit of dose equivalent

rem

 

 

 

Residual resistivity (solid

 

R

 

 

state)

 

 

 

 

 

Resistivity tensor

 

 

 

 

 

Retardation factor

 

R

f

 

 

Retarded van der Waals con-

 

B

,

 

stant

 

 

 

 

 

Retention time

 

tR

 

 

 

Retention volume

 

V

R

 

 

Revolutions per minute

 

rpm

 

 

 

Reynolds number

 

Re

 

 

 

Rhombic

 

rh

 

 

 

Rhombohedral

 

rh-hed

 

 

 

Roentgen

 

R

 

 

 

Root-mean-square

 

rms

 

 

 

Rotational constants:

 

 

 

 

 

In frequency

 

A, B, C

 

In wavenumber

 

˜

˜

˜

 

A ; B ; C

Rotational term (spectros-

 

F

 

 

 

copy)

 

 

 

 

 

Rotation-reflection

 

S n

 

 

Rydberg, unit of energy

 

Ry

 

 

 

Rydberg constant

 

R, R

 

 

 

Saturated

 

satd

 

 

 

Saturated calomel electrode

 

SCE

 

 

 

Schmidt number

 

Sc

 

 

 

Second

 

s

 

 

 

Second radiation constant

 

c 2

 

 

Second virial coefficient

 

B

 

 

 

Sedimentation coefficient

 

s

 

 

 

Selectivity coefficient

 

k

 

 

 

GENERAL INFORMATION, CONVERSION TABLES, AND MATHEMATICS

 

2.33

TABLE 2.6 Abbreviations and Standard Letter Symbols (

Continued

)

Self-inductance

L

Separation factor

 

Shear modulus

G

Shear strain

 

Shear stress

(

Sherwood number

Sh

Shielding constant (NMR)

 

Short-range order parameter

 

Siemens

S

Sievert

Sv

Signal-to-noise ratio

S /N

Slightly

sl

Solid

c, s

Solid angle

6, 5

Solid angle over which lumi-

5F(P,DF)

nescence is measured (F,

 

fluorescence; P, phospho-

 

rescence; DF, delayed flu-

 

orescence)

 

Solid angle over which radi-

5A

ation is absorbed in cell

 

Solubility

s

Soluble

sol

Solution

soln, sln

Solvent

solv

Sound energy flux

P, P a

Spacing between crystal dif-

d

fracting planes

 

Species adsorbed on a sub-

ads

stance

 

Specific gravity

sp gr

Specific retention volume

V g0

Specific surface area

s

Specific volume

v,

Spectral bandwidth of emis-

em

sion monochromator

 

Spectral bandwidth of excita-

ex

tion monochromator

 

Spectral bandwidth of mono-

m

chromator

 

Spectral radiant energy

Q , dQ /d

Spectral radiant energy den-

 

sity:

 

In terms of frequency

, w

In terms of wavelength

, w

In terms of wavenumber

˜, w ˜

Spectral radiant energy flux

d /d

Spectroscopic splitting factor

g

Speed

u, w

Speed of light:

 

In a medium

c

In vacuum

c 0

Spherical polar coordinates

r, ,

Spin angular momentum

s, S

Spin-lattice relaxation time

T 1

Spin orbit coupling constant

A

 

 

Spin-spin coupling constant

J AB

 

Spin-spin (or transverse) re-

T

2

 

laxation time

 

 

 

Spin wavefunctions

,

Square

sq

 

 

Standard

std

 

 

Standard enthalpy of activa-

H

 

 

tion

 

 

 

Standard enthalpy of forma-

Hf 0

tion

 

 

 

Standard entropy

S

0

 

Standard entropy of activa-

S

tion

 

 

 

Standard Gibbs energy of ac-

G

 

tivation

 

 

 

Standard Gibbs energy of

Gf 0

formation

 

 

 

Standard heat capacity

C

p

 

Standard hydrogen electrode

SHE

 

 

Standard partial molar en-

H

0

 

thalpy

 

 

 

Standard partial molar en-

S

0

 

tropy

 

 

 

Standard potential of electro-

E 0

 

chemical cell reaction

 

 

 

Standard reaction enthalpy

rH

0

Standard reaction entropy

rS

0

Standard reaction Gibbs en-

rG

0

ergy

 

 

 

Standard temperature and

STP

 

pressure

 

 

 

Stanton number

St

 

 

Statistical weight

W,

, 6

Statistical weight of atomic

g

 

states

 

 

 

Stefan-Boltzmann constant

 

 

Steradian

sr

 

 

Stoichiometric number

v

 

 

Stokes

St

 

 

Summation sign

 

 

Surface charge density

 

 

Surface concentration

 

 

Surface coverage

 

 

 

Surface density

A , S

Surface electric potential

0

 

Surface pressure

 

 

Surface tension

,

Susceptance

B

 

 

Svedberg, unit of time

Sv

 

 

Symmetrical

sym

 

 

Symmetry coordinate

S

 

 

Symmetry number

s,

Tartrate

Tart

Temperature

, )

2.34

 

 

SECTION 2

 

 

 

TABLE 2.6 Abbreviations and Standard Letter Symbols (

 

Continued

)

 

 

 

 

 

 

 

 

 

Temperature, thermodynamic

T

 

 

Vibrational anharmonicity

0

 

Temperature at boiling point

T

b

 

constant

 

 

 

Term value spectroscopy

T

 

 

Vibrational coordinates:

 

 

Tesla

T

 

 

Internal coordinates

R i, rI , j, etc.

Tetragonal

tetr

 

Normal coordinates, di-

q r

Thermal conductance

G

 

 

mensionless

 

 

 

Thermal conductivity

, k

 

Mass adjusted

Q r

Thermal diffusivity

a

 

 

Vibrational force constants:

 

 

Thermal resistance

R

 

 

Diatomic

 

f

 

Thermoelectric force

E

 

 

Polyatomic, dimensionless

rst . .;.k rst . . .

Thickness of diffusion layer

 

 

 

normal coordinates

 

 

Thickness of layer

t

 

 

Internal coordinates

fij

Thickness (effective) of sta-

d f

 

Symmetry coordinates

F ij

tionary phase

 

 

 

Vibrational quantum number

v

 

Thickness of surface layer

(

 

 

Vibrational term

G

 

Thickness of various layers

 

 

 

Viscosity

 

,

Thomson coefficient

, (

 

Vitreous substance

vit

 

Thomson cross section

e

 

Volt

 

V

 

Time

t

 

 

Volt-ampere-reactive

var

 

Time interval, characteristic

T

, (

 

Volta potential difference

3

Tonne

t, ton

 

 

Volume

 

V, v

Torr (mm of mercury)

Torr

 

Volume flow rate

 

q v

Torque

T

 

 

Volume fraction

 

 

Total bed volume

V

tot

 

Volume in space phase

5

Total term (spectroscopy)

T

 

 

Volume liquid phase in col-

V

L

Transconductance

gm

 

umn

 

 

 

Transfer coefficient

 

 

Volume mobile phase in col-

V

M

Transit time of nonretained

tM

, t0

 

umn

 

 

 

solute

 

 

 

Volume of activation

V

Transition

tr

 

 

Volume percent

 

vol %

 

Transition dipole moment of

M,

R

 

Volume per volume

v/v

 

a molecule

 

 

 

Volume strain

 

 

 

Transition frequency

v

 

 

Watt

 

W

 

Transition wavenumber

 

 

Wavefunction

 

, 3, 2

Translation (circular)

b1;b2;b3

 

Wavelength

 

 

 

Translation vectors for

a 1 ; a 2 ; a 3

 

Wavenumber (in a medium)

 

 

crystal lattice

a ; b ; c

 

Wavenumber in vacuum

 

Transmission factor

(

 

 

Weber

 

Wb

 

Transmittance

T,

(

 

Weber number

 

We

 

Transport number

t

 

 

Weight

 

W

 

Transverse relaxation time

T

2

 

Weight of liquid phase

w

L

Triclinic

tric

 

Weight percent

 

wt %

 

Trigonal

trig

 

Weight per volume

w/v

 

Triton (tritium nucleus)

t

 

 

Wien displacement constant

b

Ultrahigh frequency

uhf

 

 

Work

 

w, W

Ultraviolet

uv

 

Work function

 

-

Unified atomic mass unit

u

 

 

x unit

 

X

 

United States Pharmacopoeia

USP

 

 

Yard

 

yd

 

Vacuum

vac

 

 

Young’s modulus

 

E

 

van der Waals constant

 

 

 

Zeeman splitting constant

B /hc

Vapor pressure

p , vp

 

Zone width at baseline

W

b

Velocity

u, w

 

Zone width at one-half peak

W

1/2

Versus

vs

 

 

height

 

 

 

 

 

 

 

 

 

 

 

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