
Новые достижения в химии и химической технологии растительного сырья. Материалы III всероссийской конференции. Книга 1 [2007]
.pdf!
!"#$%&'%!%!()&))!*%"+,-*#(')!.$/!-(%&&%&'!0!"+*%.#*1/+"2!*%"+,-& *%(#!.#3*-!"#3%!&%+*#2'!4%!#(!"5-"-6-(!6'$#!5-$17)&'!3,)!8*%!9##!
.)(#9)$$/$-:(!*%"+,-*#(')!,!#$)&&-(!,-3&-(!*%"+,-*)!;<=!#!,!#*)& &-(! *%"+,-*)! +%<='! >%$?&)@A))! 8*%!9#-*-,%)! -"1B)"+,$2$#! 51+)(! 5-"$)3-,%+)$?&-.-! -"%C3)! 5-$#-:! 0+%&-$-(! 5*#! *%:$#7&'D! "--+&-A)D!-6E)(-,!#"D-3&'D!,-3&-B)$-7&'D!*%"+,-*-,!5-$#"%D%&
*#3-,! #! -"%3#+)$2(! ,%-!.!#!(!$%"/0! ,1-!.!#!(!$%/0! ,"-!.!#!(!$%2/0! ,3-!.!#!(!#0! ,)-!.!#!(!#%"/'!F-$17)&&')! 5*)5%*%+'! .)(#9)$$/$-:! 5-3,)*.%$#! .#3*-& $#:1! ,! ")&&-@! "-$2&-@! !#"$-+)! 5*#! &%.*),%#'! =)@+*%$#:-,%&&')! #! 15%*)&&')!.#3*-$#:%+'!#"5-$?:-,%$#!3$2!"#&+):%!+*#()+#$"#$#$-,'D! 08#*-,!(-&-"%D%*#3-,%!%&%$#:!!-+-*'D!-"1B)"+,$2$#!()+-3-(!.%:-,-@! D*-(%+-.*%8##'!
G):1$?+%+'! D*-(%+-.*%8#*-,%! 4HI! 5*-#:,-3&'D! (-&-"%D%*#& 3-,! .#3*-$#:%+-,! .)(#9)$$/$-:%! 0!"+*%.#*-,%&&'D! ,-3&-B)$-7&'(#! *%"+,-*%(#! ,.#3*-!"#3-,! !%$#2! #! &%+*#2-! #! -"%C3)&&'D! 0+%&-$-(! 5*#! "--+&-A)#! -6E)(-,! ,*%"+,-*! 5-$#-:-(! ,-"%3#+)$?-! #!(!#%! #! 3%&&')! -! (-&-"%D%*#3&-(! "-"+%,)! ,")D! 8*%!9#@! .)(#9)$$/$-:%! 0!"+*%.#*1)('D!
#$)&&'(!#!#*)&&'(!,-3&'(#!*%"+,-*%(#!;<=!#!+%<=%!5-:,-$2/+!"3)& $%+?!"$)31/B#)!:%!$/7)!-!5*#*-3)!0!"+*%.#*1)('D!.)(#9)$$/$-:'!
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
.%+?%!7+-!5-$#-:&'@!!-(5$)!"%!0!"+*%.#*1)('@!#$)&&'(!,-3&'(!*%"& +,-*-(!;<=%!"-3)*C#+!6&7&()+#$.$/!1*-&-%*%6#&-!"#$%&'!
L-! 8*%!9#2D! ,"-8,)-! :%!-&-()*&-! #:()&2/+"2! (%""-,')! 3-$#! 4&.%$%!+-:'! #! 5&*%(&-:''! F-! ()*)! 6'"+*-.-! 1,)$#7)! !-&9)&+*%9##! -"%3#+)$2!&%6$/3%)+"2!6'"+*-)!1()&?A))!-+&-A)!,4&.%$%!+-:%-(,5& *%(&-:%-'!F-"!-$?!1!"!*-"+-(!-6E)(%!0+%&-$%!-"%C3%/+"2!5-$#"%D%*#3'!"! 5-C)&&-@! "+)5)&?/! 5-$#()*#:%9##%! (-C&-! "7#+%+?%! 7+-! 8*%!9##! ,"-%! ,3-%!,)-!"-3)*C%+!:!-(-$)!1$2*&'@!*%(&-.%$%!+%&'!
F*)-6$%3%/B#(#! (-&-"%D%*#3%(#! ,! .#3*-$#:%+%D! -+3)$?&'D! 8*%!9#@! .)(#9)$$/$-:%! 0!"+*%.#*1)('D! #*)&&'(! ,-3&'(! *%"+,-*-(!
"#$ !
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
!"#$%&'&($)*!+"(,-!)-.$#-!
)"&"!/012345#!6"&"!+5789:5#!;"<"!-854=529:5#!""%"!+>?9:34@A!
!"#$%&'$%(!)*'+,"&'-./001(!+0%./&'%-/-"!+2#!3&+04/"!$%"!
56"!&7*''%8'!()*+,-.!/0123456#4+57896#:6!
C5+(0/,%>5!%575)(%!!0!*5.035&&'&,->%!%4,<$705!%!),)(!%!%)54!/!' -5./>4!2!)(5/0A!0!/5+,(,2>4!%,<,2,)&5A%!:02,+,!2!)?2,)(2!/5/>!%!?20' 2,<5(!D!+)0.!&9/>A!%>4,<%!)(26+(62!!0!)25</$$!.,&5+6&$2/!$!.!))!!E(04! ?,&0)!4!20<,%!%,!./,*,.!-!%0)$(!,(!6)&,%0A!04!%><5&5/0$(!C25<)(!%&$&,! 0/(525)!0-6;0(9!%&0$/05!+,/35/(2!300!E+)(2!*026'75*,!25!*5/(!!0!%25'
.5/0! ?2,%5<5/0$! E+)(2!+300! /!! )25</''! .,&5+6&$2/6'! .!))6! %><5&$5'
.>4!?,&0)!4!20<,%(!"8F5+(,.!0))&5<,%!/0$!)(!&!+,25/9!<$*0&$(!
G! +!;5)(%5! E+)(2!*5/(!! ?5+(0/,%>4! %575)(%! 8>&! %>82!/! 2!)(%,2! ),&$/,A! +0)&,(>(! @+)(2!*02,%!/05! ?,&0)!4!20<,%! ?2,%,<0&0! ?20! 2#/#%!2#/"!%!(5;5/05!0!0!#1!;!?20!/!*25%!/00!<,!23!0!43!5H(!I>&,!6)' (!/,%&5/,%! ;(,! )/0B5/05! +,/35/(2!300! E+)(2!+300! 0! 6%5&0;5/05! %25'
.5/0!E+)(2!*02,%!/0$!?20%,<0(!+!2,)(6!%>4,<!!?5+(0/,%!)(!8&(!#*(! J!&55! <&$! ?5+(0/,%! 8>&0! ,?25<5&5/>! -/!;5/0$! 4!2!+(520)(0;5'
)+,A! %$-+,)(0! 6!7! %! %,<5(! J&$! ?5+(0/,%%! %><5&5//>4! 0-! +,2/$! <$*0&$%! ?,! 62!%/5/0'! D!2+!'K6/!'L!6%0/+!+! 6!7/"%#48#3928D3%0:! 8>&0! 2!));0' (!/>!-/!;5/0$!)25</5A!.,&5+6&$2/,A!.!))>!;!!)(!8&(!#*(!!
! |
"## |
!
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
?!)+#*4:<%>!&+04*%!0.,4!$&41%/%)4!@&+"6'4))4%!1./%,%)'%!ABC! '=!"4&):!/:9',:!$&'!"4()+*)4>!*%($%&+*2&%!$4#,%/41+*%,-)4>!40&+04*+ "4>!&+#*14&+('!.!'!#/0+)4>!1234!'!'=25%)4!1,':)'%!*%($%&+*2&.!8"#+ *&+9'&41+)':!)+!1.;4/!'!"+5%#*1%)).>!#4#*+1!ABC%!D+)).%!$4!1.;4/2! ABC!1!&+=,'5).;!2#,41':;!'=!"4&):!/:9',:!$&%/#*+1,%).!1!*+0,'6%!"%!
?'/)4'! 5*4! $&'! "4()+*)4>! *%($%&+*2&%! '! $&'! $&4/4,7'*%,-)4#*'! 8"#*&+9'&41+)':!#5!5!)+0,3/+3*#:!04,%%!1.#4"'%!=)+5%)':!1.;4/+!ABC%!!
E6%)%)+! &+#*14&'(4#*-! 9%('6%,,3,4=! 1! &+=,'5).;! &+#*14&'*%+ ,:;6! 14/%'! 0%)=4,%'! *4,24,%'! *%*&+;,4&(%*+)%'! *&';,4&(%*+)%'! 9%"#+)%%! F#*+)41,%)4'!5*4!$4,25%)).%!9%('6%,,3,4=.!)%!&+#*14&:3*#:!1!$%&%+ 5'#,%)).;!4&9+)'5%#"';!&+#*14&'*%,:;'!+!1!14/%!*4,-"4!)+02;+3*%!
G+0,'6+!#%! ?.;4/'!;+&+"*%&'#*'5%#"+:!1:="4#*-!7!8!'!#&%/)::! (4,%"2,:&)+:!(+##+!,!!$%"*')41.;!1%<%#*1!'=!"4&):!/:9',:!
H!! |
F#,41':!1./%,%)':! |
?.;4/'!0! |
7!8'!/,99! |
,!! |
(%*4/+! |
|
|
|
|
(! |
"!:!;!5'!&I!:!"'!<!:!5/!=J! |
#>'.! |
/'"! |
5///! |
((! |
"!:!;!5'!&I!:!#'!<!:!5/!=J! |
#;'.! |
/'5! |
#>///! |
(((! |
"!:!#?!5'!&I!:!"'!<!:!./!=J! |
"/';! |
/'.! |
#?///! |
(*! |
"!:!#?!5'!&I!:!#'!<!:!./!=J! |
#@'/! |
/'>! |
A.///! |
G+0,'6+!"%! ?.;4/!'!"+5%#*1%)).>!#4#*+1!9%('6%,,3,4=!'=!"4&):!/:9',:!
H!! |
F#,41':!1./%,%)':! |
?.;4/'! |
K+5%#*1%)).>!#4#*+1! |
(%*4/+! |
|
0! |
|
(! |
"!:!>!5'!.0!1234'!<!:!"?!=J! |
"A! |
A,3"4=+'!9+,+"*4=+'!(+))4=+%! |
|
"!:!>!5'!#/0!1234'!<!:!"?!=J |
;! |
A,3"4=+'!9+,+"*4=+! |
((! |
"!:!#5!5'!.0!1234'!<!:!"?!=J |
.#! |
A,3"4=+'!9+,+"*4=+! |
|
"!:!#5!5'!#/0!1234'!<:"?!=J |
#A! |
A,3"4=+'!9+,+"*4=+! |
(((! |
"!:!>!5'!.0!1234'!;4,4/! |
#>! |
A,3"4=+'!9+,+"*4=+! |
(*! |
"!:!#5!5'!.0!1234'!;4,4/! |
#@! |
A,3"4=+! |
"#" !
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
!"#$%&'()&**+,!"-&*!+!.&/$-#0#"1!!"23!
#$'()&**$-3!"$4$2'!"5!$!6+72'!"5!
*#*#!(89:;<9=>$!&#.#!/?@AB;C9=>$!*#)#!$=>B9=>$!)#+#!4>DC;B!
!"#$%'(!')&%'%$%!*'+''!'+"!,"-"!./01"y!34!5,6#!
!"#$%!$51&&'7%!&'()*+,!-)./012*/*034"*/5"/6!
F!)-,0$#B''!1&'+#!1!"*0'&-08&'!$0,80,018'0!.*+*<',7-#!.-&-70'( &*,0*7-! /'+*='""A"$6! 7$&5! "*,01'))*=5! ,*E*&,7$9! *! (-8&,7$9,!! I+'A0,#!"*J:!$0&51$<)5'!(-))5'!%$!7$"*<',01'))$9!$=')7'!$0('":( )5.! /&8%%%! 0-7*.! 7-7! ! "'/7$(! *! 0&8()$/*(&$"*68'+5'! %$"*,-.-&*(5%! /'7,$6-)5%! %')0$6-)5%! 8&$)$15'! 7*,"$05%! 1! 0$! 1&'+#! 7-7! ,0&8708&)5'! *,,"'($1-)*#%! &-1)$! 7-7! *! ,1'(')*#! $! 15('"')**! *)(*1*(8-":)5.! /'( +*='""A"$6!$0,80,018A0,!!
K708-":)$,0:!*68<')*#!/'+*='""A"$6%!7-7!*!%$"*,-.-&*($1!1!='"$+%! 6-7"A<-'0,#!1!%$6)-)**!<&'615<-9)$!,"$G)$9!0$)7$9!,0&8708&5!%&*&$(( )$9!+-7&$+$"'78"5%!0-7!*!1!J*&$7$+!(*-%-6$)'!E*$"$/*<',7$9!-70*1)$( ,0*!%$"*,-.-&*($1%!8,0-)$1"')**!7$&&'"#=*9!/,0&8708&-(-70*1)$,0:0,!!
F! I&IL! ?M! NK;! %&$1$(*0,#! +)$/$"'0)''! ,*,0'+-0*<',7$'! *68( <')*'!.*+*<',7$/$!,$,0-1-!7$&5!"*,01'))*=5!,*E*&,7$9!*!(-8&,7$9%!1! 0$+! <*,"'! *! %'70*)$15.! %$"*,-.-&*($1%! *! )-! O0$9! E-6'! 1! )-,0$#B''! 1&'+#!,$6(-'0,#!0'.)$"$/*#!O7,0&-7=*$))$9!%'&'&-E$07*!7$&5!,!%$"8(
! |
"#$ |
!
!"#$"%! &! '"(&)*! +!"(",-! %",$.$#/0$1! '("'2(23+&%! '("'2(23+&! '$4"& &+5+! $! /"6-/0+1+789/3&"##+5+! #27#2!"#$8'! :(",'+6252"3/8%! !3+! +/#+&& #;%$! '(+,)032%$! <),)3! 8&683-/8! &+/0%! 2#3$+0/$,2#3#;9! 0+%'6"0/%! &+,+(2/3&+($%;"!&"4"/3&2%!'"03$#;!$!/+(<"#3!(#)'!!
=!(2%021!>3$1!$//6",+&2#$9!&!,2##+9!(2<+3"!'(+&","#2!0+6$!"/3&"#& #28!+."#02!5"%$."66*6+7!0+(;!6$/3&"##$.;!/$<$(/0+9!$!,2)(/0+9'!?20@"! '(",/32&686+!$#3"("/!+'(","6"#$"!,+6$!'"03$#+&;1!'+6$/212($,+&!&!%2/& /"! )56"&+,#+5+! 0+%'6"0/2! 0+(;%! '+/0+6-0)! >3+3! '+02723"6-! +027;&2"3! &6$8#$"!#2!>0+#+%$!"/0$"!'2(2%"3(;!3"1#+6+5$$!'"("(2<+30$!0+(;'!
A+6+."66*6+7)! &;,"686$! !"("7! ,"6$5#$B$02.$*! '(",&2($3"6-#+! +<"//%+6"##+9!>3$62."323+%!0+(;!*&;1+,!>3$62."323#+5+!>0/3(2032!#+,! +3!&"/2!2</+6*3#+!/)1+5+!/;(-8!*&'2'/'/'--!/!'+%+4-*!#.,!#2,)0/)/#+9! 0$/6+3;! (")%! &;1+,! 1+6+."66*6+7;! /+/32&$6! $"%",! +3! &'2'/'/'! C"%$."6& 6*6+7;! ! '+6)!26$! &;/2@$&2#$"%! $7! /'$(32! B(20.$+#$(+&2##;1! +,! *B(20.$8!/-!$!#0%+,!*B(20.$8!//-!1234!!(2/3&+(+&!'+6$/212($,+&!$!+!$& /30$!$1!,$26$7+%!#2!."66+B2#+&;1!%"%<(2#21'!=;1+,;!B(20.$9!/+/32& &$6$! 5%#,! $! #%.,! +3! &'2'/'/'%! /++3&"3/3&"##+'! =! '(+,)0321! 5$,(+6$72! B(20.$$! /! '+%+4-*! DA! $,"#3$B$.$(+&2#;! 2(2<$#+72%! 526203+72%! 56*& 0+72%!0/$6+72%!B(20.$$!//!6!56*0+72%!%2##+72'!E+,"(@2#$"!!&."66*6+7;! $!6$5#$#2!&!0+("!/+/32&$6+!7$%#,!$!$#%5,!+3!&'2'/'/'!/++3&"3/3&"##+'!
=! FG6/'"03("! B(20.$$! /! /+,"(@$3/8! '+6+/2! '+56+4"#$8! #0+.! /%6#%! /++3&"3/3&)*428!'+56+4"#$*!/&+<+,#+9!02(<+0/$6-#+9!5()'';!&!/+/32&"! 0$/6;1!'+6$/212($,+&%!&!FG&/'"03("!B(20.$$!!//!!+#2!+3/)3/3&)"3'!?20$%! +<(27+%%!0$/6;"!'+6$/212($,;%!/+,"(@2#$"!0+3+(;1!&!0+("!6$/3&"##$.;! /+/32&68"3!"%0,!(7)%!/+/(",+3+!"#+!562%!+<(27+%!&!!/+/32&"!B(20.$$!!/'!!
:+!(2/!"3#;%!,2##;%!/+,"(@2#$"!'"03$#+&;1!'+6$/212($,+&!/+& /32&68"3! "8%0,! +3! /+,"(@2#$8! 5"%$."66*6+7! &! 0+("! 6$/3&"##$.;! /$& <$(/0+9!$!,2)(/0+9'!
H2<+32!&!,2##+%!#2'(2&6"#$$!'(+,+6@2"3/8'!
!"#$%'%&!
#'! D2<0$#! ='I'%! J/3(+)1+&2! K'I'%! L260+&! M'I'%! F&2#+&2! E'N'! $! ,('! H"/)(/+/<"("52*428! $! >0+6+5$!"/0$! <"7+'2/#28! '"("(2<+302! ,("&"/$#;!$!0+(;!6$/3&"##$.;!99!O2)02!6!'(+$7&+,/3&)'!"..$'!P"'!
"'! J<+6"#/028!I'='%!Q6-#$.028!N':'%!K"+#+&$!!I'I'!K2<+(23+(#;"!(2<+& 3;!'+!1$%$$!,("&"/$#;!$!."66*6+7;'!L'!#88#'!7".!/'!
7'! F&2#+&2!O'='%!J&+,+&2!H'C'%!D2<0$#!='I'!J<428!12(203"($/3$02!'+6$& /212($,+&! 0+(;! 6$/3&"##$.;! 99! A$%$8! (2/3$3"6-#+5+! /;(-8'! "..:'!
P#'!E'!#+6#8'!
"#$ !
!"#$%$&$'($!)!&$*+&,#'!-!).//0! "!&(/.1.#(%!2!(3!4$&+1(!(!/!&!)0!5#$6(1(!
&"."!3789:;<=>#$!/"2"!/:;<=7?;<=#$!$"%"!4@<?A9>#$!/"2"!B<8CAD%!
!!"#$%$&$"'%(%%")*+",-.#"/0$"!%%"12$"*134%56#$67&#"!&'#" *134%56#$67"(,6##%8)"
*9%'66723"#7%:"%"#$%$&$";%660<3"%=2#76:"'%(%%")*+",-.#"
*134%56#$67"(,6##%8)"+,-./01"23456/7.89:-./0$6;""
!"#$%$&'()*&!+,'%#"-".%/*!,0."123$!0,'(423!%!5(6"!5"7)23! 8.2++2!+.%.,/)*-!#,&/%)&)%9!%!28'&5,/,5!%!+.&/#$"5':3$!#,0,9!0*&
#$.,5,#+.,%15,/%6*&! ..#*! ,.8")%;<%-! 5&=$5! #! 2)%<"'()*6%! >%1%<,&-%6%;<%6%! %! 0%,',8%;<%6%! #5,9#$5"6%'! +.%5'&<"3=%6%! 5)%6")%&! -%6%<,5'! >".6"<,',8,5'! $,<#%<,',8,5! %! /.28%-! #+&?%"'%&
#$,5(! @5,9#$5"! +,'%#"-".%/,5! ,+.&/&':3$#:! %-! 6,),#"-".%/)*6! #,&
#$"5,6! %! 6,'&<2':.),9! 6"##,9(! A"%0,'&&! +,'),! %12;&)*! +,'%#"-".%& /*!%1!6,.#<%-!5,/,.,#'&9!)#*!%!5*#4%-!'&<".#$5&))*-!."#$&)%9!)"%+*'! ,0'"/"3=%-! 4%.,<%6! #+&<$.,6! >".6"<,',8%;<%-! B>>&<$,5(! @,& 8'"#),! ),*'! 0%,',8%;<,9! "<$%5),#$(3! ,0'"/"3$'! <"<! +."5%','! 28'&& 5,/)*&!#,&/%)&)%:!#,!#.&/)&9!%!6"',9!#$&+&)(3!+,'%6&.%1"?%%(!C,& '%#"-".%/*!%1!4&'2-%!%!#,',6*!8.&;%-%!%12;&)*!6"',(!
!")&&! )"6%! 0*'%! 5*/&'&)*! +,'%#"-".%/*! +,#'&/,5"$&'(),9! B<#& $."<?%&9! 5,/,9'! ,<#"'"$,6! "66,)%:! %! =&',;(3! %1! ,$-,/,5! +.,%15,/&
#$5"!8.&;%-%'!5*."=&)),9!5!C.%6,.#<,6'!D."#),:.#<,6'!E'$"9#<,6!%! D."#),/".#<,6! ! <.":-'! %! ,+.&/&'&)! ! %-! 6,),#"-".%/)*9! #,#$"5! )$*(! F#$"),5'&),!$"<7&!%)8%0%.23=&&!/&9#$5%&!5,/)*-!%!,<#"'"$)*-!B<#& $."<$,5!4&'2-%!8.&;%-%!-<"<!%!.%#".!)"!<,..,1%3!#$"'%!)/*(!!
A"#$,:=":! ."0,$"! :5':&$#:! +.,/,'7&)%&6! %##'&/,5")%9! +,'%#"-"&
.%/,5'!,+%#"))*-!5!)$*'!%!+,#5:=&)"!%12;&)%3!6&$,/,6!5*#,<,B>>&<$%5& ),9! B<#<'31%,)),9! -.,6"$,8.">%%! -GHHI.! 6,'&<2':.),&6"##,5,8,! ."#& +.&/&'&)%:! -JJ!.! 5! )%-! >."<?%90! 0&'<,5,&+,'%#"-".%/),8,! <,6+'&<#"! -KCD.'!+,'%#"-".%/,5!-C@.!%!)%1<,6,'&<2':.)*-!#,&/%)&)%9!-A@.(!!
L+.&/&'&)%&!JJ!!+,'%#"-".%/,5!+.,5,/%'%!6&$,/,6!GHHI!+,!6&& $,/%<&'!."1."0,$")),9!5!)1*(!E)"'%1!5*+,'):'%!)"!7%/<,#$),6!-.,6"$,&
8.">&!23456789!:;&"<=!>?@54ABACB!-M+,)%:.!#!.&>."<$,6&$.%;<%6!/&& $&<$,.,6!DEF<=!%!/&$&<$,.,6!)"!/%,/),9!6"$.%?&!2>F&G"<=(!!"1/&'&&
)%&! +.,5,/%'%! )"! <,',)<&! 23@7BH! =I634J6K! L2&$"<! MN! -23@O6! FBAK@'!
! |
"#$ |
!
!"#$%&%&! '()*$+! '! ,%-%.+%((%/#01$$1&! 0#-1&! .2#/#.+3! "#-0%4$#5! 6178! #!9((9%$)! :1(%,/#0#;$8*! 2/%08*! -(&! #"/*-*(*$%&! 9#(*2<(&/$#5! 91..8!
.+/#%(%! "#! .+1$-1/+19! "<((<(1$#0! "/#%70#-.+01! 6%/98! *+,-.! /012,! 3!"#$%&%!0!-%1"17#$*!9#(*2<(&/$8=!91..!#+!4)5!-#!677!2>1)!?1"%.3!%!#,8 /1,#+2<! =/#91+#@/199! "/#0#-%(%! .! "#9#A3)! "/#@/199$#81""1/1+$#@#!
2#9"(*2.1!9:;,<=>?,1!@0A)!#)"#!*B#!3*+?C.DE=&!!"#$%&%)!>(&!1$1(%71!%..(*8
-<*98=!"#(%.1=1/%-#0!#+,%/1(%!+#;$<)!$10*.2<!"/#,8!#F!9@&!/1.+0#/&(%! **! 0! #F! 9(! -%.+%((%/#01$$#5! 0#-8! 3"/%! 2#9$1+$#5! +*9"*/1+</*%)! B#(<8 ;*$$85! /1.+0#/! ! 6%(3+/#01(%! ;*/*7! 9*9,/1$$85! 6%(3+/! G=A.H,! "4I! .! /179*/#9!"#/!F&J4!929!%!1$1(%7%/#01(%!9*+#-#9!CDDE)!
C!/1,#+*!K4L!<.+1$#0(*$#&!;+#!BF!0#-$#5!%!#2.1(1+$#5!'2.+/12G%5! 0.*=!#,/17G#0!HI!%!HF8J!#+(%;1)+.&!"#08J*$$89!.#-*/41$%*9!@()2#8 78&! 1! A*(#;$#5! '2.+/12G%%! '! %9*)+! ,#(**! .(#4$85! 9#$#.1=1/%-$85!
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
L#(*2<(&/$#891..#0#*!/1."/*-*(*$%*!6/12G%5!"#(%.1=1/%-#0!%7! 0#-$#5&!#2.1(1+$#5!%!A*(#;$#5!'2.+/12+#0!J*(<=%!@/*;%=%!3HI%!
|
|
M*(2#0#8 |
B#(%.1=1/%-$1&! |
N%72#9#(*2<(&/8 |
|||
|
|
"#(%.1=1/%-$8*! |
|||||
F8/3*! |
D2.+/1@*$+! |
6/12G%&! |
$8*!"/%9*.%! |
||||
|
|
2#9"(*2.8! |
|
|
|
|
|
|
|
L-&!2>1 |
N! |
L-&!2>1! |
N! |
L-&!2>1! |
N! |
|
BFQQ!0#-8 |
OPFF! |
F&$! |
|
|
P&"! |
"4! |
|
"#"&J! |
"F&6! |
|
|
F&$! |
J&"! |
|
|
$#5!'2.8 |
OPFF! |
$&6! |
||||
|
4F&J! |
#F&5! |
F&P! |
"#&F! |
|||
|
+/12G%%! |
|
|
||||
|
"4&5! |
4&5! |
|
|
F! |
J&7! |
|
|
|
|
|
||||
HI8$Q! |
BF!#2.18 |
OPFF! |
P! |
|
|
#&"! |
J5&F! |
(1+$#5!'2.8 |
#44&7! |
#7&5! |
OPFF! |
"&$! |
F&"! |
#F&P! |
|
|
+/12G%%! |
4#&"! |
#"&4! |
|
|
F! |
P&4! |
|
BF!A*(#;8 |
P$#&5! |
PF&7! |
|
|
F&P! |
J&J! |
|
$#5!'2.8 |
JP&5! |
J6&$! |
OPFF! |
#F&$! |
F! |
$&$! |
|
+/12G%%! |
|
|
||||
|
|
|
|
|
|
|
|
B/%9*;1$%*R!Q!HI8$!'!J*(<=1!@/*;%=%!K4L&!QQBF!'!"#(%.1=1/%-8! |
|
"#$ !

!
!"#$%'"%$$(!)#*+(,!%%&!-!./0#1+(,!%2&!345&"%4)!-6!7/08,-!'"/1-,-!"%6'
+(,!5#")(!#!)!9:'*+!!"!)!9:',+!-!)!9:'#.!
;(0#! 85&%+#)0/+#/! 1! <"-! %+%0-6/! )#*+(,! 345&"%4)! -6! 7/08,-! '"/1-,-! </")($! <-4#$! +%! ,"#$%'"%$$%,! )(,#*-&! )(5#4#$#0/480="' +(>!2/04#)#'<#0-5%,%"-*+(>!4#$<0/45!0!?1!2!-..!4@%/!4#"(>!*/&/4' &-"8/&5=! -! "/A"%4$/&"-1/54-$! -! 5</4&"#A#$/&"-1/54-$! %<"-! ",.! +$&! */&/4"%$-3! B#1+8C! $#0/480="+8C! $%558! 3'#! 2/04#)#' <#0-5%,%"-*+#'#!4#$<0/45%!+/)#6$#D+#!85&%+#)-&E/!&%4!4%4!<"/*/0!345'
40C6--! ! 4#0#+4-! 456789! :;<5=><?! @4'A".! BC!5#5&%)0=/&! -..! 4@%3! F#'
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
G"-!%+%0-6/!#45%0%&+(,!345&"%4)!-6!7/08,-!'"/1-,-!+%!,"#$%' '"%$$%,/!&%4D/!4%4!-!+%!,"#$%'"%$$%,!)#*+(,!345&"%4)/!</")($! <-4#$! )(,#*-&! )(5#4#$#0/480="+(>! 2/04#)#'<#0-5%,%"-*+(>! 4#$' <0/45!%G;H&/!6%&/$!)!<-4!<#0-5%,%"-*+#>!A"%4I--/!50/*#$!)!<-4-!2/0' 4#)#'<#0-5%,%"-*+(,! 4#$<0/45#)/! %! <#50/*+-$-! )! <-4-! +-64#$#0/48' 0="+(,! <"-$/5/>3! ?#0/480="+#'$%55#)#/! "%5<"/*/0/+-/! A"%4I->! )! #45%0%&+(,! 345&"%4&%,! -6! 7/08,-! '"/1-,-! +/54#0E4#! #&0-1%/&5=! #&!
! |
"#$ |
!
!"#$!%&%'%()*!+!+,&(-.!/0#1!"01".%!2!$%!+34!,5%!%&6&!,#(,+(,%!,1')' 5)%! 7"0'45"%1#*! +! 1,8&! 51,! #,&%!9"()%! ()70,8,'%03'*!(-.! $!)8%#%:! 7("5)1%'6(,!;,'6<%&!5%8!+!+,&(-.!/0#1!"01".&!)!,()!)8%41!)(1%(#)+' (,%!$,=',>%()%!$!)!"$(!(8%!
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
!"#$%"!
#%!B%1,&,8!+-#,0,/@@%01)+(,:!/0#0'47)+(,:!.!,8"1,=!"@))!3#' 1"(,+'%(,&! 51,! $,')#"."!)&-&! $,'35%((-%! $,#'%&,+"1%'6(,:! /0#1!"0' A)%:! +,&,:&!,0#"'"1,8! "88,()*! )! %&0)8! ("1!,8! )7! ,1.,&,+! $!,)7+,&' #1+"! =!%5).)! *<%'3."! )! #,',8"+&! #,&%!9"1! (%! 1,'60,! $,')#"."!)&(-%! @!"0A))&! (,! )! ;%'0,+,'$,')#"."!)&(-:! 0,8$'%0#&! )! ()70,8,'%03'*!' (-%!#,%&)(%()*%!
"%! 2-.,&! $,')#"."!)&(,:! @!"0A))&! ;%'0,+,'$,')#"."!)&(,=,! 0,8$'%0#"!)!()70,8,'%03'*!(-.!#,%&)(%():!7"+)#)1!,1!#,!1"!!"#1%()*! )!,1!3#',+):!/0#1!"=)!,+"()*%!
!"#$%'%&!
#%! D,%(0,! E%F%&! G!140,+! G%G%&! H,7',+#0"*! I%?%&! B)!,<()5%(0,! 2%G%&! J'*0,+!K%L%!M,#1%!)(%!2'"&)+,#1,0&!#001%!"#"!#%!!
"%! ?,$,+! N%2%! 27")8,&%:#1+)%! @"=,A)1,+! 8'%0,$)1"4>).! #! $,')#"."' !)&"8)!!"#1%():%!N-01-+0"!&!"(("%!#((!#%!!
.%! C+,&,+!E%N%!22!L),,!="()5%#0"*!.)8)*%!#00$%!O%!"/%!P!1%!N%!/$.)3(#%! /%! H!)<1"(,+"! F%G%&! N"@,(,+"! B%E%&! L,',1,+"! 2%Q%&! ?"+',+"! J%R%&! N"'
0"(*(!J%S%!22!2%#1()0!2KT%!N%!)*4!U)8)*&!L),',=)*&!V"!8"A)*%!"((3%!
P#%!N%!"#")""#%!
3%! M%8(3.,+"! D%G%&! O,8<)5! N%2%&! W0,!)("! J%R%&! H'-0,+! G%K%! 22! X?U%! "((/%!O%!11%!2-$%!1%!N%!##0")##0,%!
,%! ?"1%(1! YV! P! ""$0,.0%! N$,#,;! 7">)1-! #1"')! 2! M%8(3.,+"! D%G%&! Z%!' (,+!L%L%&![%1)()("!K%G%&!U"!5%(0,!T%2%&!V%&,!)>%+"!K%G%!2!
1%! N3.,+%!.,+! N%2%! 22! X3!("'! "("')1)5%#0,:! .)8))%! "(("&! O%! 31%! P##%!
N%!#"##)#"#$%!
"#$ !
!"#$%&'&($)*!$+!,-#.'$!!")%"#/-0/$1&!
#"&"!+23456789#$!%":"!;73<=>%$!&":"!17826789&$!%":"!%56782?678#$! -")"!,@7?=49#!
!!"#$%$&$"'%(%%")*+",-.#"/0$"!%%"12$"*134%56#$67&#"!&'#" *134%56#$67"(,6##%8)"
*9%'66723"#7%:"%"#$%$&$";%660<3"%=2#76:"'%(%%")*+",-.#" *134%56#$67"(,6##%8)"
+)31>"256#$6="?:"<6#&430#$52""?:"&"%520#%$2$#"
*134%56#$67"(,6##%8)",-./012"1/34056$789$:;"
!"#$#%#""&'"()! #%*#+(%! #,-&./012)34! 5-2! #623%7)! 3)84"! 5#+& 3#9")6"27&%!5-)+3%&:940%!3#,#;!5)-35)7%2:"#)!:#.#,"#:94)8#)!-&3%2& %)9<"#)!3(-<)!+94!*2826)37#;!5-#8(=9)""#3%2'!>+"&7#!+#!"&3%#41)& $#!:-)8)"2!59#+#:()!#,#9#672!(=)9/*&!292!9/.$&)!:!#3"#:"#8!235#9<&
./0%34!:!:2+)!%#592:&'!!
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
M(*#+! 5#9/6)""(*! 5#923&*&-2+#:! :! .&:2328#3%2! #%! 3#-%&! -&3%)&
"24!3#3%&:29!3##%:)%3%:)""#!#%-./"%##%!"%-./0%1$!2!-%23/2%.45!#%!8&3&
3(! 3/*#$#! 3(-<4'! L);%-&9<"()! 8#"#3&*&-2+(! (-&8"#./%! &-&,2"#./%! 7329#./%!$907#./%!$&9&7%#./!2!8&""#./)!2+)"%2H2@2-#:&92!2!#5-)+)94& 92!2*!7#926)3%:)""#)!3#+)-'&"2)!3!5#8#1<0!NOP!2!NOP&!K!:!:2+)! &@)%&%#:! 5#92#9#:%! &! /-#"#:()! 7239#%(%! 7#%#-()! ")! +&0%! 5#92#9#:! :! A%2*!/39#:24*%!#5-)+)9492!:!:2+)!&@)%&%#:!8)%29$927#.2+#:'!!
F#9/6)""()! -)./9<%&%(! 5#7&.(:&0%%! 6%#! A73%-&7%(! 5#+3#9")6"#;! =)9/*2!,#9))!-&."##,-&."(!5#!3#3%&:/!:!3-&:")"22!3!A73%-&7%&82!=)9/&
! |
"#$ |