
Новые достижения в химии и химической технологии растительного сырья. Материалы III всероссийской конференции. Книга 1 [2007]
.pdf!
!"#$%&"!%&! '"(")*+(%,*%)%!-(./0)*.1!2%*(.1"2%3!2%*(045+6!,7+,84! '"9.*2"3!(!*(%:*.(0),0,2"3!)%,$.*;)!,.$.7;!-<+2%&;*! -(+/=%/(.$%9.1"22.6!+,!,.$32.6!)%,$.*.6!
>(./.$?%- |
>(./.$?%- |
C./+(?"2%+! |
D",*1.(%7.,*8! |
D",*1.(%7.,*8! |
*+$82.,*8!1;- |
*+$82.,*8!2%*- |
"9.*"*!'/!$*$2)! |
1!"&+*.2+*! |
1!,-%(*.E:%(- |
/+(?%1"2%3!1! |
(.1"2%3!./01*! |
,! |
'3!")!,! |
2.6!,7+,%*! |
!@AB*!7%2! |
7%2! |
|
|
'3!")!,! |
$! |
"2! |
"+*2! |
"$$! |
"1! |
#$! |
"2! |
""*4! |
"$$! |
+5! |
"+$! |
"2! |
"+*2! |
"$$! |
"#! |
"5$! |
"2! |
"+*1! |
"$$! |
1%! |
$! |
1$! |
"1*%! |
"$$! |
"5! |
$! |
#$! |
"1*%! |
"$$! |
"6! |
!
!")%7! .#("9.7*! -(%! 2%*(.1"2%%! ,.$.7;! -<+2%&;! 2%*(045+6! ,7+,84*! ,./+(?"5+6! !@AB*! 1.! 19"%7./+6,*1%+! ,! 2%*(045+6! ,7+,84! 1,*0-"4*! 1,+! ,*(0)*0(2;+! ).7-.2+2*;! ,.$.7;(! &+$$4$.9"*! =+7%&+$- $4$.9;!%!$%=2%2&!F%*(.1"2%+!,.$.7;!-<+2%&;!1!,(+/+!!@AB!-(%1.- /%*!)!-.$0G+2%4!-(./0)*.1!,!1;,.).6!(",*1.(%7.,*84!%!#.$8<%7!).- $%G+,*1.7! ,139"22.=.! "9.*"*! G*.! -(+/.-(+/+$3+*! %H! 2+.#H./%7;+! -.- *(+#%*+$8,)%+!)"G+,*1"!1.!72.=%H!*("/%&%.22;H!/$3!2%*("*.1!&+$$4- $.9;!,:+("H!-(%7+2+2%3&!!
I7++*!#.$8<.+!92"G+2%+*!G*.!2%*(.1"2%4!-./1+(="+*,3!2+-.,(+/- ,*1+22.! $%=2.0=$+1./2;6! 7"*+(%"$*! #+9! -(+/1"(%*+$82.=.! 1;/+$+2%3! &+$$4$.9;*! G*.! 1! -+(,-+)*%1+! -.91.$3+*! .*)"9"*8,3!.*! ./2.=.! %9! 2"%- #.$++!!*.),%G2;H!H%7%G+,)%H!-(.%91./,*1!7!&+$$4$.92.6!1"()%&!!
J"?2.*!G*.!.#("9045%6,3!-(%!2%*(.1"2%%!,.$.7;!-<+2%&;!2%*- (.$%=2%2*! *")?+! 2+! $%<+2! -.$+92;H! ,1.6,*1&! F"-(%7+(*! 2%*(.1"2%+! =%/(.$%92.=.! $%=2%2"! 31$3+*,3! ./2%7! %9! 2"%#.$++! (",-(.,*("2+22;H! ,-.,.#.1! +=.! 0*%$%9"&%%&! >(%,0*,*1%+! =+7%&+$$4$.9! 1! -(./0)*+! 2%*- (.1"2%3!31$3+*,3!-(%G%2.6!,2%?+22.=.!,./+(?"2%3!"9.*"!1!-(+-"("*+*! +=.!2+./2.(./2.,*%&!!
K)*0"$+2*! *")%7! .#("9.7*! -.%,)! ("&%.2"$82;H! ,-.,.#.1! -(+/.#- ("#.*)%! 7"*+(%"$"! 1+/05%H! )! 0/"$+2%4! =+7%&+$$4$.9*! -.1;<+2%4! (+")&%.22.6!,-.,.#2.,*%&!L::+)*%12;7%!9/+,8!7.=0*!#;*8!)%,$.*2;6! =%/(.$%9*! 19(;12.6! "1*.=%/(.$%9! %! /(0=%+! %91+,*2;+! 1%/;! -(+/.#("- #.*)%!$%=2.0=$+1./2;H!7"*+(%"$.1&!
"#$ !
!""#$%&'()!$!*&"#$%&'(+$#,)&-!&./(.&+0!! %/$'$"!)1!'2/1')13!('+&4!%/!2&3!
!!+/!5+&/60"6")&-!0!"#&+&-!
&"("!*789:8;<#!&"!"!+=><?7#!("""!07@:A=8#!+"$"!B:8!!
!"#$%&'(%!)*&+,$-./001%!+0(./-&(#/#"!2-#!3/0(0$"!$%"!
4$-0$+""!$&$'()!*5*&&(6+!,-./012!30456/789:.#/;<#=<!
!"#$%&'(%'! #)'&! *&%+'('(%,! (%-&"-./! 0'1121.34! /! &"31%5(46!
.71"#-,6! *&.+4$1'((.#-%! #-%+81%&8'-! *&./'9'(%'! %##1'9./"(%:! *.! ("*&"/1'((.+8! &';81%&./"(%2! .#(./(46! )%3%<.$6%+%5'#<%6! 6"&"<-'$ &%#-%<! =-%6! /">(46! *&.%3/.9(46! 0'1121.34%! ?'.76.9%+.#-@! &"3&"$ 7.-<%! (./46! -'6(.1.;%:! *.185'(%,! (%-&"-./! 0'1121.34&! ('*.#&'9#-$ /'((.!%3!9&'/'#%(4&!7'3!*&'9/"&%-'1@(.;.!&"39'1'(%,!''!("!<.+*.('($ -4&!*&%.7&'-"'-!/!("#-.,A''!/&'+,!.#.782!"<-8"1@(.#-@%!B!=-.:!#/,3%! *'*'<-%/(4+!,/1,'-#,!+'-.9!*&,+.;.!(%-&./"(%,!9&'/'#%(4!/!#&'9'! -&%)-.&8<#8#(.:!<%#1.-4!'"(%!
C1,! %##1'9./"(%,! %#*.1@3./"1%! .*%1<%! 9&'/'#%(4! 1%#-/'((.:! %! 6/.:(.:! *.&.9! &"3+'&.+! )&*!++%! ?%-&./"(%'! /'1%! 9/8+,! #*.#.7"+%%! !"#-%-'1@(.'! #4&@'&! *.9/'&;(8-.'! /3&4/(.+8! "/-.;%9&.1%38! +,,)!-.&! /!+%(&! /DE"0&! .7&"7"-4/"1%! #+'#@2! "3.-(.:! %! -&%)-.&8<#8#(.:! <%$ #1.-&! #.9'&>"A':! #)1! "3.-(.:! <%#1.-4! %! 2)1! -&%)-.&8<#8#(.:! <%$ #1.-4! *&%! -'+*'&"-8&'! /)!-.! #! &"31%5(.:! *&.9.1>%-'1@(.#-@2! &'"<$ 0%%!%!>%9<.#-(.+!+.981'%!
B-.&.:!#*.#.7!.-1%5"1#,!-'+&!5-.!&"#-%-'1@(.'!#4&@'&!*.9/'&;(8-.'! /3&4/(.+8!"/-.;%9&.1%38&!*&'9/"&%-'1@(.!/49'&>%/"1%!/!-&%)-.&8<#8#$ (.:! <%#1.-'&! "! 3"-'+! 9.7"/1,1%! "3.-(82! <%#1.-8!',(%! E&.98<-4! &'"<0%%! (%-&./"(%,!9&'/'#%(4!.7&"7"-4/"1%!/!-'5'(%'!,!5!<%*,A':!9%#-%11%&.$ /"((.:!/.9.:&!#!0'1@2!;%9&.1%3"!-&%)-.&"0'-%1@(46!;&8**&!<.-.&4'!74$ 1%!//'9'(4!/!<.+*.('(-4!9&'/'#%(4!("!#-"9%%!*&'9.7&"7.-<%%!F.9'&>"$ (%'!"3.-"!.*&'9'1,1%!)'&&.#81@)"-(4+!+'-.9.+&!.*%#"((4+!/!&"7.-'!'/(%!
E.#1'9./"-'1@(",! .7&"7.-<"! 9&'/'#%(4! /3&4/(4+! "/-.;%9&.1%$ 3.+&! "! 3"-'+! #+'#@2! "3.-(.:! %! -&%)-.&8<#8#(.:! <%#1.-! #*.#.7#-/8'-! -.+8&!5-.!/!*&.0'##'!+.9%)%0%&./"(%,!.7&"382-#,!(%-&"-4!0'1121.$ 34!#!#.9'&>"(%'+!"3.-"!.-!"/&"!9.!"/&31%!E&.98<-4!(%-&./"(%,!#.!#-'$ *'(@2!*.1%+'&%3"0%%!22)4*))!*.1(.#-@2!&"#-/.&,2-#,!/!"0'-.('!%!("! *)4521! /! #*%&-.=)%&(.:! #+'#%%! F.9'&>"(%'! "3.-"&! &"#-/.&%+.#-@! /!
! |
"#" |
!
!"#$%! '! ()'*$%+,'*&%-! (.#('! )*%/01$%2! &'$*%2!&'3%! )%405#&&67! )%(4#/%2!$#48&%-! %9*!9%$1%-! /*#2#('&6! 2:*62&6.!!2$%;'/*%4':%.%! !! :!$#.! &'$*0<=#-! (.#(8<%! 26>#%! 5#.! 0! )*%/01$%2! &'$*%2!&'3%! )%40& 5#&&67! %9*!9%$1%-! /*#2#('&6! $%481%! &'$*0<=#-! (.#(8<'! ?$%! 01!:6& 2!#$! &!! 02#4'5#&'#! '7! %/&%*%/&%($'! )%! (%($!20! '! ($*01$0*#'! @!1'.! %9*!:%.%! 2:*62&%-! !2$%;'/*%4':! .%A&%! '()%48:%2!$8! 1!1! %/'&! ':! .#& $%/%2!)*#/2!*'$#48&%-!%9*!9%$1'!/43!*#;04'*%2!&'3!(2%-($2!)%405!#&
.67!)*%/01$%2!'!)%26>#&'3!'7!%/&%*%/&%($''!
B%4'5#($2%! /#-($20<='7! *#!;#&$%2%! )%$*!5#&&67! &!! *#!1"'<! &! 2!A&6-! )%1!:!$#48! )*'! *!:*!9%$1#! ()%(%9%2! .%/','"'*%2!&'3! /*#2#& ('&6!(.#(8<!!:%$&%-!'!$*',$%*01(0(&%-!1'(4%$!($!94'!")'!
C&'A#&'#!*!(7%/!!&'$*0<=#-!(.#('!(A'/1%($&%;%!.%/043)!/%!$*! ()%(%9($20#$! %9*!:%2!&'<! )*%/01$!! &'$*%2!&'3! )%! (2%-($2!.! ((%/#*& A!&'<!!:%$!!+!""%,-!'!*!($2%*'.%($'!2!!"#$%!+!..-!'!()'*$%+,'*& &%-! (.#('! +! #.-)! (*!2&'.%;%! (! /'&'$*!$%.%! )%405#&&6.! ':! ':%4'*%& 2!&&%-!"#44<4%:6'!
D6(%1!3!*!($2%*'.%($8!)*%/01$%2!&'$*%2!&'3!/*#2#('&6!%('&6!2! !"#$%! '! ()'*$%+,'*&%-! (.#('! 01!:62!#$! &!! *!2&%.#*&%($8! :!.#=#& &'3! ;'/*%1('48&67! ;*0))! &'$*%;*0))!.''! E*#/%9*!9%$1!! 2:*62&6.! !2$%;'/*%4':%.! (%)*%2%A/!#$(3! )%405#&'#.! &'$*!$%2! "#44<4%:6! & )%(*#/($2#&&%!':!/*#2#('&6%!1%$%*6#!!(%/#*A!$!)*'.#('!)*%/01$%2! /#($*01"''! ;#.'"#44<4%:! '! 4';&'&!%! 5$%! )%/$2#*A/#&%! .#$%/%.! FB& ()#1$*%(1%)'''!
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
.#*#!/*#2#('&6!%('&6%!9#*#:6!'!(%(&6!($!94'!$)'!!
E*%/01$6! &'$*%2!&'3! /*#2#('&6! 4'($2#&&67! '! 72%-&%-! )%*%/%! )%405#&&6#! )%(4#/%2!$#48&%-! %9*!9%$1%-! $*',$%*01(0(&%-%! !! :!$#.! !:%$&%-! 1'(4%$!.'%! &!! )%/2#*;&0$0<! 2:*62&%.0! !2$%;'/*%4':0! *!($'& $#48&0<!$1!&8%!(%/#*A!$!""%,+"%#-!!:%$!'!D.#($#!(!$#.!02#4'5'2!#$(3! *!($2%*'.%($8!)%405#&&67!)*%/01$%2!&'$*%2!&'30!2!!"#$%!/%!"//-!'! 2!()'*$%+,'*&%-!(.#('!/%!#/+1/-'!C$#)#&8!)%4'.#*':!"''!':.#&3#$(3!
2!)*#/#4!7!%$!2//!/%!23/'!!
"#$ !
!"#$%&"!"%! '()*+,("!-.)/01,)(!2%,.)("2%3!/.4(4+%25&!-)$0642257! -)+$4/)(",4$8259!/4*+,(%49!(:.5(2);)!"(,);%/.)$%:"! 2%,.0<=4*!+94+8<!(!,4642%4!#'!9%2&!+!>%/1)+,259!
9)/0$49!),!"(!/)!$(!
|
@%/1)+,25*! |
')/4.>"2%4!)*+&!,! |
|
?"+,().%9)+,8!! |
|
|
9)/0$8! |
"&4,)2&!,! |
+-%.,)AB%.2"3!+94+8&!,! |
||
|
|
||||
|
"(! |
"'&-.'&$! |
/0.1&'! |
|
-#.1&'! |
|
1(! |
""&$.'&$! |
/2.1&'! |
|
#/.1&'! |
|
$(! |
""&0.'&$! |
/1.1&'! |
|
('.1&'! |
|
('! |
"$%/.'&$! |
/2.1&'! |
|
0'.1&'! |
!"#$%&"!1%! C.)/01,5!2%,.)("2%3!-)/(4.;20,)*!(:.5(2)90! "(,);%/.)$%:0!/.4(4+%25&!-)$0642254!-)+$4/)(",4$8259! /4*+,(%49!,.%B,).01+0+2)*!%!":),2)*!1%+$),!
|
D%/!! |
')/4.>"2%4! |
?"+,().%9)+,8! |
',4-428! |
|
|
|
+-%.,)AB%.2"3! |
|||
|
/.4(4+%25! |
)*+&!,! |
"&4,)2&!,! |
-)$%94.%:"&%%! |
|
|
+94+8&!,! |
||||
|
|
|
|
|
|
|
E+%2"! |
""%#.'&$! |
/#.1&'! |
#2.1&'! |
-''.1'! |
|
F4.4:"! |
""%(.'&$! |
/2.1&'! |
0'.1&'! |
-2'.1'! |
|
')+2"! |
""&$.'&$! |
/2.1&'! |
#'.1&'! |
-('.1'! |
G4)#7)/%9)!),94,%,8&!6,)!(!.4:0$8,",4!():/4*+,(%3!(:.5(2);)!"(3 ,);%/.)$%:"! 2"! /.4(4+%20! -)$06"<,+3! #)$44! )/2).)/254! -.)/01,5! 2%,.)("2%3!-)!+."(242%<!+!)#.":&"9%&!-)$0642259%!#4:!-.4/)#."#),3 1%%!H:(4+,2)&!6,)!-.%!)#."#),14!/.4(4+%25!(:.5(259!"(,);%/.)$%:)9&! ;49%&4$$<$):5!-."1,%64+1%!-)$2)+,8<!-)/(4.;"<,+3!/4+,.01&%%%!
E64(%/2)&! 6,)&! %:94233! 0+$)(%3! %! -.)/)$>%,4$82)+,8! -.4/)#."3 #),1%!."+,%,4$82);)!+5.83&!9)>2)!-)$06",8!24-)+.4/+,(422)!%:!/.4(43 +%25! 2%,.",5! &4$$<$):5! +! .":$%6259! :"94=42%49! ;%/.)1+%$8257! ;.0--!0!I4+,);)&!(,).);)!%!,.4,84;)!",)9)(!0;$4.)/"!2"!2%,.);.0--5%!
!"1%9! )#.":)9&! -)+$4/)(",4$82"3! )#."#),1"! /.4(4+%25! 94,)/)9! (:.5(2);)! "(,);%/.)$%:"&! ,.%B,).01+0+2)*! %! ":),2)*! 1%+$),"9%! +-)3 +)#+,(04,!,)90&!6,)!(!-.)&4++4!44!9)/%B%&%.)("2%3!)#.":0<,+3!2%,."3 ,5! &4$$<$):5&! )/2).)/254! -)! +)+,"(0! %! +,.01,0.4! %! 24! +)/4.>"=%4! -.%94+4*!-.)/01,)(!/4+,.01&%%!;49%&4$$<$):!%!$%;2%2"%!!
!"#$%'%&!
"%! C",42,!J1"0-/2-'1!)?K+!4!L%H%!M"$)61%2&!G%'%!N"+81)&!H%G%!O.;%2"!4! "///%!
1%! L%+%!"#"0/"()?K+!4!P%L%!C4.I%2"&!G%'%!N"+81)&!E%L%!C"26421)!4!"//"%! $%! P);%2)(!D%F%!Q4,)/%64+1%4!01":"2%3!1!$"#).",).2)90!-."1,%1090!-)!10.3
+0!5R%9%3!%!,472)$);%3!&4$$<$):5!%!44!AB%.)(6%!F%*+1&!"/2"%!S%!1%!'%!"2%!
! |
"#$ |
!
!"#$%&'()$'*"+,'"!+-%.+!-)!-%&%#)+!-%#'$/0! +$"1)((/0!23'#%-!4"5565%7/!
)"+"!+898:;<#!2"("!6=>?@;9ABC<B#!D"#"!#B@E;FGCH98C<!!
!"#$%&'($)*!+),)$-"'%+&-.-/)0%($)*!)&(')'1'#!!"#$%&'! $234%$)('"&%!&"'()*+!,)-)./01(2'()*345!
!"#$%&'(%! )&(! *+,-.! /$0010(".%! %(2$-345,$! #! %#($6! %(%&4#$! &(078(! '$,('(9$''.$! "46$%&,&$0,%! (:04241&! (;-$2$0$''(<! ;(#$-='(& %&'(<!48&,#'(%&71!'4!9-4',/$!-4"2$04!-4%(-!'!'4%.5$''.<!;4-!(")*!
>4;-,6$-%! 6$&,0/$0010("4! +?@,! %(! %&$;$'71! "46$5$',A! "%#'"%-! %',34$&! ;(#$-='(%&'($! '4&A3$',$! #(2.! 2(! .%/'.%$""/&0! '16! (8%,*&,0& /$0010(".!+BC@,*!!
D!*&(<!%#A",!;-$2%&4#0A$&%A!,'&$-$%'.6!,"E)$',$!;(#$-='(%&'.=! %#(<%! %,'&$",-(#4''.=! '46,! #(2(-4%(-,6.=! *+,-(#! /$0010(".%! &48,=! 848! 4/$&,06$&,0/$0010("4! +DF?@,%! 4/$&,0/$0010("4! +DGF@,%! 4/$&,0+(%+4&/$0010("4! +DFH(@,! ,! >&84-:(8%,6$&,0/$0010("4! +>& DI?@,%!;-,!-4"0,)'.=!&$6;$-4&E-4=*!
J(#$-='(%&'($! '4&A3$',$! +!,! #(2'.=! -4%(-(#! ,"E)4$6.=! *+,& -(#! /$0010(".! (;-$2$0A0(%7! ! 6$&(2(6! 2648%,6407'($! 24#0$',$! ;E& ".-78(#3! '4! ;-,:(-$! G$:,'2$-4! ;-,! 0.!4K*! J(#$-='(%&'($! '4&A3$',$! -4%(-(#! -4%%),&.#40(%7! ;(! +(-6E0$! ,"! (0)*! J(0E)$''.$! -$"E07&4&.! ;-,#$2$'.!#!&4:0,/$!"*!
L4''.$! &4:0,/.! "! %#,2$&$07%E1&! (! &(6%! )&(! 20A! %,'&$",-(#4'& '.=!*+,-(#!/$0010(".!=4-48&$-'(!E6$'7M$',$!;(#$-='(%&'(9(!'4&A3$& ',A!-4%(-(#!%!#("-4%&4',$6!&$6;$-4&E-.*!C&(!%#A"4'(!%!E6$'7M$',$6! ;(#$-='(%&'(9(!'4&A3$',A!%46(<!#(2.!,!42%(-:/,(''.=!%#(<%!*+,-(#! /$0010(".! %! ;(#.M$',$6! &$6;$-4&E-.*! J(#$-='(%&'($! '4&A3$',$! -4%& (-(#! DFH(@! ,! >&DFI?@! %! ;(#.M$',$6! &$6;$-4&E-.! #! '4)407'.=! %&42,A=! '$"'4),&$07'(! E6$'7M4$&%A! ,! (%&4$&%A! ;-48&,)$%8,! ;(%&(A'& '.6*! J(&#,2,6(6E%! %! ;(#.M$',$6! &$6;$-4&E-.! E#$0,),#4$&%A! %&$;$'7! 2,%%(/,4/,,!84-:(8%,07'(<!9-E;;.!%!(:-4"(#4',$6!>5! ,!'KBB'!,('(#%! 8(&(-.$!%;(%(:%E1&!E#$0,)$',1!;(#$-='(%&'(9(!'4&A3$',A!#(2.*!
!
"#$ !

!"#$%&"!"%! !'"(%)%*+),-!.+(/012+),2+3+!2",45/2%4!0"),(+0+(! )*/6"2271!89%0+(!&/$$:$+;7!+,!,/*./0",<07!&='"()!3*>$+!
|
!(!@! |
|
?9%07!&/$$:$+;7! |
|
|
|
ABCD! |
AEBD! |
ABF+D! |
G,AB@CD! |
|
|
|
||||
|
-./! |
0.(#! |
$-(.! |
#1(0! |
#$(2! |
|
1)1! |
0/(2! |
$-(-! |
#-($! |
#1(#! |
|
1"/! |
02($! |
$"($! |
#"(2! |
#1(/! |
|
1-/! |
0#(#! |
$"(1! |
#"(1! |
#1(0! |
|
11/! |
0#(0! |
$)(/! |
#"()! |
#1(1! |
!
H"$//!#7$%!0"))I%,"27!,/0*+>%2"*%I/)J%/!."0"*/,07!">)+0#&%%! )%2,/;%0+("2271!89%0+(%!K;(/),2+(!I,+!>$4!2/%+2+3/2271!LBA!(/$%,
I%2"!.+(/012+),2+3+!>"($/2%4!!!'!")3"!&3>/!")!!%!"!!.+(/012+),2+/!2", ,45/2%/! 0"),(+0%,/$4! %! 0"),(+0"! )++,(/,),(/22++! )(4;"2"! )! ">)+0#&%, +227*%! ."0"*/,0"*%4! J+2),"2,+M! N/20%! &@5+(! J+2),"2,+M! ">)+0#&%+2, 2+3+!0"(2+(/)%4!&@$+(!*"J)%*"$-2+M!/*J+),-:!*+2+)$+4!&N#+%!?,%!!.", 0"*/,07!#7$%!(7I%)$/27!.+!)$/><:O%*!9+0*<$"*4!
>$4!0";#"($/2271!0"),(+0+(!LBA4!
"#! % " % !$ $! 6!
>$4!#+$//!(7)+J%1!J+2&/2,0"&%M4!
"#! % "# 78&" & %!+( !
,%J%! 9:! ;! "(! *+52+! .0/2/#0/I-! />%2%&/M! (! 9+0*<$/%! !+3>"! 9+0*<$"!
.0%+#0/,"/,!)$/><:O%M!(%>4!
!*<='!N#!78@$!%=6!
%# |
% |
" |
' |
" |
|
%! |
|
! |
"# |
"# $ !$ $ |
# |
||||
|
|
|
L+!8,%*!9+0*<$"*!*+3<,!!#7,-!0"))I%,"27!;2"I/2%4!@$!%!N#%! H$4! +.0/>/$/2%4! ,/0*+>%2"*%I/)J%1! ."0"*/,0+(! %).+$-;+("$%!
)$/><:O%/!)++,2+6/2%44!!
! |
"#$ |
!
!"#!$%&'())!*)++,-!! !$"!%!&!'()*+,!-! !!$.!%!&!'()*+"-!
."#!/01&'2%0,3%04!-53)1%0,3)/! "!%!'()*+,!-!
."#!3&/"036!-.,0'+7))! ! !0!%!'(.12!)*!+"32(4!
."#!$%&'()4!-.,0'+7))! ! !5!%!1!0&!$43(! 893&:!")%&4%0(0!'&;&%)#!9'-1%&%)#!<&%(:='-!%-!0,%01&!.-%%62!
/01&'2%0,3%0(0! %-3#>&%)#! %-:)! %-4.&%6! ,"&.9=?)&! @%-A&%)#6! 50%& ,3-%3-! -.,0'+7)0%%0(0! '-1%01&,)#! B"/! :-5,):-"C%-#! -.,0'+7)#! *#/! 50%,3-%3-!-.,0'+7))!*&%')!!
B(!%!B*#!)!/01&'2%0,3%04!-53)1%0,3)!"!%!+'(7!
80! 3&:/&'-39'%04! @-1),):0,3)! 50%,3-%36! -.,0'+7))! 0/'&.&"#")! 3&':0.)%-:)A&,5)&!/-'-:&3'6!-.,0'+7))7!
80"9A&%%6&!'&@9"C3-36!/')1&.&%6!1!3-+")7&!.7!
D'-1%)3&"C%64!-%-")@!3-+")A%62!.-%%62!,1).&3&"C,319=3!0!'0,& 3&! /01&'2%0,3%04! -53)1%0,3)! ,! 91&")A&%)&:! ().'0E0+%62! '-.)5-"01! 18DF94! 1! :-5'0:0"&59"&! ,:&;-%%62! $E)'01! 7&""="0@67! F-.0! 03:&& 3)3C/!A30!10!1,&2!,"9A-#2!,!91&")A&%)&:!().'0E0+%62!('9//!1!:-5'0& :0"&59"&! /01&'2%0,3%-#! -53)1%0,3C! 91&")A)1-&3,#! ,! '0,30:! 3&:/&'-& 39'67!!
G%-A&%)&! 1&")A)%! 50%,3-%36! *&%')! )! <&%(:='-! 91&")A)1-&3,#! 5-5! ,! 91&")A&%)&:! ,0.&'>-%)#! ().'0E0+%62! ('9//! 1! :-5'0:0"&59"-2! )@9A-&:62!$E)'01!7&""="0@6/!3-5!/')!10@'-,3-%))!3&:/&'-39'67!H-@& :&'6! ! /0,-.0A%62! /"0?-.05! :0"&59"! ."#! 1,&2! ),,"&.9&:62! 0+'-@701! /0A3)!0.)%-5016!)!10@'-,3-=3!,!/016;&%)&:!3&:/&'-39'67!!!
805-@-%0/! A30! -.,0'+7)#! ),,"&.01-%%62! ,0&.)%&%)4! %-! ('-%)7&! '-@.&"-! >).50,3C! 8! (-@! 20'0;0! 0/),61-&3,#! 9'-1%&%)&:! <&%(:='-7! I6")!3-5>&!0/'&.&"&%6!@%-A&%)#!,10+0.%04!$%&'())!!$:! -.,0'+7))!,! /0:0?C=!9'-1%&%)#!;;!@-50%-!3&':0.)%-:)5)6!
!$:%!!0:!8!(!5:7!
G%-A&%)#! !F-! ."#! 1,&2! $E)'01! 7&""="0@6! /0"0>)3&"C%6&7! D9.#! /0! 1&")A)%&! !F-/! :0>%0! /0"-(-3C/! A30! '-,310'&%)&! 0+'-@701! $E)'01! 7&""="0@6! 1! 10.&! ).&3! ,! 16.&"&%)&:! 3&/"-/! )! /0$30:9! #1"#&3,#! ! 16& (0.%6:7!!
"## !

!"#$%&"!"#! !'()*+%,")%-'./%'!0"(")'1(2!"+.*(#&%%!.)'3",,24!56%(*7!&'$$8$*92!,"!:(",%&'!("9+'$"! ;%+/*.1<!$!:"9!
=6%(2!! |
!%!>! |
! |
'( |
)*! |
|
!%! |
>$! |
! |
'( |
),! |
! |
)"" |
)#./! |
#A"! |
#-/! |
|
&'$$8$*92! |
>& |
|
! |
" |
+)*$<! |
?" |
|
-( |
'( ! |
@;+)*$<! |
@;+)*$<! |
@;+)*$<! |
||||
|
|
|
|
, ) |
|
|
|
|
|
|
|
|||||
A)BC>DE! |
"01! |
'%*"! |
*%'(! |
2,! |
'%1"! |
11! |
0%,1! |
',%'3! |
1,%2! |
|||||||
|
*(1! |
'%*0! |
*%2,! |
21! |
'%04! |
10! |
'(%1"! |
! |
12%,! |
|||||||
|
*'1! |
'%43! |
4%"4! |
0"! |
'%1"! |
0*! |
''%2'! |
! |
1,%,! |
|||||||
|
*"1! |
'%4'! |
4%3"! |
04! |
'%,*! |
02! |
'"%'3! |
! |
1,%3! |
|||||||
|
**1! |
'%43! |
4%*2! |
0'! |
'%44! |
'("! |
'*%,(! |
! |
11%(! |
|||||||
BCF*E! |
"01! |
3%2'! |
'4%*'! |
"0'! |
'%0(! |
1,! |
''%("! |
'(%4,! |
2"%'! |
|||||||
|
*(1! |
3%2,! |
'4%,"! |
*("! |
'%12! |
10! |
''%22! |
! |
24%,! |
|||||||
|
*'1! |
3%,"! |
'4%2,! |
*'(! |
'%,'! |
''"! |
'*%((! |
! |
21%2! |
|||||||
|
*"1! |
,%"1! |
',%'3! |
*1,! |
'%4,! |
'("! |
'*%01! |
! |
1"%(! |
|||||||
|
**1! |
,%21! |
'2%'"! |
4("! |
'%42! |
''4! |
'4%"1! |
! |
1*%(! |
|||||||
BGCE! |
"01! |
2%'1! |
'3%2(! |
"'2! |
'%2"! |
0"! |
'"%,4! |
1%*4! |
2(%3! |
|||||||
|
*(1! |
2%"*! |
',%3'! |
",3! |
'%2'! |
10! |
'*%"3! |
! |
2"%4! |
|||||||
|
*'1! |
2%3"! |
'2%2*! |
"1,! |
'%,1! |
04! |
'4%4"! |
! |
2,%4! |
|||||||
|
*"1! |
1%'"! |
'2%0"! |
"01! |
'%,3! |
01! |
'3%'4! |
! |
21%1! |
|||||||
|
**1! |
1%*,! |
'1%*4! |
***! |
'%,'! |
'(2! |
'3%43! |
! |
20%1! |
|||||||
BCDE! |
"01! |
'"%'4! |
"4%*'! |
33(! |
'%0"! |
12! |
'0%,1! |
,%'3! |
1,%2! |
|||||||
|
*(1! |
'"%*3! |
"4%23! |
3,'! |
'%13! |
0'! |
"(%1*! |
! |
12%,! |
|||||||
|
*'1! |
'"%1*! |
"4%0,! |
3,3! |
'%1"! |
04! |
"'%4(! |
! |
1,%,! |
|||||||
|
*"1! |
'*%"2! |
"3%*1! |
321! |
'%21! |
02! |
""%"3! |
! |
1,%3! |
|||||||
|
**1! |
'*%3(! |
",%'"! |
31*! |
'%12! |
''"! |
"*%,(! |
! |
11%(! |
',2!
!
!
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
#$'1;1-4!.("$!C<#%:1$'9#8/!).<++!,!*&*0$,-!4$%.&4&'-%<')!!
!"#$%'%&!
")! D14&/1#!E)F)(!G$1%$#&,$!H)E)!>141;-*%$(!4&"1C1%$:1(!*!4-0&"!+&% ,8A-#1(! 0-.4&*&'-<*0&6;1,&*01! "1*+-.*#8/! *1*0-4)! I$<;)! %&C)! +&! +.&5'-4$4!#-C01!1!)$3$)!FEI>!1!JB!14)!J<5%1#$+!0-31*8!"&%'$"&,)!
F)(!",--)!-.!*)!!
/)! H$5&.$0&.#8-! .$5&08! 1! 3$"$;1! +&! %&''&1"#&6! /1411! 0! +&"! .-")!
J)K)!L.&'&,$!1!M)N)!J&.&"*%&)&)!F)(!",$#)!N)!"./)!
.)! B&,-./#&*0#8-!(,'-#1(!1!!%&''&1"#&%$%01,#8-!,-2-*0,$+!*+.$,&;#1%!0! M5.$43!M)M)(!O&5.&,$!H)P)(!G$(;-#%&!H)B)(!1!".)!H)(!",$1)!.,/!*)!
()*+,+,(+!-./01.0/2!3(-.45!6(-0!78(.,45! 9+!!:!4)2!;/(!<)=(*4>+5-.<((!-!<4>45!
("<"!!?@&ABC&#!!"="!=D$E"A&!!
!"#$%&'(%)*+,-!.%*/)'$*#("001-!/0,("$*,#"#"!! 2$#!3"0,0'"!$$"!!"#$%&'(%)*+"!4"*2/56,+'!7'$"6,8!%4%**,8&! '()*+,-!./0*123*45*1678#9/!
E3,-*0#&(!;0&!*,&6*0,$!:-''='&38!1!%$;-*0,&!+.&"<%0&,!#$!--!&*% #&,-! 3$,1*(0! &0! 1*/&"#&)&! *8.9((! *+&*&5$! -)&! /141;-*%&6! &5.$5&0%1(! <*'&,16! +.&,-"-#1(! 0-/#&'&)1;-*%&)&! :1%'$)! E34-#-#1-! *,&6*0,! 1*% /&"#&)&! *8.9(! 1! )&0&,&6! +.&"<%:11! 0-*#&! *,(3$#&! *! 134-#-#1(41! *0.<%0<.#&)&!*&*0&(#1(!:-''='&38!#$!#$"4&'-%<'(.#&4!1!4&'-%<'(.%
"#$ !

!"#! $%"&!'! %"&'! ()$*'!+'! ,-%$.-$%/! 0'1121")/! +! ''! +)#'!'!+3! 4"5! &")5'6,-&+'#!&!'7!+8!9:.-"%"&!3&13'-,3!&:;!"6!4%+.1:5!"6!):5:*'6'!!
<!5:!!"6!%:="-'!+)$*:1",>!&1+3!+'!!:,/?'!+3!&"5"6!!:! +)#'!'( !+'! ,-%$.-$%/! *+,-"6! =+,$1>9+-!"6! 0'1121")/'! @=%:)0/! 0'1121")/! 5%'&',!"6! #:,,/! =/1+! 4%'5",-:&1'!/! 0'1121")!"(=$#:;!/#! ."#=+( !:-"#! )A'! B"!5"4"A:*'! ! C'!-A'!"A%:##/! "=%:)0"&! =/1+! 4"1$*'!/! !:! :&-"#:-+*',."#! 5+9%:.-"#'-%'! DC@E(+,! +)1$*'!+'! -./F! )G0",$1213*!! &! A'"#'-%+38! !:! "-%:;'!+'! +! !:! 4%",&'-'! (,,1'5"&:1+,>! "=%:)0/! &/( ,$7'!!"6!+!!:,/?'!!"6!&"5"6!0'1121")/'!!
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
! !
C+,'!"'!D+9%:.0+"!!/'!.:%-+!/!%:,,'3!+3!"-!&/,$7'!!"A"!+!4%"4+-:!!"A"!&"( 5"6!"=%:)0:!0'1121")/!5%'&',!"6!#:,,/!"-,!3-/'!!:!-.!+)1$*'!++!&!A'"#'-%++! !:!"-%:;'!+'!):*!+!&!A'"#'-%++!!:!4%",&'-!)=*!
! |
"#$ |