Новые достижения в химии и химической технологии растительного сырья. Материалы III всероссийской конференции. Книга 1 [2007]
.pdf
!
!"#$%&'()*+&,,-.!/.##0#*1,-.!2&'.)(-"! !2.3&,,-.!4%()-!/.##0#*1-#!!(,'.1()*+&,,-.! ,&!*!,*+.!5*)*36*+-7!/.##0#*1!#$,&#!7#*56&! (!8).+.!(,-!
2$&$!'9:;9<9=!!
!"#$%$&$!'%(%%!)*+!,-.!/0*"!&1#!23-45(67#869"!$%"!
:;8$;486-!&/5##%9'!()*+,-.!*+/01-02034*+,-#15!
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
C! /%$*+(2?$-)5! %+8)#$! )&49$(2$"! &,"#$0! ! &42<=+#,%)(+"".7! 1$2232)0!,!,7!&-$:+"".7!A=,%)(!(!&42<=+#)(!'+%8)'&,-$#,21$2232)0.! )>DEF*'!&42<=+#)(!1,+")A#,21$2232)0.!)>FGF*!"+!)&")($!%4'#4%")!(! -)*,=,1,%)(+"".7!1$2232)0".7!-+#$%,+2)(!)/)%):')(.7!1$2232)0*&!!
|
|
|
|
|
|
|
|
|
|
|
- |
- |
-.+/+-.+//01 |
|
|
|
|
|
- |
- |
|
/ |
"&!+,+- +//01 -/ |
|
/5/601 |
|
|
/ |
|
||
|
|
|
|
|
-.+/- |
|
|
|
|
|
|||||
-/ |
|
/- |
|
|
|
. |
|
|
|
/ |
|
- |
|
||
|
- |
|
/ |
|
- |
|
.&!234!5/6 |
|
- |
- |
|
|
|||
|
|
|
|
|
|
|
|
|
|||||||
|
- |
|
|
6&!01/- |
|
|
|
- |
|
||||||
|
|
|
|
|
|
|
- |
|
/ |
||||||
|
|
|
|
- |
|
|
|
|
|||||||
|
|
- |
|
|
|
/ |
|
|
|
|
|
|
|||
|
|
|
-/ |
- |
|
|
|
|
|
-/ |
/5/601 |
|
|||
|
|
|
|
|
|
|
|
|
|
|
|||||
|
|
-.+/- / |
|
|
|
|
|
|
|
|
- |
|
|||
|
|
|
|
- |
- |
|
-.+/+-.+//01 |
|
|
||||||
- |
|
|
|
|
- |
|
|
|
|
! |
|||||
|
|
|
|
|
|
|
|
|
|
|
|
|
|||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
>#$/$"<!0+-$9$",?!/)!&42<=+#".-!@%4//+-!&)+(2?$#!$'7(.'$8!/)! '+%8)'&,-$#,2<".-!$'.("'!A#,21,+")(.-!@%4//+-!$'.($'7&!;)%):')(.$! 1$2232)0.!/%),0($*$".!)8%+8)#')5!8$2$".7!1$2232)0!2<"+'!*%$($&,".! 2,($"".7!/)%)*!,!1$2232)0.!72)/'+!*$5(,$-!%+02,6".7!*$%4'#,% %39,7! +@$"#)(! )',&2)#! H<3,&+'! &)2?")5! ',&2)#.'! /$%)'&)-)")&$%")5! ',&2)#.*&! >;! 1$2232)0".7! -+#$%,+2)(! (+%<,%)(+2+&<! (! /%$*$2+7! .$$(
"#$ !
"$$$%!!"#$%&'()$!*%)+,'--).$+*"/! .'+,)! 0!+)(,$1)%"0'((23!4"%"5*'3! )16.$("!7$,"#"7!#)8%'*9))!%$(,:$("0+*)3!-6.$/%!
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
! |
"#" |
!
!"#$#%&'"()#"!*#+","-&"!+#,-./!!0(1+#!#+! )#2*$")(0!)0!3#)(&2"1&$4"$$5$#6.! (!%&,!06&,#2!&6#-&)#1&-#+#7!)&($#1.!
0"("!189:;<#!="$"!=>?89>@><#!2"5"!28A:?;BC:D><:#! ("3"!/:E@?;@><:#!,"!/>BC:F><:!!
!"#$%$&$!'%(()*+"%,-#.(/!0%1%%!23!456"! &7#!8#!2'9&77+-:+"!$%"!;+<.-"$!&56'-.%#$+"'!! ()*+,-.!,/012*34560,#728!
!"#$%!$&!$#'(#)$*#+!,-&*$*-./$0)1!#-2,-*3(#$4!2+356(#$1!7$% &$+3+8$6()9$! -9'$*#:0! 3(9-,)'*(##:0! *(/()'*! 1*31(')1! )$#'(&! $! $)% )3("+*-#$(!)*+4)'*!3(9-,)'*(##:0!),(")'*!#-!+)#+*(!%+"$7$;$,+*-#% #:0! %-3+'+9)$6#:0! 2,$,+"#:0! *:)+9+%+3(9531,#:0! )+("$#(#$4&! <,$,+"#:(!*:)+9+%+3(9531,#:(!)+("$#(#$1'!*!+'3$6$(!+'!)$#'('$6(% )9$0'!*!)*+(4!+)#+*(!$%(.'!583(*+"#5.!)',59'5,5!$!2+='+%5!2,+1*31%
.'!%(#>?5.!'+9)$6#+)'>!$!356?5.!7$&$+3+8$6()95.!)+*%()'$%+)'>&! @-$A+3((!2(,)2(9'$*#:%$!"31!,(?(#$1!#-)'+1/(4!2,+A3(%:!1*31.')1! 2,+$&*+"#:(!$!9+%23(9)#:(!)+("$#(#$1!#-!+)#+*(!9-,A+9)$%('$3;(3% 3.3+&:! (BCD)'! )',59'5,-! 2+3$%(,#+4! %-',$;:! 9+'+,+4! 2+&*+31('! )+&"-*-'>!+,$8$#-3>#:(!3(9-,)'*(##:(!2,(2-,-':&!!
E! ='+%! -)2(9'(! $#'(,()#:%$! 2,(")'-*31.')1! $))3("+*-#$1! 2,(2-% ,-'+*'!2+356(##:0!25'(%!*93.6(#$1!*!%-',$;5!2+3$%(,%#+)$'(31!BCD! $&*()'#:0!2,+'$*+'5A(,953(:0!2,(2-,-'+*!*"+&!F'+!2+&*+31('!;(3(#-% 2,-*3(##+! $&%(#1'>! $0! 7$&$9+%0$%$6()9$(! $! %("$9+%A$+3+8$6()9$(! )*+4)'*-'!'-9$(!9-9!)2(;$7$6()9-1!-9'$*#+)'>'!%(%A,-#+',+2#+)'>'!'+9% )$6#+)'>'!*,(%1!"(4)'*$1'!,(&$)'(#'#+)'>!$!",&!
E!,-A+'(!2,+*("(#:!$))3("+*-#$1!,(+3+8$6()9$0!2(,(,-A+'+6#:0! )*+4)'*! %-9,+%+3(9531,#:0! 9+%23(9)+*'! 2+356(##:0! )*1&:*-#$(%! 8$",+&$"-! $&+#$9+'$#+*+4! 9$)3+':! (GH@B)! )! %-9,+%+3(953+4! %+"$% 7$;$,+*-##+4! ,-%BCD'! $%(./(4! )'(2(#>! 2+3$%(,$&-;$$! (I<)! #..! $! )'(2(#>!&-%(/(#$1!2+!9-,A+9)$%('$3>#:%!8,522-%!/0&!
C+"$7$9-;$1!)3+J#+4!2+3$%(,#+4!%-',$;:!,-%BCD!*!2,+;())(! 2(,$+"-'#+8+!+9$)3(#$1!$!"-3>#(4?(8+!0$%$6()9+8+!)*1&:*-#$1!1!%+%
"#$ !
!"#$!%&'!()*+!%&'!,!-./%0-1%2'"&!,!-3245!#-&6!"#,245!/%01"71!"2( 245!,7/$#7$/)!6/'1-8'7!#!,$9",71"22-&$!'0&"2"2':!,7/$#7$/4*!!
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
),,!"8-1%2'"! /"-!-I'F",#'5! ,1->,71! $&"/"22-(#-2<"27/'/-1%2( 245! 1-8245! /%,71-/-1! ,%(+@A! '! #-&6!"#,%! &-8'?'<'/-1%22->! ,%( +@A!,!()*+!1",J&%!'2?-/&%7'12-)!6-,#-!J#$!'&"22-!/"-!-I'F",#'"! ,1->,71%! 2%'.-!""! F$1,71'7"!J24! #! '0&"2"2'=&! &-!"#$!=/2->! ,7/$#( 7$/4!6-!',%5%/'8-1*!!
K4!-!6-#%0%2-)!F7-!',,!"8-1%224"!,',7"&4!/%,71-/-1!,%(+@A!'! ""! #-&6!"#,%! 1! 6/-<",,"! 7"F"2'=! '&":7! 5%/%#7"/! %2-&%!''! 1=0#-I-! 7"F"2'=)!,1->,71"224>!6,"18-6!%,7'#%&*!!
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
! |
"#$ |
!
!! "#$%&! '#%$%()*#+,)#! )++$#-%./0)1! +)+2#&! $/%345! )! ##! ,%&% 6$#,+/!6%,/78./92!+:;#+2.#008#!'/7$)*)1!.!6%.#-#0))!)<!,%0"#02')% '%./008<!'/+2.%'%.&!%6'#-#$1#&8<!+2':,2:'%=!)+<%-0%=!&/2')"8!$/% 345&!'/7.#2.$#00%+2>9!+2':,2:'8!$/%345&!?%'&)':#&%=!.!6'%"#++#! 6#')%-/20%(%! %,)+$#0)1&! )! 6')'%-%=! ,%&6$#,+%%@'/7:9;#(%! $#,/'+2%
.#00%(%!6'#6/'/2/!ABC3'!!
D$1!)7:*#008<!+)+2#&!'/+2.%'%.!$/%345!)!##!,%&6$#,+/!'/++*)% 2/08!.#$)*)08!,/E:;#=+1!F0#'())!/,2)./"))!.17,%(%!2#*#0)1!!",/E!.! -)/6/7%0#! 2#&6#'/2:'! ()*+,#,3'! G0/*#0)1! !",/E&! 1.$19;)#+1! '%=! )02#0+).0%+2)! E&%$#,:$1'0%(%! .7/)&%-#=+2.)1! &/,'%&%$#,:$! .! '/+2.%'/<! -#.&! /! )0/*#! (%.%'1&! ,%+.#00%=! </'/,2#')+2),%=! 6'%*0%+2)! +2':,2:'8! 6%$)'08<! 2#,:*)<! +)+2#&! .! '/+2.%'/<&! 6').#-#08! 0)E#/! -$1!.%-0%(%!'/+2.%'/!!
$/%345/!!",/E0!(1&*"!,DE2&%$>3!
'/+2.%'/! &%-)?)")'%./00%(%! ,%&6$#,+0%(%! 6'%)7.%-0%(%! $/%345! +! ABC3/!!
!",/E0!,*&()!,DE2&%$>3!
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
.%-08<!'/+2.%'%.'!I/,)#!'/+2.%'8!+!@%$##!+$%E08&)!/++%")/2).08&)! %@'/7%./0)1&)!</'/,2#')7:92+1!@%$##!.8+%,%=!6'%*0%+2>9!+2':,2:'8'!
J8$)! %"#0#08! .#$)*)08! 5.17,%+208<! %@K#&%.6! 78! )$)! +'#-0#% +2/2)+2)*#+,)<! '/7'%.! ,)0#2)*#+,)<! #-)0)"! -#.'! !#$)*)08! 78! 1.% $192+1!,/*#+2.#00%=!</'/,2#')+2),%=&!,%2%'/1!6%7.%$1#2!%"#0)2>!6%-%
.)E0%+2>!+2':,2:'08<!F$#%.!)!)<!'/7'8'!!
!#$)*)08! 78! -$1! '/+2.%'%.! $/%345! )! ##! &%-)?)")'%./008<! ,%&6$#,+08<!6'%)7.%-08<!6').#-#08!.!2/@$)"#'!!
"## !
!"#$%$%&$!'(")*+,%*-*!*./$#0!%&!*,!,$#1$20,324!&!%012(5$%&(! +6'&-0!!!67(!+&+,$#!20+,'*2*'!'0(89:!&!$$!#*6&;&<&2*'0%%*-*! )*#17$)+%*-*!12*&"'*6%*-*!
!)!?0! |
@)!8! |
'0(89:! |
8*#17$)+!+!=!>8! |
|||
|
|
%&!!*"+,-!)!#-!! |
.!"+/)#! |
%&!!*"+,-!)!#-! |
.!"+/)#! |
|
|
,/0! |
""$,)1! |
,,$)/! |
"2+/),! |
,$2)1! |
|
1)-"! |
-"-! |
",+/)+! |
,,/)$! |
"22/)+! |
,1")+! |
|
-,0! |
",$0)0! |
,-,)1! |
"01-)+! |
,1$)+! |
||
|
||||||
|
-#-! |
"-"#)+! |
,-$)/! |
,+"$)$! |
,2,)+! |
|
|
,/0! |
2,-)$! |
"/-)#! |
"+0,)-! |
,,"),! |
|
"+)+! |
-"-! |
21,)/! |
"/1)0! |
"",+)$! |
,,-)0! |
|
-,0! |
2/1)#! |
"//)2! |
""2$)0! |
,,2)-! |
||
|
||||||
|
-#-! |
0-$)2! |
,+,)/! |
",21)+! |
,--)+! |
|
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
I7(!'*6%4B!20+,'*2*'!'0(89:!'$7&A&%4!%&!$D,!+3H$+,'$%%*!
#$%FG&$! "%0A$%&(! 1*! +20'%$%&D! +! %&! $$! #*6&;&<&2*'0%%4B! )*#( 17$)+%4B! 12*&"'*6%4B*! J*7$$! '4+*)&$! '$7&A&%4! %&! 67(! )*#17$)+0! *12$6$7(D,+(! '4+*)*E! +,$1$%FD! 3+G&')&4! 20"'$,'7$%%4B! +,23),32! '! '*6%4B! +2$60B)! .*7$$! '4+*)*E! &%,$%+&'%*+,FD! #$5#*7$)37(2%4B! '"0*6$E+,'&E)!0!K,*)!+**,'$,+,'$%%*)!12&'*6&,!)!'*"20+,0%&D!20"#$( 2*'!0++*<&0,&'%4B!+,23),32%4B!*.20"*'0%&E*!!
@0)! *.20"*#)! &++7$6*'0%4! 2$*7*-&A$+)&$! +'*E+,'0! 3#$2$%%*( )*%<$%,2&2*'0%%4B!20+,'*2*'!'0(89:!&!$$!#*6&;&<&2*'0%%*-*!)*#( 17$)+%*-*! 12*&"'*6%*-*! +! =!>8*! ?*)0"0%*)! A,*! 12&2*60! 1*7$2%*E! #0,2&<4!'0(89:!&!&"#$%$%&$!$$!+,2*$%&(!'!12*<$++$!#*6&;&)0<&&!&! )*#17$)+**.20"*'0%&(! +! =!>8! ('7($,+(! *+%*'%4#! ;0),*2*#)! *12$6$( 7(DH! +,23),323! 1*7$2%4B! +&+,$#! &! 2$*7*-&A$+)&B! +'*E+,'! )*%( <$%,2&2*'0%%4B!20+,'*2*'*!!
! |
"#$ |
!
!"#$%'%&!
"%! !"#$"%&$'()*!+%&!!&(,-$".(-/)*!+%&!01$&/)*!2%0%!''!34!!05667%! "()#%!8)%!6%!*+%!
,%! 9"#&'*!4%6%&!+)$"#&.)*!+%4%&!:"#)()*!;%4%&!<%!!&5-#)*!''!05%!%-$%!
,"#/%!,--$%!8,%!6%!").,,%!
*%! <'.#)=&*>)*1?-@!A%4%!A-(#)B->C/D'!-!E&1.-E/)!5&$'F'//D'!GB-#D! H'>>I>)5D!-!-%!$)(-B-?&H-J!=".'$!%-$-E'1?)K)!1L-*&/-J%!M%&!"(//%! ,(/!1%!
#%! 9)#/'#!7%N%!9')#'.-E'1?-'!)1/)*D!='#'#&O).?-!=)>-$'#)*&!:%&!"())%!
#$#!1%!
(!()*+,-+!./)+012/!34567*!+,,78!!,-14/152! 9+!!:!5;7!,/!50,52+!65<-=-9-452/,,5>5!!
9+!!:!5;505<+4?/@+>5!074AB!
;"1"!2&C"D"E&#$!B"."!/F%&GHI%$!J"/"!3HEHG&%$I&$!2"="!0HK"E#$!
2"2"!,&G$L#E"MHI#!
!!"#$"!%$&"#"'(%))*$$%"+,-,./"&0'((12'"
(!"#$"#&%+3$"&0'((12'""
)0'((14(514"61715'*896.':';1<9(514"=.1>9?(1898"
17+"@+)+"A9.B9:99>,%"A'(5>,"&0'((12'",*-./01"23//4567.389:5+:;"
P5*'1./)&!E.)!=#-!=)>"E'/--!=#)$DL>'//D%!/-.#&.)*!H'>>I>)5D! /')O%)(-$)!"E-.D*&.C!?&E'1.*)!H'>>I>)5/)K)!1D#CJ&!?).)#)'!*)!$/)0 K)$! )=#'('>J'.! .'%/)>)K-E'1?-'&! B-5-?)0$'%&/-E'1?-'&! %-$-E'1?-'! 1*)@1.*&! =#)("?H--%! P5$'/'/-J! *! ?&E'1.*'//D%! =)?&5&.'>J%! 1D#CJ! /&! B)/'! *)5#&1.&IF'@! 'K)! H'/D! -! ('B-H-./)1.-! 1)5(&I.! 1"F'1.*'//D'!
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
"#$ !
!"#$%&''!(')*('+,#-./0!."()"-&'.#'0!(%-/1'.#2!+"3'*,-"!!.#,)",%-! 4'&&5&%6/! %!7&! 2-&2',*2! #*(%&86%-".#'! ()'9-")#,'&8.%:%! :#9)%"! #*;%9.%:%!4'&&5&%6%*%9')<"=':%!*/)82!*!(%0%=85!*&"$%:%!)"*,-%)"! 0#.')"&8./;!+#*&%,!."!*,"9##!':%!%3#*,+#'!
>!+"3'*,-'!"&8,').",#-.%:%!4'&&5&%6%*%9')<"=':%!*/)82!)"**0",( )#-"5,*2!;&%(+%-/?!.,!%3#='../?!#!.'%3#='../?)!&8.2.%'!-%&%+.%)! 9)'-'*."2! 4'&&5&%6"! -! @%)0'! *("(+"+! -! *)"-.'.##! *%! 1,",.%?! ;&%(+%( -%?! 4'&&5&%6%?! ABCD! ,-,)!:#9)%%-"..%?! ;&%(+%-%?! 4'&&5&%6%?! ! #! 6")E$'<.%?!;&%(+%-%?!4'&&5&%6%?!(%!+&"**#@#+"4##!CFG'!!
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
.#2!!7!6"!*3',!)'"+4##!9'.#,)"4##'!K'.#,)"4##!!7!()#!+#*&%,.%*,#! *)'9/)! *%%,-',*,-E5='?! )'"+4#%..%?! *0'*#)! -*':9"! *%(E,*,-E5,! -,%( )#3./'!%+#*,'&8./'!()%4'**/'!L3',!#!E()"-&'.#'!I,#0#!()%4'**"0#! -!;%9'!(%&E3'.#2!4'&'-%:%!()%9E+,"!()'9%()'9'&25,!+"3'*,-%!4'&'-%( :%! ()%9E+,")! ':%! ;#0#3'*+E5! 3#*,%,E)! *,%?+%*,8)! -26+%*,./'! (")"0',( )/)!"!,"+<'!,';.%&%:#3.%*,8!(')')"$%,+#!-!#69''!
B(/,!()20%?!.#,)"4##!.,"!."!)"6./;!()'9()#2,#2;!%,)"*!(%( +"6"&)! 3,%! %,)"$%,"../'! +#*&%,/! ! (%*&'! ()%-'9'.#2! -! I,%?! +#*&%,.%?! *0'*#! -,%)%?! .#,)"4##! (%*&'! *%%,-',*,-E5='?! +%))'+,#)%-+#! *%*,"-"! 6"! *3',! *-'<'?! MNC! 6":)26.25,*2! #6(6"! -/*%+%?! 6"*%)'..%*,#! */)82)! "! ,"+<'!*#&8.%!6"*%)25,!%$%)E9%-".#'!."!E3"*,+";!9'.#,)"4##!#!+%.4'.( ,)#)%-".#2! *').%?! +#*&%,/'! O"+%-/'! +%&&%+*#./! (%*&'! %,$'&+#! (%! +"3'*,-'../0!(%+"6",'&20!!.'!E9%-&',-%)2!,)'$%-".#20!ABCD"'!
>! *-26#! *! I,#0! ()'9E*0",)#-"',*2! E.#-')*"&8."2! (%9:%,%-+"! )"6(
./;!,#(%-!4'&&5&%6!+!+#*&%0E!:#9)%E'!K&2!I,%:%!#*(%&86E',*2!"(("( )",! ()'9-")#,'&8.%:%! .":)'-"! *! 0'1"&+"0#! #! (")%-/0#! *,)E?./0#! ."( :)'-",'&20#)! +%,%)/?! )"60'='.! -! 4';'! %*.%-.%:%! ()%#6-%9*,-"! !7'! >! I,#;! E*&%-#2;! %*E='*,-&2',*2! %,9'&'.#'! ()#0'*'?! ! -! -%9.%?! +#*&%?! *)'9')! %9.%-)'0'..%! ! ()%#*;%9#,! 3"*,#3."2! 9'*,)E+4#2! 4'&&5&%6.%:%! */)82'!H)%4'**!+#*&%:%!:#9)%"!*!(%0%=85!*&"$/;!0#.')"&8./;!+#( *&%,! %"6%,.%?! #! *').%?! +#*&%,/&! #! *0'*#! %,)"$%,"../;! +#*&%,! (%(
! |
"#$ |
!
!"#!$%!&'()'*"#+$,!-.!"%&'()!/'!!!0&$!*+'"++!,1!2!3.&,#4!,!)."##!5#/!*! (!&'('!0&$!0-*'&$4#"6+./!!$(/#"65#+$$!0.-7.4.*"#++.7.!!8&6,!*!('-! /.-#&+$($&.*'++8%!/#"6+$9'%.!:.0."+$4#"6+8#!.0#&'9$$!.)"'7.&';$/ *'+$,!024#/!<#".5+.7.!7$-&."$('!!!0.!"#-2=<#>!3$!".*3.>!$!.4)#"3.>!! *! ?4./! !"25'#! $!3"=5'=4!,.! @!+.*+8#! A$($3./%$/$5#!3$#! %'&'34#&$/ !4$3$!0."25'#/.>!9#""=".(8!$(!"$+4'!!..4*#4!4*2=4!B@1C!&0&%!'!3'5#/ !4*#++8#! 0.3'('4#"$! 9#""=".(8! 0.! *,(3.!4$! +#! 2!420'=4! ('&2)#;+./2! '+'".72.!
1&'*+$4#"6+',! %'&'34#&$!4$3'! 3'5#!4*#++8%! 0.3'('4#"#>! 0&./ /8D"#++8%!+$4&'4.*!9#""=".(8!+'!.!+.*#!&'("$5+8%!4$0.*!7$-&."$/ (.*'++.>!9#""=".(8!0-!4'*"#+'!*!4')"$9#!(.!
E! '! !.-#&;'+$#! /$3&.0&$/#!#>! /#4'"".*! *! 3."".3$!"$+#! -",!
FGH! !.!4'*",#4! 1/'!!.)23! 45! '! +%++")%! 67! '! +%+++")%! 89! '! +%+++"-)%! 1:!'!+%+++++;)!
I$4&.*'+$#! 9#""=".(8! 0&.$(*.-$4!,! !! 25#4./! $+7$)$&.*'+$,!
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
!
"#$ !
!
!
!"#$%&"!"#! '%(%)*$+%,%-./)%.!+"0")1.0%/1%)%!0"($%-23+!1%4*5!!&.$$6$*(*/*7.08"9.:*!/30;<!
|
|
|
|
|
|
G0.5./$ |
|
=$*4)*5"<! |
||
|
|
=$*4)*5"<!%=>&! |
|
|
'()$*$+,-.%./&! |
|||||
|
B"%,.2*5"2%.!! |
|
2"<!%GH&! |
F;2<2"<! |
||||||
|
|
|
|
|
?@A! |
|||||
|
4*)"("1.$.C! |
|
|
|
|
I!5%7.! |
%J%C/)&! |
|||
|
=>$+0! |
F%21!DE?!! |
|
|
|
|
|
|||
|
|
|
=>$3! |
44"4)%5! |
|
"!)$"// |
|
+!)$"//! |
||
|
|
DE?!!010! |
23"3#,! |
|
|
|
|
|
|
|
|
K"//*5"<!7*$<!! |
1-81161! |
! |
|
116+! |
3181+! |
1-60! |
|
|
! |
|
L$&.$$6$*(36!7! |
|
|
|
|
|
|
|
|
|
|
K"//*5"<!7*$<!0"/15*0%$ |
8! |
! |
|
8! |
! |
! |
0! |
||
|
,3+!5.9./15!5!9.$*-%6!7! |
|
|
|
|
|
|
|
|
|
|
2.!#*$..! |
|
|
|
|
|
|
|
|
|
|
G%2",%-./)"<!5<()*/1;6! |
+0! |
! |
|
362! |
"28+-! |
098-,! |
9698",61! |
",82-! |
|
|
,M"#/! |
|
|
|
|
|
|
|
|
|
|
N"/*0.22*/1;67! |
! |
B.!#*$..! |
|
8! |
-8",! |
! |
|
|
! |
|
|
|
960! |
|
|
|
|
|
|
|
|
K"//*5"<!7*$<!(*$36!7! |
,#"8,62! |
"6-8"61! |
|
,6"0! |
,6"8,62! |
,62! |
B.!#*$..!,62! |
||
|
N0.$*/1;67! |
! |
3,830! |
|
8! |
! |
! |
|
|
! |
|
K"//*5"<!7*$<!43$%6!7!!! |
+6,! |
! |
|
! |
! |
! |
|
|
! |
|
K"//*5"<!7*$<!$%:2%2"#!7 |
8! |
8! |
|
8! |
,628,#9! |
,608"6,! |
|
|
! |
|
?,"-%5".,*/1;6!:! |
"90! |
! |
|
!"9:62! |
! |
"208"90! |
8! |
||
!
!
!
"91!
!