- •Introduction
- •Chapter # 1. The foundations of atomic-molecular studies. The laws and concepts of stoichiometry
- •Vocabulary
- •Subject and Tasks of Chemistry
- •General notions of atomic-molecular studies
- •Amount of substance. Mole. Avogadro’s Number. Molar mass
- •Number of moles of an element
- •Mass of an element (grams)
- •X Molar mass of element (Mm)
- •Number of atoms of an element
- •Example of solution
- •4. The laws and concepts of Stoichiometry
- •5. Types of chemical reactions
- •Chapter # 2. Atomic structure
- •Vocabulary
- •General notions
- •Theories of atomic structure
- •Figure 3. Spatial orientation of p-orbitals
- •3. Principles for distribution of electrons in atoms Distributions of electrons in atoms on energy levels and sub-levels may be presented in the form of electronic formulas.
- •Ground state
- •4. Valency and Oxidation number as function of electrons distribution
- •Practice problems
- •Chapter # 3. The periodic law and periodic table of chemical elements
- •Vocabulary
- •1. Formulation
- •2. Physical meaning of the chemical periodicity
- •3. The Periodic Table
- •Periodical table of chemical elements named by d.I. Mendeleev
- •Practice problems
- •Chapter # 4. Chemical bonding
- •Vocabulary
- •Types of Chemical Bonds
- •Ionic bond
- •Nonpolar-covalent bond
- •P olar-covalent bond
- •Figure 10. Formation of Hydrogen Bonds between water molecules
- •Figure 11. Depending of boiling-points (b.Pt) of double Hydrogen-contained compounds from nature of the second atom and presence of Hydrogen bonding
- •Why does Chemical Bond occur?
- •Practice problems
- •Сhapter # 5. Laboratory glassware, labware and rules of laboratory research
- •Vocabulary
- •Chemical glassware
- •2. Chemical reagents and their storage
- •3. Elementary operations carrying out
- •4. Safety rules during carrying out laboratory works
- •5. Rules for reagents and equipment use
- •6. Rules for work carrying out and results design
- •Chapter # 6. The main classes of inorganic compounds
- •Vocabulary
- •Classification of inorganic substances
- •Inorganic substances
- •Compounds
- •2. Relation between main classes of inorganic substances
- •3. Oxides
- •Preparation
- •Chemical properties
- •4. Bases
- •Preparation
- •Chemical properties
- •5. Acids
- •Preparation
- •Chemical properties
- •6. Amphoteric hydroxides
- •Preparation
- •7. Salts
- •Preparation
- •Chemical properties
- •Chemical properties
- •6. Thermal decomposition with medium salts formation:
- •Structural-graphic formulas of chemical compounds
- •Example of solution
- •Chapter # 7. Theory of electrolytic dissociation
- •Vocabulary
- •Solutions
- •Concentration of solutions
- •Molarity (molar concentration)
- •Theory of dissociation
- •Degree of dissociation
- •Main classes of inorganic substances from viewpoint of theory of electrolytic dissociation
- •6. Ionic equations
- •Laboratory training
- •Chapter # 8. Ionic product of water. Hydrolysis of salts
- •Vocabulary
- •Ionic product of water. Notion of pH
- •General notion of Hydrolysis
- •Different types of Hydrolysis
- •Laboratory training Experiment 1. Identification of reaction medium in solutions of salts
- •Experiment 2. Influence of temperature to hydrolysis
- •Chapter # 9. Oxidation-reduction reactions
- •Vocabulary
- •1. Oxidation of Elements
- •2. Oxidation-Reduction Reactions
- •3. Compiling Equations of Oxidation-Reduction Reactions
- •4. Most Important Oxidizing and Reducing Agents
- •Types of Redox Reactions
- •Influence of Medium to Redox Reactions
- •Electromotive Series of Metals
- •Laboratory training Experiment 1. Reducing properties of metal ions of lower oxidation number
- •Chapter # 10. Complex (coordination) compounds
- •Vocabulary
- •1. General characteristics
- •2. Nomenclature
- •3. Rules for naming of coordination compounds
- •Laboratory training
- •Chapter # 11. The halogens
- •Vocabulary
- •1. General characteristics
- •2. Chlorine
- •Laboratory training
- •Experiment 2. Halogens oxidative activity in free state
- •Experiment 5. The salts of hydrohalogen acids insoluble in water
- •Chapter # 12. The chalcogens
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Oxygen
- •3. Sulfur
- •Experiment 6. Dilution of concentrated Sulfuric acid
- •Experiment 9. Instability of thiosulfuric acid
- •Chapter # 13. Nitrogen, phosphorus
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Nitrogen
- •3. Phosphorus
- •Phosphorus behaves as the typical non-metal. It reacts with Oxygen, formed acid oxides:
- •Experiment 2. Oxidation and reducing power of nitrous acid and Nitrites
- •Chapter # 14. Chemistry of main biometals
- •Vocabulary
- •1. The Alkali Metals
- •Industrial Information
- •2. Other bioactive metals
4. Safety rules during carrying out laboratory works
All experiments with poison, fugitive, inflammable substances and substances with a specific odor are to be carried out in ventilating hoods.
It is forbidden to smell evolving gases, stooping close to a vessel. If it is necessary to smell the gas, cautiously direct by hand the flow of air from vessel to nose.
It is forbidden to leave working electrical and gas equipment without supervision.
At pouring liquids, and also at heating of vessel with liquid it is forbidden to stoop above it or to direct its aperture on other people, in order to prevent hit of drops of a liquid on the face or clothes. If drops of a liquid hit on the face or the hands, it is necessary to wash them off immediately with water and to wipe with rag. The drops of concentrated acid are to be washed off with a plenty of water then injured places are to be washed with weak soda solution. The alkali is necessary to be washed off with water until skin will not be slip.
In case of a fire in laboratory use the fire extinguisher. For extinguishing benzene, alcohol or ether, it is necessary to use sand, strewing flame with it. In case of thermal burn (by flame of the burner or hot subjects) it is necessary to moisten the burnt place with strong solution of Potassium permanganate so that the skin became brown, or to put cotton wool moistened with liquid against burns. If burns are heavy, it is necessary to call for the doctor immediately.
It is strictly forbidden to eat, to smoke, to taste anything, to make the disorder in chemical laboratory.
After the end of the work in the laboratory it is necessary to check up, that gas, heating, measuring or other electrical equipment is switched off.
5. Rules for reagents and equipment use
Solutions and solid reagents are to be stored in glassware (flasks, boxes), covered with glass (ground), rubber or cork stoppers. All flasks with reagents are to be kept closed and are to be opened only when being used. Closing flasks do not confuse stoppers, or reagents will be contaminated and unfit. Before taking the flask with reagent from the shelf, read the etiquette with its name attentively; after using it is necessary to bring the flask back.
All flasks with reagents always must be provided with the etiquette with the substance name or chemical formula. For solutions the concentration should be marked. Reagents in the flasks without etiquette are to be excluded and exterminated.
If there is no instruction on the reagents dosage, it is necessary to take reagent as little as possible, namely: the amount that covers the bottom of the test tube of solid substance and 1-2 mL of solutions. It is not allowed to bring remains of reagents back to the glassware where they were taken from. After the using of reagent it is necessary to cover the box or flask with stopper immediately and bring it back to its place.
Solid substances are to be taken with dry and clean horn, porcelain, metallic spoons or spreading rods (shovels), after using they are to be wiped thoroughly (the best is with filter paper).
When liquid is poured from the flask, keep the flask so that etiquette is on the top in order the drops of reagent flowing down could not damage etiquette. Practically, it is necessary to take the flask so that etiquette is in your palm and to take off the last drop of reagent with the edge of glassware where reagent is poured in. Using pipette, it is necessary to wash it thoroughly before taking the reagent from other flask.
At diluting the concentrated acid (Sulfuric especially) it is necessary to pour acid in water, but not on the contrary.
Excess amounts of reagents containing poisonous substances are not allowed to be poured to the sewerage; they are to be poured in special flasks.
