- •Introduction
- •Chapter # 1. The foundations of atomic-molecular studies. The laws and concepts of stoichiometry
- •Vocabulary
- •Subject and Tasks of Chemistry
- •General notions of atomic-molecular studies
- •Amount of substance. Mole. Avogadro’s Number. Molar mass
- •Number of moles of an element
- •Mass of an element (grams)
- •X Molar mass of element (Mm)
- •Number of atoms of an element
- •Example of solution
- •4. The laws and concepts of Stoichiometry
- •5. Types of chemical reactions
- •Chapter # 2. Atomic structure
- •Vocabulary
- •General notions
- •Theories of atomic structure
- •Figure 3. Spatial orientation of p-orbitals
- •3. Principles for distribution of electrons in atoms Distributions of electrons in atoms on energy levels and sub-levels may be presented in the form of electronic formulas.
- •Ground state
- •4. Valency and Oxidation number as function of electrons distribution
- •Practice problems
- •Chapter # 3. The periodic law and periodic table of chemical elements
- •Vocabulary
- •1. Formulation
- •2. Physical meaning of the chemical periodicity
- •3. The Periodic Table
- •Periodical table of chemical elements named by d.I. Mendeleev
- •Practice problems
- •Chapter # 4. Chemical bonding
- •Vocabulary
- •Types of Chemical Bonds
- •Ionic bond
- •Nonpolar-covalent bond
- •P olar-covalent bond
- •Figure 10. Formation of Hydrogen Bonds between water molecules
- •Figure 11. Depending of boiling-points (b.Pt) of double Hydrogen-contained compounds from nature of the second atom and presence of Hydrogen bonding
- •Why does Chemical Bond occur?
- •Practice problems
- •Сhapter # 5. Laboratory glassware, labware and rules of laboratory research
- •Vocabulary
- •Chemical glassware
- •2. Chemical reagents and their storage
- •3. Elementary operations carrying out
- •4. Safety rules during carrying out laboratory works
- •5. Rules for reagents and equipment use
- •6. Rules for work carrying out and results design
- •Chapter # 6. The main classes of inorganic compounds
- •Vocabulary
- •Classification of inorganic substances
- •Inorganic substances
- •Compounds
- •2. Relation between main classes of inorganic substances
- •3. Oxides
- •Preparation
- •Chemical properties
- •4. Bases
- •Preparation
- •Chemical properties
- •5. Acids
- •Preparation
- •Chemical properties
- •6. Amphoteric hydroxides
- •Preparation
- •7. Salts
- •Preparation
- •Chemical properties
- •Chemical properties
- •6. Thermal decomposition with medium salts formation:
- •Structural-graphic formulas of chemical compounds
- •Example of solution
- •Chapter # 7. Theory of electrolytic dissociation
- •Vocabulary
- •Solutions
- •Concentration of solutions
- •Molarity (molar concentration)
- •Theory of dissociation
- •Degree of dissociation
- •Main classes of inorganic substances from viewpoint of theory of electrolytic dissociation
- •6. Ionic equations
- •Laboratory training
- •Chapter # 8. Ionic product of water. Hydrolysis of salts
- •Vocabulary
- •Ionic product of water. Notion of pH
- •General notion of Hydrolysis
- •Different types of Hydrolysis
- •Laboratory training Experiment 1. Identification of reaction medium in solutions of salts
- •Experiment 2. Influence of temperature to hydrolysis
- •Chapter # 9. Oxidation-reduction reactions
- •Vocabulary
- •1. Oxidation of Elements
- •2. Oxidation-Reduction Reactions
- •3. Compiling Equations of Oxidation-Reduction Reactions
- •4. Most Important Oxidizing and Reducing Agents
- •Types of Redox Reactions
- •Influence of Medium to Redox Reactions
- •Electromotive Series of Metals
- •Laboratory training Experiment 1. Reducing properties of metal ions of lower oxidation number
- •Chapter # 10. Complex (coordination) compounds
- •Vocabulary
- •1. General characteristics
- •2. Nomenclature
- •3. Rules for naming of coordination compounds
- •Laboratory training
- •Chapter # 11. The halogens
- •Vocabulary
- •1. General characteristics
- •2. Chlorine
- •Laboratory training
- •Experiment 2. Halogens oxidative activity in free state
- •Experiment 5. The salts of hydrohalogen acids insoluble in water
- •Chapter # 12. The chalcogens
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Oxygen
- •3. Sulfur
- •Experiment 6. Dilution of concentrated Sulfuric acid
- •Experiment 9. Instability of thiosulfuric acid
- •Chapter # 13. Nitrogen, phosphorus
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Nitrogen
- •3. Phosphorus
- •Phosphorus behaves as the typical non-metal. It reacts with Oxygen, formed acid oxides:
- •Experiment 2. Oxidation and reducing power of nitrous acid and Nitrites
- •Chapter # 14. Chemistry of main biometals
- •Vocabulary
- •1. The Alkali Metals
- •Industrial Information
- •2. Other bioactive metals
Figure 11. Depending of boiling-points (b.Pt) of double Hydrogen-contained compounds from nature of the second atom and presence of Hydrogen bonding
The evaporation of sweat, used by many mammals to cool themselves, achieves this by the large amount of heat needed to break the hydrogen bonds between water molecules.
Moderating temperature shifts in the ecosystem (which is why the climate is more moderate near large bodies of water like the ocean).
Multiple hydrogen bonds in alive objectes:
hold the two strands of the DNA double helix together:
hold polypeptides together in such secondary structures as the alpha helix and the beta conformation;
help enzymes bind to their substrate;
help antibodies bind to their antigen
help transcription factors bind to each other;
help transcription factors bind to DNA.
Why does Chemical Bond occur?
The fascinating variety of materials in the world around us is possible because chemical bonds unite atoms of the elements in so many different combinations. Some elements are found in nature only in chemical compounds. Even the atoms of elements that can be found in nature in uncombined form - such as Oxygen and Nitrogen in the air, of Gold and Copper in the Earth’s crust - do not exist as independent atoms. They are bonded together.
If their potential energy is lowered by the change, two atoms will form a chemical bond. Throughout nature, changes that decrease potential energy are favored. Books fall off desks, and the result is lower potential energy for the books. Most atoms have lower potential energy in bonds than as independent atoms.
Chemical-bond formation is often energy - releasing process. Experiments also show that the reverse - breaking chemical bonds - is often an energy-absorbing process. Atoms separated by breaking a chemical bond have a higher total potential energy than when they were bonded. Whether or not a given chemical reaction occurs spontaneously is partly dependent on whether or not forming new bonds in the products produced enough energy to break bonds in the reactants.
Covalent, ionic and metallic bond all decrease the potential energy of the combined atoms.
Practice problems
What are the three major types of bonds?
What is the role of electronegativity in the determination of the ionic or covalent character of a bond?
What type of bond would be expected between H and F; Cu and S; Br and I?
List the three bond pairs referred to in the previous question in order to increase ionic characters.
Сhapter # 5. Laboratory glassware, labware and rules of laboratory research
Vocabulary
English |
Українська назва |
English |
Українська назва |
Test-tube |
Пробірка |
Gooch crucible |
Тигель Гуча |
Beaker |
Стакан |
Cylinder |
Циліндр (мірний) |
Walter’s Crucible Holder |
Держач для тиглів Вальтера |
Mortar |
Ступка |
Pestle |
Пестик |
||
Buchner Funnel |
Воронка Бюхнера |
Spatula |
Шпатель |
Clamp |
Зажим |
Pump |
Пробовідбірник (хімічний) |
Crystallizing Dish |
Кристалізатор |
Erlenmeyer’s flask |
Колба Ерленмеєра |
Dropper Bottle |
Крапельниця |
Volumetric flask |
Мірна колба |
Cork |
Корок |
Evaporation dish |
Випарювальна чашка |
Florence flask |
Круглодонна колба |
Pipette |
Піпетка |
Forceps |
Пінцет |
Filtering funnel |
Воронка для фільтрування |
Glass jar |
Склянка |
The most useful chemical glassware is presented in Fig. 12 and 13.
F
igure
12. Chemical Glassware
Test tube |
Beaker |
Erlenmeyer Flask |
Florence Flask |
Volumetric Flask |
Dropper Bottle |
Glass Jar |
Filtering Funnel |
Buchner’s Funnel |
Gooch’s Crucible |
Walter’s Crucible Holder |
Pi-Pump |
Graduated Cylinder |
Test tube clamp |
Clamps |
Watch glass |
Thermometers |
Spatulas
Volumetric pipettes
Evaporation dish |
Pestle and mortar |
Forceps |
Crystallizing Dish as sand bath
Figure 13. Separate varieties of laboratory glassware
