- •Introduction
- •Chapter # 1. The foundations of atomic-molecular studies. The laws and concepts of stoichiometry
- •Vocabulary
- •Subject and Tasks of Chemistry
- •General notions of atomic-molecular studies
- •Amount of substance. Mole. Avogadro’s Number. Molar mass
- •Number of moles of an element
- •Mass of an element (grams)
- •X Molar mass of element (Mm)
- •Number of atoms of an element
- •Example of solution
- •4. The laws and concepts of Stoichiometry
- •5. Types of chemical reactions
- •Chapter # 2. Atomic structure
- •Vocabulary
- •General notions
- •Theories of atomic structure
- •Figure 3. Spatial orientation of p-orbitals
- •3. Principles for distribution of electrons in atoms Distributions of electrons in atoms on energy levels and sub-levels may be presented in the form of electronic formulas.
- •Ground state
- •4. Valency and Oxidation number as function of electrons distribution
- •Practice problems
- •Chapter # 3. The periodic law and periodic table of chemical elements
- •Vocabulary
- •1. Formulation
- •2. Physical meaning of the chemical periodicity
- •3. The Periodic Table
- •Periodical table of chemical elements named by d.I. Mendeleev
- •Practice problems
- •Chapter # 4. Chemical bonding
- •Vocabulary
- •Types of Chemical Bonds
- •Ionic bond
- •Nonpolar-covalent bond
- •P olar-covalent bond
- •Figure 10. Formation of Hydrogen Bonds between water molecules
- •Figure 11. Depending of boiling-points (b.Pt) of double Hydrogen-contained compounds from nature of the second atom and presence of Hydrogen bonding
- •Why does Chemical Bond occur?
- •Practice problems
- •Сhapter # 5. Laboratory glassware, labware and rules of laboratory research
- •Vocabulary
- •Chemical glassware
- •2. Chemical reagents and their storage
- •3. Elementary operations carrying out
- •4. Safety rules during carrying out laboratory works
- •5. Rules for reagents and equipment use
- •6. Rules for work carrying out and results design
- •Chapter # 6. The main classes of inorganic compounds
- •Vocabulary
- •Classification of inorganic substances
- •Inorganic substances
- •Compounds
- •2. Relation between main classes of inorganic substances
- •3. Oxides
- •Preparation
- •Chemical properties
- •4. Bases
- •Preparation
- •Chemical properties
- •5. Acids
- •Preparation
- •Chemical properties
- •6. Amphoteric hydroxides
- •Preparation
- •7. Salts
- •Preparation
- •Chemical properties
- •Chemical properties
- •6. Thermal decomposition with medium salts formation:
- •Structural-graphic formulas of chemical compounds
- •Example of solution
- •Chapter # 7. Theory of electrolytic dissociation
- •Vocabulary
- •Solutions
- •Concentration of solutions
- •Molarity (molar concentration)
- •Theory of dissociation
- •Degree of dissociation
- •Main classes of inorganic substances from viewpoint of theory of electrolytic dissociation
- •6. Ionic equations
- •Laboratory training
- •Chapter # 8. Ionic product of water. Hydrolysis of salts
- •Vocabulary
- •Ionic product of water. Notion of pH
- •General notion of Hydrolysis
- •Different types of Hydrolysis
- •Laboratory training Experiment 1. Identification of reaction medium in solutions of salts
- •Experiment 2. Influence of temperature to hydrolysis
- •Chapter # 9. Oxidation-reduction reactions
- •Vocabulary
- •1. Oxidation of Elements
- •2. Oxidation-Reduction Reactions
- •3. Compiling Equations of Oxidation-Reduction Reactions
- •4. Most Important Oxidizing and Reducing Agents
- •Types of Redox Reactions
- •Influence of Medium to Redox Reactions
- •Electromotive Series of Metals
- •Laboratory training Experiment 1. Reducing properties of metal ions of lower oxidation number
- •Chapter # 10. Complex (coordination) compounds
- •Vocabulary
- •1. General characteristics
- •2. Nomenclature
- •3. Rules for naming of coordination compounds
- •Laboratory training
- •Chapter # 11. The halogens
- •Vocabulary
- •1. General characteristics
- •2. Chlorine
- •Laboratory training
- •Experiment 2. Halogens oxidative activity in free state
- •Experiment 5. The salts of hydrohalogen acids insoluble in water
- •Chapter # 12. The chalcogens
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Oxygen
- •3. Sulfur
- •Experiment 6. Dilution of concentrated Sulfuric acid
- •Experiment 9. Instability of thiosulfuric acid
- •Chapter # 13. Nitrogen, phosphorus
- •Vocabulary
- •1. General characteristics
- •Industrial Information
- •2. Nitrogen
- •3. Phosphorus
- •Phosphorus behaves as the typical non-metal. It reacts with Oxygen, formed acid oxides:
- •Experiment 2. Oxidation and reducing power of nitrous acid and Nitrites
- •Chapter # 14. Chemistry of main biometals
- •Vocabulary
- •1. The Alkali Metals
- •Industrial Information
- •2. Other bioactive metals
3. The Periodic Table
The Periodic Table is an arrangement of the elements according to their atomic numbers so that elements with similar properties fall in the same column.
The length of each period in the Periodic table determinates by the sublevel being filled with electrons as shown in table 7. The first energy level holds only two electrons in its 1s sublevel. Hydrogen and Helium are presented in the first period. The second main-energy level holds two electrons in 2s-sublevel and six electrons in 2p-sublevel. These eight electrons account for the eight elements presence in the second period. In eight elements of the third period, 3s- and 3p-sublevels are being filled.
Table 7. Relationship between quantity of elements in period and sublevels being filled in the Periodic Table
Period Number |
Number of Elements in Period |
Energy Sublevels in Order of Filling |
1 |
2 |
1s |
2 |
8 |
2s 2p |
3 |
8 |
3s 3p |
4 |
18 |
4s 3d 4p |
5 |
18 |
5s 4d 5p |
6 |
32 |
6s 4f 5d 6p |
7 |
23 (to date) |
7s 5f 6d etc. |
Filling 3d and 4d-sublevels in addition to s and p sublevels adds 10 elements to fourth and fifth periods, which therefore include totally 18 elements each. Filling 4f sublevels in addition to s, p, d sublevels adds 14 elements to the sixth period, for totally of 32 elements in the sixth period. As new artificial elements are created, the 23 known elements in period 7 could be extended to 32.
The period of element can be determined from its electron configuration. For example, Arsenic (As) has the configuration [Ar]3d104s24p3. The “4” in “4p3” indicates that the highest one occupied energy level is the fourth energy level. Arsenic is therefore in the fourth period in the Periodic Table.
There are a lot of styles for presentation of Periodical Table of Chemical Elements (authors Stowe, Benfey, Zmaczynski, Gicuere - more details http:/chemlab.pc.maricopa.edu/periodic/styles.html). In Ukraine the most popular one is so-called “Short-Periodic” form, presented in Appendix 1. The Modern style of so-called “Long-Periodic” table is presented in Fig. 4.
Periodical table of chemical elements named by d.I. Mendeleev
Figure 4. “Long-Periodic” style of Periodic table
A science exhibit designer, Roy Alexander, to eliminate the confusion and apparent inconsistencies in the flat table by arranging the elements contiguously and continuously according to the atomic number without disturbing the accepted group, originated the improvement for learning and using the Periodic Table and property interrelationships previously found in the periodic chart (see Fig. 5).
Figure 5. Roy Alexander Arrangement of the Elements
The resulting form has three parts looping outwards from a relatively central point. The elements in Groups 0 (VIII), Ia, IIa, IIIb, IVb, Vb, and VIIIb are in the narrowest and tallest part, which forms a tube in the upper part, topped by a “crown” of Hydrogen. From the lower part of this component the sides branch to a lengthier loop showing IIIa, IVa, Va, VIa, VIIa, VIII, Ib, and IIb groups. From the lower half of this, the third, and longest loop protrudes the f-block.
Printed as a flat sheet, it can be easily assembled into a 3-D model by teacher or student. All printed element data, therefore, have a common plane so their electron numbers can trace the elements without changing direction or leaving the surface.
