
- •11.1 Cooling
- •Table 11.2 Molecular Lowering of the Melting or Freezing Point
- •11.2 Drying and Humidification
- •11.3 Boiling Points and Heating Baths
- •Table 11.8 Organic Solvents Arranged by Boiling Points
- •Table 11.9 Molecular Elevation of the Boiling Point
- •11.4 Separation Methods
- •Table 11.11 Solvents of Chromatographic Interest
- •11.4.1 McReynolds’ Constants
- •11.4.2 Chromatographic Behavior of Solutes
- •11.4.3 Ion-Exchange (Normal Pressure, Columnar)
- •Table 11.16 Guide to Ion-Exchange Resins
- •Table 11.18 Relative Selectivity of Various Counter Anions
- •11.5 Gravimetric Analysis
- •Table 11.19 Gravimetric Factors
- •Table 11.20 Elements Precipitated by General Analytical Reagents
- •Table 11.21 Cleaning Solutions for Fritted Glassware
- •Table 11.25 Tolerances for Analytical Weights
- •Table 11.26 Heating Temperatures, Composition of Weighing Forms, and Gravimetric Factors
- •11.6 Volumetric Analysis
- •Table 11.28 Titrimetric (Volumetric) Factors
- •11.6.3 Standard Volumetric (Titrimetric) Redox Solutions
- •11.6.4 Indicators for Redox Titrations
- •11.6.5 Precipitation Titrations
- •11.6.6 Complexometric Titrations
- •11.6.7 Masking Agents
- •11.6.8 Demasking
- •Table 11.30 Standard Solutions for Precipitation Titrations
- •Table 11.31 Indicators for Precipitation Titrations
- •Table 11.32 Properties and Applications of Selected Metal Ion Indicators
- •Table 11.41 Pipet Capacity Tolerances
- •Table 11.43 Buret Accuracy Tolerances
- •11.7 Laboratory Solutions
- •11.7.1 General Reagents, Indicators, and Special Solutions
- •Table 11.49 TLV Concentration Limits for Gases and Vapors
- •Table 11.52 Chemicals Which Polymerize or Decompose on Extended Refrigeration
- •11.9 Thermometry
- •11.9.1 Temperature and Its Measurement
- •11.10 Thermocouples
- •Table 11.63 Type T Thermocouples: Copper vs. Copper-Nickel Alloy
- •11.11 Correction for Emergent Stem of Thermometers

11.150 |
SECTION 11 |
11.11 CORRECTION FOR EMERGENT STEM OF THERMOMETERS
When a thermometer which has been standardized for total immersion is used with a part of the liquid column at a temperature below that of the bulb, the reading is low and a correction must be applied. The stem correction, in degrees Celsius, is given by
|
KL (to |
tm ) degrees Celsius |
where K |
constant, characteristic of the particular kind of glass and temperature (see Table 11.49) |
|
L |
length of exposed thermometer, |
C (that is, the length not in contact with vapor or liquid |
|
being measured) |
|
to |
observed temperature on thermometer |
|
tm |
mean temperature of exposed column (obtained by placing an auxiliary thermometer |
|
alongside with its bulb midpoint) |
|
|
|
|
|
||
For thermometers containing organic liquids, it is |
sufficient to use |
the approximate value, |
K |
|||||
0.001. |
In such thermometers the value of |
K is practically independent of the kind of glass. |
|
|||||
TABLE 11.64 Values of |
K |
for Stem Correction of Thermometers |
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|
Temperature, |
|
C |
Soft glass |
Heat-resistant glass |
|
||
|
|
|
|
|
|
|
|
|
|
0– 150 |
|
0.000 |
158 |
0.000 |
165 |
|
|
|
200 |
|
|
0.000 |
159 |
0.000 |
167 |
|
|
250 |
|
|
0.000 |
161 |
0.000 |
170 |
|
|
300 |
|
|
0.000 |
164 |
0.000 |
174 |
|
350 |
0.000 |
178 |
400 |
0.000 |
183 |
450 |
0.000 |
188 |
|
|
|