- •11.1 Cooling
- •Table 11.2 Molecular Lowering of the Melting or Freezing Point
- •11.2 Drying and Humidification
- •11.3 Boiling Points and Heating Baths
- •Table 11.8 Organic Solvents Arranged by Boiling Points
- •Table 11.9 Molecular Elevation of the Boiling Point
- •11.4 Separation Methods
- •Table 11.11 Solvents of Chromatographic Interest
- •11.4.1 McReynolds’ Constants
- •11.4.2 Chromatographic Behavior of Solutes
- •11.4.3 Ion-Exchange (Normal Pressure, Columnar)
- •Table 11.16 Guide to Ion-Exchange Resins
- •Table 11.18 Relative Selectivity of Various Counter Anions
- •11.5 Gravimetric Analysis
- •Table 11.19 Gravimetric Factors
- •Table 11.20 Elements Precipitated by General Analytical Reagents
- •Table 11.21 Cleaning Solutions for Fritted Glassware
- •Table 11.25 Tolerances for Analytical Weights
- •Table 11.26 Heating Temperatures, Composition of Weighing Forms, and Gravimetric Factors
- •11.6 Volumetric Analysis
- •Table 11.28 Titrimetric (Volumetric) Factors
- •11.6.3 Standard Volumetric (Titrimetric) Redox Solutions
- •11.6.4 Indicators for Redox Titrations
- •11.6.5 Precipitation Titrations
- •11.6.6 Complexometric Titrations
- •11.6.7 Masking Agents
- •11.6.8 Demasking
- •Table 11.30 Standard Solutions for Precipitation Titrations
- •Table 11.31 Indicators for Precipitation Titrations
- •Table 11.32 Properties and Applications of Selected Metal Ion Indicators
- •Table 11.41 Pipet Capacity Tolerances
- •Table 11.43 Buret Accuracy Tolerances
- •11.7 Laboratory Solutions
- •11.7.1 General Reagents, Indicators, and Special Solutions
- •Table 11.49 TLV Concentration Limits for Gases and Vapors
- •Table 11.52 Chemicals Which Polymerize or Decompose on Extended Refrigeration
- •11.9 Thermometry
- •11.9.1 Temperature and Its Measurement
- •11.10 Thermocouples
- •Table 11.63 Type T Thermocouples: Copper vs. Copper-Nickel Alloy
- •11.11 Correction for Emergent Stem of Thermometers
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PRACTICAL |
LABORATORY INFORMATION |
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11.137 |
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11.8 SIEVES AND SCREENS |
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TABLE 11.53 |
U.S. Standard Sieve Series |
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Sieve opening |
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Sieve opening |
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Sieve no. |
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mm |
inch |
Sieve no. |
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mm |
inch |
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125 |
5.00 |
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10 |
2.00 |
0.0787 |
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106 |
4.24 |
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12 |
1.70 |
0.0661 |
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90 |
3.50 |
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14 |
1.40 |
0.0555 |
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75 |
3.00 |
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16 |
1.18 |
0.0469 |
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63 |
2.50 |
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18 |
1.00 |
0.0394 |
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53 |
2.12 |
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20 |
0.850 |
0.0331 |
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45 |
1.75 |
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25 |
0.710 |
0.0278 |
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37.5 |
1.50 |
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30 |
0.600 |
0.0234 |
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31.5 |
1.25 |
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35 |
0.500 |
0.0197 |
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26.5 |
1.06 |
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40 |
0.425 |
0.0165 |
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22.4 |
0.875 |
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45 |
0.355 |
0.0139 |
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19.0 |
0.75 |
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50 |
0.300 |
0.0117 |
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16.0 |
0.625 |
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60 |
0.250 |
0.0098 |
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13.2 |
0.530 |
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70 |
0.212 |
0.0083 |
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11.2 |
0.438 |
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80 |
0.180 |
0.0070 |
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9.5 |
0.375 |
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100 |
0.150 |
0.0059 |
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8.0 |
0.312 |
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120 |
0.125 |
0.0049 |
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6.7 |
0.265 |
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140 |
0.106 |
0.0041 |
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3.5 |
5.60 |
0.223 |
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170 |
0.090 |
0.0035 |
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4 |
4.75 |
0.187 |
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200 |
0.075 |
0.0029 |
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5 |
4.00 |
0.157 |
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230 |
0.063 |
0.0025 |
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6 |
3.35 |
0.132 |
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270 |
0.053 |
0.0021 |
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7 |
2.80 |
0.111 |
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325 |
0.045 |
0.0017 |
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8 |
2.36 |
0.0937 |
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400 |
0.038 |
0.0015 |
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Specifications are from ASTM E.11-81/ISO 565. The sieve numbers are the approximate number of openings per linear inch.
11.9 THERMOMETRY
11.9.1Temperature and Its Measurement
The new international temperature scale, known as ITS-90, was adopted in September 1989. How- |
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ever, neither the definition of thermodynamic temperature nor the definition of the kelvin or the |
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Celsius temperature scales has changed; it is the way in which we are to realize these definitions |
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that has changed. The changes concern the recommended thermometers to be used in different |
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regions of the temperature scale and the list of secondary standard fixed points. The changes in |
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temperature determined using ITS-90 from the previous IPTS-68 are always less than |
and |
0.4 K, |
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almost always less than |
over0.2theK,range |
0– 1300 K. |
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The ultimate definition of thermodynamic temperature is in terms of |
pV (pressure |
volume) |
in |
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a gas thermometer extrapolated to low pressure. The kelvin (K), the unit of thermodynamic tem- |
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perature, is defined by specifying the temperature of one fixed point on the |
triple pointscale— the |
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