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1. Muzzarelli R.A.A. Chitin. Oxford: Pergamon Press, 1977. 573 1.
2;,0(8+ =.>., ?$%.2" @.>., A"#0,+7 B.?. // C(*&/0 /0300. 1977. D. 46. E9*.
8. B. 1470–1487.
3.Chitin and Chitosan: Sources, Chemistry, Biochemistry, Physical Properties and Application / Ed. T. Anthonsen. L.; N.Y.: Elsevier. 1990. 918 1.
4.F"('1+7") G,&8'1+##") 3081+(8+*0) 0 1'2+7(804 3081+"#",0! / ;+% 1&%. E.H. ;&'1+7". I., 1984. B. 301–305.
5.A&/"#% H., A"#6 F., J033&1 E., K3+,.8& F. HJ-(*&8'1+(8+*0) *+,03&1+7.
I., 1976. B. 472–473.
6.Paspiezny H., Struszozyk H., Chirkov S.N., Atabekov J.G. // CHITIN WORD / Ed. By Karnicki Z.S.: Wirshaftsverlag NW, 1995. P. 246–254.
7.L018+7 B.F., H,.0#" M.E., B$12$-&7" ?.>. 0 %1. // M0!0+,+20) 1"('. 2001. D. 48. N6. B. 890–896.
8.L018+7 B.F., B$12$-&7" ?.>., O"3!"!"%& >.H. 0 %1. // A>? F>?. 1998. D. 30.
N2. B. 271–273.
9.Sayora Rashidova, Martin Peter, Rakiya Milusheva, Nadejda Voropaeva, Igor Ruban, Characterization of deacetylated chitosan from chrysalis of silkworm Bombyx mori, In the book «World polymer congress MACRO 2004». 2004. P. 53–95.
10.K"'P'&4# >.H., E91(804 Q.;. ;1"8'0-&(8+& 1$8+7+%('7+ *+ +*1&%&,&- #05 3+,&8$,)1#9/ 7&(+7 0 3+,&8$,)1#+-7&(+7+2+ 1"(*1&%&,) *+,03&-
1+7. I.; @., 1969. 188 (.
11. Roberts A.F.R. Chitin Chemistry, Hounmills Macmillan, Press Ltd., 1992. P. 106–110.
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