
Новые достижения в химии и химической технологии растительного сырья. Материалы III всероссийской конференции. Книга 1 [2007]
.pdf!
!"#$%'%&!
"%! !"#"$%&'"&! (%)%! *+,+-./0+.! 1$.'$"2.%+3! 4$.'./+%5! '! $."06+37! 8' "90+9+$&'"%+3! +! :;.$.<+0"6++(! 4+/%!)4&0;%! 7+,%! %"=0(! $*%+"%$#%!>$"/%&'
3$/0&!",,,%!#-$!/%!
+%! ?'.#4+%"! @%>%&!!+$A$&'.$! (%B%&! C&A$5%+%! (%D%&!E=,"%&'"! E%D%&!F"/&'.%' %"3!G%D%!*"$"0;.$+/;+0"!,&9.0=93$%&',"//&'&H&!$"/1$.4.9.%+3!6.99I9&' #5! +#! 4$.'./+%5! A.$.#5! '! #"'+/+,&/;+! &;! /7.,5! &;A.90+! +! 2.9&-%&H&!
.1$.4/$.'"%+3/!00!*+,+3!4$.'./+%5%!",-"%!J+%!K%!1"21*%!!
#%! >&$+%&'"!G%L%&!!"#"$%&'"!(%)%&!89M7&'!L%D%!G9+3%+.!2.9&-%&N!&A$"A&;' 0+! %"! +#,.%.%+.! /;$=0;=$5! 4$.'./+%5! 00! *+,+3! $"/;+;.9M%&H&! /5$M3%! +$$#%!J3%!K%!"12+3%!
3%! G&$&%&'"!B%O%&!P.;$&'"!K%(%&!@.A.4.'"!E%(%&!P$=/&'!D%(%&!?"7"$&'!D%)%!8! $&9+! 2.9&-+! '! /;$=0;=$%57! +#,.%.%+37! 9M%3%&N! 6.99I9! 00! Q=$%"9!
1$+09"4%&N!7+,++%!+$$#%!J"+%!K%!+$3#2+$31%!
*%! B=/".'! *%(%&! >+%! )%B%&! (+0&%&'+-! )%G%! P$+,.%.%+.! ,.;&4"! ;=$A+4+' ,.;$+-./0&H&! ;+;$&'"%+3! 493! +//9.4&'"%+3! ,&9.0=93$%&',"//&'&H&! $"/' 1$.4.9.%+3! /=9M<+;%&N! 6.99I9! 1$+! "6.;+9+$&'"%++! 00! *+,+-./0+.!
'&9&0%"%!",,$%!J4%!K%!#42#-%!
4%! P";.%;! R&//++! J+"#"--3%! K1&/&A! 0"$A&0/+,.;+9+$&'"%+3! 9+H%&=H9.'&4' %57! ,.;.$+"9&'! 0! !"#"$%&'"! (%)%&! E&0"$.'"! O%G%&! )"9&-0+%! D%O%&! B"$'
0+%!G%O%!0!",,,%!!
1%! 8A&9.%/0"3!G%G%&!S.H&9.'!G%P%&!D0+,!)%@%&!T,.9M3%&'"!O%?%!+!4$%!P$"0;+' -./0+.!$"A&;5!1&!7+,++!4$.'./+%5!+!6.99I9!B%&!",4*%!3""!/%!
()!*+,!-./01!2)2345!6*!!7!)80"! +4.9)+2:(*3:!:.)54//)1!5!!;.*5*2:/*! 2,2<*/8:)//0(!2<)2)9)(!
*#5#!+&=>#&"!;#/#!2?@?=?A"!/#B#!9&C&%D?A&"!5#:#!(&%@"D!
!"#$%&'(%!)*&+,$-./001%!+0(./-&(#/#"!2-#!3/0(0$"!$%"!
4$-0$+""!$&$'()!*5*&&(6+!,-./012!./34056789.:;;<#/=>#3>!
>"$A&0/+,.;+9+$&'"%+.!6.99I9!!'!/&/;"'.!4$.'./+%5!1$&'&43;!'! /$.4.! '&4%&H&! +! A.#'&4%&H&! 1$&1"%&9"'+%! G! /$.4.! '&4%&H&! 1$&1"%&9"'+! &A$"#=I;/3!1$&4=0;5!/!A&9..!'5/&0+,+!#%"-.%+3,+!/&4.$U"%+3!0"$A&0' /+,.;+9M%57!H$=11!+!/!A&9..!'5/&0&N!$"/;'&$+,&/;MI!'!'&4.!+!45'%&,! $"/;'&$.!H+4$&0/+4"!%";$+3!1&!/$"'%.%+I!/!1$&4=0;",+&!1&9=-.%%5,+!'! /$.4.! A.#'&4%&H&! 1$&1"%&9"'+! 6"&! +7%! V/;"%&'9.%&&! -;&! ,&9.0=93$%5N! /&/;"'! 6.99I9! #%"-+;.9M%&! #"'+/+;! &;! 0&9+-./;'"! '&45! '! 1$&6.//.!
"#$ !
!"#$%&$'!$()*($+,-!.)"/"0-&1!2")".!,*)($,0-3"+-#-)$/*&-"3$!*!+*,4"! $+! 02$0$(*! /1."#"&-5! %#&'! 6*3-! 2)$/"."&$! -00#".$/*&-"! /#-5&-5! 70#$( /-'!0+*.--!,*)($,0-3"+-#-)$/*&-5!&*!3$#",7#5)&1'!0$0+*/!8"##9#$:1! /! 0$0+*/"! ,*)($,0-3"+-#-)$/*&&$'! .)"/"0-&1! );<=*'! =*&&$"! -00#".$( /*&-"!2$:/$#-+!2$#7%-+>!($#""!2$#&$"!2)".0+*/#"&-"!$!2)$8"00*?$!2)$( -0?$.5!-?!2)-!,*)($,0-3"+-#-)$/*&--!.)"/"0-&1'!
<$#",7#5)&1'! 0$0+*/! ,*)($,0-3"+-#-)$/*&&$'! 8"##9#$:1! );<@*! -:7%*#-! &*! 2)-3")"! $()*:8$/! ;<@$! /1."#"&&1?! &*.7,070&$'! ,-0#$+$'! )6A;*! -:! .)"/"0-&1$! ,*)($,0-3"+-#-)$/*&&$'! /! 0)"."! /$.( &$B$! %+&! -! (":/$.&$B$! 2)$2*&$#*(,! %-&'!C:! 2)$.7,+$/! ,*)($,0-3"+-#-( )$/*&-5! .)"/"0-&1! /1."#5#-! ,*)($,0-3"+-#8"##9#$:7! 3"+$.$3! ;9)D&")*! -! &*.7,070&$'! ,-0#$+$'! 2$! 3"+$.-,*3$! )*:)*($+*&&13! .#5! /1."#"&-5!8"##9#$:1!-:!.)"/"0-&1'!
EF! ,*.$,0"&$/$B$! )*0+/$)*! ;<@$! /1."#"&&$'! 2$! ;9)D&")7! -:! ;<=$!2$#7%"&&$'!/!0)"."!(":/$.&$B$!2)$2*&$#*(,$!.$0+*+$%&$!/10$,*5! ).$! +..*'! G1?$.! ;<@! 2$0#"! /1."#"&-5! -:! ;<=! 0$0+*/#5"+! +./$! 0$(
.")4*&-"!;<H!+*,$"!4"$!%+$!-!/!-0?$.&$'!;<=!)+01/*'!! <$#",7#5)&79! &"$.&$)$.&$0+>! ;<@! -:7%*#-! 3"+$.$3! +7)(-.-(
3"+)-%"0,$B$! +-+)$/*&-5! %1&'A0+*&$/#"&$$! %+$! 3$#",7#5)&1'! 0$0+*/! ;<@!$.&$)$."&!-!2)*,+-%"0,-!&"!:*/-0-+!$+!2)$.$#4-+"#>&$0+-!,*)( ($,0-3"+-#-)$/*&-5!))-0'!"*'!!
;<@$! /1."#"&&*5! 2$! ;9)D&")7! -:! ;<=$! 2$#7%"&&$'! /! 0)"."! /$.&$B$!2)$2*&$#*(,$!5/#5"+05!($#""!."0+)7,+-)$/*&&$'!)EF!;<@!,.0 2.$!/1?$.!0!&"!($#""!"+/*'!F)-!I+$3!0$.")4*&-"!;<H!+*,$"!4"$!%+$!-!/! -0?$.&$'!;<=!)30".!/*'!<$#",7#5)&1'!0$0+*/!;<@$!/1."#"&&$'!!2$! ;9)D&")7! -:! .)"/"0-&1$! ,*)($,0-3"+-#-)$/*&&$'! /! 0)"."! /$.&$B$! 2)$2*&$#*(,$!3"&""!$.&$)$."&$!%"3!.#5!$()*:8$/!;<@$!/1."#"&&1?!2$! ;9)D&")7!-:!.)"/"0-&1$!,*)($,0-3"+-#-)$/*&&$'!/!0)"."!(":/$.&$B$! 2)$2*&$#*(,!))-0'!,*'!
;<@$!/1."#"&&*5!6A;!/!0+*&.*)+&1?!.#5!8"##9#$:1!70#$/-5?!-:! ;<=$! 2$#7%"&&$'! /! 0)"."! (":/$.&$B$! -! /$.&$B$! 2)$2*&$#*0,$! 0-#>&$!
."0+)7,+-)$/*&*4!:&*%-+"#>&*5!%*0+>!;<=!).$!+./*!2")"?$.-+!/!/$.$( )*0+/$)-3$"! 0$0+$5&-"$! ,$+$)79! /10*4-/*#-! *8"+$&$3'! G10*4"&&*5! %*0+>! 2$#&$0+>9! )*0+/$)5"+05! /! ,*.$,0"&"! -! /! !"#$%&$3! )*0+/$)"$! -3""+! &-:,-"! :&*%"&-5! EF5+.0-.! -! /10$,$"! 0$.")4*&-"! ,*)($,0-3"( +-#>&1?! B)722! ):&*%-+"#>&$! /1D"$! %"3! /! /1."#"&&$3! $0+*+,"! ;<@*'! G")$5+&""! /0"B$$! %+$! /10*4"&&*5! %*0+>! 2)".0+*/#5"+! 0$($'! 03"0>! )*/( &$3")&$(:*3"!"&&$'! ;<@! -! ,*)($,0-3"+-#-)$/*&&1?! H<@$! +','! /!
.*&&1?! 70#$/-5?! ,*)($,0-3"+-#-)$/*&-5! 2)-! 3*#$3! 4-.,$0+&$3! 3$(
! "#"

! |
|
|
|
|
|
|
|
!"#$! %&'()(*+,$-$..&$! /0(!")1&! '(20+.341'3! %! 0+'151$#6.(,! )(,% |
|||||||
/#$)'$&!705!!$8'1%55!%(!.(9(!0+'1%(0+!:;<!=15!/0(!")1&!/$0$2(!31!%! |
|||||||
0+'1%(0'!+!*+1$,!%&'+>5%+41'3!+?$1(.(,'!@1(!'%(8'1%$..(!!#3!)+0A()% |
|||||||
'5,$15#50(%+..&2!BCD&! |
|
|
|
|
|
||
|
*!! |
|
|
|
|
|
|
|
|
*!+!"# |
|
|
|
|
|
|
|
%!+!"# |
|
|
|
|
|
|
&! |
|
|
|
|
|
|
|
%! |
|
|
|
|
|
|
($)"! |
#! |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
" |
|
|
|
|
|
|
|
|
$! |
|
|
|
|
|
|
|
! |
|
|
|
|
|
|
|
!"#! |
!"#$ |
!"## |
!"#% |
!"#& |
!"'! |
!"'$ |
|
|
|
|
! |
|
|
! |
|
|
|
|
|
|
|
|
E5'&!"&!C(#$)"#30.&8!'('1+%!<CD'!%&!$#$..(8!/(!<40F.$0"!5*!<CG'! |
|||||||
/(#"@$..(8!%!'0$!$!A$*%(!.(9(!/0(/+.(#+%$!'!0+*.(8!/0(!(#>51$#6.('164! |
|||||||
'5.1$*+!! |
|
|
|
|
|
|
|
|
*#! |
|
|
|
|
|
|
|
|
*!+!"# |
|
|
|
|
|
|
*$! |
%!+!"# |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
*!! |
|
|
|
|
|
|
|
&! |
|
|
|
|
|
|
"($)"! |
%! |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
#! |
|
|
|
|
|
|
|
$! |
|
|
|
|
|
|
|
! |
|
|
|
|
|
|
|
!"'# |
!"'% |
|
!"'& |
!"%! |
!"%$ |
!"%# |
|
|
|
|
! |
|
|
! |
|
|
|
|
|
|
|
|
E5'&!$&!C(#$)"#30.&8!'('1+%!<CD'!%&!$#$..(8!/(!<40F.$0"!5*!<CG'! |
|||||||
/(#"@$..(8!%!'0$!$!%(!.(9(!/0(/+.(#+%$!'!0+*.(8!/0(!(#>51$#6.('164! |
|||||||
'5.1$*+!! |
|
|
|
|
|
|
|
"#$ ! |
|
|
|
|
|
|
|

!"#$! %&'"(")&! $%&'! *+&! ,-.! /0,1-1)$.! 234! $(! 235! )1&67&,$#&! $8%&-9(&/"+9!"()*):;!)",:'8:8):;!'$8-&+:'!%<$!=+!%<&,&->$+1-9* )&8+9!&6<"6&+'$!)1!,&->)"!%<1/0?"+9!"(!#$)+!@!%<1,-&>1))07!)"#$! :8-&/$.7! /0,1-.1+8.! 234! 8! 8&,1<>")$1#! &8+"+&*)07! #&)&8"7"<$,&/! ,'")!-"'#)!A-;'&("!$!.'/)!'8$-&("0+!!
2"<6&'8$#1+$-B1--;-&("'! /0,1-1))".! )",:'8:8)&C! '$8-&+&C! /! %<1,-&>1))07!)"#$!:8-&/$.7'!$(!,<1/18$)0'!'"<6&'8$#1+$-$<&/"))&C! /!8<1,1!61(/&,)&A&!%<&%")&-"*,'!%&!8&,1<>")$;!23D!8<"/)$#"!8!")"-&* A$*)&C!234'!/0,1-1))&C!%&!2;<?)1<:'!)&!$#11+!6&-11!/08&':;!EF+! 3&-1':-.<)0C! 8&8+"/! #1)11! &,)&<&,1)! %&! 8<"/)1)$;! 8! &6<"(B"#$! 234'!/0,1-1))0#$!%&!2;<?)1<:'!)&!+"'>1!%<"'+$*18'$!)1!("/$8$+!&+! %<&,&->$+1-9)&8+$!8+",$$!'"<6&'8$#1+$-$<&/")$.!-<$8+!#0+!!
G6<"(B0! 234'! /0,1-1))01! !H2! $(! ,<1/18$)0'! '"<6&'8$#1+$-$* <&/"))&C!/!8<1,1!/&,)&A&!%<&%")&-"*,'!$#1;+!6&-11!)$(':;!EF!-"..1 "".0! $! 6&-11! /08&'&1! 8&,1<>")$1! 23D! -".1"/)0! %&! 8<"/)1)$;! 8! &6* <"(B"#$! 234'! /0,1-1))0#$! !H2! $(! ,<1/18$)0'! '"<6&'8$#1+$-$<&* /"))&C!/!8<1,1!61(/&,)&A&!%<&%")&-"*,+!I+&!8/.(")&!8!6&-9?1C!A-:6$* )&C! %<&+1'")$.! <1"'B$$! '"<6&'8$#1+$-$<&/")$.! /! 8<1,1! /&,)&A&! %<&* %")&-"*,+! 3&-1':-.<)0C! 8&8+"/! 234'! %&-:*1))&C! <"()0#$! 8%&8&6"*
#$'!$#11+!6-$('$C!7"<"'+1<!<"8%<1,1-1)$.!-<$8+!#120+!
|
#%! |
|
|
|
|
|
|
|
|
-!.!"# |
|
|
|
|
|
|
#!! |
#!.!"# |
|
|
|
|
|
|
|
&!.!"# |
|
|
|
|
|
|
|
)!.!"# |
|
|
|
|
|
|
+%! |
|
|
|
|
|
|
|
+!! |
|
|
|
|
|
|
"*+,"! |
-%! |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
-!! |
|
|
|
|
|
|
|
%! |
|
|
|
|
|
|
|
! |
|
|
|
|
|
|
|
!"#$ |
!"#% |
!"#& |
!"#' |
!"#( |
!"#) |
!"$! |
|
|
|
|
! |
|
|
! |
|
|
|
|
|
|
|
|
J$8+!#+!3&-1':-.<)0C!8&8+"/!234'!/0,1-1))&C!!H2!$(!,<1/18$)0'! |
|||||||
'"<6&'8$#1+$-$<&/"))&C!/!8<1,1!61(/&,)&A&!%<&%")&-"*,!8!<"()&C! |
|||||||
%<&,&->$+1-9)&8+9;!8$)+1("!! |
|
|
|
|
|
||
! |
|
|
|
|
|
|
"## |

! |
|
|
|
|
|
|
|
|
|
|
*,! |
|
|
|
|
|
|
|
|
|
|
*!.!"# |
|
|
|
|
|
|
|
|
*!! |
)!.!"# |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
(! |
|
|
|
|
|
|
|
|
+,-"! |
&! |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
" |
#! |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
,! |
|
|
|
|
|
|
|
|
|
! |
|
|
|
|
|
|
|
|
|
!"#$ |
!"## |
!"#% |
!"#& |
!"#' |
!"#( |
!"#) |
!"%! |
!"%* |
|
|
|
|
|
! |
|
|
|
! |
|
|
|
|
|
|
|
|
|
|
!"#%!$%!!$%&'()&*+,-.!#%#/01!2$3&!1-4'&',,%.!562!"7!4+'1'#",-&!(0+8%(' |
|||||||||
#"9'/"&"+%10,,%.!1!#+'4'!1%4,%:%!;+%;0,%&0'(!#!+07,%.!;+%4%&<"/'&=,%#/=>! |
|||||||||
#",/'70! |
|
|
|
|
|
|
|
|
|
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
!"#$%'%&!
"%. $0+(",!G%H%&!I070+,%10!5%J%&!J0&%@(",!K%H%&!L0B0+%10!G%G%!H##&'4%10,"'! +'0(D""! (0+8%(#"9'/"&"+%10,"*! 4+'1'#",-! %#",-! 9'/%4%9! ;%&,%:%! M0(' /%+,%:%!E(#;'+"9',/0!!++!H71'#/"*!1)7%1%!N"9"*!"!B"9"@'#(0*!/'B,%&%:"*%! ",,-%!G-;%!.%!O%!"/-0"""%!
(%. $0+(",!G%H%&!I070+,%10!5%J%&!J0&%@(",!K%H%!H7)@',"'!1&"*,"*!;+'4%8+0' 8%/("! ,0! (0+8%(#"9'/"&"+%10,"'! 4+'1'#",-! 8'+'7-! 1! #+'4'! "7%;+%;"&%' 1%:%!#;"+/0!++!?&0#/"@'#("'!90##-%!",,-%!P1%!O%!#"0#$%!
#%. 20&>/0! Q%G%&! O%(%&%1! A%5%&! I070+,%10! 5%J%&! $0+(",! G%H%! $%&'()&*+,-.! #%#/01! D'&&>&%7-! ;%#&'! ''! C'&%@,%.! %8+08%/("! 1! #%#/01'! 4+'1'#",-! ++!
"#$ !
!"#$%!&"'()*%+),!#!-).))!)!-)./%'0"1!(%-+"2"3))!45'()(%26+"3"!'$46,%!
.5(&!'''!7'%4"'&!0"+8&!954+5:2(!)**+&!;&!")+,"#*&!
-&! <5(%+(! ="''))! >)"#*.-+&! ;?"'"@! 054@"0').%()2)4"#5+),! 2)3+":32%#"&/ +$-!.%(%4)52"#!0!A52"/0)+!B&C&(!95D54+"#5!!&A&(!E540)+!7&C&(!F4%'(6,+/ +)0"#5!!&C&(!G5'(5#%+0"!!&7&!0!"...&!!
$&! H@"2%+'05,!7&7&(!I%3"2%#!7&<&(!B0).!A&J&(!K.%26,+"#5!C&G&!)!&4&!<450()/ /%'0)%!45@"($!?"!-).))!&4%#%')+$!)!L%22M2"D$!E&(!".1$&!-""!'&!
1&! 94:%#)/(! A&N&(! !5&*).:(&)+"#! O&! P450L)"+)4"#5+)%! )! ."2%0:2,4+"/
.5''"#"%! 45'?4%&%2%+)%! 054@"0').%()2L%22M2"D$! 00! Q).),! &4%#%')+$&! ".+1&!>1&!;&!2,"*&!
+&! F52M(5! K&7&(! 95D54+"#5! !&A&(! E540)+! 7&C&! 72),+)%! ?4"&"2*)(%26+"'()! "@45@"(0)! +5&:0':'+"1! 0)'2"("1! 054@"0').%()2)4"#5++"1! &4%#%')+$! +5!'#"1'(#5!#$&%2,%."1!054@"0').%()2L%22M2"D$!00!Q).),!45'()(%26+"3"!
'$46,&!)**1&!>)&!;&!).,#"&!
!"#$%'()*+!,",-./!0$##1#"2*"! %.(3"%,4!$-4#4("/.))"+!/!5($/$,4)$! -/$(5"6.2)*!!,7","3"!!
$#/#!%89:;8"!4#/#!!<=>?<@8"!/#4#!!8A=<@"!)#B#!38C8A@DE8!
!"#$%&'(%!)*&+,$-./001%!+0(./-&(#/#"!2-#!3/0(0$"!$%"!
4$-0$+""!$&$'()!*5*&&(6+!,-./012!./34056789.:;;<#/=>#3>!
F54@"0').%()2)4"#5+)%!&4%#%')+$!?4"#"&,(!050!':'?%+D)"++$.(!(50! )! (#%4&"85D+$.! '?"'"@5.)(! 45D.52$#5,! &4%#%')+:! #! ?4)':('(#))! (#%4/ &$-! 520)2)4:MR)-! 4%53%+("#! 33)&4"0')&5! +5(4),! )! ."+"-2"45L%(5(5! +5(4),4! #! #)@4"L%+(4"@%*+"1! .%26+)L%! 37SE4&! <"2:/%++$%! ?4"&:0($! ).%M(!'45#+).$%!'#"1'(#5!'!?4"&:0(5.)!':'?%+D)"++"3"!'?"'"@5!054/ @"0').%()2)4"#5+),(! "&+50"! ?4"&"2*)(%26+"'(6! ')+(%D5! ?4)! .%-5+"/ -).)/%'0".! 054@"0').%()2)4"#5+))! D+5/)(%26+"! '"045R5%(',! 3&"! )*!
.)+4! 5"6&! !5.)! )''2%&"#5+! ."2%0:2,4+$1! '"'(5#! L%22M2"D$(! 054@"0/ ').%()2)4"#5++"1!#!&4%#%')+%!.%-5+"-).)/%'0).!'?"'"@".&!
CD#%'(+"(!/("!'!:#%2)/%+)%.!&"!)*!.)+!?4"&"2*)(%26+"'()!"@45/ @"(0)! &4%#%')+$! #! 7SE! ?4")'-"&)(! :?"4,&"/)#5+)%! %%! '(4:0(:4$(! :'(5+"#2%++"%! .%("&".! (%4.".%-5+)/%'0"1! '?%0(4"'0"?))! 5)6&! H@45/ @"(05!*%!&4%#%')+$!#!7SE!#!?4)':('(#))!(#%4&"3"!75H!!:*%!#!(%/%/
! |
"#$ |

!
!"#!%!$"!!%&'%'(!)!&*#'(*)+',)-.!##!%-*/0-/*/!)!)1'2"3!'!*)+$'1/!,! -#3#!"#!&'!$"!(!
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
>+$#!55!/%1',"5!$#@)!'@"$"3#%0'2'!%"!-#+)!,&*"!&'%-'5!!'$!%'* '-!'<#!""! *#)2#!-',! =4:*#,0+1230+1AKL;4"0')%0')%/)! !)$"! &'1/3#* !6! '(*)+86! 0)*('0%"$#-"1"*',)!!'7! :*#,#%"!6)! "! "+! !"@! $#-':'$! ;9*<!#*)!,6:#1#!)!;AG(!!
A'1#0/15*!67! %'%-),! ,"+/3)1"! $#-':'$! -/*(":"$#-*"3#%0'2'! -"-*',)!"5! -5./! 8#1191'+6! ,! :*#,#%"!#)! 0)*('0%"$#-"1"*',)!!'7! $#* @)!'@"$"3#%0"$!%&'%'('$)!('1##!':!'*':#!!&'!%*),!#!"9!%!8#1191'* +'7)! ,6:#1#!!'7! "+! :*#,#%"!6)! *)+$'1'-'7! ,! &*"%/-%-,""! +123! "1"! (#+!!#2'!,*"%/!0"!"6&/(!
|
#$ |
!"#$%&'(,)*%+,+&&'(,-+,,.,$/' |
|
|
|
|
|||
|
|
|
|
|
|
||||
|
|
0$",+,1'/2$,',),3+4+&!+,)!,2!& |
|
|
|
|
|||
|
#! |
0$",+,1'/2$,',"$,5+,$46.,),3+4+&!+,)!,2!& |
|
|
|||||
|
|
|
|
|
|
|
|
|
|
|
)$ |
|
|
|
|
|
|
|
|
|
)! |
|
|
|
|
|
|
|
|
()*"! |
+$ |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
" |
|
|
|
|
|
|
|
|
|
|
+! |
|
|
|
|
|
|
|
|
|
$ |
|
|
|
|
|
|
|
|
|
! |
|
|
|
|
|
|
|
|
|
!"#$ |
!"%! |
!"%$ |
!"$! |
!"$$ |
!"&! |
!"&$ |
!"'! |
!"'$ |
|
|
|
|
|
! |
|
|
|
! |
|
|
|
|
|
|
|
|
|
|
B"%(!"(!A'1#0/15*!67!%'%-),!8#1191'+6)!,6:#1#!!'7!"+!:*#,#%"!6)! |
|||||||||
&':,#*2!/-'7!$#@)!"3#%0'$/!*)+$'1/! |
|
|
|
|
|||||
"#$ ! |
|
|
|
|
|
|
|
|
|

|
+! |
|
|
|
|
|
|
|
|
|
|
|
'!,!"#,-.*,!! |
|
|
|
|
|
|
||
|
|
'!,!"#,-.+,!! |
|
|
|
|
|
|
||
|
#! |
'!,!"#,-.&!,!! |
|
|
|
|
|
|
||
|
|
&!,!"#,-.+,!! |
|
|
|
|
|
|
||
|
*! |
|
|
|
|
|
|
|
|
|
"(')"! |
'! |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
&! |
|
|
|
|
|
|
|
|
|
|
! |
|
|
|
|
|
|
|
|
|
|
!"!# |
!"!$ |
!"!% |
!"&! |
!"&' |
!" |
!"&$ |
!"&% |
!"'! |
!"'' |
|
|
|
|
|
|
! |
|
|
|
! |
|
|
|
|
|
|
|
|
|
|
|
!"#%!&%!$%&'()&*+,-.!#%#/01!2$3'!1-4'&',,%.!"5!2$6!#!+05&"7,-8"! |
||||||||||
)#&%1"*8"!8'90,%9"8"7'#(%:%!#",/'50! |
|
|
|
|
|
;0!<=!"!8%&'()&*+,-.!#%#/01!2$3!5,07"/'&>,%!1&"*?/!)#&%1"*! 8'90,%9"8"7'#(%:%! (0+@%(#"8'/"&"+%10,"*! (4"08'/+! A0+%1! )! "! B+%* 4%&C"/'&>,%#/>!#",/'50+!(+"#%!&'!/0@&%+%!!
D0("8! %@+05%8'! %4,%+%4,%#/>! E'&&?&%5-! 1! #%#/01'! 4+'1'#",-! #,"C0'/#*! B%#&'! +058%&0! 1! 1"@+%E',/+%@'C,%.! 8'&>,"E'%! F@+0@%/(0! 4+'1'#",-!1!B+"#)/#/1""!,0F;!B%1-A0'/!%4,%+%4,%#/>!8%&'()&*+,%* :%! #%#/010! E'&&?&%5-! 1! #%#/01'! 4+'1'#",-%! 20+@%(#"8'/"&"+%10,"'! 4+'1'#",-! 8'90,%9"8"7'#("8! #B%#%@%8! B+"1%4"/! (! %@+05%10,"?! %4* ,%+%4,%.!2$3!1!#%#/01'!2$6%!!
<1%.#/10!(0+@%(#"8'/"&"+%10,,%.!E'&&?&%5-'!1-4'&',,%.!"5! 4+'1'#",-'!(0+@%(#"8'/"&"+%10,,%.!1!+05&"7,-9!)#&%1"*9! 8'90,%%@+0@%/("!!
G#&%1"*!%@+0@%/("!
=+%4%&C"/'&>* 2$H'!-! <I! <=! ,%#/>'!8",! 6"08'/+!A0+%1'!88!
|
#! |
.'"! |
"/! |
&"0! |
&0! |
1! |
$'&! |
&&! |
"$0! |
|
"0! |
/'&! |
&1! |
"#0! |
"0! |
1! |
$'0! |
&"! |
&$0! |
! |
"#$ |
!
!"#$%'%&!
"%! !"#$%#! &'(())! *&"#"$$'%! +,'('-! ."/-'.()0$#)1)/'2"%)3! 1)4%'541$2'6( %78!0"#$/)"1'2!)9%:%!;"<"/%'2"*!=%>%!?'."/$2"*!>%=%!@"/.)%*!A%=%!:"1'B(
.)%!)!&+%+,%"---%!
&%! @$#'67! )((1$6'2"%)3! 6/$2$()%7! )! $$! ,/')<2'6%78.! 5B$-%'$! ,'('-)$! )! 9%:%!;"<"/%'2"*! C%>%! D"/,'2"*! =%;%!D"#/".'2! )! 6/%/! ,'6! /$6%! 9%:%!;"<"/%'2'E%!;"/%"51*!&++&%!",+!(%!
#%! @5("$2! F%9%*! D'<)%! :%@%*! 9).'%'2)B! :%>%! !/)0$%$%)$! 0$#'6"! #5/-)6)( 0$#/)B$(.'4'! #)#/'2"%)3! 613! )((1$6'2"%)3! 0'1$.513/%'(0"(('2'4'! /"(( ,/$6$1$%)3! (51GH)#%'E! I$11J1'<7! ,/)! "I$#)1)/'2"%))! ! ))! F)0)B$(.)$!
2'1'.%"%!"--+%!*,%!+%!#,0#$%!
'%! ;/5$2)B! :%K%*! 9"6L)05#6)%'2! M%! N/".I)'%)/'2"%)$! )! 0'1$.513/%'( 0"(('2'$! /"(,/$6$1$%)$! ."/-'.()0$#)1I$11J1'<7! ))! F)0)3! 6/$2$()%7%! "-1,%!*,%!+%!$0"+%!
()*+,(-./01.!.*,2)3.0!21,*.43,5,! 60!!7!,8,-,90*:);05,!-<*=>!
0"2"!?@A%"B&!!
!"#$%$&$!'%(%%!)*+!,-.!/0*"!&1#!23-45(67#869"!$%"!
:;8$;486-!&/5##%9'!()*+,-.!/012+3,4+)567895*,#:1*,;8#2/!
D"/-'.()0$#)1'27$!OH)/7!I$11J1'<7!3213J#(3!./5,%'#'%%"L%7( 0)! )! 2'(#/$-'2"%%70)! /"<1)B%70)! '#/"(130)! ,/'07P1$%%'(#)! ,/'( 65.#"0)%!=<2$(#%'*!B#'!2!,/')<2'6(#2$!O#'4'!.1"(("!,/'(#78!OH)/'2!I$1( 1J1'<7!0'45#!-7#G! )(,'1G<'2"%7!I$11J1'<7*!/"<1)B"JQ)$(3!,/')(8'( L6$%)$0! )! (,'('-'0! ,'15B$%)3*! "! #".L$! %$'-1"4'/'L$%%7$! %$-$1$%7$! 6/$2$(%7$!I$11J1'<7*!('6$/L"Q)$!1)4%)%!)!6/54)$!,/)0$()%!9$-$1$%'$! I$11J1'<%'$! 2'1'.%'! ,/)0$%3$#(3! 613! )<4'#'21$%)3! /"<1)B%78! 2)6'2!
."/#'%"*!)!0'L$#!-7#G!2.1JB$%'!2!.'0,'<)I)J!4"<$#%'E!-50"4)%!!'O#'( 05! )(,'1G<'2"%%5J! ."/#'%%5J! #"/5! )! 4"<$#7! 0'L%'! /"((0"#/)2"#G! .".! 2#'/)B%'$! I$11J1'<'('6$/L"Q$$! (7/G$! 613! ,/')<2'6(#2"! OH)/'2! I$1( 1J1'<7%! &"<2)#)$! O#'4'! %",/"21$%)3! )(,'1G<'2"%)3! ,'1)0$/%78! '#8'( 6'2!)<!,/)/'6%78!0"#$/)"1'2!0'L$#!,'0'BG!/$P)#G!,/'-1$05!5#)1)<"( I))!-'1GP'4'!.'1)B$(#2"!0".51"#5/7!2!./5,%78!4'/'6"8%!
R6%".'! 0".51"#5/%"3! 0"(("! 3213$#(3! B/$<27B"E%'! %$'6%'/'6%70! ,'! .'0,'%$%#%'05! ('(#"25! 2#'/)B%70! ,'15H"-/)."#'0*! %$.'#'/7$!
"#$ !
!"#$! %&'()%*+*$! ,+-&.*/0! 1(&21/0%! 1/3,/*+*.&3"! 14++!%! *&,/4*".+& 4+0'!5/6./37!#4)!,/47-+*")!2$(8)%!.+9*"-+21"!,("'/#*/'/!#4)!,+(+(&& :/.1"! !! 6;"($! <+44=4/%$%! <+4+2//:(&%*/! ,+(+!/#".8! +'/! !! /-">+*& *7=%!/:4&'/(/?+**7=!<+44=4/%7'!!
@$4"! ,/47-+*$! *&.("+!$+! 2/4"! 1&(:/12"3+."4<+44=4/%$! "%! /:& 4&'/(/?+**$9!<+44=4/%/2/#+(?&>"9!/.9/#/!!(*+:+4+*/'/!"!:+4+*/'/!
.&(*/'/! 1&(./*&%! '&%+.$)! "! "9! ,/(/A1/!$9! ;/(3'! B:4&'/(&?"!&*"+! 2$(8)! /27>+2.!4)4"! /:(&:/.1/0! +'/! >+4/-*$3! (&2.!/(/3! 2.&:"4"%"& (/!&**/'/! ,+(/12"#&! !/#/(/#&%! 1/./($0%! 1&1! ,/1&%$!&=.! "224+#/!&& *")%! :4&'/.!/(*/! !4")+.! *&! 7#&4+*"+! 1/3,/*+*./!! 14++!%! 2!)%7=>"9! !+>+2.!!2!,/!+(9*/2."!!/4/1*&!"!,+(+!/#7!"9!!!(&2.!/('!5/(/A1/!$0! 3&.+("&4! ,/47-+*! '"#(/4"."-+21/0! /:(&:/.1/0! /:4&'/(/?+**/'/! 3&&
.+("&4&! ,+(/12"3/*/2+(*/0! 1"24/./0'! C;"($! <+44=4/%/2/#+(?&>"9! ,(/#71./!! 2"*.+%"(/!&*$! ?"#1/;&%*$3! 2,/2/:/3%! !/%#+02.!"+3! 1&(& :/12"3+."4"(7=>+'/! (+&'+*.&! *&! !4&?*7=! >+4/-*7=! 3&227! !! 2(+#+! /('&*"-+21/'/!(&2.!/(".+4)'!
D.+,+*8! %&3+>+*")! 2"*.+%"(/!&**$9! 1&(:/12"3+."4"(/!&**$9! ,(/#71./!!*&!/2*/!+!1&(./**/'/!2$(8)!*&9/#".2)!!!,(+#+4&9!*%#!*%+,%! (&2.!/("3/2.8! !! !/#+! -! ./!$*,0! /.*/2".+48*&)! !)%1/2.8! ",&*$9! (&2&
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
! |
"#$ |