Новые достижения в химии и химической технологии растительного сырья. Материалы III всероссийской конференции. Книга 3 [2007]
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!"#$%& '(#)#$* +,-+,./(%* 0/1/%$, * 01*2$*# 3,+,%(#+, 0/-4#5'(0*2 $/6#0/5 7,+$*(&+8 $, $#7/ 0 -,0*'*9/'(* /( %/$'(+&%(*0$83 * (#3$/1/- 7*:#'%*3 ),+,9#(+/0 9,;*$8 ' &:#(/9 $#%/(/+83 )/%,-,(#1#5, (,%*3 %,%: 41*$, 0/1/%$, (b3); 0$#;$22 &4#1<$,2 )/0#+3$/'(< (b8); '/)+/(*01#$*# )+/4,01*0,$*= (y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1.E#7/"%*5 F.F., G/$:,+/0 H.I. C,-9,180,=B## /./+&4/0,$*# * )/47/- (/0%, .&9,6$/5 9,''8. A., 1990. 224 '.
2.J80;#0 K.H., F,0*"%*5 L.L. A#3,$*:#'%/# 4*')#+7*+/0,$*# 0/1/%- $*'(83 9,(#+*,1/0: M:#.. )/'/.*#. N+,'$/2+'%, 1991. 216 '.
115
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!!! «"#$%&'()* +,-», #.. "%/01'(23, 129, "%(%., 4%.%5%6'(23 %7.., 162135 (8%'')3) E-mail: com-paper@yandex.ru
!"#$%'() )*"+#,# -*")#+* $% .*-/0*)/"1 –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–4]. @*- ("4'() /'4"6*+$8 ,$'"#A#5$%*)#"#& $ .40-#,# #-+*, * )*-64 (&8%/:;4,#, B$"#-# $(3#07%/:)(8 -"*<.*01 "*%0$9+#,# 3"#$(<#6'4+$8 $ A/+->$#+*07+#- ,# +*%+*94+$8.
C '*++1< #31)+#-3"#.1B04++1< $((04'#&*+$8< 510* >407 /()*- +#&$)7 ("*&+$)407+/: 2AA4-)$&+#()7 3 .*"#- -"*<.*0#& +* '$+*.$-/ /0/9B4+$8 -*94()&* 5/.*,$ '08 ,#A"$"#&*+$8 $ -*")#+* '08 30#(-$< (0#4& ,#A"$"#&*++#,# -*")#+*.
D(+#&+14 <*"*-)4"$()$-$ $(31)/4.1< -"*<.*0#& 3"4'()*&04+1 & )*50$>4 1.
E*50$>* 1. D(+#&+14 <*"*-)4"$()$-$ $(31)/4.1< -"*<.*0#&*
F*"-* -"*<.*0* |
C*bond |
G-150 |
G-135 |
!"#$(<#6'4+$4 |
@*")#A407+1= |
@/-/"/%+1= |
@/-/"/%+1= |
?#++1= 3"$%+*- |
@*)$#++1= |
@*)$#++1= |
@*)$#++1= |
H&4) |
G401= |
G401= |
G401= |
C0*6+#()7, % |
17 |
15 |
15 |
"I |
4,5 |
6-8 |
6-8 |
J)434+7 %*.4;4+8 |
0,056 |
0,048-0,05 |
0,048-0,05 |
*@"*<.*0 .*"-$ «C*Bond» 3"#$%'()&* -#.3*+$$ «Cerestar», * «G-150», «G-135» -#.3*+$$ DKD L!M «M#(($=(-$4 -"*<.*0#3"#'/-)1».
116
!"#$%&%'( )*+(,-'). /00%1,)$'#*,) 1"-23-4#$ «5-150» ) «5- 135», $6-3%' 1"-23-4- 3-"1) «C*Bond» $ 777 «892#'*1): ;5<»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
I)1*)"#$-4)*? "-*2#&( 2)3)1-,#$, +#&-$-%3(2 '- 5FG: "-*2#& 1"-23-4- +# +")3%'.%3(3 3-"1-3 9A),($-4*. +# 0-1,)A%*1#: $("-- =#,1% $ 6-$)*)3#*,) #, $(+9*1-%3#: +"#&91B)).
F-''(%, +#49A%''(% $ 2#&% #+(,'#-+"#3(@4%''(2 )**4%$-'): "-*2#&9 1"-23-4#$ ) 9&%"H-')) $#4#1'-, +"%&*,-$4%'( $ ,-=4)B-2 2 ) 3.
F4. #=#*'#$-''#*,) $($#$ +# /00%1,)$'#*,) *"-$')$-%3(2 1"-23-4#$, =(4) +"#$%&%'( )**4%$-'). $4).'). 1"-23-4#$ '- 1-A%- *,$# >4-$'(2 $)$ +"#&91B)) +# *,-'&-",'(3 +#1-6-,%4.3 1-A%*,$-. J*+(,9%3-. +"#&91B).: 5FGK1 (5-150) – 50-112; <-125; 5FGK2 (5- 150) – 50-112;<-125; 5FGK1 (5-135) – 50-112; <-140; 5FGK2 (5-135)
– L7MN< 125;<-125.
M-=4)B- 2. I-1,)A%*1)% 9*"%&'%''(% "-*2#&( 1"-23-4#$ +# $)&-3 +"#&91B))
E)& +"#&91B)), |
O-*2#& 1"-23-4- |
O-*2#& 1"-23-4- |
O-*2#& 1"-23-4- |
3-**- 1 32 $ >. |
8* bond, 1>/, |
5-150, 1>/, |
5-135, 1>/, |
593->- 5-0, 112 |
7,45 |
6,10 |
- |
<-",#', 125 |
5,45 |
5,60 |
6,77 |
<-",#', 140 |
7,10 |
7,10 |
8,13 |
L7MP<, 125 |
7,65 |
- |
6,50 |
M-=4)B- 3. |
8"-$'),%4?'(% &-''(% +# +#1-6-,%4C «Q&%"H-')% |
|
|||||
|
$#4#1'-», % |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
5FG |
8* bond |
|
5-150 |
5FG |
8* bond |
|
5-135 |
K 1 |
88,4 |
|
90,5 |
K 1 |
91,8 |
|
93,0 |
K2 |
88,4 |
|
90,5 |
K2 |
89,3 |
|
92,5 |
117
!"##$% &' ())%*+,-#'.+, -/,0#,0 *1"23"/'- #" *"4%.+-' 563"7, , *"1+'#" &1%8.+"-/%#$ #,9% (: - &1,1";%#,% &'*"<"+%/0; =- .#,9%#,% &'*"<"+%/0).
>1"23"/ ?-150, &1, &1',<-'8.+-%:
?63"7, |
|
>"1+'#" |
|
@'1A%-'% .9"+,% |
= #" 3% |
B9"+,% *'/CA" |
: #" 13,5% |
D8%/C#'% .'&1'+,-/%- |
: #" 5% |
E5.'/F+#'% .'&1'+,-- |
: #" 24% |
#,% 1"<1$-6 |
|
/%#,% &1'8"-/,-"#,F |
|
E5.'/F+#'% .'&1'+,-- |
: #" 2,8% |
B'&1'+,-/%#,% ,</'36 |
: #" 20,9% |
/%#,% &1'8"-/,-"#,F |
|
|
|
G&,+$-"%3'.+C |
= #" 5,1% |
G&,+$-"%3'.+C |
: #" 27% |
>1"23"/ ?-135, &1, &1',<-'8.+-%:
?63"7, |
|
>"1+'#" |
|
@'1A%-'% .9"+,% |
: #" 14,5% |
B9"+,% *'/CA" |
: #" 11,9% |
D8%/C#'% .'&1'+,-/%- |
= #" 3,6% |
E5.'/F+#'% .'&1'+,-- |
= #" 1,5% |
#,% 1"<1$-6 |
|
/%#,% &1'8"-/,-"#,F |
|
E5.'/F+#'% .'&1'+,-- |
: #" 0,7% |
B'&1'+,-/%#,% ,</'36 |
= #" 6,5% |
/%#,% &1'8"-/,-"#,F |
|
|
|
G&,+$-"%3'.+C |
= #" 13,9% |
G&,+$-"%3'.+C |
= #" 25,3% |
H5'5;%##$% &'*"<"+%/, 8/0 '5',2 3"1'* *1"23"/'- ?-150 , ?-135:
?63"7, |
|
>"1+'#" |
|
@'1A%-'% .9"+,% |
: #" 5,3% |
B9"+,% *'/CA" |
: #" 12,7% |
D8%/C#'% .'&1'+,-/%- |
: #" 0,7% |
E5.'/F+#'% .'&1'+,-- |
: #" 11,2% |
#,% 1"<1$-6 |
|
/%#,% &1'8"-/,-"#,F |
|
E5.'/F+#'% .'&1'+,-- |
: #" 1,7% |
B'&1'+,-/%#,% ,</'36 |
: #" 6,7% |
/%#,% &1'8"-/,-"#,F |
|
|
|
G&,+$-"%3'.+C |
: #" 9,5% |
G&,+$-"%3'.+C |
: #" 1,35% |
B1"-#%#,% -/,0#,0 *1"23"/'- ?-150 , B* bond, &' 8-63 563"7'8%- /"+%/C#$3 3"I,#"3, 8"/' ./%86F;,% 1%<6/C+"+$:
?!JK 1 |
|
?!JK 2 |
|
@'1A%-'% .9"+,% |
< 6 B* bond |
@'1A,'##'% .9"+,% |
< 6 ?-150 |
D8%/C#'% .'&1'+,-/%- |
< 6 ?-150 |
D8%/C#'% .'&1'+,-/%#,% |
< 6 ?-150 |
#,% 1"<1$-6 |
|
&1'8"-/,-"#,F |
|
E5.'/F+#'% .'&1'+,-- |
< 6 B* bond |
E5.'/F+#'% .'&1'+,-- |
= B* bond |
/%#,% &1'8"-/,-"#,F |
|
/%#,% &1'8"-/,-"#,F |
|
G&,+$-"%3'.+C |
< 6 B* bond |
G&,+$-"%3'.+C |
< 6 ?-150 |
B9"+,% *'/CA" |
< 6 ?-150 |
B9"+,% *'/CA" |
< 6 ?-150 |
E5.'/F+#'% .'&1'+,-- |
= B*bond |
E5.'/F+#'% .'&1'+,-- |
< 6 ?-150 |
/%#,% &1'8"-/,-"#,F |
|
/%#,% &1'8"-/,-"#,F |
|
B'&1'+,-/%#,% ,</'36 |
< 6 B*bond |
B'&1'+,-/%#,% ,</'36 |
< 6 B* bond |
G&,+$-"%3'.+C |
= B*bond |
G&,+$-"%3'.+C |
< 6 B*bond |
118
!"#$%&%'& $(')%') *"#+,#(-$ .-150 ' !* bond, /- 0$1, 21,#3-0&- (#4&(5%6, ,#7'%#,, 0#(- 8(&019:'& "&;1(54#46:
.<=> 1 |
|
.<=> 2 |
|
?-"@&$-& 8A#4'& |
= !* bond |
?-"@'-%%-& 8A#4'& |
< 1 !* bond |
B0&(5%-& 8-/"-4'$(&- |
< 1 .-150 |
B0&(5%-& 8-/"-4'$(&- |
< 1 !* bond |
%'& "#;"6$1 |
|
%'& /"-0#$('$#%'9 |
|
C28-(94%-& 8-/"-4'$- |
< 1 !* bond |
C28-(94%-& 8-/"-4'$- |
< 1 .-150 |
(&%'& /"-0#$('$#%'9 |
|
(&%'& /"-0#$('$#%'9 |
|
D/'46$#&,-845 |
< 1 .-150 |
D/'46$#&,-845 |
< 1 !* bond |
!A#4'& *-(5@# |
< 1 .-150 |
!A#4'& *-(5@# |
= !* bond |
C28-(94%-& 8-/"-4'$- |
< 1 !*bond |
C28-(94%-& 8-/"-4'$- |
< 1 !* bond |
(&%'& /"-0#$('$#%'9 |
|
(&%'& /"-0#$('$#%'9 |
|
!-/"-4'$(&%'& ';(-,1 |
= !*bond |
!-/"-4'$(&%'& ';(-,1 |
< 1 !* bond |
D/'46$#&,-845 |
< 1 !*bond |
D/'46$#&,-845 |
< 1 !*bond |
E; /"-$&0&%%6+ -/64%--/"-,67(&%%6+ '88(&0-$#%'F ,-A%- 80&(#45 8(&019:'& -8%-$%6& $6$-06:
1.G"' '8/64#%'' /"&084#$(&%%6+ *1*1"1;%6+ *"#+,#(-$, ,#"*' «.-150», «.-135», 4"10%-84&F $ /"'3-4-$(&%'' *(&F84&"# ' '+ 0-;'"-$- *& %& %#2(90#(-85.
2.H1*1"1;%6& *"#+,#(6, /"&084#$(&%%6& I'",-F JCJ KGG «L-88'F8*'& *"#+,#(-/"-01*46» /- MII&*4'$%-84' $ -8%-$%-, %& 18- 41/#94 *#"4-I&(5%-,1 *"#+,#(1 ,#"*' !* bond.
3.H"#+,#(6 .-150 ' .-135 -4&N&84$&%%-3- /"-';$-084$# $ /-")0*& ',/-"4-;#,&:&%') "&*-,&%01&48) '8/-(5;-$#45 $ /"-';$-084$& 4#"%6+ *#"4-%-$ '; ,#*1(#41"6 $ *#N&84$& MII&*4'$%6+ 8$);19:'+ ' 10&"A'- $#9:'+ 8"&084$.
!"#$%'%&
1.='"-$6& 4&%0&%@'' $ "#;$'4'' 4&+%'*' ' 4&+%-(-3'' /&"&"#2-4*' ,#*1(#41"6 / <.C. <1(5*'%, E.O. H-$&"%'%8*'F, D.E. H-,#"-$, D.C. !/'"'0-%-$. C"+#%3&(58*, 2002. 109 8.
2.P2(-N*'% O.E., H-,#"-$ D.E., H-$&"%'%8*'F E.O. =#*1(#41"# $ 4&+- %-(-3'' *#"4-%#. C"+#%3&(58*, 2004. 252 8.
3.Papermaking Science and Technology. Book 7. Recycled Fiber and Deinking. Book editor: Gottsching L., Pakarin&n H. – Jyvaskyla, Finland, 2000. 649 p.
4.P2(-N*'% O.E. G-$67&%'& *#N&84$# 4&84-(#F%&"#: 0'8. … *#%0. 4&+%. %#1*. C"+#%3&(58*, 2005. 176 8.
119