Новые достижения в химии и химической технологии растительного сырья. Материалы III всероссийской конференции. Книга 3 [2007]

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E8%($)*3$+&-./+>3* *%%.$:1'-+*03* :18-2-+- ()-'13$)+1%&/ *%(1./21'-+*0 2-81+- F$+)* ' "%.1'*09 1%"#$%&'.$+*0 %*+&$2- G*<$- )--H)1(<-. I)* )-%&'1)$+**: cl*,i ! cg,i / Hei , 7:$, - 81+%&-+&> F$+)* 1()$:$.0@&%0 '>)-4$+*03* [2, 3]:

!"! 2 =8,8073·106exp(769,491/T)/P,

167

#$!" =1,366·107exp(424,565/T)/P,

#$!"2 = 4,8502·107exp(–636,999/T)/P,

#$#2"= 105 exp(!!2" – n 0,0181705)/P,

##2"0=8,44317+49,5974/T– 0,278896 lnT–1,30377 10-6 T2-4378.02/T2

#$!#4 $ 105 " exp(H!# 0 ! 28 " 0.0190354) / %

H!&0 $ 0,300209 !114,655 / T #1,02385" lnT ! 2,53913"10!6 "T 2 ! 4257,18 / T 2

#$Ar =16.52 107 exp (2253/8.31 T)/P

# #$%&'()##: c*g,i $ cl,iPi / P , & *&+,-(($. %&'/#&01)2( 3&40()#( 2%'(3(0.(5$. %2 62'7,0&7:

#$# 2" $ 105 " exp(H# 2"0 ! 28 " 0.0605329)

H# 2"0 $ 7.88232 #14.4370 /T ! 0.0648305 " lnT ! 465952 /T 2

#$!nY2 m =1.7838·107exp(-427.218(1/T-1.0298·10-3)n)/8

92$*201*, '(&*/#. $#)5(:& # $2%'242+3&;-&. (( '(&*/#. $34#<& %'25(*&;5 4 +#3*2= 6&:( )& $,$%()3#'24&))27 *&5&0#:&52'(, )(2>?2- 3#72 ,@#5A4&51 $*2'2$5# 6&:24A? %('(?2324 <&:-+#3*2$51 4$(? '(&- <()524 # #:7()()#( B5#? $*2'2$5(= $ 5(7%('&5,'2=. !>20(( %20)&. $ B52= 52@*# :'()#. 723(01 $#)5(:& C#D('&-E'2%D&, %2 )&D(7, 7)(- )#;, '&:'&>25&)& 8&32$27 # 3' [4]. "3)&*2 B5& 723(01 )( ,@#5A4&(5 '(&*/#; $34#<& # 2>'&5)A= %('(?23 %'23,*524 '(&*/## #: +#3*2= 4 <&:24,; 6&:,.

8&:'&>25&))&. )&7# 7&5(7&5#@($*&. 723(01 $#)5(:& C#D('&- E'2%D& %'(3%20&<&(5 #3(&01)2( 4A5($)()#( %2 <&:242= # %'23201)2( %('(7(D#4&)#( %2 +#3*2= 6&:(.

F4(3(7 $0(3,;-#( 2>2:)&@()#.: Xi ,Yi 4($24A( 320# [*</*<] 4 <&:(

# +#3*2$5#

168

1%'2'3 $"45' 3&/+ + 3&/0()' 2&/+:

Cl,i, Cg,i – [Kmol/m3] % 5+24$+ + ,"-', cl,i, cg,i – [mol/mol]

67+$)%"'$#8 2%' !'"49++: :&;#$%'((& #+($'- <+='!"->!&.=":

CO !(1! m / n )H2 " n1 CnH2m ! H2O

?'"49+8 #2%+,":

CO! H2O #CO2 !H2

6!"%('(+8 ;"/"(#" 3"##) +3'@$ %+2: 1 ,"-&%&* A"-' (Xi) + 5+24&* A"-' (Yi)

C2'#0 D7+$)%"'$#8 !"#$%&!'(+' ,"-&%)E 4&3.&('($ % 5+24&* A"-'

(i=1,2,3,4)

169