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CAIJ., EAJJ
w(F)
= \JI (U)
= x(X, t)

6,.1 General Remarks on Constitutive Equations

209

either J = detF .approaches +oo or o+, i.e.

 

 

w{F) ->- +oo

as

detF -+ +oo ,

}

w(F)-+ +oo

as

detF 4 o+

(6.6)

 

Physically, that means that we would require an .infinite amount of strain energy in order to expand a continuum body to the infinite range or to compress it to a point with vanishin_g volume..

For further discuss.ions see the books by, for example, CIARLET [1988] and OGDEN

[19.97].

E-quivalent forms of .the strain-energy func.tion. In order to illustrate \JI w.e imagine a stretched (rubber) band with a certain amount of energy stored. The strain energy

w{F) _generated by the motion x is assumed to be objective. This means, after a (possibly time-dependent) translation and rotation of the stretched (rubber) band in space, that the amount of energy stored is unchanged.

Hence, the strain energy w(F) must be equal to the strain energy \ll(F+) generated by a second motion x+ = x+(x, t+) which differs from x by a superimposed rigid-body motion (recall Section 5.2). Employing the transformation rule for the deformation gradient (5.33)a~ we see that \JI cannot be an arbitrary function of F. In

.particular, it must obey the restriction

 

w(F) = w(F+) = ·w-(QF)

(6.7)

for all tensors F, with detF > 0, and for all orthogonal tensors Q, since F transforms into QF, i.e. Fd;1 = QabFbA·

In order to obtain equiva]ent formulations of (6.7) we take a special choice for

Q, namely the transpose of the proper orthogonal rotation tensor, RT, and use the right polar decomposition (2.91) 1Then, from (6.7), we find that \JI (.F) = '11 (RTF) = w(.RTRU), and finally,

w(Jr) = w(U) ,

(6.8)

which ho"lds for arbitrary F.

= RU. We

From (6.8) we learn that \JI is .independent of the rotational part of F

conclude that a hyperelastic material depends only on the stretching part of F, i.e. the symmetric right stretch tensor U. It is important to note that the relation

specifies the necessary and suffic~ent condition for the strain energy to be objective during superimposed rigid-body motions.

Since the right Cauchy-Green tensor and the Green-Lagrange strain tensor are given by C = U2 and E = (U2 - I) /2, we may express \JI as a function of the six components

of the symmetric material tensors C, E, respectively. Hence, we may write

w(F) = w(C) = w(E) .

(6.9)

210

6 Hyperelastic IVlatcri.als

For notational simplicity, here and elsewhere we wiJl use the same Greek letter \II for different strain-energy functions.

Reduced forms of constitutive equations. In the following we present some re·- duced forms of constitutive equations for hyperelastic materials at finite strains.

Consider the derivative of the strain-energy function ·w (F) = \JI (C) with respect to time t. By means of the chain rule of differentiation, property (.l .93) 1 and the comb.i.. nation of (2.166) i. and (2.163) J., we obtain the .expressions

.

= tr

[(aw(F))T ·];

 

tr

"[(Dw(C))

·]

 

 

\JI

 

DF ·

F· =

 

 

DC ·

C .

 

 

 

= tr

~[8\Jl(C)

(-T-

T")J:

(aw(C)

T•)

(6...10)

 

!

DC

 

F F + F

F .

= 2tr .

ac

F F

 

which must be val.id for arbitrary tensors F. Since C is a syn1metric second-order tensor, the gradient of the scalar-valued tensor function w(C), used in (6.10), is also symmetric. From (6.10) we deduce immediately that

D\Jl(F))T = ?Dlll(C)

T

(6.1 l)

( BF

.... ac

.F '

which, when substituted back into (6.2)3, gives an important reduced form of the con.. stitutive equation for hyperelastic materia.ls, namely

 

u = J

_ 1

 

(aw(F)) ·r

= 2.J

_1

Dw(c)

T

 

 

 

F

DF

 

F

DC

F ·

(6.12)

 

 

 

 

~i . aw

_ ~J _

 

~~·-- .

aw

 

 

_

 

 

 

or

aub -

J

FaA DL? . - ... J

 

1Fn..tFbu ac .

 

 

 

 

 

I'bA

 

 

 

 

.rAJJ

 

Alternative expressions may be obtained for the Piola-Kirchhoff stress tensors ·p (which is non-symmetric) and S (which is symn1etric). From (3.8) and (3.65) 1 we .find, by means of the stress relation (6. l2h, the chain rule and 2E = C - I, that

 

 

D\Jl(C)

8\J! (C)

O\JI (E)

 

 

P=2F

ac ··

,

S = 2· DC

=

DE

(6.13)

 

 

aw

 

D\JJ

a\v

or

 

 

 

Pa;1 = 2F'i111DC. .

SAFI== 2DC

DE.~111

 

 

 

 

1 AIJ

 

·-'All

 

Note that the response function occurring in the general constitutive equation (5.82) is with reference to (6.13h determined by SJ(C) = 2()\:fJ{C)/DC.

= x(X, i;)

6.1 General Remarks on Constitutive Equations

.211

The Es.helby tensor and the tensor of chemical potential. The Eshclby tensor (or the (e.Jastic) energy..momentum tensor) is a crucial quanti-ty infi·acture mechanics and the continuum theoJ)' <~ldislocatimzs (which are not discussed in this text). However,

for completeness we present the (isothermal) ·refe·rential Eshelby tensor G, which is, in general, non-symmetric and is de.fined as

= - JF·T!_ (·q!(F))

or

a ( \(~,')

(6~:14)

G

f . DF

J

 

G An = -J.Fr,/-r DF

 

 

 

 

 

n/J

 

(see ESHELBY [1.975] and CHADWICK [1975]}, where J = detF denotes the volume ratio4 The physical dimension of the Eshelby tensor is the same .as that of the strain energy.

The symmetric tensor of chemkal potential k is related to G according to

or

(6.15)

see, for example, BOWEN [l976a].

The spatial tensor of chemical potential is required in the theory of diffusing mix.. tures (see TRUESDELL [ 1984] which contains more details).

Work done on hyperelastic mater"ials. We consider a dynamical process within some dosed time interval denoted by [t 1, t2] .in which the two arbitrary instants t 1 and t 2 are .elements of the interval. The dynamical process is given by a motion x

and the stress u with the corresponding Cauchy traction vector t and the body force ·b. During the process the body deforms according to the deformation gradient F = F(t), with t E [t1, t2J.

We say that a dynamical process is closed if F 1 = F 2. We introduce the definitions F 1 = F(t 1) and ·F2 = F(t2 ) of the deformation gradients in the initial configuration and the final configuration of the dynamical process, respectively.

Our nex.t step is to determ.ine the work done by the stress field on a continuum body of unit volume during a certain time interval ft t, t2]. Consider a body whose material properties .are hype.relastic according to the general constitutive equation given in (6. l ). Hence, from (4.1.0.l )1 and the above definitions we find by m-eans of the chain rule that

f•l

 

t·.•)

·t·J

 

 

' .

/-; .a~u .

/-: Dw(F)

(6.16)

./ P:Fdt=.

DF:Fdt=. Dt dt=\ll(F2)-W(F1),

 

l 1

t J

t l

 

 

which_, for a closed dynamical process with F1

= F2 , reduces to

 

 

 

I.',!

 

 

 

 

Ip: Fdt = W(F2) -

\J!(Fi) = 0 .

(6.17)

 

l

J

 

 

 

212 ·6 Hyperelastic Materials

Thus, as distinct from Cauchy-elastic materials (see Section 5.4), the actual work done by the stress field on a hyperelastic material during a certain (closed) time inter- val depends only on the initial and.final configurations (path independent). In fact, the work is zero in closed dynamical processes. This important result also holds for contin- uum bodies which may undergo inhomogeneous deformations, in which W = \Jl(F, X) and Po = Po(X), with F = F(X, t).

EXERCISES

l . Expand the strain-energy function \JI (F) in the form of tensorial :polynomials in the vicinity of the reference configuration, i.e. for F = I,

W(F) = W(I} + (F - I) : a~r) + ·-> 0

for all F - I. Using relations (6.4) and (6.5) show that the stress in the reference configuration is zero.

2.Recall the definitions of the referential Eshelby tensor G and the tensor of chemical potential k.

(.a) Show that the forms

 

 

 

G ·=w{F)I - JFTuF-T ,

·:k = w(F)I -

r

(6.18)

are equivalent to those given in (6.14) and (6.15), where T

is the Kirchhoff

stress tensor, as defined in eq. (3.62).

 

 

 

(b) By applying requirement (3.10), show with (6.18)1 that

GC = CGT '

with the right Cauchy~Green tensor C = FTF, as defined in eq. (2.64).

6.2 Isotropic Hyperelastic Materials

We now restrict the strain-energy function by a particular .property that the material may possess, namely isotropy. This property is based on the physical idea that the response of the material, when studied .in a stress-strain experiment, is the same in all directions. ·One example of an (approximately) isotropic material with a wide range of applications is rubber.

In this section we are concerned with the mathematical formulation of isotropy within the context of hyperelasticity.

6.2 Isotropic Hyperelastic Materials

213

Scalar...valued isotropk tensor function.

We consider an

arbitrary po.int X of

an elastic ·continuum body occupying the region 00 (reference configuration) at time t = 0. A motion X may carry this point X E fl0 to a place x = x(X, t) specifying a location in the region fl (current ·Configuration) at time t.

We now study the effect of a rigid-body ·motion superimposed on the reference

co1rfiguration. We postulate that the body occupying the region !10 is tmnslated by the vector c and rotated by the orthogonal tensor Q according to

X* = c+QX ,

(6.19)

whic'h moves no to a new region no (new reference configuration), and the arbitrary point with position vector X to a new location identified by the position vector X* E f20

{see Figure 6.1).

X ' Xr* '"•

3' 3 ' :i.3

time t = 0

time ·t

x(X, t) = x*(X*, t)

Figure 6.1 Rigid.. body motion superimposed on the reference configuration.

We now demand that a different motion x = x* (X*, t)

moves n~ to the current

configuration n so that

 

x = x(X, t) = x*(X*, t) ,

(6.20)

mapping X* to place x. By the chain rule and relation (6. l 9) the deformation gradient

214

 

 

6 Hyperelas.tic Materials

F may be expressed as

F= i; = :~Q=F*Q

 

 

 

 

fJ:ru

_

 

 

(6.21)

or

-1

_

D:ra (l .

_

F* ) .

Fa.4

-

a·· ~~

-

a·· ~-:"'* ·1t JJA

-

a.11(" JJA

 

 

 

...·\.A

 

_:\.. ll

 

 

where F* =.Dx/Dx*·is defined to be the deformation gradient relative to the reg.ion 00. From (6..21 )a we find the important transformation, namely

or

FaA -

r u/J'-·t: AB ..

(6.22_)

 

* -

I; /"""} ..

 

Hence, we say that a hyperelastic .material is isotro.pic relative to the reference configuration n0 if the values of the strain -energy \JI (F) and \JI (Fk) are the sa.me for all orthogonal tensors ·Q. With (6.22) we may write

\ll(F) = w(F*) = w(FQT) .

(6..23)

I.n other words, if we can show that a mot.ion of an elastic body superimposed on any particularly translated and/or rotated reference configuration leads to the same strain-energy function at time t, then the material is said to be .isotropic. However, if a superimposed rigid-body motion changes the strain-energy function in the sense that (6.23) is not satisfied (W(F) ~ w(F*)) the hypere.lastic material is said to be :anisotropk (see, for example, TRUESDELL and NOLL [1992, .Section 33] and ·OG- DEN .[ 1997, Section 4.2~5])..

lt is important to mention that .relation (6.23) is .fimdamentally distinct fro.m requirement {6.7), which says that the strain energy .must be objective during rig.id-body motions, i.e. independent of an observer~ The later condition hoJds for all materials {it is a fundamental physical requirement and must be satisfied) while the condition of isotropic response (6.23) holds only for some mate.rials (it -~s a material-dependent

.requirement and may or may not be satisfied), namely for .isotropic materials, wh.ich ,makes a crucial difference.

I.n addition, it is important to note that for the material-dependent requirements (6.22) and (6.23) it is the reference configuration that has been translated and rotated. For that case the deformation gradient Fis multiplied ·on the right b_y ·QT, whereby Q acts with material coordinates, i.e. CJAH· However, for the objectivity requirements

(5.33h and (6.7), it is the current configuration that has been translated and rotated, and F .is multiplied on the left by Q, acting with spatial coordinates, i.e.. Q011

We now suppose that during .motion x == x(X, t) the strain-energy function may adopt the form w(F) = w(C); recall eq. (6..9)i. If we restrict the hyperelastic material to isotropic hypere.lastic response we require that '11 (C) = \JI (C* ), with C* = F*'rF*. With reference to (6.22) we conclude that

(6.24)

If a scalar-valued tensor function is

6.2 lsotro.pic Hyperelastic Materials

215

implying with the right Cauchy-Green tensor C = FTF, that

(6.25)

If the requirement for -isotropy (6.25) holds for all symmetric tensors ·C and orthogonal tensors Q, we say that the strain-energy function \V (C) is a scalar-valued isotropic tensor function of one variable C or simply an .invariant of the symmetric tensor C. We can show, if the strain-energy function is an invariant, then its gradient .is a tensor-valued isotropic tensor function.

EXAMPLE 6.1 Assume that the hyperelastic material is restricted to isotropic re...

sponse. Show that the strain ene(gy may be expressed by the identity

\ll(C) = W(b) ,

(6.26)

where W(b) characterizes an isotropic function of the (spatial) left Cauchy..Green ten- sorb =FFT .

Solution. We substitute for Qin condition (6.25) the proper orthogonal rotation ten...

sor .R. Then, kinematic relation (2. l07):i implies (6.26), which holds for any isotropic deformation. •

Constitutive equations in terms of invariants.

an .invariant under a rotation, according to (6.25), it may be expressed in terms of the principal invariants of its argument (for example, C orb), which is a fundamental result for .isotropic scalar functions, known as the representation theorem for inva.riants

(for a proof see, for exam.pie, GURTIN [.198.la, p. 231] or TRUESDELL and NOLL [l 992, Sect.ion l OJ)..

Having this in mind, the strain energies, as established in eq. (6.26), may be expressed as a set of independent strain invariants of the symmetric Cauchy-Green ten~ sors C and :b, namely, through ! 0 = Ia(C) .and J,1 = Iu(b), a = 1, 2, 3, respectively..

With reference to {6.26), we may write equivalently

(627)

Again, (6.27) is exclusively valid for isotropic hyperelast.ic materials satisfying condition (6.25) for all orthogonal tensors·Q. Since C and b have the same eigenvalues, which are the squares of the principal stretches,,\?,., a = 1., 2, 3, we conclude that

(6.28)

where the three principal .invariants are explicitly given in accordance with .eqs. (5.89)-

216 6 .Hyperelastic Materials

(5.91). Note that for the stress-free reference configuration, the strain-energy functions (6.27), with (5.89)-(5.91), ·must satisfy the normalization condition (6.4), i.e. '11 =

0, for 11 = 12 = 3 and / 3 = 1. The representation in the form of invariants was established in the classical work of RIVLIN [1948].

In order to determine constitutive equations for isotropic hyperelastic materials in terms of strain invariants, consider a differentiation of w{C) = \J!(Ii, 12, 13 ) with respect to tensor C. We assume that \ll(C) has continuous derivatives with respect to the principal invariants Ia, a = 1, 2, 3. By means of the chain rule of differentiation we find

aw(C) =

aw OI1 + aw aI2 + aw 8!3

3

 

= I: aw Bla .

(6.29)

8C

811 8C 812 8C 8Ia 8C

a=I 8Ia 8C

 

The derivative of the first invariant / 1 with respect to C, as needed for (6.29), gives

with (6.28_)i, (5 ..89)1 and the .property (1.94) of double contraction

 

811

= 8trC = 8(1 : C) =

1

or

8/i

8

(6.30)

ac

ac

ac

 

 

acA.n =

AB

The derivatives of the remaining two invariants with respect to C follow from eqs. (5.90)1 and (5.9l)i, by means of (6.28), (6.30h, the chain rule and relations ( 1.252)2, ( 1.241) (use the symmetric tensor C in the place of A), and have the forms

 

 

 

2

 

 

ala= I3 c-i

812

= ! (2 CI8tr(C )) =I1l - C

'

ac

2 tr

 

ac

 

ac

 

 

 

 

 

 

(6.31)

or

812

=

I .r

C

8/3

I c-1

8cAB

}U..4B -

'AB ·'

ac·

=.:: :1 AB .

 

 

 

 

AB

 

Substituting (6.29)-(6.31) into constitutive equation (6.13)2 gives the most general form of a stress relation in terms of the three strain invariants, which characterizes isotropic hyperelastic materials at finite strains, i.e.

s = 9 BW(C) =?.[(aw

+

1

aw) 1

_aw c

+

1

aw c-i.]

(6.32)

... 8C

- 811

1

812

812

3

81

 

 

 

 

 

 

 

 

 

3

 

The .gradient of the invariant w{C) = \J!(li., 12 , / 3 ) has the simple representation {6.32), which is a fundamental relationship in the theo.ry of finite hyperelasticity. Note that (6.32) is a general representation for three dimensions, in which \II may adopt .any

scalar-valued isotropic function of one symmetric second-order tensor variable.

Multiplication of (6.32h by tensor C from the right-hand side or from the left-hand side leads to the same result. We say that 8\f!(C)/BC commutes (or, is coaxial_) with

C in the sense that

aw(qc = caw(C)

(6.33)

ac

ac '

 

which is an essential consequence of isotropy.

6.2 Isotropic Hyperelastk Materials

217

Next, we present the spatial counterpart of constitutive equation (6.32). According to relation (3.66), the Cauchy stress u follows from the second Piola-Kirchhoff stress

S by the Piola transformation u = J- 1FSFT. By multiplying the tensor variables I., C, c-1 with F fro-m the left-hand side and with FT fron1 the right-hand side, we may write by means of the left Cauchy-Green tensor b = FFT, that FIFT = FFT = b,

FCFT = (F-FT) 2 ·=b2 , Fc-1 FT = (FF- 1){F-TFT) =I. With (6.32) we deduce from u = J-1FSFT that

_

'J _ 1

·[ . aw

( aw

+ 11

aw ) . _ aw 2]

(6.34)

u -

~J

Ia 8!3 I+

811

812 b 8/2b

Following arguments analogous to those which led from (5.88) to (5.94), we find an alternative form to (6.34), namely

u = 2J-1. ((12aw

+ /3 aw) 1+ aw h -

Ia awh-1]

(6.35)

8!2

8/3

8!1

. 812

 

By comparing (6.34) and (6.35) with (5.88) and (5.94) we ·may derive the response coefficients aa, .a= -0, 1, 2, and {30 , a= 0, 1, -1, in terms of the strain-energy function (6.27). We obtain the forms

2

J

_ 1 ( a'll

aw)

o:i =

8I1

+ Ir 8I2 '

(6.36)

/31 = ?.J_1 aw

.... 811 ,

(6.37)

which specify the first and the second representation theorem for isotropic tensor func- tions, .i.e. (5.88) and (5.94), respectively.

Note that in order to formulate constitutive equations which are not restricted to isotropic response and which satisfy the objectivity requirement, it is ~ppropriate to use .quantities which are referred to the reference configuration. Within the context of hyperelasticity it is obvious to use the right Cauchy-stress tensor C and its work co~jugate stress .field, i.e. the second Piola-Kirchhoff stress tensor S.

Constitutive equations derived from '11 (b) and '!I(v). If the strain-energy function

depends on the (symmetric) left Cauchy-Green tensor b, then the isotropic hyperelastic response is

= ?J-1 ·B\J1(b)b = ?.J-1b8\Jl(b)

or

(6.3.8)

u ~

8b

..

8b

 

 

218

6

Hyperelastic Materials

(see also TRUESDELL and NOLL

[1992, Section 85, p. 313]), where w{b) is .a scalar-

valued isotropic function of the tensor variable b = FFT. This constitutive equation plays an essential part in isotropic finite hyperelastici.ty. On comparison with eq. (5.85) we deduce that the right-hand side of eq. (6.38) corresponds to the response function

IJ(b).

Proof In order to obtain the constitutive equation (6.38), we start by differentiating the postulated stra:in-ene.rgy function \V (b) with respect to time t. Considering symmetries, a straightforward algebraic manipulation gives, by means of the chain rule, relution (2.169) and the property (1.95) of double contraction,

¢ = D\Jt(b) . b = D\J!(b)

. (lb

+

bfr).

 

.

Bb .

 

.ab

.

 

 

 

_

9 aw (b)

. lb _ ')aw (h) h .

1

1

(639)

-

- ob

. -

 

 

 

 

 

... Db . . .

 

 

where 1is the spatial velocity gradient, .in general a non-sym1netric tensor.

 

With respect to eqs. (6.32) and (6.33),

taking b

.in place of C, we deduce that

D\JI (b) / 8b commutes with the symmetric s·econd-order tensor b, in the sense that

 

aw(b)

 

aw(b)

 

 

 

 

 

 

ob

b = b

ah

· ,.

 

 

 

 

(6.40)

implying the sym·metry of tensor (aw (b) /Db) h~

However, from (4.154), we know that for perfectly elastic mater"ials (for which Vint = 0) the stress power Wint per unit reference volume equals \JI. The combination

of identity (4J 13)h i.e. Wint = .Ju : d, and eq. (6.39)4 with the requirement (6.40) for isotropy implies

.

d = ?aw{b)b ~

d = ?baw(b) . d

'

(6.41)

~Ju .

-

Db

.

~

ob .

where the rate of deformation tensor d is the symmetric part of I.

For this relation we

used the fact that the double ·Contraction of a symmetric tensor and a skew tensor is zero.

Simple arguments ·reduce .relation (6.41) to the desired fundamental constitutive

equation (6.38) for ·isotropic response.

Since the ·1eft stretch tensor v =

b 112 is the unique square root of b, the strain

energy may also be expressed as an isotropic function of v; thus, relation (6.26) may be extended to 'P (C) = \JI (b) = '1T (v). Note that for notational convenience, we do not distinguish between different strain-energy functions \Ji.

With .respect to constitutive equation (6.38) we derive an equivalent form in terms of the left stretch tensor v. Analogous to the procedure which was used to establ.ish

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