Molecular Switches
.pdf
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M M 0 M |
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M |
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0 M |
M |
P M |
M |
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M |
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M |
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M
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M
&
M
M
F V F M V
F V
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(A) |
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20 |
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(a) |
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A |
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(b) |
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10 |
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I / |
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(c) |
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0 |
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0 |
0.2 |
0.4 |
0.6 |
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E / V |
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(B) |
16 |
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12 |
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/ A |
8 |
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cat |
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I |
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4 |
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0 |
4 |
8 |
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12 |
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0 |
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Cycle number
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0 M P M |
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0 M |
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F V F V F V
N |
N NAD+ |
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N NAD+ |
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+ |
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N |
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UV |
Visible Light |
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CH3CH2OH |
N |
N |
Red |
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NAD+ |
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AlcDH |
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D I |
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O |
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NADH |
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CH3CH |
N |
N |
Ox (DCIP) |
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O |
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O |
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C NH2 |
O |
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–O P O |
O N |
CH2CNH |
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O |
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OH N |
NH |
CH CO2CH3 |
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HO |
N |
CH2 |
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–O P O |
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O |
N |
N |
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O |
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HO |
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OH |
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N N |
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O |
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O |
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C NH2 |
O |
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UV |
–O P O |
O N |
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CH2CNH |
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O |
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NH |
CH CO2CH3 |
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OH N |
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HO |
N |
CH2 |
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Visible |
–O P O |
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O |
N |
N |
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O |
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HO OH |
N N |
(32a) |
(32b) |
M
F V
F V F V
F V F V F V
F V
F V
F V
F V
F V
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M |
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M |
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M |
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M |
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M |
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M M |
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1 mm