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H.O. Pierson. Handbook of carbon, graphite, diamond and fullerenes. Properties, processing and applications. 1993

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396 Carbon, Graphite, Diamond, and Fullerenes

Pyrolytic

carbon

 

 

 

 

 

applications

 

 

of

161

 

 

is used

to

densify

163

 

structure

of

 

160

 

 

 

Pyrolytic

graphite

57,

141

 

as a coating

 

 

142,

162

 

structure

of

 

151

 

 

 

Pyrolyzation

temperature

210

 

Q

 

 

 

 

 

 

 

 

 

 

Quantum

numbers

13

 

 

R

 

 

 

 

 

 

 

 

 

 

Radical

sponge

 

368

 

 

 

Radio

frequency

 

(RF)

 

311

 

Radioactive

 

 

 

 

 

 

 

 

definition

 

 

19

 

 

 

 

Raman

spectroscopy

 

338

 

Rate

of

reaction

 

 

 

 

 

of vitreous

 

carbon

133

 

Raw

materials

 

 

 

 

 

 

for

molded

 

graphite

 

88

 

Rayon

209

 

 

 

 

 

 

 

carbonized

 

 

166

 

 

 

Rayon-based

 

fibers

 

 

 

 

166,

173,

187,

194

 

Refractory

 

 

 

 

 

 

 

 

composites

 

 

163

 

 

 

materials

 

52

 

 

 

 

metals

319

 

 

 

 

 

Resilience

 

 

 

 

 

 

 

 

modulus

of

 

294

 

 

 

Resins

 

 

 

 

 

 

 

 

 

matrix

materials

203

 

Resistance-heating

elements

162

Resistivity

 

 

 

 

 

 

 

 

electrical

 

 

195

 

 

 

 

of diamond

 

 

270

 

 

 

Reticulated

vitreous carbon

 

 

(RVC)

 

135

 

 

 

 

RF activation

 

 

 

 

 

 

 

for

DLC

deposition

 

346

 

RF plasma

 

314

 

 

 

 

Rhombohedral

 

 

 

 

 

stacking

 

sequence

46

Ribbons

 

 

 

 

 

 

 

graphitic

 

129

 

 

 

 

Roughness

 

 

 

 

 

 

 

of CVD

diamond

350

 

 

of DLC

coatings

 

350

 

 

Roving

 

 

 

 

 

 

 

carbon

fiber

201

 

 

S

 

 

 

 

 

 

 

Salt-dome

calcite

23

 

 

Scleroscope

 

96,

103

 

 

Seal rings

 

117

 

 

 

 

Sebastian

adhesion

tester

349

Semi-metal

 

 

 

 

 

 

 

graphite

 

as

61

 

 

 

Semiconducting

 

 

 

 

 

properties

of DLC

350

Semiconductor

 

 

 

 

 

applications

of

molded

 

 

graphite

114

 

 

 

characteristics

of CVD

 

 

diamond

324

 

 

 

fullerene

 

as

367

 

 

 

properties

of

 

 

 

 

diamond

 

244,

 

269, 270

Semiconductor

applications

for CVD

 

diamond

327

 

Shear strength

 

 

 

 

 

of carbon

fibers

 

187

 

 

Shrinkage

 

 

 

 

 

 

 

of precursor

polymer

 

134

Sigmaorbital

 

30,

34

 

 

Sigma-bond

energy

30

 

 

Silicon carbide

327

 

 

fibers

172

 

 

 

 

 

Single-crystal

diamond

321

Single-point

turning

295

 

 

Sizing

 

 

 

 

 

 

 

of grains

91

 

 

 

 

“Skin”

 

 

 

 

 

 

 

of the fiber

179

 

 

 

Skin-core

 

 

 

 

 

 

 

 

structure

 

186

 

 

 

 

Soft fillers

 

89

 

 

 

 

 

Solvent-catalyst

reaction

285

Sound

waves

268

 

 

 

 

sp2 bonds

 

247

 

 

 

 

sp3 bonds

 

25,

179,

247

 

Specific

 

heat

 

 

 

 

 

 

of diamond

262

 

 

 

 

of graphite

 

54

 

 

 

 

Specific

 

strength

 

 

 

 

of graphite

 

101

 

 

 

 

Speed

of sound

269

 

 

 

Spinning

 

 

 

 

 

 

 

 

of mesophase

pitch

 

185

 

of PAN-based

fibers

 

174

Sputtering

 

 

 

 

 

 

 

process

and

equipment

344

yield

 

343

 

 

 

 

 

Stabilization

 

 

 

 

 

 

 

of stretched fibers

 

176

 

of the

sp3 dangling

bonds

306

Standing

waves

13

 

 

 

 

Steel

 

 

 

 

 

 

 

 

 

worldwide

production

 

of

110

Strength

 

 

 

 

 

 

 

 

of carbon

fibers

171

 

of carbon-carbon

211

 

of diamond

 

271

 

 

 

 

of molded

graphite

 

 

100

 

Stretching

 

 

 

 

 

 

 

of spun

fibers

176

 

 

 

rayon-based

fibers

 

 

188

 

Structural

 

composites

 

 

198

 

Structural

 

material

 

 

 

 

carbon-carbon

209

 

 

 

Structure

 

 

 

 

 

 

 

 

of mesophase-pitch

 

carbon

fibers

 

186

 

 

 

 

of PAN-based

carbon

fibers 178

Sub-shells

 

14

 

 

 

 

 

Sublimation

 

 

 

 

 

 

 

of diamond

 

257

 

 

 

 

of graphite

 

52

 

 

 

 

 

 

 

 

 

Index

397

Substrate

materials

 

 

 

for CVD-diamond

coatings

326

Superconductivity

 

 

 

of fullerenes

370

 

 

Supersaturation

 

253

 

 

Surface

energy

 

 

 

 

in graphite

63

 

 

 

Surface

reaction

 

 

 

of carbon

fibers

204

 

 

Synthesis

 

 

 

 

 

 

low-pressure

303

 

 

of diamond

285

 

 

Synthetic

 

 

 

 

 

 

carbon

and

graphite

70

 

production

processes

5

 

Synthetic

diamond

245, 282

 

crystals

293

 

 

 

high-pressure

 

245

 

 

market

 

292

 

 

 

production

 

292

 

 

T

 

 

 

 

 

 

Temperature

 

 

 

 

 

effect

on

conductivity

261

 

effect

on

deposition

156

 

effect

on

molded

graphite

100

for

graphitization

 

82

 

 

of carbonization

 

178

 

Temperature

 

coefficient

of resistance

of molded

graphite

 

108

 

Tensile

 

 

 

 

 

 

modulus

 

178

 

 

 

 

properties

of fibers

 

171

 

strength

 

186,

191,

219,

221

strength

of molded

graphite

101

Terminology

 

2

 

 

 

 

Test

methods

 

 

 

 

 

for

molded

graphite

 

96

 

Testing

 

 

 

 

 

 

of carbon

 

fibers

189

 

Tetragonal

 

 

 

 

 

 

bonds

130

 

 

 

 

orbital state 247

 

 

 

Tetravalent

 

16

 

 

 

 

398 Carbon, Graphite, Diamond, and Fullerenes

Textile

fibers

166

 

 

 

 

Them-A

 

 

 

 

 

 

 

 

applications

of CVD

diamond

327

Thermal

coefficient

of expansion

 

 

(CTE)

97, 194

 

 

 

Thermal

conductivity

 

186,

244

 

by flow

of phonons

319

 

 

in CVD diamond

322

 

 

of

carbon-fiber,

metal-matrix

 

 

composites

216

 

 

 

of composite

206

 

 

 

of diamond

 

258,

259

 

 

of molded

graphite

104

 

 

of

pryolytii

graphite

158

 

Thermal

CVD

 

 

 

 

 

 

of diamond

 

317

 

 

 

 

Thermal

expansion

 

 

 

 

of diamond

 

262

 

 

 

 

of

molded

graphite

105

 

 

of

pyrolytic

graphite

159

 

Thermal

insulation

136

 

 

Thermal

process

 

 

 

 

 

for

production

of carbon

black

229

Thermal

properties

 

 

 

 

of carbon fibers

194

 

 

of graphite

54

 

 

 

 

of vitreous

carbon

 

131

 

 

Thermal

shock

 

 

 

 

 

characteristic

of molded

 

 

 

 

graphite

107

 

 

 

Thermionic

applications

 

 

 

of CVD

diamond

326

 

 

Thermodynamic

stability

 

 

of fullerenes

364

 

 

 

Thermodynamics

 

 

 

 

 

of

pyrolysis

 

144

 

 

 

 

Thermoplastic

polymers

204

 

Thermosetting

 

 

 

 

 

 

of mesophase

pitch

185

 

Thorium

carbide

149

 

 

 

TNT

289

 

 

 

 

 

 

 

Tows

 

189

 

 

 

 

 

 

Transition

metals

 

 

 

 

as solvent-catalysts

 

285

 

Transition

reaction

 

 

of graphite-diamond

283

Transmittance

 

 

 

 

of diamond

 

264

 

 

Tribological

 

 

 

 

 

applications

of DLC 351

Trigonal

 

 

 

 

 

 

bonding

 

340

 

 

bonds

 

130

 

 

 

Trigonal

orbital

33

 

 

Triple point

 

 

 

 

of graphite

 

51

 

 

Tungsten

carbide

 

 

cemented

326

 

 

Turbostratic

 

 

 

 

 

carbon

47

 

 

 

conversion

from

 

82

structure

 

151,

178

Twinning

 

250,

319

 

Type I, Type

II fibers

190

U

 

 

 

 

 

 

Ultramafic

bodies

279

Ultraviolet

spectrum

 

262

Uranium

carbide

149

V

 

 

 

 

 

 

Valence

electrons

 

16

van der

Waals

 

 

 

attraction

 

76

 

 

bond

45

 

 

 

 

forces

 

366

 

 

 

Vapor

 

 

 

 

 

 

carbon

37

 

 

 

Vapor-phase

 

 

 

 

diamond

 

245

 

 

fibers

 

173,

188

 

 

precipitation

155

 

process

 

142

 

 

Vein

 

 

 

 

 

 

graphite

 

227

 

 

Visible spectrum

262

Vitreous

carbon

122

foam

135

 

 

 

Index 399

properties

 

of

131

 

 

spheres

 

137

 

 

 

structure

of

129

 

 

 

types

of

 

131

 

 

 

Volatile

compounds

 

 

 

diffusion

of

72

 

 

 

Volumetric

expansion

 

 

 

of vitreous

carbon

 

127

 

W

 

 

 

 

 

 

 

 

Wave

function

25

 

 

 

Wear

applications

 

 

 

of DLC

351

 

 

 

Wear

resistance

 

 

 

 

of CVD diamond

324

 

Weave

 

 

 

 

 

 

 

of carbon

fibers

201

 

patterns

 

202

 

 

 

Weight

loss

 

 

 

 

 

 

of vitreous

carbon

 

126

 

Wet-spinning

process

174

 

Wool

fibers

 

166

 

 

 

Woven

carbon

fibers

 

202

 

X

 

 

 

 

 

 

 

 

X-ray

 

 

 

 

 

 

 

 

applications

 

of CVD

diamond

331

luminescence

279

 

 

X-ray

diffraction

 

 

 

 

to

analyze

structure

80

 

X-ray

lithography

 

 

 

DLC coatings

in

353

 

X-ray

transmission

 

 

 

of diamond

 

268

 

 

 

Y

 

 

 

 

 

 

 

 

Yarn

 

 

 

 

 

 

 

 

carbon-fiber

 

201

 

 

 

Yield

73.

See

Carbon

yield

 

Young’s

modulus of elasticity

 

of graphite

 

62

 

 

 

Z number 13

Copyright 0 1993 by Noyes

Publications

 

 

 

No part of this book

may be reproduced

or utilized in

any form or by any means,

electronic

or mechanical,

including

photocopying,

recording

or

by any

information

storage

and retrieval

system,

without

permission

in writing

 

from

the Publisher.

 

Library of Congress Catalog Card Number: 93-29744

ISBN: O-8155-1339-9

Printed in the United States

Published in the United States of America by

Noyes Publications

Mill Road, Park Ridge, New Jersey 07656

10987654321

Library

of Congress

Cataloging-in-Publication

Uata

Pierson,

Hugh

0.

 

 

 

 

 

Handbook

of carbon, graphite,

diamond,

and fullerenes : properties,

processing, and

applications

/ by

Hugh

0.

Pierson.

 

P.

cm.

 

 

 

 

Includes

bibliographical

references

and

index.

ISBN O-8155-1339-9

 

 

 

 

1. Carbon.

 

I. Title

 

 

 

 

TP245.C4P54

 

1993

 

 

 

 

661’

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by John D. Buckley

and Dan

D. Edie

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

CODE

COMPLIANCE

FOR ADVANCED

TECHNOLOGY

FACILITIES:

by William

R. Acorn

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