Новые достижения в химии и химической технологии растительного сырья. Материалы II всероссийской конференции [2005]

! "#$%& '(#)*+,(-.#/01 '(*"#22- -3$*4#(-"00 '(*,#)#/5 022$#- )*,-/01 ,*64*7/*2+0 '*$89#/01 :;<-5 , 2(#)# ,*)/*3* (-2+,*(- Na- ;:<. =2+-/*,$#/*, 9+* '(*"#22 -3$*4#(-"00 4*7/* '(#)*+,(-+0+% '(0 02'*$%6*,-/00 ,*)/5> (-2+,*(*, Na-;:< /-90/-1 2 ?*/"#/+(-"00 0,05%. @-?7# 82+-/*,$#/*, 9+* , '(*"#22# '*2$#)*,-+#$%/*A, 4/*3*- ?(-+/*A !BC 0 =D *E(-E*+?# 202+#4 :;< – Na-;:< 2+#'#/% 6-4#.#- /01 '*2$#)/#3* '(-?+09#2?0 /# 064#/1#+21, - 2+#'#/% '*$04#(06-"00 2/07-#+21 /- 30–50%. F+* 2/07#/0# +#4 E*$%G#, 9#4 ,5G# 02>*)/-1 2+#'#/% '*$04#(06-"00 ;:<.

H0)(*3#$0 06 :;<-5 6/-90+#$%/* 82+*A90,5, 04#&+ ,52*?0# 6/-- 9#/01 2+#'#/0 /-E8>-/01 0 ,*)*8)#(7-/01, *)/-?* '*),#(7#/5 20/#- (#6028 6- 29#+ '*2+#'#//*A -3$*4#(-"00.

IE(-6#" :;<-5, '*$89#//5A , (-2+,*(# 0,5% ,*)/*3* (-2+,*(- Na-;:<, '(-?+09#2?0 /# '*),#(7#/ 20/#(#6028. =2+-/*,$#/*, 9+* J+- 202+#4- /# '*),#(7#/- 20/#(#6028 '(0 (-6E-,$#/00 :;<-5 )* ?*/"#/- +(-"00 0,00039%, 9+* *EK12/1#+21, ,0)04*, '(#)*+,(-.#/0#4 '(*"#22- -3$*4#(-"00 40?(*9-2+0" :;< 6- 29#+ *E(-6*,-/01 40"#$1(/*A *E*- $*9?0 ,*?(83 ?-7)*A 9-2+0"5 :;< 06 4-?(*4*$#?8$ Na-;:<, 2,16-/- /5> '*2(#)2+,*4 ,*)*(*)/5> 2,16#A 0 040+0(8&.0> ,6-04**++-$?0- ,-&.0# *+(0"-+#$%/5# 6-(1)5.

@-?04 *E(-6*4, /-A)#/5 82$*,01 ,*64*7/*2+0 '*$89#/01 40?(*- 9-2+0" 2 /-/*(-64#(/*2+%&, 2'*2*E/5# , ,*)/*A 2(#)# *E(-6*,5,-+% 82+*A90,5# 30)(*3#$0, ?*+*(5# /# '*),#(7#/5 20/#(#6028 '(0 6/-90- +#$%/5> 0> (-6E-,$#/01>.

L*$89#//5# 30)(*3#$0 '(#)2+-,$1&+ 0/+#(#2 )$1 2*6)-/01 /*,5> M*(4 E0*$*309#2?0 -?+0,/5> '*$04#(/5> 202+#4 2 (#38$0(8#454 ,5- )#$#/0#4 -?+0,/*3* /-9-$-.

@-E$0"- 2. N64#/#/0# 4*$#?8$1(/5> '-(-4#+(*, (-2+,*(*, Na-;:< '(0 '*2$#)*,-+#$%/*A !BC 0 =D *E(-E*+?# :;<

21

!"#$%#& '#(#)&*+,- # (&'.%#)&*+,- /&0#%1&23.4## %. *!,-*1!. 4&""5",06

..2. 07879:;, (.!. 37<=>?@, ..%. A9=B:;,

1.%. "CDC<C;7, *.(. A9=B:;7

!"#$%$&$ '%(%% )*#$+,),+ -./, &0. .1*23(%43#1*5, 1,

!+*",+,, 153045 (-,##%5) E-mail: anp@isc-ras.ru

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

B C)*5 6&%:7 *1+&4&%&'" )&1%*)" $20(3*4&5-)$(# $*4", DAB> ( 9('0+'"/ +0-)$*+()&%&5 ($*40–C)0'*%, $*40–DAB>) - *9+02603( 4+&- $&-'*5 1*+*E.*$*5 6&%%7%*2", 1*%;,&''"3( 1;)&3 /(3(,&-.*5 ( 3&- /0'(,&-.*5 4&2(')&=+06(( 1+( 298 F. G0--,()0'" )&1%*$"& C??&.)" -*%:$0)06(*''"/ $20(3*4&5-)$(5 6&%%7%*2" - ('4($(4;0%:'"3( ( -3&E0''"3( +0-)$*+()&%#3(. @*.020'* $%(#'(& -)+;.);+'"/ *-*9&'- '*-)&5 *9+026*$ 6&%%7%*2" ( -)+;.);+'"/ *-*9&''*-)&5 -3&E0''"/ +0-)$*+()&%&5 '0 )&+3*4('03(,&-.(& /0+0.)&+(-)(.( $20(3*4&5-)$(# 6&%%7%*2" - '(2.*3*%&.;%#+'"3( 8(4.*-)#3(.

H-)0'*$%&'*, ,)* 20$(-(3*-)( !H-3. = f(XC)0'*%) '*-#) S-*9+02'"5 $(4, )(1(,'"5 4%# 4+;=(/ $"-*.*3*%&.;%#+'"/ -*&4('&'(5 (.+0/30%0,

8&%0)('0 ( 4+.). @+( C)*3 '0 )&1%*$"& C??&.)" $ -%;,0& 3(.+*.+(- -)0%%(,&-.*5 6&%%7%*2" (AFI) 30%* $%(#&) -*4&+80'(& C)0'*%0 $ -3&E0''*3 +0-)$*+()&%&. >9+0J0&) '0 -&9# $'(30'(& )*) ?0.), ,)* 20$(-(3*-): )&1%*$*=* C??&.)0 $20(3*4&5-)$(# *) -*-)0$0 -3&E0''*=* +0-)$*+()&%# 4%# *9+026*$ 6&%%7%*2", 4&2(')&=+(+*$0''*5 '0 C.-)+;-

22

!"#", $%&"" '()%*"#+,-./, -"+ !&0 123 4#, 5%!"#6/.,, 54,#*/ %* 0 !% 0,7 +.!. 7 %$&/5*, +%&8.9: !%&"; 54,#*/ $%&8<" -"+ 0,7, %./ +"."" '()%*"#+,-./.

=%(/)/.%, -*% )/>,5,+%5*8 *"4&%>%?% '@@"(*/ >)/,+%!";5*>,0 123 5% 5+"58A >%!/–B1CD %* 5%5*/>/ $&,)(/ ( &,.";.%;. 7 5&E-/" '(5*#E!"#.%; F"&&A&%)9 '*/ )/>,5,+%5*8 .%5,* '(5*#"+/&8.9; :/#/(- *"# 5 +,.,+E+%+ '()%*"#+,-.%5*, > %$&/5*, 5%!"#6/.,0 B1CD %* 0,2

!% 0,4 +.!.

G/55-,*/.9 *"4&%*9 5%&8>/*/F,%..9: >)/,+%!";5*>,; %$#/)F%> F"&&A&%)9 5 >%!%;. H%&8</0 5%&8>/*,#EAI/0 54%5%$.%5*8 >%!9 ( 123 4% 5#/>.".,A 5 F"&&A&%)%;, !"),.*"?#,#%>/..%; ./ '(5*#E!"#", %$E5&%>&"./ !"@"(*.%5*8A (#,5*/&&,*%> F"&&A&%)9, > #")E&8*/*" -"?% E>"&,-,>/A*50 )/*#/*9 '."#?,, ./ ./$E:/.," (#/)#9> ,&, %5&/$&".," +"6+%&"(E&0#.9: 5>0)"; +/(#%+%&"(E& F"&&A&%)9).

J5*/.%>&".%, -*% E>"&,-".," +,(#%4%#,5*%5*, +,(#%(#,5*/&&,- -"5(%; F"&&A&%)9 , "" >95%(/0 #"/(F,%../0 54%5%$.%5*8 5>0)/.9 5 #%5*%+ -,5&/ !"@"(*.9: (#,5*/&&,-"5(,: %$#/)%>/.,; , >%)#/5*/.,"+ >.E*#".."; 4%>"#:.%5*, 4%&,+"#/. B&0 %F".(, >.E*#".."; 4%>"#:.%- 5*, ,55&"!E"+9: %$#/)F%> F"&&A&%)9 ./+, $9&, 4%&E-".9 ,)%*"#+9 /!5%#$F,, (#/5,*"&0 (%.?% (#/5.%?% ./ F"&&A&%)" ,5:%!.%; , +,(#%- (#,5*/&&,-"5(%;, / */(6" ./ F"&&A&%)", !"),.*"?#,#%>/..%; ./ E!/#-

.%-%*#/6/*"&8.%; +":/.,-"5(%; E5*/.%>(" , '(5*#E!"#". K)%*"#+9 /!5%#$F,, $9&, %4,5/.9 E#/>.".,"+ *"%#,, %$L"+.%?% )/4%&.".,0 +,(#%4%#, (%*%#%" 5>0)9>/"* )./-".,0 #/>.%>"5.%; 5%#$F,, , 4/#/- +"*# n, :/#/(*"#,)EAI,; +,(#%4%#,5*%5*8 5%#$".*/ (E#/>.".," BE$,-

.,./-M5*/:%>/):

lnCF = lnC! – (RT/E)n (lnCs/Cp)n,

?!" N – :/#/(*"#,5*,-"5(/0 '."#?,0 /!5%#$F,,; Cs – #/5*>%#,+%5*8 (#/5,- *"&0; Cp , CF – #/>.%>"5.9" (%.F".*#/F,, (#/5,*"&0 > %$L"+.%; , /!5%#$- F,%..%; @/)/: 5%%*>"*5*>"..%; C! – 4#"!"&8./0 (%.F".*#/F,0 (#/5,*"&0 > /!5%#$F,%..%; @/)"; n – F"&%" -,5&%, 4#",+EI"5*>"..% 1, 2 , 3.

J5*/.%>&".%, -*% 4%(/)/*"&8 5*"4"., n #/>". 1 4#, /!5%#$F,, (#/5,*"&0 ./ ,5:%!.%; , !"),.*"?#,#%>/..%; ./ E!/#.%-%*#/6/*"&8.%; E5*/.%>(" F"&&A&%)". =#, '*%+ ./$&A!/"*50 .")./-,*"&8.%" E>"&,-"-

.," 4#"!"&8.%; 5%#$F,, (#/5,*"&0 C! 5 0,023±0,001 !% 0, 026±0,001 +%&8/(? F"&&A&%)9 , :/#/(*"#,5*,-"5(%; '."#?,, /!5%#$F,, 5 4,0±0,2

23

!" 4,4±0,2 #$%/&"'(. )*+ ,-*-."!- # ,"*"/#"0"1 2-''3'"4-, !-4+5- 6-7*+*"0855"1 58 9#:6*;!-*- + .+&+<-:#+& :,":"="& (>?@), ,"#848- 6-'( :6-,-5+ n 0"4*8:68-6 !" 2, 8 0-'+<+58 A !" 10,9±0,5 + 10,3±0,5

#$%/&"'( :""60-6:60-55". )":#"'(#; n .8*8#6-*+4;-6 &+#*","*+:6;3 :6*;#6;*; 8!:"*=-568, 6", "<-0+!5", <6" ,*"2-:: ,"';<-5+B ,"*"/#"- 0"1 2-''3'"4C (9#:6*;!-*) + >?@ :,":"=:60;-6 *840+6+3 &+#*","- *+:6":6+ 2-''3'"4C + ;0-'+<-5+3 -- 05;6*-55-1 ,"0-*.5":6+.

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

F-8#2+"558B :,":"=5":6( # 0+:#"4""=*84"085+3 ",*-!-'B'8:( &-- 6"!"& 9&;'(:+"55"7" #:856"7-5+*"085+B 2-''3'"4C *84'+<5C& #"'+- <-:60"& :-*";7'-*"!8 (GGS2) ,*+ ",*-!-'-55"& :"!-*%85++ 7+!*"#:+!8 586*+B (GNaHI). J-& 0C/- *-8#2+"558B :,":"=5":6( 2-''3'"4C, 6-& &-5(/- :-*";7'-*"!8 6*-=;-6:B !'B ,"';<-5+B D+'(6*;3K-1:B 0+:#"- 4C. E 6" %- 0*-&B 0+:#"48 :<+68-6:B D+'(6*;3K-1:B, -:'+ 48&-!'-5+- D+'(6*82++ 5- ,*-0C/8-6 250 : (LHGM 9003-75). E #8<-:60- ,"#8486-'B *-8#2+"55"1 :,":"=5":6+ +:,"'(4"08'":( "65"/-5+- GGS2/GNaHI + 0*-- &B D+'(6*82++ 0+:#"4C 0 :-#;5!8.. NC'" ;:685"0'-5", <6" *-8#2+"5- 58B :,":"=5":6( # 0+:#"4""=*84"085+3 9#:6*;!-*5"1 + >?@ 2-''3'"- 4C 458<+6-'(5" 0C/-, <-& 2-''3'"4C, !-4+56-7*+*"0855"1 58 ;!8*5"- "6*8%86-'(5"1 ;:685"0#- + +:."!5"1 '+:6"0"1 40/11 – 26!, 40/11 – 3!, 80/11 – 198! + 90/11 – 201!:""60-6:60-55".

24

!"#$%#& '()')*+ ,&-#%.&/0+1## 1&""2")-3 %+ && '.045.40%)-')0*1#)%%3& '!)6'.!+

# 0&+51#)%%42 '()')*%)'.7

+./. -898:;<, =.#. !;:;>;<8, +.%. (:?@;<, ).!. '?:;<

!"#$%$&$ '%(%% )*#$+,),+ -./, &0. .1*23(%43#1*5,1,

!+*",+,, 153000 (-,##%5) E-mail: miv@isc-ras.ru

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

D5(',#5$+(.81& ,",(9(110) , *+(2.411&% 2&1+()1(5( :5(:#5#+ -(../.&"0 :&%(@#.*4 , ?==3"$&113/ 4<()23, 2&+&5#4 :5('3*%#+5$,#-

.# 1#.$<$( 3*+5&)*+,#, :&",&.4/@(B& "#250,#+8 ?==3"$&11&( &+,(5- *+$( 1# :(5$&' ,0;&'# 1# "#'#110) 5(6$% $"%(5(1$). E==3"$&11#4 4<()2#, ,0:&.1(11#4 $" 1(56#,(/@() *+#.$ $ *1#76(11#4 #./%$1$(- ,&) %(%75#1&), $%(.# '$#%(+5 ?==3"$&11&B& &+,(5*+$4 5,2 %2%, ,13+- 5(11$) &7F(%, 3,5 *%3. G*;&'1#4 %#**# "#B536#(%&B& , 4<()23 &75#"-# *&*+#,.4.# 0,1–0,13 B.

H#5#2+(5$*+$2$ +5(; $**.('&,#110; 1#%$ &75#"-&, -(../.&"0 :5('*+#,.(10 , +#7.$-(. I(../.&"3, :&.3<(113/ %(+&'&% ;$%$<(*2&) '("$1+(B5#-$$, , '#.81()9(% 73'(% 1#"0,#+8 %$25&25$*+#..$<(*2&) (AJI). K+(:(18 :&.$%(5$"#-$$ (KD) &:5('(.4.$ ,$*2&"$%(+5$<(*2$ :& ,4"2&*+$ 5#*+,&5# -(../.&"0 , 2#'&2*(1(, 5(1+B(1&*+532+3510)

25

!"!#$% &'()(*$#$ "! *$+'!,-(./-'/ 0123-3, &'$./"44 5u67, .("(- 8'(.!-$%$'()!""(/ *)(9":. +$#;-'(. 1(<<!. =6-<&/,-': <"$.!#$ "! <&/,-'(+(-(./-'/ Avatar 360FT-IR ESP ) (>#!<-$ ?!<-(- 4000–400 <.-1. @(-(A'!+$$, <"4-:/ "! B#/,-'(""(. .$,'(<,(&/ < C)/#$?/"$/. !5000 &(,!%!#$, ?-( $% -'/8 */%$"-/A'$'()!"":8 D/##E#(% )(#(,"$<-!4 <-'C,-C'! <(8'!"4/-<4 -(#;,( *#4 <C#;+$-"(9 D/##E#(%:, */%$"-/A'$- '()!""(9 "! C*!'"(-(-'!F!-/#;"(9 ./8!"$?/<,(9 C<-!"(),/. G/8!"$- ?/<,(/ )(%*/9<-)$/ "! #$<-()CE D/##E#(%C ) B,<-'C*/'/ (*!)#/"$/ <F!-$4 $ <*)$A():/ C<$#$4) &'$)(*$- , C(-"/"$E D/##E#(%"(A(

.!-/'$!#!, */<-'C,D$$ D/##E#(%":8 )(#(,(", <(&'()(F*!EH/.C<4 <"$F/"$/. 5I, ! -!,F/ &(#"(.C '!%'CJ/"$E )(#(,"$<-(9 <-'C,-C':. G6K, &(#C?/""!4 ,$<#(-":. A$*'(#$%(., &'/*<-!)#4/- <(>(9 ,'$- <-!##$?/<,$9 &('(J(,. 1/!,D$(""!4 <&(<(>"(<-; , )$<,(%((>'!%()!- "$E (&'/*/#4#!<; ./-(*(. B.C#;<$(""(A( ,<!"-(A/"$'()!"$4 D/##E- #(%: '!%#$?":. ,(#$?/<-)(. </'(CA#/'(*! (55S2) &'$ (&'/*/#/""(.

<(*/'F!"$$ A$*'(,<$*! "!-'$4 (5Na23). L$<,(%! <?$-!/-<4 +$#;-'CE- H/9<4, /<#$ %!./*#/"$/ +$#;-'!D$$ "/ &'/):J!/- 250 < (M25N 9003-

75). L ,!?/<-)/ &(,!%!-/#4 '/!,D$(""(9 <&(<(>"(<-$ $<&(#;%()!#(<; (-"(J/"$/ 55S2/5Na23 $ )'/.4 +$#;-'!D$$ )$<,(%: ) </,C"*!8.

O!'!,-/'$<-$,$ (>'!%D() D/##E#(%:, */%$"-/A'$'()!""(9 '!#$?":.$ <&(<(>!.$

26

!""#$%&''() )*+&,&) '-)% .&/#0*'( %$&+*1)( ,*2&134%% 5&,(

.1% +*).*1-+#1-6 298–308 7 2 +1*6 ,*$%'+*81%1&5-''(6 1-$/%0'()% 2.&2&3-)% 4*//9/&$, 5(,*1:-''(6 5 .-1-6 5&,( ,& 1-5'&5*2'&; 5/-:'&2+% % '-3#6<%6 5 =&'+-=+* 2 :%,=&; 5&,&; (1%2. 1). >&/#0*''(* +*).*1-+#1'(* $-5%2%)&2+% -..1&=2%)%1&5-/%2? #1-5'*'%*) 7/-.*;- 1&'--7/-#$%#2- 5%,-:

ln(P) = – a/t + b,

8,* a = !H"T/R, - b = !S"T/R.

@- 2+-',-1+'&* 2&2+&A'%* 5(31-'& .-14%-/?'&* ,-5/*'%* '-2(- B*''&8& .-1- 5&,( .1% +*).*1-+#1* C. D<%3=- .1% &.1*,*/*'%% ,-5- /*'%A .& .&+&=# 8-$- %$ E""#$%&''&; =-)*1( 2&2+-5/A*+ 2–3%. >&/#- 0*''(* +*1)&,%'-)%0*2=%* 6-1-=+*1%2+%=% ,*2&134%% 5&,( .1*,2+-5- /*'( '- 1%2#'=* 2.

7-= 5%,'& %$ 1%2#'=&5, 1-$/%0'(* 2.&2&3( ,*$%'+*81-4%% %26&,- '&; /%2+&5&; 2#/?"%+'&; 4*//9/&$( .1%5&,A+ = 2#B*2+5*''() 1-$/%- 0%A) 5 $'-0*'%A6 .1*,*/?'&; 2&134%% 5&,( (FG), 1-220%+-''&; .& #1-5'*'%9 H#3%'%'--I-,#<=*5%0-, &3B*8& =&/%0*2+5- 25A$-''&; 5&,( 5 4*//9/&$* (F) % E'+-/?.%% ,*2&134%% 5&,( 2 4*//9/&$( (JdesH).

F'-/%$ %$&+*1) % +*1)&,%'-)%0*2=%6 6-1-=+*1%2+%= ,*2&134%% 5&,( 2 +1*6 1-$/%0'() 2.&2&3&) ,*$%'+*81%1&5-''(6 4*//9/&$ .&=-- $(5-*+, 0+&:

–,/A 52*6 +1*6 %22/*,&5-''(6 4*//9/&$ .1*,*/?'-A 2&134%A &,%- '-=&5- ,/A &31-$4&5, 5(,*1:-''(6 5 .-1-6 5&,( ,& 1-5'&5*2'&; 5/-:- '&2+% % '-3#6<%6 5 =&'+-=+* 2 :%,=&; 5&,&;;

–5*/%0%'- .1*,*/?'&; 2&134%% 5&,( ,/A +1*6 %22/*,&5-''(6 4*//9/&$ #5*/%0%5-*+2A 2 #5*/%0*'%*) K7, 0+& .1&+%5&1*0%+ &3B*-

.1%'A+&)# .1*,2+-5/*'%9 & +&), 0+& =&/%0*2+5& 25A$-''&; 5&,( &.1*- ,*/A*+2A ,&/*; -)&1"'&; 0-2+%. D,'-=& E+& 5*1'& +&/?=& ,/A &31-$4&5,

.&,5*18'#+(6 &,'&+%.'() &31-3&+=-), L7M .1*,2+-5/A*+ 2&3&; %'&; +%. 2&13*'+-, .& 21-5'*'%9 2 .&1&<=&5&; 4*//9/&$&; (E=2+1#,*1'&;

%#,-1'&-,%2=&5&;). >1&%26&,%+ $-.&/'*'%* 2&13%1#*)()% )&/*=#/-- )% (5 '-<*) 2/#0-* – )&/*=#/-)% 5&,() &3N*)- -,2&13%1#9B%6 .&1 (,*"*=+( =1%2+-//%0*2=&; 2+1#=+#1( 4*//9/&$() 5 2&&+5*+2+5%% 2

.&/A)% -,2&134%&''(6 2%/ 5 '%6, - '* 5$-%)&,*;2+5%* )&/*=#/ 5&,( 2 -=+%5'()% 4*'+1-)%, +.*. 8%,1&=2%/?'()% 81#..-)% 4*//9/&$(;

27

–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

B(,*% #$2(/#%, !"#!#$)#!08 !#2$*2#5(08 5#.4 .79 02&' *!!7&.#- 5())<' 3&77;7#/ )& ,#22&7*24&0 ! >?, >F, 2(/%&2(%* ,2*!0(77*0#5, 5 0# 6& 52&%9 /(5*!*0 #0 !"#!#$( .&/*)0&12*2#5()*9. I0# #"2&.&79&0!9 '(2(,0&2#% "&2&!02#-,* 5#.#2#.)<' !59/&- 5 3&77;7#/& "2* 2(/7*+- )<' %&'()*+&!,*' 5#/.&-!05*9'. ?2* :0#% 2&(,3*#))(9 !"#!#$)#!08 3&77;7#/< ()("2*%&2, 5 2&(,3** 5*!,#/#$2(/#5()*9) ,#22&7*24&0 ! 5&7*+*)#- "2&.&78)#- (.!#2$3**, ( )& ! #$=*% ,#7*+&!05#% 4.&26*- 5(&%#- 5#.<.

29