3451
.pdfforming process for cement-based materials // Advances in Cement Research/
2009. V. 21. № 3. P. 125-133.
5. PОЫЫШЭ A., MцХТЧРО В., RКЧРОКЫН D. ОЭ КХ. UЬО ШП ЫКЦ ОбЭЫЮНОЫ КЬ К МШm-
bined rheo-tribometer to study the behaviour of high yield stress fluids at low
strain rate // Rheologica Acta, Springer VerlКР. 2012. V. 51. № 8. P. 743-754.
6. PОЫЫШЭ A., RКЧРОКЫН D., MцХТЧРО В. ОЭ КХ.. EбЭЫЮЬТШЧ МЫТЭОЫТШЧ ПШЫ ПТЫЦ cement based materials // Applied Rheology. 2009. V.19.
7.Slavcheva G. S., Babenko D S., Shvedova M. A. [Analiz i kriterial'naya ocenka reologicheskogo povedeniya smesej dlya stroitel'noj 3D pechati] Stroitel'nye materialy [Building materials]. 2018. V. 12. P. 34-40. (in Russian).
8.Ur'ev N.B. [Fiziko-himicheskaya dinamika strukturirovannyh nanodispersnyh sistem i nanodispersnyh kompozicionnyh materialov. Ch. 1] Fizikohimiya poverhnosti i zashchita materialov [Physical chemistry of surfaces and protection of materials]. 2010. V. 46. No 1. P. 3-23. (in Russian).
9.Rebinder P.A. Poverhnostnye yavleniya v dispersnyh sistemah. Fizikohimicheskaya mekhanika. Izbrannye Trudy [Surface phenomena in dispersed systems. Physico-chemical mechanics. Selected works]. Moscow: Nauka, 1979. 384 p. (in Russian).
10.Kruglickij N.N. Ocherki po fiziko-himicheskoj mekhanike [Essays on physical and chemical mechanics]. Kiev: Naukova dumka, 1988. 224 p. (in Russian).
11.Ratinov V.B., Rozenberg T.I. Dobavki v beton [Additives in concrete]. Moscow, Strojizdat, 1989. 188 p. (in Russian).
12.Shabanova N.A., Popov V.V., Sarkisov P.D. Himiya i tekhnologiya
nanodispersnyh oksidov [Chemistry and technology of nanodispersed oxides].
MШЬМШа, «AФКНОЦФЧТРК», 2006. 309 Щ. (in Russian).
13. Greenwood N.N., Earnshaw A. Chemestry of the Elements. V. 1. (Rus. Ed.: Grinvud N.N., Ehrshno A. Himiya ehlementov. T.1. Moscow: Binom. 2008. 607 p.)
40
, |
№ 1 (20), 2019 |
– |
- |
. |
, |
|
|
, |
|
|
|
|
- |
– |
. |
. |
, |
|
- |
|
– |
|
|
|
|
|
– |
2- |
, |
. |
052, |
|
7.10781.2018/11.12 |
|
|
« |
, |
- |
|
|
». |
- |
|
|
- |
||
. |
. . . |
||
|
41
666.3.032
,
. . |
|
*, . . |
, . . |
|
|
|
|
|
|
, |
|
|
|
, 394006, . |
, . 20- |
, 84 |
|
* |
|
: |
, E-mail: alla.purik@mail.ru |
|
|
|
|
|
|
- |
- |
, |
|
, |
|
. |
- |
|
|
, |
|
|
- |
, |
|
|
|
|
. |
, |
|
|
, |
|
- |
|
|
- |
|
. |
|
|
|
|
|
. |
|
|
|
|
|
|
- |
|
|
, |
. |
|
|
|
|
: |
, |
|
|
, |
, |
, |
|
|
|
ANALYSIS OF FACTORS INFLUENCING STRUCTURE FORMATION
AND RAW SHARD OF CERAMIC BRICKS
A.V. Khorina*, T.I. Shelkovnikova, E.V. Baranov
Voronezh State Technical University, Russian Federation
394006, Voronezh, ul. 20th Anniversary of October, 84
*Address for correspondence: Khorina Alla Vladimirovna, E-mail: alla.purik@mail.ru
© |
. ., |
. ., |
. ., 2019 |
42
, |
№ 1 (20), 2019 |
The article describes the structure of ceramic materials at the macro and micro levels, identifies factors and parameters that influence the formation of the shard. A scheme for the formation of ceramic minerals, depending on the type of clay. The chemical and mineralogical composition of clays, as well as their ratio, influence the course of phase transformations, the nature of the crystalline phases and the structure of the ceramic shard. It is established that the nature of phase transformations, the order of phase formation affect the physicomechanical properties of ceramic products. The methods for obtaining high-quality ceramic bricks with a uniform arrangement of the crystalline, vitreous and gas phases are indicating.
Keywords: structure of ceramic materials, structure of a ceramic shard, macro level, micro level, mechanical strength
. |
|
, |
|
|
- |
. |
|
- |
, |
, |
- |
|
|
. |
|
, |
|
|
– |
- |
- |
- |
[1]. |
|
|
|
|
|
, |
|
|
- |
|
Д2Ж. |
|
|
. 1: |
|
|
|
|
- |
|
, |
|
|
|
- |
( |
|
|
), |
|
- |
. |
|
|
|
|
. 1. |
Д3Ж |
43
|
|
|
|
|
, |
|
|
|
|
, |
|
, |
|
|
|
|
|
|
|
[1]. |
- |
|
, |
|
|
|
|
|
|
|
. |
- |
, |
|
|
|
|
|
|
|
|
|
- |
|
|
|
, |
|
, |
|
|
. |
|
- |
|
|
|
|
|
|
|
|
, |
|
|
|
|
|
|
|
, |
|
|
. |
|
, |
|
, |
|
|
|
|
|
|
|
|
- |
|
|
|
Д4Ж. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
- |
|
|
|
|
|
, |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
. |
|
|
|
( . . |
, . . |
|
, . . |
|
.) |
- |
|
|
( . . |
|
, |
. . |
, |
. . |
|
|
, . . |
- |
, |
. . |
|
, |
. . |
, |
. . |
|
, |
. . |
, |
. . |
, |
. . |
|
, |
. . |
, |
. . |
, |
. . |
, |
. . |
, . . |
, . . |
|
.) |
|
. |
|
|
||
|
|
|
|
|
|
|
|
, |
|
- |
|
|
|
|
|
|
|
|
25 |
. |
|
|
|
|
|
, |
|
, |
|
|
, |
|
|
|
|
|
|
, |
|
|
, |
|
|
|
[1, 4]. |
|
|
, |
|
|
|
|
|
- |
|
|
|
, |
|
|
. 1. |
|
|
|
|
|
|
, |
|
|
|
|
|
|
|
1 |
|
|
|
|
|
|
|
|
|
|
,
44
, |
№ 1 (20), 2019 |
-
-
. |
- |
( . 2).
2
|
|
|
1 |
25 - 40 |
|
|
|
|
2 |
70 |
- 400 |
|
|
|
3 |
500 |
- 1000 |
|
|
|
|
|
, |
|
- |
|
|
. |
|
- |
|
|
, |
|
- |
|
|
. |
|
|
|
|
, |
|
|
|
|
. |
|
- |
|
, |
, |
|
|
|
|
. |
|
|
|
|
( |
, |
- |
, |
, |
, |
|
- |
) |
|
|
Д2, 4, 5Ж. |
|
|
|
, |
|
- |
|
|
|
. |
- |
, |
|
, |
|
- |
|
|
. |
|
|
|
, |
|
|
, |
|
|
( |
. 2). |
|
|
|
|
( |
|
, |
, |
. .) |
|
- |
45
|
, |
, |
|
Д5Ж. |
- |
|
, |
|
|
, |
|
R2O. |
1100-1200 |
. |
. 2.
46
, |
№ 1 (20), 2019 |
|
|
|
SiO2c /Ʃ |
( |
Ʃ – |
|
|
- |
|
|
|
, %) |
|
|
|
|
- |
|
|
|
. |
|
|
1050-1250 |
|
|
|
|
, |
|
1250 |
|
|
|
- |
|
|
|
|
|
. |
|
|
- |
|
|
|
|
|
|
|
|
- |
|
. |
|
|
|
|
SТ 2 |
12 |
3 |
|
|
|
. |
|
|
|
|
- |
|
|
|
|
|
|
|
, |
- |
|
|
|
1300° |
|
|
|
1,9- |
|
2,0 / |
3 [5]. |
|
|
|
|
|
|
|
|
|
- |
|
|
|
, |
|
- |
|
|
|
, |
|
|
|
|
|
|
. |
1300° |
|
|
|
|
|
- |
|
|
|
, |
|
|
|
|
- |
( |
|
|
), |
|
|
|
|
- |
|
|
. |
|
|
|
|
|
|
|
|
|
|
|
|
. |
|
|
|
|
|
- |
|
|
|
|
|
|
1200-1250° |
|
|
|
|
. |
|
|
|
|
- |
|
|
|
|
|
- |
( |
20 %) |
|
Al2O3 |
|
|
|
|
- |
|
. |
|
|
|
|
1050-1100 |
|
- |
|
|
|
. |
|
|
, . . |
|
|
|
|
|
|
|
|
|
|
- |
|
. |
|
|
. |
|
|
|
|
|
, |
|
, |
|
|
, |
|
- |
|
|
|
. |
|
, |
|
|
- |
|
|
|
|
, |
|
. 3. |
|
|
47
3
,
|
|
|
|
|
|
|
, |
, |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
: |
- |
|
; |
|
|
- |
|
; |
( |
) |
- |
|
; |
|
|
|
|
; |
|
. |
|
|
: |
|
|
|
- |
( |
|
|
, |
|
, |
. .); |
|
|
- |
( |
|
) |
- |
|
|
|
; |
- |
|
; |
|
|
|
- |
|
|
|
- |
|
|
|
|
- |
|
|
|
|
- |
|
, |
|
|
- |
|
|
; |
|
|
- |
|
, |
|
- |
|
|
|
Д6Ж; |
|
- |
|
|
|
|
48
, |
№ 1 (20), 2019 |
|
|
|
|
|
- |
|
; |
. |
|
|
|
|
|
|
|
|
- |
. |
|
, |
, |
, |
- |
|
, |
|
|
|
- |
|
|
|
, |
|
|
|
|
. |
|
|
- |
, |
, |
|
|
|
|
|
, |
|
|
|
- |
|
|
[1, 2, 5]. |
|
|
|
|
|
|
|
|
- |
|
, |
, |
, |
|
|
|
, |
. |
|
|
- |
|
|
, |
|
|
- |
|
, |
|
. |
|
- |
|
|
, |
|
|
|
|
|
. |
|
|
- |
|
Д7Ж. |
|
|
|
|
|
. |
, |
|
- |
- |
|
|
|
|
|
- |
|
|
. |
|
|
- |
|
, |
|
|
|
- |
|
|
. |
|
|
- |
|
, |
, |
|
|
- |
|
|
|
|
, |
- |
|
|
, |
|
|
|
|
. |
|
|
|
|
49