- •It is recommended for publishing as a study aid by the Editorial Board of Tomsk Polytechnic University
- •Соntents
- •Introduction
- •1. History of knowledge development about biosphere chemical composition and scale of its transformations
- •Global emission of chemical elements (thous.T/year) (according to V.V. Yermakov, 2003)
- •2. Key approachers to classification of chemical elements
- •Fig. 1 Classification of elements in human organism in terms of abundance and use (Underwood e., 1962)
- •Vital elements in composition of organisms (according to а. Lenindger)
- •Content of some elements in plants, animal and human organisms, mg/kg
- •Concentration of cations in marine water and organisms liquids of some mammals and birds, mg/kg (Bgatov а.V., 1999, with recalculations of Ignatova т.N., 2009)
- •Biogenetic classification of elements
- •3. Factors and processes element composition formation of living matter
- •4. Regional aspects of biogeochemistry
- •4.1. Conditions of the Natural Environment Components According to Ecological-Geochemical Monitoring and Population Health Data (Tomsk Region)
- •Geochemical specific characteristics in districts of Tomsk region to maximum element concentration in pathologically changed thyroid glands (relative to regional monitoring)
- •Different diseases of separate thyroid gland pathology types in districts of Tomsk region per 1000 persons (during 5 years)
- •4.2. Element composition of human organs and tissues
- •Contemporary estimation of the environmental pathology (wt. %) and trace elements (mg/kg) in a human body (From Ulf Lindh, 2005 with changes)
- •Comparative estimation of element analysis results obtained by inaa method with published data of domestic and international standards
- •4.3. Biogeochemistry of uranium and thorium
- •Thorium content in the plants of the Large Vasyugan marsh, mg/kg (dm) (“Geochemistry…”, 2002)
- •4.4. Rare earth element in human organs and tissues
- •4.5. Element content in children hair samples
- •Comparative analysis of evaluation level of the chemical element concentration in human hair (mg/kg, dry weight)
- •Comparative data of children hair composition (mg/kg, dry weight) from different regions of Russia, Belorussia and Kazakhstan
- •Geochemical specification of population hair in Tomsk oblast and other regions (n – number of samples)
- •Conclusion
- •References
- •Geochemistry of living organisms
- •Published in author’s version
- •Printed in the tpu Publishing House in full accordance with the quality of the given make up page
Geochemical specific characteristics in districts of Tomsk region to maximum element concentration in pathologically changed thyroid glands (relative to regional monitoring)
District |
Geochemical specific characteristics |
Tomsk |
Br74-Fe4,5-U3,5-Hf2,8-Cr1,9-Rb1,9-Na1,8-Hg1,3-Sb1,3 |
Asinovsk |
Sb20- Fe3,4- Na2,7- Br1,9- Rb1,7- Hf1,7- Hg1,5- Cr1,3-Co1,2 |
Pervomaisk |
Fe2,4-Hf1,7- Rb1,5- Sb1,5- Hg1,4- Br1,3 - Cr1,3- Na1,2-Zn1,1 |
Zirjansk |
Br10- Fe8- Hg3- Zn1,6- Sb1,3- Co1,1-La1,1 |
Bakcharsk |
Cr4,8- Fe3,8- Na2,4- Rb1,4-Sc1,3-Sb1,3- Br1,3- |
Parabelsk |
Na2,9- Rb1,8-Au1,7- Br1,5- Hg1,5- Fe1,2 |
Kozhevnikovsk |
Sb24- Fe3,3-Hf2,2-Na1,8- Hg1,8-Rb1,8- Br1,7-Au1,4 |
Chainsk |
Br33- Na3- Fe1,8- Cr1,6- Hf1,5- Rb1,5- Co1,1 |
Molchanovsk |
Fe5- Hg3- Sb2,2- Na1,9- Cr1,9- Br1,7- Rb1,5- Co1,2- Au1,1 |
Kolpashevsk |
Br28- Fe6,2- Na6- Rb3,3- Sb2,1- Hf1,8- Hg1,7- Co1,2- Zn1,1 |
Aleksandrovsk |
Br116-Cr4,1-Na4-Rb4-Sb3,7-Fe3,6-Ce2-Hf1,6-Hg1,4-Co1,3-Zn1,1 |
Shegarsk |
Br269-Sb9- Fe5- Hg4- Na3,4- Cr3,4- Th3- Rb2,4- Hf2- Zn1,4 |
Kargasoksk |
Sb85- Fe5- Cr4,2-Rb1,8- Au1,7- Hf1,7- Br1,5- Sc1,3- Hg1,3 |
Krivosheinsk |
Th5,5-Na5-Rb4,7-Br2,7-Sb2,3-Fe2,1-Co2-Hg2-Au1,7-La1,3-Zn1,3 |
Verneketsk |
Cr6-Hg5-Fe4,7-Th3,2-Sb2,7-Br2,6-Na2,3-Rb1,4-La1,4-Zn1,3-Au1,2Co1,1 |
The calculation of the above-mentioned coefficient, which includes the sum of integrated factorial air pollution, drinking water and soil contaminant coefficients and, which are in its turn, are determined in accordance to methodic recommendations N 01-19/17-17 (1996), resulted in the division of districts into groups with different degrees of hygiene and sanitary welfare (Zinchenko, 1999).
One should take note of the fact that some districts are immediately near mega-enterprises which are located in proximity from Tomsk (such districts as Asinovsk, Teguldetsk, Tomsk, as well as, Pervomajsk and Zirjansk); Parabelsk, with its intensive oil and gas recovery and zones of falling detached missile parts.
Fig.10. Ranking districts in Tomsk region according to content of several micro-elements (mg\kg) and Th/U ratio in human thyroid glands
Fig. 11. Spatial value distribution of human thyroid gland concentration coefficients relative to regional norms in districts of Tomsk region
Fig.12. Schematic map of Tomsk region in accordance to integrated contaminant environment coefficient [Zinchenko (1999)]
According to the hygiene ranking of the territorial region to degree of sanitary-hygiene intensity conditions and based on methodic recommendations of State Committee in Sanitary- Epidemic Inspection (N 01-19/17-17, 1996), the following five district groups were highlighted (Fig. 13). The territories with maximum unfavorable environment are Tomsk, Asinovsk, Pervomajsk and administratative districts in Parabelsk (Zinchenko, 1999).
According to the following scientists N.V. Vasilev, A.P. Vorobjeva, I.I. Balashova and others, the existence of anomaly biochemical areas on the territories of Tomsk region is due to the development of specific diseases (for example, leucaemia and others).
Thus, research data in determining the characteristic distribution of nosologic forms of thyroid gland diseases [Baranovskaya et al (2006)] indicated the following fact that these diseases are located in highly unfavorable areas to ecological coefficients (Table 2). At the same time, their spatial localization distinctly indicates maximum ecological unfavorable zones, for example, north-southern part of Tomsk district (Fig.14). This can be also stated in reference to other disease types (Sukhikh, 2005; Rikhvanov et al., 2006).
In conclusion, all research data is considered to be evaluating and exceptional preliminary, as data number is insufficient to obtain more reliable coefficients, excluding only the data for Tomsk district (Rikhvanov et al., 2006). However, above-mentioned research results highlight the existing problem and indicate the necessity in integrated ecological-geochemical monitoring of Tomsk region environment, which in its turn, significantly influences the population welfare and health as observed in Tomsk district (Sukhikh, 2005; Rikhvanov et al., 2006) and other districts of Tomsk region (Zinchenko et al., 1999).
Fig.13. Distribution of districts in Tomsk region to degree of sanitary-hygiene intensity conditions [Zinchenko (1999)]
This information can be considered as the quantity evaluation basis for potential population health risk of Tomsk region to natural environment quality including numerous factors, termed as «quality». The next research stage is the risk identification (Scherbo, 2002).
Table 2
