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Книги2 / 1993 Dutton , Yu -Technology CAD_Computer Simulation

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Chapter 2

Introduction to SUPREM

2.1Introduction

While the exact form that VLSI technology would take in the future was uncertain in late 1970s, it seemed evident that costly and timeconsuming empirical approaches to developing and optimizing such technology are a luxury few will be able to afford or wish to justify. A far more attractive alternative is the formulation of accurate models of the basic physical processes involved, and their implementation in a comprehensive computer program. Such a program would allow predictions of device structures resulting from any proposed fabrication sequence and would minimize the need for empirical iterative attempts. Since its inception, the process simulator SUPREM has been one such attempt to realize this goal. Beginning with SUPREM I and proceeding to SUPREM II and III, each version has drawn from the models and physical understanding of fabrication processes then available.

The overall objective of SUPREM is to permit a technology designer to accurately simulate complete technology sequences. The program input is, in essence, a processing schedule specifying a sequence of times, temperatures, ambients, depositions, implants, and other necessary process specification inputs. The program output is available after each step in the sequence and includes one-dimensional impurity distributions in all layers including dielectrics and polysilicon. Also available are layer thicknesses, junction depths, and electrical data such as sheet resistance and threshold voltage.

To see how the SUPREM III program works, we will consider the

38 CHAPTER 2. INTRODUCTION TO SUPREM

c

I

 

~

 

MASK #1

 

Phosphorus III

 

SELECT N-WELL

t

 

~HH

 

LOCATIONS

 

L--___p___---'r~-:·

 

 

 

 

ION IMPLANT

 

 

t

 

 

+oxide

 

 

 

 

 

N-WELL

 

t growth

 

~------~h

 

DIFFUSION

 

 

 

P

well

 

,

 

' --_______-1 diffusion

MASK #2

STRIP & REGROW

 

 

 

OXIDE

 

SELECT FIELD

OXIDE REGIONS

NITRIDE DEPOSITION/ETCH

ION IMPLANT

t

LOCAL FIELD OXIDE

GROWTH

Figure 2.1: (a) Process flow for the n-well diffusion and local oxidation to create the isolation regions for an n-well CMOS process. Both schematic process description and representative technology crosssections are shown.

process sequence that creates the n-well in the Stanford CMOS technology. Figure 2.1 (a) illustrates the process flow. The wafer is oxidized and dopant atoms are ion implanted. A short well drive-in is carried out in an oxidizing ambient, and is then followed by a longer drive-in in an inert ambient. Next, a nitride layer is deposited and patterned for the local oxidation step used to isolate the devices. The p+ channel-stop diffusions are also patterned during this local oxidation sequence. (A third mask, not shown in Figure 2.1 (a), is used to exclude boron from the n-well regions.)

A sequence of steps used for the SUPREM III input is listed in Figure 2.1 (b). The first input commands give essential data concerning the starting material and grid structure needed to model the ensuing steps. The total window of interest is less than 51lm with a minimum grid spacing of 100 A; the starting substrate material is < 100 > silicon doped to 9 x 1014 cm-3 with boron. Subsequent input commands model

2.1. INTRODUCTION

39

title

Stanford CMOS: N-Well Region

 

comment

start

with <100> silicon, p doped to 20 ohm resistivity

 

initialize

<100>

silicon boron concentration=ge14

 

+thickness=7.0 spaces=150

comment

initial pad oxide

deposition

oxide thickness=0.04

comment

n-well

implant

grid

layer.l xdx=O.12 dx=O.OOS

implant

phosphorus dose=2.Se12 energy=lOO

print

layer

 

plot

chemical net plotdev=xterm

comment

n-well drive-in

diffusion

time=12 temperature=800 t.rate=16.67

diffusion

time=lS temperature=lOOO

diffusion

time=lO temperature=lOOO dryo2

diffusion

time=30 temperature=lOOO weto2

diffusion

time=9

temperature=lOOO t.rate=16.67

diffusion

time=960 temperature=11S0

diffusion

time=60 temperature=llSO t.rate=-S.O

print

layer

 

plot

chemical net

comment

oxide

etch

etch

oxide

 

comment

field

oxidation

diffusion

time=12 temperature=800 t.rate=16.67

diffusion

time=18 temperature=lOOO

diffusion

time=lO temperature=lOOO dryo2

diffusion

time=190 temperature=lOOO weto2

diffusion

time=lO temperature=lOOO dryo2

diffusion

time=40 temperature=llSO t.rate=-S.O

print

layer

 

plot

chemical net

stop

Figure 2.1: (b) Typical SUPREM input statements are shown for the sequence up to MASK # 2 shown in Figure 2.1 (a).

40

CHAPTER 2. INTRODUCTION TO SUPREM

••..

011

!; c

~II

o u

c....

.3

011

!;

~IIC .

~ J.r--_

""

.3

'123'4517

Ol.lane. 'roltl aur'Qc. '''Ilcron.)

11234511

DlaLance '1"'0111 .urfac. (nuerona)

Figure 2.1: (c) Semi-logarithmic plots of the net doping profile (both phosphorus and boron) after the three steps listed in Figure 2.1 (b) implantation, drive-in, and field oxidation.

2.1. INTRODUCTION

 

 

41

MASK #1

G

 

Sb III

SELECT BURIED

 

 

 

 

LAYER

 

 

 

 

LOCATIONS

ION IMPLANT

 

 

 

 

 

~

 

 

 

BURIED LAYER

 

 

 

 

DIFFUSION

 

 

 

 

 

~

 

new oxide

 

EPITAXIAL LAYER

 

epitaxial silicon

 

 

GROWTH

- (

 

 

OXIDATION

n+

 

 

 

p

MASK #2

 

 

 

 

 

 

 

ISOLATION STEP

 

 

 

 

(JUNCTION OR

 

 

 

 

LOCAL OXIDATION)

 

 

 

Figure 2.2: (a) Process flow for a portion of an epitaxial buried layer bipolar process sequence. Both schematic process description and technology cross-sections are shown.

the sequence of steps as discussed above and shown in Figure 2.1 (a), and the remaining commands relate to the display of results. Note that some layers are grown/deposited, then etched away. Figure 2.1

(c) shows the cross-section of the n-well diffusion after the three steps listed in Figure 2.1 (b). Some of the details shown in Figure 2.1 (b) are representative of the real process but non-essential for simulation. In particular, the temperature ramping (t.rate) steps reflect actual furnace conditions but, for long drive-in conditions such as the n-well, are not essential.

Figures 2.2 detail another useful example - the process flow for a standard double-diffused bipolar technology. Figure 2.2 (a) shows the process flow in schematic form. Note that the surface becomes terraced following the various masking and oxidation steps. Figure 2.2 (b) shows the process flow in terms of the input file for SUPREM simulation. In

42

CHAPTER 2. INTRODUCTION TO SUPREM

title

Bipolar transistor buried/epitaxy layers

comment

initialize the silicon substrate

initialize

<100> silicon boron concentration=5e14

+thickness=5.0 dx=O.Ol xdx=0.05 spaces=100

comment

grow masking oxide for non-active regions

diffusion

temperature=1150 time=100 weto2

comment

etch the oxide over the buried layer (pattern n-)

etch

oxide

comment

implant and drive-in the antimony buried layer

implant

antimony dose=5e14 energy=120

plot

net chemical xmax=5

diffusion

temperature=1150 time=15 dryo2

diffusion

temperature=1150 time=300

print

layer

plot

net chemical xmax-5

comment

etch off the oxide

etch

oxide

comment

grow 1.6 micron of arsenic doped epi-layer

epitaxy

temperature=1050 time=4 growth.rate=0.4

+arsenic gas.conc=5e15

comment

grow a 400A pad oxide

diffusion

temperature=1060 time=20 dryo2

plot

net chemical xmax=5

comment

deposit nitride to mask the field oxidation

deposit

nitride thickness=0.08

comment

plot the chemical impurity distributions at this point

print

layer

plot

chemical boron xmax=5 clear ~axis linetype=2

plot

chemical arsenic xmax=5 ~clear ~axis linetype=4

plot

chemical antimony xmax=5 ~clear ~axis linetype=5

plot

chemical net xmax=5 ~clear axis linetype=l

stop

 

Figure 2.2: (b) Typical SUPREM input statements for the bipolar buried-layer/epitaxy sequence shown in Figure 2.2 (a).

2.2. ION IMPLANTATION

43

this example, a buried layer of dopant is introduced before the growth of an epitaxial layer. After the epitaxial growth, the structure contains a highly doped n+ layer buried below the n-epitaxiallayer. Figure 2.2 (c) shows the output results for the SUPREM input given in Figure 2.2 (b). The n- region results in a low collector capacitance, while the n+ region provides a low-resistance path to the external collector contact. Following the epitaxial layer growth, sequential masking steps are used to create the base and emitter regions.

Figures 2.3 shows the structure and profiles obtained from the sequence of diffusions following epitaxial growth as detailed above. Figure 2.3 (b) profiles the extrinsic base region, without emitter diffusion, while Figure 2.3 (c) shows the cross-section including the emitter. The high-concentration phosphorus present in the emitter enhances the diffusion of boron in the underlying base region. The net result is that the intrinsic base is "pushed out" beyond its depth in the extrinsic base region.

Base push-out is just one example of the situation in which boundary conditions can dramatically alter dopant diffusion. The enhanced diffusion of dopants under oxidation is another such effect. These effects, and others, are built-in features of the process models. The remainder of this chapter will consider these models in greater detail and will discuss the users' means to the controlling of model parameters.

2.2 Ion Implantation

Ion implantation is a critical tool in achieving process control for both bipolar and MOS devices. For MOS devices, ion implantation's precise control of dose and range facilitates the exact tailoring of parameters such as threshold and punch-through voltages. In this section, we will look in greater detail at the ion implantation models used in SUPREM III.

Modeling can be useful for many aspects of the ion implantation. If the implanted profile experiences sufficient thermal cycling, the initial profile shape will be masked and the primary quantities of interest in the simulation will be simply the ion dose and range. Figure 2.4 (a) is an example of a SUPREM III program in which only the "dose" and

"energy" parameters are called out in the input deck.

If the energy

is sufficient to penetrate a multilayer target - which for

the example

44

CHAPTER 2. INTRODUCTION TO SUPREM

'"'.e.

~

~ 19

E

< 18 o

011

~<

~18

u~

01 IS o

I

~

I

..

Cl_tones fro," Burfoca (M,cron.)

0;....

~

~ 18

E

 

 

 

1

2

J

..

 

 

 

 

C •• t.onee

frOM

aurfoce

hllicrona)

 

 

 

 

 

 

BORON Chelll.

.2a

 

 

 

 

AItSEN[C

Che

 

 

 

-.....

A.NTIUONY

en

u

 

 

 

 

- Net Chell.

"-

 

 

 

 

 

 

 

2L9

 

 

 

 

 

 

~

 

 

 

 

 

 

 

E

 

 

 

 

 

 

 

C 19

 

 

 

 

 

 

o

 

 

 

 

 

 

 

C; 11

 

 

 

 

 

 

...

 

 

 

 

 

 

 

L

 

 

 

 

 

 

 

C

 

 

 

 

 

 

 

~ l6

llt-----'..

 

 

 

C

 

 

 

 

uo

15

 

 

i:

 

 

 

CI

 

 

 

..'

 

 

 

o

 

 

 

 

 

 

 

 

o

1

lrcm

a

 

 

 

 

 

Olstonce

sur-Foce (mLcrons)

Figure 2.2: (C) Semi-logarithmic plot of doping versus depth for the SUPREM III input sequence shown in Figure 2.2 (b). The profiles shown correspond to the n+ Sb implant, diffusion, and n- epitaxial growth.

2.2. ION IMPLANTATION

45

~y

(a)

0 X

I

(b)0

E

-Xox 0

M

E

T

A

(e) L

-XM

I x

~ p

(e)

C(x)

P

X

Xepi

C(x)

0

X

Xepi

Xj

Figure 2.3: Bipolar device cross-section with one-dimensional profiles in the emitter and base shown, (a) the complete cross-section, (b) the extrinsic base net region doping profile, (c) the net doping profile under the emitter.

46

CHAPTER 2. INTRODUCTION TO SUPREM

title

Multi-Layer Implantation

initialize <100> silicon boron concentration=ge14

+thickness-l.0 dx=O.Ol spaces-50

comment

multi-layers created

deposition

oxide thickness=0.04 dx=O.002

deposition

nitride thickness=O.04 dx=0.002

comment

implant boron

implant

boron dose=7.5ell energy=35

comment

display results

print

layers

plot

boron chemical cmax=le17 xmax=0.25

stop

 

 

(a)

-aORON Ch•••

;;;

E

o

"- co

o

~IG

o

c o

~

o

~

..L

cIS

o c o u

rn

...o

o

1.05

e. I

1.15

0.2

e. 2S

Distance fl""om surFece (mlcrons)

(b)

Figure 2.4: SUPREM input file and output display for boron implantation into a multilayer target, (a) the input file, (b) the semi-logarithmic concentration plot indicating the dopant distribution in all layers.