Книги2 / 1993 Dutton , Yu -Technology CAD_Computer Simulation
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148 |
CHAPTER 4. PN JUNCTIONS |
interface. We will see that this does not occur. In fact, the bands are continuous across the interface as is shown in Figure 4.4 (b). One can realize that this bending of the bands implies two things. First, the concentration of holes and electrons varies across the region of transition from n- to p-type materials, as evidenced by the variation of Eo - Ep. Second, band bending implies that fields are present. The direction and value of the field are such as to oppose the diffusion tendencies of carriers. Consider Eqs. (4.46-4.47). An electric field is necessary to maintain the concentration gradient.
The electric field in the transition region (and in any region for that matter) is related to the gradient of the potential energy. That is, the force on an electron is -q£(x) and this force must equal the negative of the gradient of potential energy for electrons (because of E(x) = -fJ1f;(x)/fJx). The potential energy for free electrons can be represented by energy Eo for homogeneous material neglecting the bandgap narrowing effect. Hence,
E(x) = ! fJEo. |
(4.52) |
q fJx |
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One may also observe that the intrinsic Fermi level follows Eo under the same condition as specified above. Thus the gradients of Eo and Ei are the same, and it follows that
E(x) =! fJEi. |
(4.53) |
q fJx |
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Notice from Figure 4.4 (b), that E(x) is positive in the +x direction in this case.
For no current flow across the transition region:
(4.54)
If we use Eqs. (4.24) and (4.53) in the above expression (realizing that the concept of Ep is valid for this equilibrium condition) we obtain
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EF |
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kT + qJ.t |
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1 fJE- |
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-qD ni- e E. |
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qDp |
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fJEp] |
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p-- |
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~' ' |
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o IJ.p |
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(4.55) |
4.5. THE P N JUNCTION - EQUILIBRIUM CONDITIONS |
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From the above equation and using the Einstein relationship (Eq. (4.48», the terms with fJEdfJx cancel and it follows that
fJEF |
= 0 |
(4.56) |
j.LpPa;- |
Because P and j.tp can never be zero, so EF must be a constant independent upon the position. This derivation confirms our earlier assertion that EF is flat across the transition region.
In addition to showing that EF is flat across the transition region, we can use Eq. (4.54) to quantitatively determine the nature of the bandbending in the transition region. To maintain Jp ( x) = 0, the required field £(x) can be determined from Eq. (4.54) to be
£(x) = Dp_l_ap(x) |
(4.57) |
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JLp p(x) ax |
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Again using the Einstein relationship and expressing £: in terms of potential 'IjJ,
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kT 1 apex) |
(4.58) |
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-q- p(x)a;-' |
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It is interesting to show from the above equation that even without knowing p(x), it is possible to determine the relative potential of one side of the transition region relative to the other. By integrating Eq. (4.58) over the distance between two points where p is known, one can find
the relative potential. Integrating from some position in the n-region |
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where p |
= PnO to some position in the p-region where p |
= Ppo one |
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obtains |
r"p a'IjJ(x) dx |
= _kT lPpO _1_ ap(x ) dx |
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(4.59) |
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J"'n ax |
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PnO p(x) ax |
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The result is |
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'ljJp - 'ljJn |
(4.60) |
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That is, the electrostatic potential in the neutral p-region (where p = ppo) is less than that in the neutral n-region (where p = PnO) by an amount 'ljJo, where
'ljJo = kT In Ppo ~ kT In |
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= kT In N A ~D |
(4.61 ) |
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q PnO |
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nj / ND |
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This quantity 'ljJo is the built-in potential at the junction under equilibrium conditions.
150 CHAPTER 4. PN JUNCTIONS
Under certain circumstances, even at nonequilibrium conditions we can still obtain a relationship similar to Eq. (4.60). Specifica.l1y, assume that we apply to a pn junction an external bias, V, of a polarity so
as to oppose (or decrease) tPo, the built-in potential. Physica.l1y this corresponds to making the p-region positive in charge with respect to the n-region. Under these conditions, we assume that the current which flows externally is sma.l1 compared to the individual counterbalancing flows in the transition region, and we define this condition as quasi-equilibrium in the transition region. The concept of quasiequilibrium is that it allows us to use Eq. (4.58) to solve for the relation between potential and concentrations at the edges of the transition region. The assumption that a.l1 the applied bias appears across the transition region is reasonable as suggested by the discussion in Chapter 3 since the abundance of majority carriers outside the transition region on each side typica.l1y precludes significant resistive drops in these regions. Hence the new potential difference across the transition region is given by tPo - V. The hole concentrations at the edges of the transition region are now given by Pn, which is not equal to PnO, and Ppo is assumed not to be altered under low level conditions. Thus for the nonequilibrium case
tPo - V = kT In Ppo |
(4.62) |
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at the edges of the transition region. This can be rewritten as |
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Pn = ppoe-q"po/kTe qV/ kT |
(4.63) |
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Using the relationship for Ppo,tPo, and PnO given in Eq. (4.61) one can rewrite the above equation as
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(4.64) |
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Similarly for electrons at the p-side edge of the transition region, |
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pO |
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(4.65) |
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The essence of deriving Eqs. (4.64-4.65) is the assumption that quasiequilibrium exists across the transition region. The applied bias is assumed to alter the energy bands just across the transition region. Also the net current flow is assumed sma.l1 compared with the individual drift and diffusion components. The conditions for equilibrium and quasiequilibrium (for an applied bias potential of +V from P to n) are shown
4.5. THE P N JUNCTION - |
EQUILIBRIUM CONDITIONS 151 |
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qll/lol |
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/ - : .. _ ----- Ec |
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/"';"';1"-- -.~ - |
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Efn --e." |
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~....---------- Ev |
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n material |
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Figure 4.5: The relationships of potential and Fermi-level to (a) the equilibrium condition, (b) a +V applied to the p-side (relative to the n).
in Figures 4.5 (a) and (b), respectively. Note that for quasi-equilibrium conditions the quasi-Fermi levels have been added. Their indicated flatness ({JEFn/{JX ::::::i 0, {JEFp/{JX::::::i 0) in the transition region reflects the assumption that· the total current in that region is small compared to either term in Eq. (4.54). The larger dots at the edges of the transition region indicate the points where Eqs. (4.64-4.65) are assumed as the "boundary equations". Although we have considered the conditions of the quasi-equilibrium at the edges of the transition region only, an interesting result is that everywhere in the transition region
(4.66)
Tha.t is, the quasi-Fermi levels are separated exactly by qV (again, a.s depicted in Figure 4.5 (b)). Outside the transition region, as the carriers diffuse and recombine during the process of current flow, conditions of equilibrium are restored, as can be evidenced by the return to a single Fermi level. A final observation regarding the assumption that
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CHAPTER 4. |
PN JUNCTIONS |
OEFp/OX ~ 0 can be made. For nonequilibrium Eq. (4.56) becomes |
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(4.67) |
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This is the expression for the total hole current at any point. To validate the quasi-equilibrium assumption, this flow must be shown to be small compared to either term in Eq. (4.54). A reasonable point at which to make this comparison might be where EF and Ei cross, in the middle of the transition region. Certainly the assumption becomes less valid as the so-called "neutral" regions are approached.
Before considering the actual flow of carriers in the neutral regions resulting from the boundary conditions given by Eqs. (4.64-4.65), let us consider the nature of the transition region more carefully. For a material assumed to be uniformly doped n-type for x < 0 (with ND) and p-type for x > 0 (with NA), the hole and electron concentrations vary markedly around x = 0 (due to the displacement of the bands relative to the Fermi-level), while the ionized impurity concentrations do not vary. The variations of free carriers compared with the constant dopant concentrations look quite different on logarithmic and linear plots (see Figures 4.6 (a) and (b». However, in terms of practical charge distributions, the linear plot results in a net charge distribution density, p, which is given by Figure 4.6 (c). It is reasonable to assume effectively "complete depletion" of donors over a distance from the metallurgical junction at x = 0 to x = -In and for acceptors to x = Ip. One realizes that for x < -In and x > Ip there are no net fields. However, for the range -In < X < Ip the field variation with charge density is given by the Poisson's equation:
o£(x) _ ~ ox £8
Hence in the range 0 > x > -In' p = qND and
o£(x) qND
---ax- = fa
Integration of the above equation with x from -In' to any point -In < X < 0 gives:
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o£(O |
1 qND |
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oe |
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--d(,= |
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(4.68)
(4.69)
where £( -In) = 0,
(4.70)
4.5. THE P N JUNCTION - EQUILIBRIUM CONDITIONS |
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'§ JO IO |
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Lineor Concentration, |
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p Net Charge Density. |
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Figure 4.6: Plots of concentrations in a pn junction, (a) shown on semilogarithmic scale, (b) linear scale, and (c) the net charge used in Poisson's equation.
154 |
CHAPTER 4. PN JUNCTIONS |
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where ~ is the integral variable, or |
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£(x) = qND(X+ln) |
for -In < X < 0 |
(4.71) |
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At X = 0 a maximum is reached for £ and |
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£max = £(0) = qNDln |
(4.72) |
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For lp > x> 0 the charge density is now given by p = -qNA. For £(x) to equal zero for x > lp it must be true that "+" and "-" charges are equal from the requirement of the overall charge neutrality. Hence
(4.73)
Using Eq. (4.72) and the new expression for p, one can find the expression for the electric field in the range of lp > x > 0 as follows.
(4.74)
If we define the total depletion layer width as
(4.75)
and integrate the electric field through the entire depletion region ([-in, lp)) knowing that the potential difference across this region if 'ljJo - V, one should be able to obtain the following expressions for alII's using known parameters.
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(4.76) |
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-2~('ljJo-V) ( 1 |
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Having obtained expressions for Ip and in, it is useful to consider how the "space-charge" contained within these limits varies with applied voltage. Define Q(V) as the total negative space-charge (on the p-side):
(4.79)
4.6. THE PN JUNCTION - NON-EQUILIBRIUM |
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where A is the area of the junction cross section and Alp thus represents the space-charge volume. If V increases, the space-charge region narrows on the p-side as holes flow in to compensate the ionized acceptors. On the n-side, electrons flow in to compensate ionized donors, a flow of current in the same sense as for holes. This conductive current (due to the carrier motion) is made continuous by the so-called displacement current, which is given by
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aQ(V) av |
(4.80) |
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at - |
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One can observe that for the +6.V, ative (since lp decrease with +6.V).
I6.QI becomes smaller or less negUsing Eqs. (4.76-4.77) one obtains
aQ(V) |
NDNA |
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[2fs |
( 1 |
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av |
-qA NA + ND av |
q('l/Jo - V) |
NA + ND |
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(_1_ + _1_)] -1/2 = f.sA |
(4.81) |
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This result represents the total junction capacitance due to the spacecharge region. Note that this capacitance is defined in terms of changes in charge and voltage, hence it is an incremental (or called differential) capacitance at a given voltage. We define the space-charge capacitance as
(4.82)
Note that this capacitance is defined in terms of changes in charge and voltage, hence it is an incremental (or called differential) capacitance at for a given (dc) bias. The relationship of Q(V), Cj(V) and V are shown in Figures 4.7 (a) and (b). It is important to note from these figures that Q(V) and Cj(V) cannot be defined for V > 'l/Jo. In fact this is not possible in practice since as the junction becomes forward biased toward ('l/Jo) the Ohmic voltage drop in the bulk quasi-neutral regions due to the large flow of carriers precludes voltage drops of this magnitude across the space-charge region. A more general treatment on the space-charge capacitance can be found in [4.15]
4.6The pn Junction - Non-equilibrium
Under nonequilibrium conditions in a pn junction, with an applied voltage, current flows. This flow of carriers is governed by the continuity
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CHAPTER 4. PN JUNCTIONS |
(a)
(b)
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Q(V)
----------~r--r-------- |
V |
----------~--_~LO-------- |
V |
q(v)
---=~--~~~---------- |
V |
V,
Figure 4.7: (a) The "space-charge" on thep-side as a function of V, (b) junction capacitance Cj (V) as a function of V, where C(V) = fJQ / fJV,
(c) incremental space-charge needed to achieve a given bias condition.
equations for holes and electrons. In our earlier discussions regarding nonequilibrium, we assumed to a first approximation that all the applied voltage is dropped across the transition (or space-charge) region. This, along with the assumption of quasi-equilibrium across the spacecharge region, resulted in Eqs. (4.64-4.65). These equations provide one set of boundary conditions for the continuity equations in the neutral regions. The second set of boundary condition must be specified at some other points in space where concentration values are always known (for now it is assumed that we are only dealing with steady-state or boundary-value problems). To see how the solutions depend on these boundary conditions, consider the two characteristic problems shown in
4.6. THE PN JUNCTION - NON-EQUILIBRIUM |
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Figures 4.8 (a) and (b). In both figures we depict a pn junction with
-- Ppo
(a)
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+Ip |
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Eq. (4.91) |
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Eq. (4.93) |
Eq. (4.92) |
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Eq. (4.94) |
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J~~L-L--- |
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Xi • I
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+--. X" |
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Figure 4.8: (a) Hole and electron distributions for Wn ~ L p, Wp ~ L n ,
(b) hole and electron distributions for Wn ~ L p, Wp ~ Ln.
contact at Wp in the p-region and Wn in the n-region. The contacts are assumed to impose the boundary conditions that equilibrium of excess carriers is restored at these points. For Figure 4.8 (a) Wp ~ Ln and vVn ~ Lp which means that all excess carriers have already reached equilibrium before reaching the contacts. For Figure 4.8 (b), Wp ~ Ln and lVn ~ Lp. In this case, the effects of the contacts are important in determining (excess) minority carrier concentrations. To see how the spatial dependencies of the carrier concentrations come about, consider
