DOE handbook.Chemical management / doe-hdbk-1139-3-2005

68This section contains a summary of the training requirement that are common to most of the chemicals listed. The exact requirements for each chemical may vary, and the chemical-specific regulation cited should be reviewed for specific training details.

69 These appendices contain additional information regarding the chemicals’ physical and chemical properties, safety and health data, medical surveillance, emergency actions, etc.

138

139

DOE-HDBK-1139/3-2005

5.0Source Documents

NFPA 55 (1998), “Storage, Use, and Handling Of Compressed and Liquefied Gases in Portable Cylinders”.

NFPA 432 (1997), “Storage of Organic Peroxide Formulations”.

10CFR850, “Chronic Beryllium Disease Prevention Program”.

29CFR1910.119, “Process Safety Management of Highly Hazardous Chemicals”. 29CFR1910.132, “Personal Protective Equipment. General Requirements.” 29CFR1910.134, “Respiratory Protection”.

29CFR1910.253, “Oxygen-fuel Gas Welding and Cutting”. 29CFR1910.1001, “Asbestos”.

29CFR1910.1003, “4-Nitrobiphenyl”. 29CFR1910.1017, “Vinyl Chloride”. 29CFR1910.1018, “Inorganic Arsenic”. 29CFR1910.1025, “Lead”. 29CFR1910.1027, “Cadmium”. 29CFR1910.1028, “Benzene”.

29CFR1910.1044, “1,2-dibromo-3-chloropropane”. 29CFR1910.1045, “Acrylonitrile”. 29CFR1910.1047, “Ethylene Oxide”. 29CFR1910.1048, “Formaldehyde”. 29CFR1910.1050, “Methylenedianiline”. 29CFR1910.1051, “1,3-Butadiene”. 29CFR1910.1052, “Methylene Chloride”. 29CFR1910.1200, “Hazard Communication”.

29CFR1910.1450, “Occupational Exposure to Hazardous Chemicals in Laboratories”. 29CFR1926.21, “Safety Training and Education”.

140

DOE-HDBK-1139/3-2005

INTENTIONALLY BLANK

141

DOE-HDBK-1139/3-2005

Complete List of Sources70

ANSI Z49.1 (2000), “Safety in Welding, Cutting, and Allied processes”.

CGA G-1 (1996), "Acetylene".

CGA P-1 (1999), "Safe Handling of Compressed Gases in Containers".

Department of Energy (July 1999), “Guidelines on Export Control and Nonproliferation”. Department of Energy Acquisition Regulation (DEAR) 970.5204-2, “Integration of Environment, Safety and Health into Work Planning and Execution”.

Department of Energy Personal Property Letter, Issue Number 970-3, Revision 1 (February 3, 1998).

DOE Acquisition Letter AL-2000-03, “Greening the Government Requirements in Contracting” (May 16, 2000) (Superceded by AL-2002-05).

DOE Acquisition Letter AL-2002-05, “Greening the Government Requirements in Contracting” (July 10, 2002).

DOE O 151.1, “Comprehensive Emergency Management System”. DOE O 225.1A, “Accident Investigations”.

DOE O 420.1A, “Facility Safety”.

DOE O 440.1A, “Worker Protection Management for DOE Federal and Contractor Employees”. DOE O 450.1, “Environmental Protection Program”.

DOE O 460.1A, “Packaging and Transportation Safety”.

DOE O 460.1B, “Packaging and Transportation Safety” [NOTE: This order, issued on 4/4/2003, cancels the DOE O 460.1A].

DOE O 5480.19, “Conduct of Operations Requirements for DOE Facilities”.

DOE-STD-1027-92, “Hazard Categorization and Accident Analysis Techniques for Compliance with DOE O 5480.23, Nuclear Safety Analysis Reports”.

DOE-STD-1120-98, “Integration of Environment, Safety, and Health into Facility Disposition Activities”.

DOE-STD-3009-94, “Preparation Guide for U.S. DOE Nonreactor Nuclear Facility Safety Analysis Reports”.

DOE-STD-3011-94, “Guidance for Preparation of DOE 5480.22 (TSR) and DOE 5480.23 (SAR) Implementation Plans”.

DOE-STD-3016-99, “Limited Standard; Hazard Analysis Reports for Nuclear Explosive Operations”.

Executive Order 12344 (February 3, 1982), “Naval Nuclear Propulsion Program”, 47 Federal Register 4979.

Executive Order 13101 of September 14, 1998, “Greening the Government Through Waste Prevention, Recycling, and Federal Acquisition”.

Executive Order 13148 of April 21, 2000, “Greening the Government Through Leadership in Environmental Management”.

70 Hyperlinks to ANSI, CGA, and NFPA requirements provided here are for general information only, as they require user subscription to a prescribed service in order to access these organizations’ source requirements.

142

DOE-HDBK-1139/3-2005

Federal Standard 123 (or FED-STD-123), “Marking for Shipment (Civil Agencies)”.

Federal Standard 313 (or FED-STD-313), “Material Safety Data, Transportation Data and Disposal Data for Hazardous Materials Furnished to Government Activities”.

The Hazardous and Solid Waste Amendments of 1984 (HSWA).

The Helium Act (Pub. L. 86-777, as amended (50 U.S.C. 167(d).

International Atomic Energy Agency (IAEA), Information Circular (INFCIRC) 254, Part 1 (“Trigger List”) and Part 2 (“Dual-use List”).

NFPA 30 (2000), “Flammable and Combustible Liquids Code”.

NFPA 45 (2000), “Standard on Fire Protection for Laboratories Using Chemicals”. NFPA 51 (2002), "Standard for the Design and Installation of Oxygen-Fuel Gas Systems".

NFPA 55 (2003), "Standard for the Storage, Use, and Handling of Compressed and Liquefied Gases in Portable Cylinders".

NFPA 430 (1995), "Code for the Storage of Liquid and Solid Oxidizers". NFPA 430 (2000), “Storage of Liquid and Solid Oxidizers”.

NFPA 432 (2002), “Code for the Storage of Organic Peroxide Formulations”.

NFPA 471 (2002), “Recommended Practice for Responding to Hazardous Materials”.

NFPA 472 (2002), “Standard on Professional Competence of Responders to Hazardous Materials Incidents”.

NFPA 484 (2002), “Standard for Combustible Metals, Metal Powders, and Metal Dusts”. NFPA 704 ( 2001), "Identification of the Hazards of Materials for Emergency Response". NFPA 1620 (1998), “Recommended Practice for Pre-Incident Planning”.

Public Law 91-596 (12/29/70), “The Occupational Safety and Health Act, 1970”

Public Law 98-525 (10/19/84), “Department of Defense Authorization Act, 1985”; also called “Department of Energy National Security and Military Applications of Nuclear Energy Authorization Act of 1985”.

Secretary of Energy Memorandum, November 12, 1999, “Pollution Prevention and Energy Efficiency Leadership Goals for Fiscal Year 2000 and Beyond”.

10CFR110, Nuclear Regulatory Commission, "Export and Import of Nuclear Equipment and Material”.

10CFR810, Department of Energy, "Assistance to Foreign Atomic Energy Activities". 10CFR830, “Nuclear Safety Management”.

10CFR835, “Occupational Radiation Protection”.

10CFR850, “Chronic Beryllium Disease Prevention Program”.

10CFR1021, “National Environmental Policy Act Implementing Procedures”.

15CFR Subpart C (Parts 730 to 774), Department of Commerce, “Export Administration Regulations” (EAR); in particular, 15CFR734, “Scope of the Export Administration Regulations”, 15CFR744, "Control Policy: End-User and End-Use Based", and 15CFR774, “The Commerce Control List”.

21CFR1316, “Drug Enforcement Administration; Administrative Functions, Practices, and Procedures”.

22CFR Subchapter M (Parts 120-130), Department of State, "International Traffic in Arms Regulations" (ITAR), and in particular, 22CFR121, “The United States Munitions List”. 27CFR22.41, “Distribution and Use of Tax-Free Alcohol, Qualification”.

143

DOE-HDBK-1139/3-2005

29CFR1910, “Occupational Safety and Health Standards”.

29CFR1910.6, "Incorporation by Reference".

29CFR1910.20, “Preservation of Records (medical and exposure)”. 29CFR1910.38, “Employee Emergency Plans and Fire Prevention Plans”. 29CFR1910.101, “Compressed Gases (general requirements)”. 29CFR1910.102, “Acetylene”.

29CFR1910.103, “Hydrogen”. 29CFR1910.104, “Oxygen”. 29CFR1910.105, “Nitrous oxide”.

29CFR1910.106, “Flammable and Combustible Liquids”.

29CFR1910.119, “Process Safety Management of Highly Hazardous Chemicals”. 29CFR1910.120, “Hazardous Waste Operations and Emergency Response”. 29CFR1910.132, “Personal Protective Equipment”.

29CFR1910.134, "Respiratory Protection". 29CFR1910.146, “Permit-required Confined Spaces”. 29CFR1910.253, "Oxygen-Fuel Gas Welding and Cutting". 29CFR1910.1001, “Asbestos”.

29CFR1910.1003, “13 Carcinogens (4-Nitrobiphenyl, etc.)”. 29CFR1910.1004, “alpha-Naphthylamine”. 29CFR1910.1006, “Methyl chloromethyl ether”. 29CFR1910.1007, “3,3’-Dichlorobenzidine (and its salts)”. 29CFR1910.1008, “bis-Chloromethyl ether”. 29CFR1910.1009, “beta-Naphthylamine”. 29CFR1910.1010, “Benzidine”.

29CFR1910.1011, “4-Aminodiphenyl”. 29CFR1910.1012, “Ethyleneimine”. 29CFR1910.1013, “beta-Propiolactone”. 29CFR1910.1014, “2-Acetylaminofluorene”. 29CFR1910.1015, “4-Dimethylaminoazobenzene”. 29CFR1910.1016, “N-Nitrosodimethylamine”. 29CFR1910.1017, “Vinyl Chloride”. 29CFR1910.1018, “Inorganic Arsenic”.

29CFR1910.1020, “Access to Employee Exposure and Medical Records”. 29CFR1910.1025, “Lead”.

29CFR1910.1027, “Cadmium”. 29CFR1910.1028, “Benzene”.

29CFR1910.1044, “1,2-dibromo-3-chloropropane”. 29CFR1910.1045, “Acrylonitrile”. 29CFR1910.1047, “Ethylene Oxide”. 29CFR1910.1048, “Formaldehyde”. 29CFR1910.1050, “Methylenedianiline”. 29CFR1910.1051, “1,3-Butadiene”. 29CFR1910.1052, “Methylene Chloride”. 29CFR1910.1200, "Hazard Communication".

29CFR1910.1450, “Occupational Exposure to Hazardous Chemicals in Laboratories”. 29CFR1926.21, ”Safety Training and Education”.

29CFR1926.65, “Hazardous Waste Operations and Emergency Response”. 29CFR1926.350, "Gas Welding and Cutting".

30CFR602, Bureau of Mines, Department of the Interior - Chapter VI - Subchapter A--Helium and Coal”.

144

DOE-HDBK-1139/3-2005

40CFR61, “National Emission Standards for Hazardous Air Pollutants” (NESHAPs). 40CFR61.156, (National Emission Standards for Hazardous Air Pollutants) “Cross-reference to Other Asbestos Regulations”.

40CFR63, “National Emission Standards for Hazardous Air Pollutants for Source Categories”. 40CFR68, “Chemical Accident Prevention Provisions”.

40CFR82, “Protection of Stratospheric Ozone”.

40CFR260-282, “The Resource Conservation and Recovery Act of 1976”. 40CFR261, “Identification and Listing of Hazardous Waste”.

40CFR273, “Standards for Universal Waste Management”.

40CFR302.4, “Listing of Hazardous Substances for the National Oil and Hazardous Substances Pollution Contingency Plan”.

40CFR355, “Emergency Planning and Notification”.

40CFR370, “Hazardous Chemical Reporting: Community Right-To-Know”.

40CFR761, “Polychlorinated Biphenyls (PCBs) Manufacturing, Processing, Distribution in Commerce, and Use Prohibitions”.

40CFR763, “Asbestos”.

48CFR970, “DOE Management and Operating Contracts“. 40CFR68, “Chemical Accident Prevention Provisions”. 40CFR1500-1508, “Chapter V-Council on Environmental Quality”.

41CFR101, “Federal Property Management Regulations” (Parts 101-1 to 101-99); in particular, Subpart H (Parts 42 to 99).

41CFR101-26.602, “Federal Property Management Regulations - Procurement Sources and Program”.

41CFR101-27.2, “Management of Shelf-Life Materials”.

41CFR102, “Federal Management Regulation” (Parts 102-1 to 102-220); in particular, 41CFR10236, “Disposition of Excess Personal Property” [NOTE: This Part is cross-referenced by 41CFR10143, “Utilization of Personal Property”, which is no longer in print], and 41CFR102-37, “Donation of Surplus Personal Property” [NOTE: This Part is cross-referenced by 41CFR101-44,“Donation of Personal Property”, which is no longer in print].

41CFR109, “Department of Energy Property Management Regulations”; in particular, Subpart H (Parts 42 to 50).

48CFR, “Federal Acquisition Regulations”.

48CFR, “Department of Energy Acquisition Regulations System”: (Chapters 1 and 9). 48CFR970, “DOE Management and Operating Contracts”.

49CFR171-180, (Subchapter C), “Hazardous Materials Regulations”. 49CFR171-179, “Hazardous Materials Transportation”.

49 FR 11945, Mar. 28, 1984, as amended at 49 FR 38950, Oct. 2, 1984. 49 FR 11945, Mar. 28, 1984, as amended at 59 FR 9105, Feb. 25, 1994. 54 FR 27646, June 30, 1989, as amended at 59 FR 9105, Feb. 25, 1994. 62 FR 2312, Jan. 16, 1997.

42 USC 6901 – 6992(k), “The Solid Waste Disposal Act of Oct. 21, 1976”. 42 USC 13101 – 13109, “The Pollution Prevention Act of 1990”.

145

DOE-HDBK-1139/3-2005

CHAPTER OVERVIEWS

CHAPTER 1: HAZARD ANALYSIS

This chapter consolidates existing DOE and other federal safety and health requirements and National Standards that address the identification of chemical hazards. State and local code requirements are not included. The consolidated requirements addressed here apply to all locations involved in the storage and/or use of chemicals and chemical products (see def.).

While this chapter is very short, its importance cannot be overstated. Several objectives of the hazard analysis requirements consolidated in this chapter include the:

•identification and analysis of potential hazards so that appropriate preventive and mitigative measures can be taken to protect workers and the general public;

•communication of hazards and associated controls to workers;

•identification of the presence and magnitude of certain hazards in order to determine the applicability of relevant safety standards (e.g., threshold quantities established in certain federal regulations).

This chapter is divided into two sections. The first section, 4.1, contains a consolidation of requirements for hazard analysis and hazard communication associated with the general use of chemicals. Section 4.2 details consolidated requirements for analyzing hazards when certain hazardous operations are involved. This section is similar to section 4.1, but contains more specificity and additional rigor regarding hazard analysis methods and documentation.

Key to this chapter is the recognition that hazard identification, though generally implied rather than being directly stated, is an underlying principle of hazard analysis, since without first being properly identified, hazards cannot be analyzed or evaluated for ultimate mitigation.

=========================================================

CHAPTER 2: CHEMICAL ACQUISITION

This chapter covers those existing DOE and other federal requirements that govern the acquisition of chemicals, and applies to all locations involved in the storage and/or use of chemicals and chemical products (see def.). State and local requirements are not included. It consolidates direct health and safety-related acquisition requirements applicable to the procurement of chemicals and summarizes implied requirements for the acquisition of chemicals and chemical products that are included in various regulations and standards but are not directly mandated by them. This chapter is divided into seven major sections. Each section of the chapter contains consolidated requirements for the procurement of a specific class or type of chemical or chemical product.

Section 4.1 of this chapter consolidates general Health and Safety requirements that must be addressed when chemicals are procured. The remaining sections of this chapter consolidate additional non-safety and health-related acquisition requirements for specific classes of chemicals and chemical products and are provided for informational purposes only. Section 4.2 consolidates requirements for the procurement of alcohol, section 4.3 requirements for the procurement of helium, section 4.4 requirements for Fuel and Petroleum, section 4.5 requirements for Arms and Ammunition, section 4.6 requirements for DOEspecific materials (Heavy Water, Precious Metals, Lithium), and 4.7 requirements for Controlled Substances.

146