DOE handbook.Chemical management / doe-hdbk-1139-3-2005

Federal

Title

Examples of Hazardous Materials

Supply

Requiring Identification

Class/Group

1375

Demolition materials

Explosive device.

Group 34

Metalworking machinery.

Equipment containing hazardous hydraulic

fluids including PCBs.

3433

Gas welding, heat cutting, and

Compressed gases.

Metalizing equipment.

3439

Miscellaneous welding,

Hazardous items such as cleaners, acids, flux

soldering and brazing supplies

and supplies that contain or produce

and accessories.

hazardous fumes.

3610

Printing, duplicating, and

Flammable or toxic lithographic solutions.

bookbinding equipment.

4240

Safety and rescue equipment

Items which involve oxygen, or compressed

gases, or contain emitting charges.

5660

Wallboard, building paper, and

Asbestos cloth which has loose fibers or

thermal insulation materials.

particles that may become airborne and

materials containing formaldehyde.

5910

Capacitors

Items that contain polychlorinated biphenyls

(PCBs) or sulfuric acid.

5950

Coils and transformers.

Items containing polychlorinated biphenyls

(PCBs).

5970

Electrical insulators and

Items containing flammable solvents.

insulating materials.

6135

Batteries, primary.

Lead-acid, lithium and mercury batteries and

Alkaline (with electrolyte).

6140

Batteries, secondary.

Items that are wet or moist containing

corrosive or other hazardous compounds.

6505

Drugs, biologicals and official

Hazardous items as defined in 40CFR101-

reagents.

42.001.

127

Federal

Title

Examples of Hazardous Materials

Supply

Requiring Identification

Class/Group

6508

Medicated cosmetics and

Hazardous items as defined in 40CFR101-

Toiletries.

42.001.

6640

Laboratory equipment and

Items containing flammable compounds,

supplies.

mercury, or asbestos.

6685

Pressure, temperature, and

Items containing mercury or compressed

humidity and measuring and

gases.

Controlling instruments.

6750

Photographic supplies.

Items containing hazardous chemicals,

solvents, thinners, and cements.

7510

Office supplies

Hazardous items, such as thinners, cleaning

fluids, flammable inks, and varnishes.

8510

Perfumes, toilet preparations,

Shipping containers, pressurized containers

and powders.

with flammable or nonflammable

propellants.

8720

Fertilizers.

Items containing weed and pest control or

other harmful ingredients or because of their

composition, are hazardous.

9390

Miscellaneous fabricated

Items containing flammable solvents or

nonmetallic materials.

asbestos.

Sources11

Consolidated Requirements12, 65, 66

29CFR1910.1200(h)(1);

4.1 General Employee Information and Training - Employers shall

29CFR1910.1450(f)

provide employees with effective information and training on hazardous

chemicals in their work area at the time of their initial assignment, and

whenever a new physical or health hazard the employees have not

previously been trained about is introduced into their work area.

Information and training may be designed to cover categories of hazards

(e.g., flammability, carcinogenicity) or specific chemicals.

29CFR1910.1450(f)(2)

4.1.1 The frequency of refresher information and training shall be

determined by the employer.

29CFR1910.1200(h)(1)

4.1.2 Chemical-specific information must always be available through

labels and material safety data sheets.

29CFR1910.1200 (h)(2)

4.1.3 Information - Employees shall be informed of:

29CFR1910.1200(h)(2)(i);

4.1.3.1 The contents of 29CFR1910.1200 and 1450 and their

29CFR1910.1450(f)(3)(i)

appendices, and,

29CFR1910.1200(h)(2)(ii)

4.1.3.2 Any operations in their work area where hazardous

chemicals are present; and,

29CFR1910.1200(h)(2)(iii)

4.1.3.3 The location and availability of the written hazard

communication program, including the required list(s)

of hazardous chemicals, and material safety data sheets

required by this section.

4.1.4 Training – Employee training shall include at least:

29CFR1910.1200 (h)(3)(i);

4.1.4.1 Methods and observations that may be used to detect the

29CFR1910.1450(f)(4)(i)(A)

presence or release of a hazardous chemical in the work

area (such as monitoring conducted by the employer,

continuous monitoring devices, visual appearance or

odor of hazardous chemicals when being released, etc.);

29CFR1910.1200 (h)(3)(ii);

4.1.4.2 The physical and health hazards of the chemicals in the

29CFR1910.1450(f)(4)(i)(B)

work area;

DOE-HDBK-1139/3-2005

Sources11

Consolidated Requirements12, 65, 66

29CFR1910.1200(h)(3)(iii);

4.1.4.3

The measures employees can take to protect themselves

29CFR1910.1450(f)(4)(i)(C)

from these hazards, including specific procedures the

employer has implemented to protect employees from

exposure to hazardous chemicals, such as appropriate

work practices, emergency procedures, and personal

protective equipment to be used; and,

29CFR1910.1200(h)(3)(iv)

4.1.4.4

The details of the hazard communication program

developed by the employer, including an explanation of

the labeling system and the material safety data sheet,

and how employees can obtain and use the appropriate

hazard information.

29CFR1910.1450(f)

4.2 Chemical Laboratories – In addition to the requirements of Section 4.1

above, employees in chemical laboratories shall also be trained as

follows:

29CFR1910.1450(f)

4.2.1 Information:

29CFR1910.1450(f)(3)(ii)

4.2.1.1

The location and availability of the employer's

Chemical Hygiene Plan;

29CFR1910.1450(f)(3)(iii)

4.2.1.2

The permissible exposure limits for OSHA-regulated

substances or recommended exposure limits for other

hazardous chemicals where there is no applicable

OSHA standard;

29CFR1910.1450(f)(3)(iv)

4.2.1.3

Signs and symptoms associated with exposures to

hazardous chemicals used in the laboratory; and

29CFR1910.1450(f)(3)(v)

4.2.1.4

The location and availability of known reference

material on the hazards, safe handling, storage and

disposal of hazardous chemicals found in the laboratory

including, but not limited to, Material Safety Data

Sheets received from the chemical supplier.

29CFR1910.1450(f)(4)(ii)

4.2.2 Training – The employee shall be trained on the applicable

details of the employer's written Chemical Hygiene Plan.

29CFR1910.132(f)(1)

4.3 The employer shall provide training to each employee who is

required by this section to use PPE.

29CFR1910.134(k)

4.4 Respirators. The employer shall provide effective training to

employees who are required to use respirators. The training must be

comprehensive, understandable, and recur annually and more often

if necessary.

DOE-HDBK-1139/3-2005

Sources11

Consolidated Requirements12, 65, 66

29CFR1910.134, App. D

4.4.1 This paragraph also requires the employer to provide the basic

information on respirators found in Appendix D of

29CFR1910.134 to all employees who wear respirators,

including those who do so voluntarily (this includes dust

masks).

29CFR1910.134(k)(1)

4.4.2 The employer shall ensure that each employee can demonstrate

knowledge of at least the following:

29CFR1910.134(k)(1)(i)

4.4.2.1 Why the respirator is necessary and how improper fit,

usage, or maintenance can compromise the protective

effect of the respirator;

29CFR1910.134(k)(1)(ii)

4.4.2.2 What the limitations and capabilities of the respirator

are;

29CFR1910.134(k)(1)(iii)

4.4.2.3 How to use the respirator effectively in emergency

situations, including situations in which the respirator

malfunctions;

29CFR1910.134(k)(1)(iv)

4.4.2.4 How to inspect, put on and remove, use, and check the

seals of the respirator;

29CFR1910.134(c)(1)(v);

4.4.2.5 What the procedures are for cleaning, maintenance and

29CFR1910.134(c)(1)(viii);

storage of the respirator;

29CFR1910.134(k)(1)(i);

29CFR1910.134(k)(1)(v)

29CFR1910.134(k)(1)(vi)

4.4.2.6 How to recognize medical signs and symptoms that may

limit or prevent the effective use of respirators; and

29CFR1910.134(k)(1)(vii)

4.4.2.7 The general requirements for Respiratory Protection

found in 29CFR1910.134.

29CFR1910.134(k)(2)

4.4.3 The training shall be conducted in a manner that is

understandable to the employee.

29CFR1910.134(k)(3)

4.4.4 The employer shall provide the training prior to requiring the

employee to use a respirator in the workplace.

29CFR1910.134(k)(4)

4.4.5 An employer who is able to demonstrate that a new employee

has received training within the last 12 months that addresses

the elements specified in paragraphs 4.3.2.1through 4.3.2.7,

above, is not required to repeat such training provided that the

employee can demonstrate knowledge of those elements.

Previous training not provided by the current employer must be

repeated under the auspices of the current employer no later than

12 months from the date of that previous training.

29CFR1910.134(k)(5)

4.4.6 Retraining shall be administered annually, and when the

following situations occur:

29CFR1910.134(k)(5)(i)

4.4.6.1 Changes in the workplace or the type of respirator

render previous training obsolete.

132

DOE-HDBK-1139/3-2005

Sources11

Consolidated Requirements12, 65, 66

29CFR1910.134(k)(5)(ii)

4.4.6.2

Inadequacies in the employee's knowledge or use of the

respirator indicate that the employee has not retained the

requisite understanding or skill.

29CFR1910.134(k)(5)(iii)

4.4.6.3

Any other situation arises in which retraining appears

necessary to ensure safe respirator use.

29CFR1910.134(k)(6);

4.4.7 The basic advisory information on respirators, as presented in

29CFR1910.134, App. D

Appendix D, shall be provided by the employer in any written or

oral format, to employees who wear respirators, when such use

is not required by 29CFR1910.134 or the employer.

29CFR1910.119

4.5 Highly Hazardous Chemicals (see definition)

29CFR1910.119(g)

4.5.1

Initial Training

29CFR1910.119(g)

4.5.1.1

Each employee presently involved in operating a

process, and each employee, before being involved in

operating a newly assigned process, shall be trained in

an overview of the process and in the operating

procedures. The training shall include emphasis on the

specific safety and health hazards, emergency

operations including shutdown, and safe work practices

applicable to the employee's job tasks.

29CFR1910.119(g)(1)(ii)

4.5.1.2

In lieu of initial training for those employees already

involved in operating a process on May 26, 1992, an

employer may certify in writing that the employee has

the required knowledge, skills, and abilities to safely

carry out the duties and responsibilities as specified in

the operating procedures.

29CFR1910.119(g)(2)

4.5.2 Refresher training shall be provided at least every three years,

and more often if necessary, to each employee involved in

operating a process to assure that the employee understands and

adheres to the current operating procedures of the process. The

employer, in consultation with the employees involved in

operating the process, shall determine the appropriate frequency

of refresher training.

29CFR1910.119(g)(3)

4.5.3 Training documentation - The employer shall ascertain that each

employee involved in operating a process has received and

understood the training required by this paragraph. The

employer shall prepare a record which contains the identity of

the employee, the date of training, and the means used to verify

that the employee understood the training.

29CFR1910.119(h)(3)

4.5.4

Contract employers shall:

29CFR1910.119(h)(3)(i)

4.5.4.1

assure that each contract employee is trained in the work

practices necessary to safely perform his/her job, and

DOE-HDBK-1139/3-2005

Sources11

Consolidated Requirements12, 65, 66

29CFR1910.119(h)(3)(ii)

4.5.4.2 assure that each contract employee is instructed in the

known potential fire, explosion, or toxic release hazards

related to his/her job and the process, and the applicable

provisions of the emergency action plan, and

29CFR1910.119(h)(3)(iii)

4.5.4.3 document that each contract employee has received and

understood the training required by this paragraph. The

contract employer shall prepare a record, which contains

the identity of the contract employee, the date of

training, and the means used to verify that the employee

understood the training.

29CFR1910.119(j)(3)

4.5.5 Training for process maintenance activities - The employer shall

train each employee involved in maintaining the on-going

integrity of process equipment in an overview of that process

and its hazards and in the procedures applicable to the

employee's job tasks to assure that the employee can perform the

job tasks in a safe manner.

29CFR1926.21

4.6 Construction

29CFR1926.21(b)(2)

4.6.1 The employer67 shall instruct each employee in the recognition

and avoidance of unsafe conditions and the regulations

applicable to his work environment to control or eliminate any

hazards or other exposure to illness or injury.

29CFR1926.21(b)(3)

4.6.2 Employees required to handle or use poisons, caustics, and other

harmful substances shall be instructed regarding their safe

handling and use, and be made aware of the potential hazards,

personal hygiene, and personal protective measures required to

safely handle or use harmful substances.

29CFR1926.21(b)(5)

4.6.3

Employees required to handle or use flammable liquids, gases,

or toxic materials shall be instructed in the safe handling and use

of these materials and made aware of the specific requirements

contained in Subparts D, F, and other applicable subparts of

29CFR1926.

29CFR1926.21(b)(6)(i)

4.6.4 All employees required to enter into confined or enclosed spaces

shall be instructed as to the nature of the hazards involved, the

necessary precautions to be taken, and in the use of protective

and emergency equipment required. The employer shall comply

with any specific regulations that apply to work in dangerous or

potentially dangerous areas.

DOE-HDBK-1139/3-2005

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Consolidated Requirements12, 65, 66

4.7 Training requirements for specific materials

NFPA 55, 1-3

4.7.1 Compressed and Liquefied Gases in Portable Cylinders –

Persons responsible for or working in the areas where

compressed gases are produced, stored, handled, or used shall be

trained in the chemical and physical properties of the materials

and the appropriate emergency response.

NFPA 430, 2-7.1 and 2-7.2

4.7.2 Storage of Liquid and Solid Oxidizers – Persons involved in

operations where oxidizers are stored shall receive instruction in

handling the materials in a safe manner, including the

manufacturer’s and processor’s recommendations. Particular

attention shall be given to proper disposal of spilled material to

prevent contamination.

NFPA 432, 2-2

4.7.3 Storage of Organic Peroxides – Personnel involved in operations

in organic peroxide storage areas shall be instructed in proper

and safe handling of such materials, proper use of personal

protective equipment, proper and safe disposal of spilled

material, and proper emergency procedures. Manufacturer’s

instructions shall be consulted for each specific formulation.

29CFR1910.253

4.7.4 Oxygen-fueled Gas Welding and Cutting

29CFR1910.253(a)(4)

4.7.4.1

Workmen in charge of the oxygen or fuel-gas supply

equipment, including generators, and oxygen or fuel-gas

distribution piping systems shall be instructed and

judged competent by their employers for this important

work before being left in charge. Rules and instructions

covering the operation and maintenance of oxygen or

fuel-gas supply equipment including generators, and

oxygen or fuel-gas distribution piping systems shall be

readily available.

29CFR1910.253(e)(6)(ii)

4.7.4.2

Regulators shall be repaired only by skilled mechanics

with appropriate training.

DOE-HDBK-1139/3-2005

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Consolidated Requirements12, 65, 66

29CFR1910.1003;

4.7.5 OSHA’s Regulated Carcinogens – Non-laboratory use of the

29CFR1926.1003-1016

following 13 carcinogens requires additional training as

prescribed in sections 4.6.5.1 and 4.6.5.2 below.

Nitrobiphenyl (CAS No.) 92933;

alpha-Naphthylamine, CAS No. 134327;

methyl chloromethyl ether, CAS No. 107302;

3,3'-Dichlorobenzidine (and its salts) CAS No. 91941;

bis-Chloromethyl ether, CAS No. 542881;

beta-Naphthylamine, CAS No. 91598;

Benzidine, CAS No. 92875;

4-Aminodiphenyl, CAS No. 92671;

Ethyleneimine, CAS No. 151564;

beta-Propiolactone, CAS No. 57578;

2-Acetylaminofluorene, CAS No. 53963;

4-Dimethylaminoazo-benezene, CAS No. 60117;

N-Nitrosodimethylamine, CAS No. 62759.

29CFR1910.1003(e)(5)(i)

4.7.5.1 Each employee prior to being authorized to enter a

regulated area (see definition), shall receive a training

and indoctrination program including, but not

necessarily limited to:

29CFR1910.1003(e)(5)(i)(A)

4.7.5.1.1

the nature of the carcinogenic hazards of a

carcinogen addressed by this section,

including local and systemic toxicity;

29CFR1910.1003(e)(5)(i)(B)

4.7.5.1.2

the specific nature of the operation involving

carcinogen addressed by this section that

could result in exposure;

29CFR1910.1003(e)(5)(i)(C)

4.7.5.1.3

the purpose for and application of the medical

surveillance program, including, as

appropriate, methods of self-examination;

29CFR1910.1003(e)(5)(i)(D)

4.7.5.1.4 the purpose for and application of

decontamination practices and purposes;

29CFR1910.1003(e)(5)(i)(E)

4.7.5.1.5 the purpose for and significance of emergency

practices and procedures;

29CFR1910.1003(e)(5)(i)(F)

4.7.5.1.6 the employee's specific role in emergency

procedures;

29CFR1910.1003(e)(5)(i)(G)

4.7.5.1.7 specific information to aid the employee in

recognition and evaluation of conditions and

situations which may result in the release of a

carcinogen addressed by this section;

136