Приложение а. Результаты расчета реактора конверсии

$ Generated by PRO/II Keyword Generation System <version 8.3>

$ Generated on: Thu Dec 04 14:44:53 2014

TITLE

PRINT STREAM=ALL, RATE=M,WT, FRACTION=M,WT, PERCENT=M,WT

DIMENSION SI, TEMP=C, STDTEMP=0, STDPRES=101.325

SEQUENCE SIMSCI

CALCULATION RVPBASIS=APIN, TVP=37.778

COMPONENT DATA

LIBID 1,H2/2,H2O/3,CO/4,CO2/5,METHANE, BANK=SIMSCI,PROCESS

ASSAY CONVERSION=API94, CURVEFIT=CURRENT, KVRECONCILE=TAILS

THERMODYNAMIC DATA

METHOD SYSTEM=SRKM, SET=SRKM01, DEFAULT

STREAM DATA

PROPERTY STREAM=S1, TEMPERATURE=800, PRESSURE=2200, PHASE=M, &

COMPOSITION(M,KGM/H)=2,1100/5,500

RXDATA

RXSET ID=REACTIONS

REACTION ID=1

STOICHIOMETRY 1,4/2,-2/4,1/5,-1

REACTION ID=2

STOICHIOMETRY 1,3/2,-1/3,1/5,-1

REACTION ID=3

STOICHIOMETRY 1,1/2,-1/3,-1/4,1

UNIT OPERATIONS

CONREACTOR UID=R1

FEED S1

PRODUCT M=S2

OPERATION ISOTHERMAL, DTFEED=-50, DP=100

RXCALCULATION MODEL=STOIC

RXSTOIC RXSET=REACTIONS

REACTION 1

BASE COMPONENT=5

CONVERSION 1

REACTION 2

CONVERSION 0

REACTION 3

CONVERSION 0

END

SIMULATION SCIENCES INC. R PAGE R-1

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM INPUT

THERMODYNAMIC DATA

==============================================================================

VLE K-VALUE DATA FOR SET 'SRKM01'

SRK SIMSCI PURE COMPONENT DATA

COMP CRITICAL CRITICAL ALPHA C1 C2 C3

TEMPERATURE PRESSURE TYPE

DEG C KPA

---- ---------- ---------- ----- ---------- ---------- ----------

1 -239.96 1313.00 6 1.2528 13.2690 0.0400

2 373.98 22055.00 6 0.3569 0.8743 2.4807

3 -140.23 3499.00 6 0.2079 0.8607 1.7188

4 31.06 7383.00 6 1.2341 1.3268 0.6499

5 -82.59 4599.00 6 0.5144 0.9903 1.0000

SRK SIMSCI INTERACTION PARAMETERS

KIJ = A(I,J) + B(I,J)/T + C(I,J)/T**2

I J KA(I,J) KB(I,J) KC(I,J) C(I,J) UNITS FROM

KA(J,I) KB(J,I) KC(J,I) C(J,I)

--- --- ---------- ---------- ---------- ---------- ----- ----

1 2 14.5760 -11494.20 1.838E+06 1.0000 DEG K SIMSCI SRKM BANK

-0.2000 0.00 0.00 1.0000

1 3 -0.1405 3.50 0.00 1.0000 DEG K SIMSCI SRKM BANK

-0.0244 0.00 0.00 1.0000

1 4 -0.4545 0.00 0.00 1.0000 DEG K SIMSCI SRKM BANK

-0.5696 0.00 0.00 1.0000

1 5 -0.7022 54.68 0.00 1.0000 DEG K SIMSCI SRKM BANK

-0.1693 0.00 0.00 1.0000

2 3 0.5000 0.00 0.00 1.0000 DEG K SIMSCI SRKM BANK

0.2357 -311.51 0.00 1.0000

2 4 0.2887 -31.05 0.00 0.7000 DEG K SIMSCI SRKM BANK

0.2774 -123.38 0.00 1.5000

2 5 0.1171 131.70 0.00 0.7606 DEG K SIMSCI SRKM BANK

1.7921 -1167.81 161363.00 1.2235

3 4 0.0500 0.00 0.00 1.0000 DEG K SIMSCI SRK BANK

0.0500 0.00 0.00 1.0000

3 5 0.0322 0.00 0.00 1.0000 DEG K SIMSCI SRK BANK

0.0322 0.00 0.00 1.0000

4 5 0.0933 0.00 0.00 1.0000 DEG K SIMSCI SRK BANK

0.0933 0.00 0.00 1.0000

SIMULATION SCIENCES INC. R PAGE R-2

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM INPUT

THERMODYNAMIC DATA

==============================================================================

THERMODYNAMIC SETS USED FOR EACH UNIT OPERATION

DEFAULT METHOD IS SRKM01

THERMODYNAMIC SET UNIT OPERATIONS

----------------- ---------------

SRKM01 R1

UNIT IDENTIFIER UNIT OPERATION THERMODYNAMIC SET

--------------- -------------- -----------------

R1 CONVERSION REACTOR SRKM01

SIMULATION SCIENCES INC. R PAGE R-3

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM INPUT

THERMODYNAMIC DATA

==============================================================================

THERMODYNAMIC METHODS USED FOR EACH SET

THERMODYNAMIC SET SRKM01 (DEFAULT)

PROPERTY METHOD

-------- ------

KVALUE(VLE) SRK-MODIFIED-PANAGIOTOPOULOS-REID

KVALUE(LLE) UNSPECIFIED

KVALUE(SLE) UNSPECIFIED

LIQUID ENTHALPY SRK-MODIFIED-PANAGIOTOPOULOS-REID

VAPOR ENTHALPY SRK-MODIFIED-PANAGIOTOPOULOS-REID

LIQUID DENSITY API

VAPOR DENSITY SRK-MODIFIED-PANAGIOTOPOULOS-REID

LIQUID ENTROPY SRK-MODIFIED-PANAGIOTOPOULOS-REID

VAPOR ENTROPY SRK-MODIFIED-PANAGIOTOPOULOS-REID

LIQUID VISCOSITY IDEAL

VAPOR VISCOSITY IDEAL

LIQUID CONDUCTIVITY IDEAL

VAPOR CONDUCTIVITY IDEAL

SURFACE TENSION IDEAL

LIQUID DIFFUSIVITY UNSPECIFIED

SIMULATION SCIENCES INC. R PAGE H-1

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM CALCULATION

HISTORY 12/04/14

==============================================================================

*** PROBLEM SOLUTION BEGINS

FEED FLASH COMPLETE

UNIT 1 SOLVED - 'R1 '

*** PROBLEM SOLUTION REACHED

*** THIS RUN USED 2.00 PRO/II SIMULATION UNITS

*** RUN STATISTICS

STARTED 14:44:39 12/04/14 NO ERRORS

FINISHED 14:44:39 12/04/14 NO WARNINGS

RUN TIMES NO MESSAGES

INTERACTIVE 0 MIN, 0.00 SEC

CALCULATIONS 0 MIN, 0.06 SEC

TOTAL 0 MIN, 0.06 SEC

SIMULATION SCIENCES INC. R PAGE I-1

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

INDEX 12/04/14

==============================================================================

PAGE CONTENTS

------ ----------------------------------------------------------------

1 COMPONENT DATA

2 CALCULATION SEQUENCE AND RECYCLES

2 SEQUENCE MAP

3 PLANT MATERIAL BALANCE

CONVERSION REACTOR SUMMARY

4 UNIT 1, 'R1'

5 STREAM MOLAR COMPONENT RATES

6 STREAM MOLAR COMPONENT FRACTIONS

7 STREAM MOLAR COMPONENT PERCENTS

8 STREAM WEIGHT COMPONENT RATES

9 STREAM WEIGHT COMPONENT FRACTIONS

10 STREAM WEIGHT COMPONENT PERCENTS

11 STREAM SUMMARY

SIMULATION SCIENCES INC. R PAGE P-1

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

COMPONENT DATA 12/04/14

==============================================================================

COMPONENT COMP. TYPE PHASE MOL. WEIGHT DENSITY

KG/M3

--------------------- ----------- ----------- ----------- -----------

1 H2 LIBRARY VAP/LIQ 2.016 70.565

2 H2O LIBRARY VAP/LIQ/SOL 18.015 999.014

3 CO LIBRARY VAP/LIQ/SOL 28.010 790.314

4 CO2 LIBRARY VAP/LIQ/SOL 44.010 816.427

5 METHANE LIBRARY VAP/LIQ/SOL 16.043 299.704

COMPONENT NBP CRIT. TEMP. CRIT. PRES. CRIT. VOLM.

C C KPA M3/KG-MOL

--------------------- ----------- ----------- ----------- -----------

1 H2 -252.760 -239.960 1313.000 0.0641

2 H2O 100.000 373.980 22055.000 0.0559

3 CO -191.450 -140.230 3499.000 0.0944

4 CO2 -78.480 31.060 7383.000 0.0940

5 METHANE -161.490 -82.586 4599.000 0.0986

COMPONENT ACEN. FACT. HEAT FORM. G FORM.

KJ/KG-MOL KJ/KG-MOL

--------------------- ----------- ----------- -----------

1 H2 -0.21599 0.00 0.00

2 H2O 0.34486 -241814.00 -228590.00

3 CO 0.04816 -110530.00 -137150.00

4 CO2 0.22362 -393510.00 -394370.00

5 METHANE 0.01155 -74520.00 -50490.00

COMPONENT DATABANK(S) USED

--------------------- ---------------------

1 H2 SIMSCI

2 H2O SIMSCI

3 CO SIMSCI

4 CO2 SIMSCI

5 METHANE SIMSCI

SIMULATION SCIENCES INC. R PAGE P-2

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

CALCULATION SEQUENCE AND RECYCLES 12/04/14

==============================================================================

CALCULATION SEQUENCE

SEQ UNIT ID UNIT TYPE

--- ------------ ----------

1 R1 CONV REAC

SEQUENCE MAP

SEQ DESCRIPTION

---- -----------------------------------------

1 CONV REAC 'R1'

SIMULATION SCIENCES INC. R PAGE P-3

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

PLANT MATERIAL BALANCE 12/04/14

==============================================================================

FEED STREAMS: S1

PRODUCT STREAMS: S2

OVERALL PLANT MOLAR BALANCE

---------------- KG-MOL/HR ---------------- PERCENT

COMPONENT FEED +REACTION -PRODUCT =DEVIATION DEV

--------------------- ---------- ---------- ---------- ---------- -------

1 H2 0.000 1999.444 1999.444 0.000 0.00

2 H2O 1100.000 -999.722 100.278 0.000 0.00

3 CO 0.000 0.000 0.000 0.000 0.00

4 CO2 0.000 499.861 499.861 0.000 0.00

5 METHANE 500.000 -499.861 0.139 0.000 0.00

TOTAL 1600.000 999.722 2599.722 0.000 0.00

OVERALL PLANT MASS BALANCE

------------------ KG/HR ------------------ PERCENT

COMPONENT FEED +REACTION -PRODUCT =DEVIATION DEV

--------------------- ---------- ---------- ---------- ---------- -------

1 H2 0.00 4030.64 4030.64 0.00 0.00

2 H2O 19816.81 -18010.28 1806.53 0.00 0.00

3 CO 0.00 0.00 0.00 0.00 0.00

4 CO2 0.00 21998.79 21998.79 0.00 0.00

5 METHANE 8021.38 -8019.15 2.23 0.00 0.00

TOTAL 27838.19 0.00 27838.19 0.00 0.00

SIMULATION SCIENCES INC. R PAGE P-4

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

CONVERSION REACTOR SUMMARY 12/04/14

==============================================================================

UNIT 1, 'R1'

OPERATING CONDITIONS

REACTOR TYPE ISOTHERMAL REACTOR

DUTY, M*KJ/HR 91.3983

TOTAL HEAT OF REACTION AT 25.00 C, M*KJ/HR 82.3189

INLET OUTLET

----------- -----------

FEED S1

VAPOR PRODUCT S2

TEMPERATURE, C 800.00 750.00

PRESSURE, KPA 2200.0000 2100.0000

REACTION DATA

--------- RATES, KG-MOL/HR ---------- FRACTION

COMPONENT FEED CHANGE PRODUCT CONVERTED

------------------ ----------- ----------- ----------- -----------

1 H2 0.0000 1999.4444 1999.4444

2 H2O 1100.0000 -999.7222 100.2778 0.9088

4 CO2 0.0000 499.8611 499.8611

5 METHANE 500.0000 -499.8611 0.1389 0.9997

TOTAL 1600.0000 999.7222 2599.7222

KG-MOL/HR FRACTION

BASE COMPONENT REACTION CONVERTED CONVERTED(1)

------------------ ----------- ----------- ------------

5 METHANE 1 500.0000 1.0000

? NO-BASE-CMPNT 2 N/A N/A

? NO-BASE-CMPNT 3 N/A N/A

(1) FRACTION CONVERTED BASED ON AMOUNT IN FEED

REACTOR MASS BALANCE

----------- Rates, KG/HR ------------ Fraction

Component Feed Change Product Converted

-------------------- ----------- ----------- ----------- -----------

1 H2 0.0000 4030.6403 4030.6403

2 H2O 19816.8077 -18010.2755 1806.5322 0.9088

4 CO2 0.0000 21998.7875 21998.7875

5 METHANE 8021.3804 -8019.1523 2.2282 0.9997

TOTAL 27838.1882 0.0000 27838.1882

SIMULATION SCIENCES INC. R PAGE P-5

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM MOLAR COMPONENT RATES 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

FLUID RATES, KG-MOL/HR

1 H2 0.0000 1999.4444

2 H2O 1100.0000 100.2778

3 CO 0.0000 0.0000

4 CO2 0.0000 499.8611

5 METHANE 500.0000 0.1389

TOTAL RATE, KG-MOL/HR 1600.0000 2599.7222

TEMPERATURE, C 800.0000 750.0000

PRESSURE, KPA 2200.0000 2100.0000

ENTHALPY, M*KJ/HR 106.4262 74.8854

MOLECULAR WEIGHT 17.3989 10.7081

MOLE FRAC VAPOR 1.0000 1.0000

MOLE FRAC LIQUID 0.0000 0.0000

SIMULATION SCIENCES INC. R PAGE P-6

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM MOLAR COMPONENT FRACTIONS 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

FLUID MOLAR FRACTIONS

1 H2 0.0000 0.7691

2 H2O 0.6875 0.0386

3 CO 0.0000 0.0000

4 CO2 0.0000 0.1923

5 METHANE 0.3125 5.3425E-05

TOTAL RATE, KG-MOL/HR 1600.0000 2599.7222

TEMPERATURE, C 800.0000 750.0000

PRESSURE, KPA 2200.0000 2100.0000

ENTHALPY, M*KJ/HR 106.4262 74.8854

MOLECULAR WEIGHT 17.3989 10.7081

MOLE FRAC VAPOR 1.0000 1.0000

MOLE FRAC LIQUID 0.0000 0.0000

SIMULATION SCIENCES INC. R PAGE P-7

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM MOLAR COMPONENT PERCENTS 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

FLUID MOLAR PERCENTS

1 H2 0.0000 76.9099

2 H2O 68.7500 3.8572

3 CO 0.0000 0.0000

4 CO2 0.0000 19.2275

5 METHANE 31.2500 5.3425E-03

TOTAL RATE, KG-MOL/HR 1600.0000 2599.7222

TEMPERATURE, C 800.0000 750.0000

PRESSURE, KPA 2200.0000 2100.0000

ENTHALPY, M*KJ/HR 106.4262 74.8854

MOLECULAR WEIGHT 17.3989 10.7081

MOLE FRAC VAPOR 1.0000 1.0000

MOLE FRAC LIQUID 0.0000 0.0000

SIMULATION SCIENCES INC. R PAGE P-8

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM WEIGHT COMPONENT RATES 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

FLUID RATES, KG/HR

1 H2 0.0000 4030.6403

2 H2O 19816.8077 1806.5322

3 CO 0.0000 0.0000

4 CO2 0.0000 21998.7875

5 METHANE 8021.3804 2.2282

TOTAL RATE, KG/HR 27838.1882 27838.1882

TEMPERATURE, C 800.0000 750.0000

PRESSURE, KPA 2200.0000 2100.0000

ENTHALPY, M*KJ/HR 106.4262 74.8854

MOLECULAR WEIGHT 17.3989 10.7081

WEIGHT FRAC VAPOR 1.0000 1.0000

WEIGHT FRAC LIQUID 0.0000 0.0000

SIMULATION SCIENCES INC. R PAGE P-9

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM WEIGHT COMPONENT FRACTIONS 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

FLUID WEIGHT FRACTIONS

1 H2 0.0000 0.1448

2 H2O 0.7119 0.0649

3 CO 0.0000 0.0000

4 CO2 0.0000 0.7902

5 METHANE 0.2881 8.0040E-05

TOTAL RATE, KG/HR 27838.1882 27838.1882

TEMPERATURE, C 800.0000 750.0000

PRESSURE, KPA 2200.0000 2100.0000

ENTHALPY, M*KJ/HR 106.4262 74.8854

MOLECULAR WEIGHT 17.3989 10.7081

WEIGHT FRAC VAPOR 1.0000 1.0000

WEIGHT FRAC LIQUID 0.0000 0.0000

SIMULATION SCIENCES INC. R PAGE P-10

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM WEIGHT COMPONENT PERCENTS 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

FLUID WEIGHT PERCENTS

1 H2 0.0000 14.4788

2 H2O 71.1857 6.4894

3 CO 0.0000 0.0000

4 CO2 0.0000 79.0238

5 METHANE 28.8143 8.0040E-03

TOTAL RATE, KG/HR 27838.1882 27838.1882

TEMPERATURE, C 800.0000 750.0000

PRESSURE, KPA 2200.0000 2100.0000

ENTHALPY, M*KJ/HR 106.4262 74.8854

MOLECULAR WEIGHT 17.3989 10.7081

WEIGHT FRAC VAPOR 1.0000 1.0000

WEIGHT FRAC LIQUID 0.0000 0.0000

SIMULATION SCIENCES INC. R PAGE P-11

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM SUMMARY 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

----- TOTAL STREAM -----

RATE, KG-MOL/HR 1600.000 2599.722

K*KG/HR 27.838 27.838

STD LIQ RATE, M3/HR 46.601 85.881

TEMPERATURE, C 800.000 750.000

PRESSURE, KPA 2200.000 2100.000

MOLECULAR WEIGHT 17.399 10.708

ENTHALPY, M*KJ/HR 106.426 74.885

KJ/KG 3823.031 2690.027

MOLE FRACTION LIQUID 0.0000 0.0000

REDUCED TEMP (KAYS RULE) 2.1274 9.3876

PRES (KAYS RULE) 0.1325 0.6402

ACENTRIC FACTOR 0.2407 -0.1098

WATSON K (UOPK) 11.860 14.199

STD LIQ DENSITY, KG/M3 597.377 324.150

SPECIFIC GRAVITY 0.5980 0.3245

API GRAVITY 105.135 304.596

-------- VAPOR ---------

RATE, KG-MOL/HR 1600.000 2599.722

K*KG/HR 27.838 27.838

K*M3/HR 6.506 10.583

NORM VAP RATE(1), K*M3/HR 35.862 58.270

SPECIFIC GRAVITY (AIR=1.0) 0.601 0.370

MOLECULAR WEIGHT 17.399 10.708

ENTHALPY, KJ/KG 3823.031 2690.027

CP, KJ/KG-C 3.050 3.307

DENSITY, KG/K*M3 4279.048 2630.462

Z (FROM DENSITY) 1.0025 1.0049

TH COND, W/M-K 0.13139 0.28721

VISCOSITY, PAS 3.72394E-05 3.18830E-05

KVIS (VISC/DENS), CSTOKE 8.7027 12.1207

(1) NORMAL VAPOR VOLUME IS 22.414 M3/KG-MOLE (273.15 K AND 1 ATM)

SIMULATION SCIENCES INC. R PAGE P-12

PROJECT PRO/II VERSION 8.3 ELEC V7.0

PROBLEM OUTPUT

STREAM SUMMARY 12/04/14

==============================================================================

STREAM ID S1 S2

NAME

PHASE VAPOR VAPOR

THERMO ID SRKM01 SRKM01

-------- LIQUID --------

RATE, KG-MOL/HR N/A N/A

K*KG/HR N/A N/A

M3/HR N/A N/A

GAL/MIN N/A N/A

STD LIQ RATE, M3/HR N/A N/A

SPECIFIC GRAVITY (H2O=1.0) N/A N/A

MOLECULAR WEIGHT N/A N/A

ENTHALPY, KJ/KG N/A N/A

CP, KJ/KG-C N/A N/A

DENSITY, KG/M3 N/A N/A

Z (FROM DENSITY) N/A N/A

SURFACE TENSION, N/M N/A N/A

THERMAL COND, W/M-K N/A N/A

VISCOSITY, PAS N/A N/A

KVIS (VISC/DENS), CSTOKE N/A N/A