- •Thermodynamics of the
- •The first law of thermodynamics as applied to the atmosphere
- •Energy equation
- •Ideal Gas
- •dui cvdTi
- •Adiabatic process
- •Dry adiabatic lapse rate
- •Polytropic processes
- •Potential temperature
- •2. Potential temperature determines total amount of energy.
- •Criterion of the atmosphere stability
- •Potential temperature decreases with height in unstable atmosphere or if potential temperature decreases
- •Theoretical support of the reasoning above
- •All above refers to the dry air (non-saturated air)
- •Adiabatic processes in moist but non-saturated air
Adiabatic processes in moist but non-saturated air
Suppose, a unit of non-saturated mass of air get some amount of
energy dq.
dq dud.a. duw.a. dw
dud.a. 1 s cv.d.dTi duw.a. scv.w.dTi
S denotes a fraction of water vapor
сv.a. and сv.a. are specific heat capacities of the dry air and water vapor respectively.
|
|
|
|
|
Pv |
R 1 s |
|
R |
s T RT |
|||||||
|
dq 1 s c |
sc |
dT Pdv |
|
||||||||||||
|
|
|
v.d. |
|
v.w. |
i |
|
i |
i |
c |
|
w |
|
i |
i |
|
|
|
|
|
|
|
|
|
|
|
Equation of state for moist, non- |
||||||
|
Pdvi |
Rc 1 s Rws dTi |
vidP |
|
saturated air |
|
|
|||||||||
|
|
|
dP |
cv R cp |
||||||||||||
dq 1 s c |
sc |
|
|
|
|
|
|
RT |
|
|
i |
|||||
|
|
|
|
|
|
|
|
|
||||||||
dT R 1 s R s dT v dPi |
|
|
||||||||||||||
|
|
v.d. |
|
v.w. |
i c |
|
|
w |
i |
i |
|
P |
vi |
|
RT |
|
|
|
|
|
|
P |
|||||||||||
|
|
|
|
|
|
|
|
|||||||||
|
dq 1 s cp. scp dTi RTi |
dP |
|
|
|
|
|
|
|
|
||||||
|
|
|
|
|
|
|
|
|
21 |
|||||||
|
|
|
|
|
|
|
P |
|
|
|
|
|
|
|
|
|
|
Rc |
287 |
J kg K |
|
|
cp.d 1005 J kg K |
cp.w 1864 J kg K |
|||||||||||||||
|
R |
461 J |
kg K |
|
|
cv.d. 718 |
J |
kg K |
|
|
|
|
J kg K |
|||||||||
|
|
w |
|
|
|
|
|
cv.w. 1409 |
|
|||||||||||||
|
|
|
|
|
|
1 0,04 1005 0,04 1864 1039 J |
|
|
|
|||||||||||||
|
|
smax 0,04 |
|
|
|
kgK |
cp.m. |
|||||||||||||||
For practical purposes |
|
g |
|
9,81 |
|
0,95 K |
100m |
1K |
100m |
|
||||||||||||
cp.m |
|
|
||||||||||||||||||||
|
|
we may adopt |
|
|
|
a |
1039 |
|
|
|
|
|||||||||||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|||
|
R R 287 J |
kgK |
|
|
R 1 0,04 287 0,04 461 294 J |
|
|
|||||||||||||||
|
|
|
c |
|
|
|
kgK |
|||||||||||||||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
||
cp cp.d 1005 J |
kgK |
|
Conclusion |
|
|
|
|
|
|
|
||||||||||||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
||||||||
At adiabatic ascent, the temperature of a moist, non-saturated parcel of air varies, practically, in the same way as a dry parcel does.
The dry adiabat is a curve of state for the moist, non-saturated air too.
22
