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Файл:Chemical Engineering of Natural Fuels and Carbon Materials. Study Guide
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Continuation of Appendix1
Hydrocarbon
Formula
Phase
∆Н
о
298
,
kJ/mole
∆G
о
298
,
kJ/mole
2- Methylhexane
3 - Methylhexane
3 - Ethypentane
2,2- Dimethylpentane
2,3- Dimethylpentane
2,4- Dimethylpentane
3,3- Dimethylpentane
2,2,3 – Trimethylbutane
Styrene
Ethylbenzene
1,2- Xylene
(O- xylene)
1,3 - Xylene
(M - xylene)
1,4- Xylene
(P- xylene)
1 - octyne
Cyclooctane
n-Propylcyclopentane
Ethylcyclohexane
1,1- Dimethylcyclohexane
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С8Н
8
С8Н
10
С8Н
10
С8Н
10
С8Н
10
С8Н
14
С8Н
16
С8Н
16
С8Н
16
С8Н
16
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
g.
l.
g.
l.
g.
l.
g.
l.
–195.254
–230.157
–192.572
–227.727
–189.975
–225.296
–206.525
–239.039
–199.528
–233.844
–202.377
–235.352
–201.832
–234.933
–205.142
–237.280
+147.572
+104.038
+29.833
–12.474
+19.023
–24.474
+17.263
–25.454
+17.975
–24.461
+82.543
–125.951
–169.360
–148.284
–189.430
–171.999
–212.517
–181.259
–219.179
+3.226
–2.849
+4.609
–1.634
+1.077
–4.358
+0.084
–4.818
+0.670
–5.321
+3.017
–2.053
+2.640
–2.891
+4.274
–0.712
+214.109
+202.670
+130.762
+119.893
+122.252
+110.490
+119.017
+107.809
+121.309
+110.239
+235.436
+90.085
+77.934
+52.626
+42.403
+39.302
+29.162
+35.280
+26.565
81
Continuation of Appendix1
Hydrocarbon
Formula
Phase
∆Н
о
298
,
kJ/mole
∆G
о
298
,
kJ/mole
1 - Octene
n- Octane
2- Methylheptane
3 - Methylheptane
4- Methylheptane
3 - Ethylhexane
2,2- Dimethylhexane
2,3- Dimethylhexane
2,4- Dimethylhexane
2,5- Dimethylhexane
3,3- Dimethylhexane
3,4- Dimethylhexane
2- Methyl -3- etilpentan
3 -Methyl -3- etilpentan
2,2,3 - trimethylpentane
2,2,4 - trimethylpentane
( Iso-octane )
2,3,3 – Trimethylpentane
2,3,4- Trimethylpentane
С8Н
16
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
g.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
–83.046
–208.746
–250.311
–215.785
–255.506
–212.936
–252.825
–212.391
–252.112
–211.176
–250.897
–225.045
–262.420
–214.235
–253.076
–219.724
–257.559
–222.950
–260.869
–220.436
–258.020
–213.313
–252.364
–211.511
–250.101
–215.282
–253.327
–220.436
–257.434
–224.458
–259.654
–216.749
–254.040
–217.754
–255.506
+104.582
+16.551
+6.620
+12.821
+3.855
+13.785
+4.693
+16.760
+7.793
+16.551
+7.542
+10.726
+3.017
+17.724
+9.092
+11.732
+3.729
+10.475
+2.472
+13.282
+5.154
+17.347
+8.506
+21.285
+12.696
+19.944
+11.271
+17.137
+9.302
+13.701
+6.914
+18.939
+10.643
+18.939
+10.643
82
Continuation of Appendix1
Hydrocarbon
Formula
Phase
∆Н
о
298
,
kJ/mole
∆G
о
298
,
kJ/mole
2,2,3,3 - Tetramethylbutane
1 -Phenyl -2- propene
(α- Methylstyrene )
1 -Methyl -2- ethenylbenzol
(O- Methylstyrene )
1 -Methyl -3- ethenylbenzol
(M - Methylstyrene )
1 -Methyl -2- ethenylbenzol
(P- Methylstyrene )
n-Propylbenzene
Isopropylbenzene
(Cumene )
1 -Methyl -2- ethylbenzene
1 -Methyl -4- ethylbenzene
1,2,3- Trimethylbenzene
1,2,4 - Trimethylbenzene
1,3,5 - Trimethylbenzene
n Butyltsiklopentan
n Propylcyclohexane
n-Nonane
3,3 – Diethylpentane
2,2,3,3 - Tetramethylpentane
2,2,3,4 - Tetramethylpentane
2,2,4,4 - Tetramethylpentane
2,3,3,4 - Tetramethylpentane
С8Н
18
С9Н
10
С9Н
10
С9Н
10
С9Н
10
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
18
С9Н
18
С9Н
20
С9Н
20
С9Н
20
С9Н
20
С9Н
20
С9Н
20
g.
l.
g.
g.
g.
g.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
g.
l.
l.
l.
l.
l.
l.
–226.218
–269.124
+113.130
+118.577
+115.644
+114.806
+7.835
–38.456
+3.939
–41.263
+1.215
–46.551
–3.268
–49.945
–9.595
–58.714
–13.953
–61.949
–16.090
–63.621
–168.522
–214.612
+193.578
–238.746
–229.361
–275.870
–275.870
–278.761
–278.174
–280.479
–278.426
+22.081
+13.115
+208.830
+214.277
+209.584
+210.506
+137.474
+124.024
+137.172
+124.477
+131.243
+117.207
+126.877
+113.302
+124.984
+110.532
+117.190
+106.874
+118.116
+103.954
+61.467
+47.389
+34.442
+24.972
+16.090
-
-
-
-
-
83
Ending of Appendix1
Hydrocarbon
Formula
Phase
∆Н
о
298
,
kJ/mole
∆G
о
298
,
kJ/mole
Naphthalene
n- Butylbenzene
1 -Methyl -4-
Isopropylbenzene
1,2,4,5 - Tetramethylbenzene
1,2,3,5 – Tetramethylbenzene
1,2,3,4 - Tetramethylbenzene
n-Pentylcyclopentane
n-Butylcyclohexane
n- Decane
2- Methylnonane
5 - Methylnonane
2 -Methylnaphthalene
С10Н
8
С10Н
14
С10Н
14
С10Н
14
С10Н
14
С10Н
14
С10Н
20
С10Н
20
С10Н
22
С10Н
22
С10Н
22
С11Н
10
g.
s.
g.
l.
l.
g.
s.
g.
l.
g.
g.
g.
l.
g.
l.
l.
l.
s.
+152.223
+78.563
–13.827
–64.023
–78.479
–45.336
–98.800
–44.875
–98.634
–41.984
–189.179
–213.481
–263.593
–250.017
–301.471
–313.161
–311.233
+33.478
+224.706
+201.539
+144.890
+129.848
+119.876
+119.637
+117.823
+118.900
+98.758
+123.588
+69.889
+56.523
+40.601
+33.394
+17.263
+7.333
+8.129
+181.427
84
APPENDIX 2
Hydrocarbon
Formula
∆Gо, kJ/mol at temperature, К
300
400
500
600
700
800
900
1000
1100
Methane
Ethyne (acetylene )
Ethene ( ethylene)
Ethane
Propyne ( methylacetylene )
Propadiene ( allene )
Propene (propylene )
Cyclopropane
Propane
1 - Butyne
2 -Butyne
1.2- Butadiene
1.3 - Butadiene
1 - Butene ( Butylene )
Isobutylene
Cyclobutane
n- Butane
Isobutane
1.2- pentadiene
СН
4
С2Н
2
С2Н
4
С2Н
6
С3Н
4
С3Н
4
С3Н
6
С3Н
6
С3Н
8
С4Н
6
С4Н
6
С4Н
6
С4Н
6
С4Н
8
С4Н
8
С4Н
8
С4Н
10
С4Н
10
С5Н
8
-50.72
209.40
68.32
-32.62
194.76
202.71
63.06
104.78
-23.22
202.59
185.95
198.94
151.13
72.03
58.62
110.75
-16.51
-20.24
211.09
-42.10
203.54
74.06
-14.44
198.13
206.53
77.98
122.73
4.99
215.58
199.78
211.76
165.34
97.33
84.68
139.90
21.33
19.15
233.68
-32.85
197.75
80.64
4.89
202.06
210.88
94.07
141.92
34.48
229.49
214.61
225.51
180.38
123.81
112.21
170.74
60.92
60.29
257.43
-23.00
192.05
87.65
25.01
206.38
215.70
110.87
161.86
64.95
243.98
230.20
239.88
196.01
151.13
140.57
202.59
101.73
102.57
281.90
-12.78
186.44
95.01
45.67
211.01
220.73
128.17
182.22
96.08
258.94
246.29
254.71
212.01
179.04
169.57
235.10
143.26
158.13
306.75
-23.05
180.92
102.61
66.70
215.84
225.97
145.85
202.96
127.59
274.19
262.71
269.84
228.27
207.20
198.98
268.03
185.24
189.05
332.14
84.22
175.49
110.42
87.99
220.09
231.41
163.83
223.96
159.43
289.70
279.47
285.21
244.70
235.69
228.69
301.26
227.68
232.92
357.87
19.32
170.13
118.36
109.48
226.05
236.74
181.97
244.95
191.40
305.37
296.40
300.72
261.29
264.26
258.61
334.61
270.26
276.92
383.51
30.25
164.83
126.37
131.06
231.29
242.43
200.20
265.94
223.49
321.08
313.41
316.26
277.88
292.88
288.61
367.96
312.87
321.04
409.36
Free energies of hydrocarbon vapors at different temperatures
85
Continuation of Appendix 2
Hydrocarbon
Formula
∆Gо, kJ/mol at temperature, К
300
400
500
600
700
800
900
1000
1100
Cis - 1. 3- pentadiene
Trans - 1. 3- pentadiene
1.4- pentadiene
2.3- pentadiene
3 -Methyl -1.2 -butadiene
2- Methyl - 1.3- butadiene
(Isoprene)
Cyclopentene
1 - Pentene
Cis -2- pentene
trans -2- pentene
2- Methyl -1- butene
3 -Methyl -1- butene
2- Methyl -2- butene
Cyclopentane
n- Pentane
2- Methylbutane
( Isopentane )
2.2- Dimethylpropane
Benzene
С5Н
8
С5Н
8
С5Н
8
С5Н
8
С5Н
8
С5Н
8
С5Н
8
С5Н
10
С5Н
10
С5Н
10
С5Н
10
С5Н
10
С5Н
10
С5Н
10
С5Н
12
С5Н
12
С5Н
12
С6Н
6
146.52
147.36
170.87
206.61
199.32
146.52
111.45
80.03
72.57
70.81
65.62
75.55
60.42
39.39
-7.54
-13.95
-14.33
130.13
170.16
171.25
193.41
230.20
223.29
170.87
138.86
115.18
107.35
106.51
100.69
111.54
96.03
79.86
40.22
34.44
37.67
146.68
195.25
196.55
217.25
254.92
248.51
196.30
168.10
151.76
144.18
143.72
137.52
148.75
133.45
122.56
90.13
84.89
91.72
164.42
221.11
222.45
241.80
280.69
274.28
222.49
198.48
189.43
182.18
182.01
175.35
187.00
172.13
166.68
141.45
136.72
146.99
182.95
247.59
248.80
266.74
307.00
300.72
249.14
229.70
227.73
220.90
221.02
213.94
226.01
211.55
211.68
193.58
189.35
203.05
202.00
274.19
275.45
291.88
333.69
327.78
276.08
261.33
266.40
260.24
260.37
252.95
265.39
251.61
257.27
246.25
242.52
259.49
221.39
301.60
302.43
317.64
360.80
354.89
303.36
293.38
305.45
299.92
300.17
292.29
305.12
292.00
303.23
299.42
296.15
316.30
241.08
328.66
329.75
343.33
387.91
382.34
330.55
325.65
344.59
339.81
340.02
331.85
345.05
332.69
349.36
352.71
349.91
373.25
260.91
356.02
356.90
369.22
415.31
409.61
357.95
357.99
383.80
379.74
380.00
371.44
384.98
373.41
395.58
406.05
403.79
430.23
280.81
86
Continuation of Appendix 2
Hydrocarbon
Formula
∆Gо, kJ/mol at temperature, К
300
400
500
600
700
800
900
1000
1100
1 – Hexyne
Cyclohexene
1 - Hexene
2- Methyl -1- pentene
3 -Methyl -1- pentene
4 -Methyl -1- pentene
2- Methyl -2- pentene
2 -Ethyl -1- butene
2.3- Dimethyl -1- butene
3.3-Dimethyl -1- butane
2.3- Dimethyl -2- butene
Cyclohexane
Methylcyclopentane
n- Hexane
2-Methylpentane
3 - Methylpentane
2.2- Dimethylbutane
2.3- Dimethylbutane
Methylbenzene (toluene )
1 - Heptene
Ethylcyclopentane
С6Н
10
С6Н
10
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
12
С6Н
14
С6Н
14
С6Н
14
С6Н
14
С6Н
14
С7Н
8
С7Н
14
С7Н
14
219.14
105.92
88.53
73.99
86.27
86.52
69.30
78.39
73.87
82.67
70.06
32.72
36.70
0.754
-4.022
-1.131
-8.841
11.40
122.91
97.12
45.71
251.94
144.97
133.66
118.99
131.57
132.82
114.81
124.02
120.25
130.73
116.90
86.57
86.27
58.45
54.47
57.44
51.91
57.03
148.28
152.22
105.09
286.18
185.87
180.51
165.92
177.66
180.59
162.57
171.37
168.44
181.43
166.34
142.75
138.27
118.58
115.35
118.45
115.06
119.46
175.19
209.33
167.22
321.50
227.85
228.65
214.11
224.58
229.61
211.60
219.98
217.88
232.55
217.04
200.53
191.82
180.25
177.78
181.01
179.58
183.44
203.12
267.95
231.08
357.49
270.59
277.59
262.71
272.35
279.89
261.46
269.84
268.16
285.34
268.58
259.15
246.33
242.94
241.05
244.53
245.24
248.38
231.73
327.49
295.94
393.82
313.66
326.90
312.57
320.12
330.59
311.74
319.70
318.44
337.71
320.95
318.27
301.39
306.21
304.78
308.68
311.11
314.00
260.77
387.45
361.43
430.69
357.07
376.68
362.44
367.88
378.36
362.85
370.40
369.56
390.51
373.75
377.64
356.86
370.02
368.93
373.16
377.39
379.91
290.18
447.95
427.63
467.69
400.56
426.58
412.72
415.65
432.41
413.97
421.09
420.68
444.14
426.54
437.02
412.55
433.96
433.29
437.94
444.31
446.19
319.78
508.58
493.96
504.64
443.97
476.53
-
-
-
-
-
-
-
-
496.18
468.32
498.02
498.19
503.26
510.93
512.35
348.45
569.21
560.45
87
Continuation of Appendix 2
Hydrocarbon
Formula
∆Gо, kJ/mol at temperature, К
300
400
500
600
700
800
900
1000
1100
1.1- dimethylcyclopentane
Methylcyclohexane
n- Heptane
2- Methylhexane
3 - Methylhexane
3 - Ethypentane
2.2- Dimethylpentane
2.3- Dimethylpentane
2.4- Dimethylpentane
3.3- Dimethylpentane
2.2.3 - Trimethylbutane
Ethenylbenzene (Styrene )
Ethylbenzene
1.2- Xylene
(O- Xylene)
1.3 - Xylene
(M - xylene)
1.4- Xylene
(P- Xylene)
1 - Octyne
С7Н
14
С7Н
14
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С7Н
16
С8Н
8
С8Н
10
С8Н
10
С8Н
10
С8Н
10
С8Н
14
40.14
28.45
9.344
4.441
5.824
11.90
1.341
1.886
4.274
3.897
5.573
214.53
131.39
122.89
119.62
121.95
236.36
101.65
91.51
76.84
72.61
73.62
80.78
72.32
70.52
74.62
73.91
77.60
237.74
166.51
158.73
155.07
157.91
289.07
165.84
157.17
147.24
143.47
144.14
152.56
145.85
142.04
147.82
146.73
152.43
262.34
203.44
196.23
192.35
195.77
343.87
231.87
224.37
219.35
216.08
216.54
226.34
221.32
215.49
222.87
221.40
228.86
287.73
241.54
235.07
230.86
234.89
400.15
298.71
292.46
292.59
285.55
289.99
301.43
298.29
290.12
299.04
297.15
306.33
313.71
280.40
274.65
270.22
274.88
457.25
365.91
361.01
366.42
364.15
363.99
376.85
375.26
365.24
375.68
373.33
384.18
340.06
319.71
314.71
310.09
315.40
514.91
433.71
429.85
440.91
438.82
438.23
452.98
452.86
440.70
452.49
449.75
463.12
366.75
359.41
355.22
350.41
356.39
573.23
501.75
498.74
515.58
513.40
512.39
528.36
529.20
516.04
529.07
525.97
541.73
393.52
399.32
395.93
390.96
397.62
631.64
569.92
567.45
590.29
-
-
-
-
-
-
-
620.12
462.28
439.28
436.72
431.57
331.18
690
88
Continuation of Appendix 2
Hydrocarbon
Formula
∆Gо, kJ/mol at temperature, К
300
400
500
600
700
800
900
1000
1100
n - Propylcyclopentane
Ethylcyclohexane
1.1- dimethylcyclohexane
1 - Octene
n- Octane
2- Methylheptane
3 - Methylheptane
4- Methylheptane
3 - Ethylhexane
2.2- Dimethylhexane
2.3- Dimethylhexane
2.4- Dimethylhexane
2.5- Dimethylhexane
3.3- Dimethylhexane
3.4- Dimethylhexane
2-methyl-3-ethylpentane
3 -methyl -3-ethylpentane
2.2.3 - Trimethylpentane
2.2.4 - Trimethylpentane
( Iso-octane )
С8Н
16
С8Н
16
С8Н
16
С8Н
16
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
С8Н
18
53.84
40.60
36.62
105.76
17.98
14.20
15.17
18.18
17.93
12.19
19.15
13.16
11.90
14.71
18.73
22.75
21.41
18.60
15.17
123.23
113.63
111.45
170.78
95.41
92.77
93.06
96.87
96.12
92.93
98.51
92.39
91.84
94.82
98.17
102.53
101.90
99.81
96.66
195.59
189.35
189.39
238.16
176.06
174.22
173.89
178.58
177.61
176.82
180.84
174.81
174.93
178.08
180.51
185.37
185.62
184.28
181.34
269.92
266.99
268.58
307.25
258.65
257.56
256.72
262.34
261.33
262.75
265.10
259.32
260.12
263.34
264.64
270.13
271.39
270.80
268.16
345.38
345.68
349.45
377.39
342.49
342.03
340.69
347.27
346.26
349.78
350.45
344.92
346.47
349.74
350.03
355.98
358.16
358.41
356.02
421.51
424.74
430.31
447.99
426.96
426.88
425.03
432.53
431.49
437.02
436.14
430.90
433.29
436.43
435.93
442.13
445.06
446.32
444.0
498.40
503.97
511.60
519.22
512.19
512.31
509.84
518.22
517.13
524.63
522.20
517.17
520.40
523.46
522.58
528.82
532.34
534.52
532.30
575.29
583.37
592.47
590.54
597.58
598.46
595.27
604.45
603.28
612.87
608.81
603.65
607.51
610.73
609.27
616.31
620.16
622.97
620.87
652.38
662.73
673.75
661.89
682.97
-
-
-
-
-
-
-
-
-
-
-
-
-
-
89
Continuation of Appendix 2
Hydrocarbon
Formula
∆Gо, kJ/mol at temperature, К
300
400
500
600
700
800
900
1000
1100
2.3.3 - Trimethylpentane
2.3.4 - Trimethylpentane
1 -Phenyl -2- propene
(α- Methylstyrene )
1-Methyl-2-ethenybenzene
(O- Methylstyrene )
1 -Methyl -3- ethenybenzene
(M - Methylstyrene )
1 -Methyl -2- ethenybenzene
(P- Methylstyrene )
n-Propyl benzene
Isopropylbenzene
(Cumene )
1 -Methyl -2- ethylbenzene
1 -Methyl -3- ethylbenzene
1 -Methyl -4- ethylbenzene
1.2.3- Trimethylbenzene
1.2.4 - Trimethylbenzene
1.3.5 - Trimethylbenzene
n - Butylcyclopentane
n - Propylcyclohexane
С8Н
18
С8Н
18
С9Н
10
С9Н
10
С9Н
10
С9Н
10
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
12
С9Н
18
С9Н
18
20.36
20.41
209.46
214.91
210.21
211.13
138.27
137.99
132.04
127.40
127.68
125.82
118.01
118.87
62.89
48.86
100.94
101.23
242.60
248.05
242.77
244.28
183.23
184.19
177.07
172.00
172.84
172.27
163.39
165.75
142.21
131.99
184.70
185.37
277.63
283.08
277.21
279.31
230.20
232.38
224.08
218.72
220.14
220.98
211.10
214.62
224.88
218.30
270.46
271.39
313.62
319.07
312.62
315.30
278.55
281.95
272.43
266.82
268.83
270.99
260.21
264.96
309.68
306.29
357.41
358.66
350.28
355.73
348.69
351.96
327.74
332.39
321.71
315.84
318.52
321.80
310.35
316.32
395.75
395.5
444.56
446.07
387.62
393.06
385.44
389.29
377.48
383.30
371.44
365.37
368.72
373.48
361.07
368.31
482.52
485.20
532.05
534.14
425.33
430.77
422.56
427.00
427.67
434.67
421.68
415.40
419.42
425.44
412.26
420.86
570.13
575.2
619.70
622.17
463.25
468.69
459.89
464.92
477.99
486.29
472.09
465.68
470.37
477.74
463.85
473.66
657.83
665.3
-
-
500.83
506.28
496.89
502.51
528.36
537.99
522.49
516.21
521.24
-
-
526.56
745.40
755.4
90
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