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Ministry of Education and Science The Republic of Kazakhstan S. Seifullin Kazakh agrotechnical university Department of chemistry and physics

Bank of exam questions (300)

On discipline General Chemistry

for students of technical specialties: 5B080600

1. What is the equivalent weight of the compound Ca3(PO4)2 (g-eq/mol)? Name it

1) 310 (calcium phosphate)

2) 155 (calcium monophosphate)

3) 51,6 (calcium phosphate)

4) 103,3 (calcium phosphide)

5) 77,5 (calcium phosphite)

2. What is the equivalent weight of the compound Fe(OH)3 (g-eq/mol)? Name it

1) 35,6 (trihydroxide iron)

2) 107 (hydroxide iron)

3) 53,5 (dihydroxide iron)

4) 26,75 (hydroxide iron (II))

5) 36,5 (trioxide iron)

3. What is the equivalent weight of the compound PbO2 (g-eq/mol)? Name it

1) 239 (lead dioxide)

2) 119,5 (lead oxide)

3) 59,75 (lead dioxide)

4) 264 (lead oxide (II))

5) 79,6 (lead dihydoxide)

4. What is the equivalent weight of the compound H3PO4 (g-eq/mol)? Name it

1) 98

2) 24,5

3) 115

4) 49

5) 32,6

5. What is the equivalent weight of the compound Al2(SO4)3 (g-eq/mol)? Name it

1) 57 (dialuminium trisulfate)

2) 342 (dialuminium trisulfite)

3) 114 (dialuminium trisulfide)

4) 85,5 (trialuminium disulfite)

5) 68,4 (aluminium trihydroxide)

6. What is the equivalent weight of the compound Na2SiO3 (g-eq/mol)? Name it

1) 122 (disodium carbonate)

2) 61 (disodium silicate)

3) 40,6 (sodium sulfate)

4) 30,5 (sodium sulfide)

5) 20,3 (disodium oxide)

7. What is the equivalent weight of the compound MnO3 (g-eq/mol)? Name it

1) 103 (magnesium oxide)

2) 51,5 (manganese oxide)

3) 17,16 (manganese trioxide)

4) 34,3 (mangenese dioxide)

5) 25,75 (trimangenese oxide

8. What is the equivalent weight of the compound NH4ОН (g-eq/mol)? Name it

1) 35 (ammonium hydroxide)

2) 17,5 (ammonium sulfate)

3) 7 (ammonium carbonate)

4) 8,75 (ammonium hydroxide)

5) 11,6 (potassium hydroxide)

9. What is the eqiuvalen weight of compound Н2SO4 (g-eq/mol)? Name it

1) 49 (sulfuric acid)

2) 98 (Sulfuric acid)

3) 32,6 (sulfurous acid)

4) 24,5 (thiosulfuric acid)

5) нет правильного ответа

10. How many degrees the temperature of the system should be increased by increasing the reaction rate by 81 times, if the temperature coefficient is equal to γ = 3?

1) 100С

2) 200С

3) 300С

4) 400С

5) 800С

11. How many times does the chemical reaction rate change at the temperature rise from 25oC to 75oC if the temperature coefficient is equal 3?

1) increases in 15 times

2) decreases in 15 times

3) decreases in 243 times

4) Increases in 243 times

5) increases in 27 times

12. How many times does the chemical reaction rate change at the temperature fall from 40oC if the temperature coefficient 4?

1) Decreases in 256 times

2) increases in 64 times

3) decreases in 16 times

4) increases in 16 times

5) decreases in 64 times

13. Write down the law of mass action for the given direct reaction:

1) V= [O2]

2) V= k[Na]4[O]2

3) V= [Na]4[O2]

4) V=k [Na]4 +[O2]

5) V= k[O2]

14. "When a system at equilibrium is subjected to change in concentration, temperature, volume, or pressure, then the system readjusts itself to (partially) counteract the effect of the applied change and a new equilibrium is established" This definition conforms to the law:

1) law of mass action

2) Vant-Hoff rule

3) Hess law

4) Le Châtelier's principle

5) Faraday law

15. Write down the law of mass action for the given direct reaction:

1) V= [SO2][CO]2

2) V= k[CO2]2

3) V= [S] [CO2]2

4) V= k[S] [CO2]2

5) V= [CO2]2

16. When the pressure increases and the concentration of hydrogen in the system: , the equilibrim will be shifts to ............

1) with increasing concentration of [H2] - to right, and pressure - to left

2) with increasing concentration of [H2] - to left, and pressure - to right

3) To right

4) to left

5) the equilibrim does not shift

17. When the temperature and the concentration of ammonium increases in the system: (∆H<O) , the equilibrim will be shifts to ............

1) To left

2) To right

3) the equilibrim does not shift

4) with increasing concentration of [NH3] - to left, and temperature - to right

5) with increasing concentration of [NH3] - to right, and temperature - to left

18. Heterogeneous reaction occurs between:

1) nitrogen and hydrogen

2) oxygen and hydrogen

3) Magnesium and oxygen

4) sulfur dioxide and oxygen

5) nitrogen dioxide and oxygen

19. Vant-Hoff rule is described by following equation:

1)

2)

3)

4)

5)

20. What is the osmotic pressure, in kilopascal of 0,1M benzene solution at Celsius?

1) 251,9kPa

2) 174,5kPa

3) 24,9kPa

4) 249,4kPa

5) 1055,6kPa

21. What is the osmotic pressure, in atmospheres of 2M ethanol solution at Celsius (R=0,082 L atm/mol K)?

1) 2,50 atm

2) 16,4 atm

3) 0,164 atm

4) 4539,4 kPa

5) 44,772 atm

22. A 4 gram of sugar dissolved in 1000 ml of solution. What is the osmotic pressure, in kilopascal of this solution at 20°С Celsius?

1) 6,371 kPa

2) 1,94 kPa

3) 34,57 kPa

4) 28,49 kPa

5) 300,50 kPa

23. What is the boiling point elevation of 2m formalin aqueous solution (ЕН2О= 0,52˚C)?

1) -0,52˚С

2) 1,04˚С

3) -1,04˚С

4) 101,04˚С

5) 100,52˚С

24. What is the freezing point of 1m glycerol aqueous solution (КН2О=1,86˚)?

1) -1,00˚С

2) -1,86˚С

3) - 3,72˚С

4) +1,86˚С

5) - 2,79˚С

25. 0,5 moles of sugar (C12H22O11) dissolved in 500 g of water. What is the freezing point of this solution (КН2О=1,86˚)?

1) 0˚С

2) -1,86˚С

3) -3,72˚С

4) -0,93˚С

5) +1,86˚С

26. What is the heat of reaction: :

-264,45 0 0 -393,5

1) +922,4 кДж/моль

2) +135,4 кДж/моль

3) -135,4 кДж/моль

4) -129,05 кДж/моль

5) -922,4 кДж/моль

27. What is the enthalpy change of the reaction:

+763 0 0 -786

1) -23,0 кДж/моль

2) +2335,0 кДж/моль

3) -809,0 кДж/моль

4) +809,0 кДж/моль

5) -2335,0 кДж/моль

28. What is the entropy change of the reaction (J/mol*K):

6 131 33 131

1) -27,0 Дж/моль*град

2) +22,0 Дж/моль*град

3) -825,0 Дж/моль*град

4) +825,0 Дж/моль*град

5) +27,0 Дж/моль*град

29. What is the change in Gibbs energy of reaction:

DG298 kL/mol -244,30 -137,15 0 -393,37

1) +11,92 кДж/моль

2) -11,92 кДж/моль

3) +286,22 кДж/моль

4) -286,22 кДж/моль

5) -123,18 кДж/моль

30. Choose substances that form aqueous solution with acidic medium (pH<7):

1) KBr

2) Na2SiO3

3) CuSO4

4) KNO3

5) KI

31. Which salt is hydrolyzed by cation?

1) ZnCl2

2) Na3PO4

3) Na2SiO3

4) Fe(CH3COO)2

5) KCl

32. The reaction of the salt with water, whereby the salt is dissociated and decomposed to form a weak electrolyte (weak acid or weak base) is called ...

1) Electrolysis

2) Hydrolysis

3) Corrosion

4) Osmosis

5) Dissosiation

33. What salt is not hydrolyzed?

1) Na2CO3

2) K2S

3) BaCl2

4) Pb(NO3)2

5) K3PO4

34. What salt aqueous solution will have alkaline medium (pH>7)?

1) MgSO4

2) FeSO4

3) Pb(NO3)2

4) К2S

5) Ag2SO4

35. Which salt is hydrolyzed by anion?

1) BaCl2

2) AgNO3

3) FeCl3

4) Pb(NO3)2

5) CH3COONa

36. Where does the acid base indicator - litmus gain of red colour?

1) Na3PO4

2) CuCl2

3) KNO3

4) KCl

5) Ba(NO3)2

37. Where does the acid base indicator phenolphthalein gain of crimson (purple) colour?

1) SnCl2

2) MgSO4

3) AgNO3

4) KI

5) Na2СO3

38. Weak basis and weak acid that form salt XA, if such ionic - molecular equation X+ + A- + H2O = XOH + HA correspond to its hydroysis. What salt is it?

1) NaNO3

2) BaCl2

3) AlCl3

4) CrCl3

5) NH4NO2

39. For an aqueous solution with pH=10, hydroxide ions concentration will be equal to.... (mol/L):

1) 10-10

2) 10-2

3) 10-9

4) 10-5

5) 10-4

40. For 0,01М sodium hydroxide aqueous solution (NaOH) its рH value will be equal:

1) 2

2) 12

3) 4

4) 10

5) 8

41. For an aqueous solution with pOH=5, hydrogen (H+) ions concentration will be equal to.... (mol/L):

1) 10-9

2) 10-5

3) 10-4

4) 10-2

5) 10-1

42. What is the pH value of the solution, with a content of [OH-] = 10-3 mol /L?

1) 3

2) 11

3) 5

4) 8

5) 9

43. What is the pOH of the solution, with a content of [H+] = 10-4 mol /L?

1) 9

2) 8

3) 6

4) 10

5) 4

44. What kind of water is obtained by passing the natural water through a system of cation and anion exchangers:

1) hardness

2) moderately hardness water

3) soft water

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