- •Describe the main types of primary electrochemical cells.
- •Construction and the reaction of zinc-manganese batteries with salt electrolyte.
- •Describe the main types of alkaline maganese-zinc cells.
- •4. Give examples of the secondary electrochemical cells.
- •5.Give the sketchy description of lead (acid) batteries construction.
- •Consider the difference between the nickel iron and nickel cadmium batteries.
- •7. Describe the main peculiarities of the lithium-ion batteries.
- •8. Give the description of requirements for battery performance for in electric vehicles.
- •9. Give the Classification of lead acid batteries. Describe the charge and discharge curves of lead acid batteries.
- •10. Describe the lithium-polymer batteries.
- •11. Various classifications of electrochemical cells. Give example.
- •12. Give the description of fuel elements.
- •13. Nickel–metal hydride battery.
- •14. Define the characteristics, which allow to compare electrochemical cells with each other.
- •16. Consider processes what is occur on the negative electrode during discharge and charge lead battery?
- •17. What are the curves shown in this figure? Compare them and make assumtions about their nature?
- •18. Which batteries provide high discharge current, nickel cadmium or lithium? Give examples.
- •19. Draw the diagram of the apparatus of a cylindrical lithium-ion battery.
- •20. Draw the diagram of the apparatus of a Lead batteries.
- •21. What the curves shown in this figure? Compare them and make assumptions about their nature
- •22. Draw a typical curve of self-discharge nickel-cadmium batteries.
- •23. Draw on the one graph any possible discharge curves of two batteries (aa type) with a capacity of 1500 mAh and 2500, respectively. The discharge current 1000 mA.
- •24. Describe the designfeatures of an electrochemical cells an example of the construction of any power source.
- •25. Explain the combination of high electrochemical activity of the lithium with very low self-discharge of the lithium electrode in an electrolyte.
- •26. Compare the specific characteristics of alkaline manganese-zinc, salt and primary lithium sells.
- •27. Draw a typical discharge curves of the lithium primary battery and alcaline battery on the picture.
- •28. Consider the impact of the discharge current, temperature on the capacitance and discharge voltage of the lead-acid batteries.
- •29. Describe the main characteristics of the battery: voltage, capacity, specific energy.
24. Describe the designfeatures of an electrochemical cells an example of the construction of any power source.
An electrochemical battery consists of cathode, anode and electrolyte. When charging the battery, the accumulation of electrons at the anode, which creates a voltage potential between the anode and the cathode. In normal operation, as power supply current flows from the cathode to the anode through the load. When charging the battery the current flows in the opposite direction. The electrodes of the battery are connected in two different ways, the first is electric circuit through which electrons flow to feed the load and the second through the electrolyte, where ions move between the electrodes through the dielectric separator (separator). The electrode that releases electrons during a redox reaction is called the anode. The electric potential of the anode of a galvanic cell is negative relative to the cathode. A chemical reaction in the battery is a reversible process, and therefore, the polarity of the electrodes changes depending on the operation mode (charge/discharge), but the terminal marking is always constant. In tables 1, 2 , 3, 4 describes the structure and processes in lithium, lead, Nickel and alkaline batteries.
Тable 1. Composition and processes in Lithium-ion batteries
Li-ion battery |
Cathode |
Anode |
Electrolyte |
material composition of the elements |
lithium metal oxides |
carbon based |
lithium salts in an organic solven |
composition and processes in charged state |
a metal oxide with an intercalation structure |
migration of lithium ions to the anode |
|
composition and processes in discharged state |
lithium ions return to the positive electrode |
mostly carbon based |
Тable 2. Composition and processes in lead-acid batteries
Lead-acid battery |
Cathode |
Anode |
Electrolyte |
material composition of the elements |
lead dioxide |
gray spongy lead |
hydrochloric acid |
composition and processes in charged state |
lead dioxide, the electrons join |
lead, electrons are detached |
strong sulphuric acid |
composition and processes in discharged state |
lead is converted to lead sulfide at the anode with the release of electrons, and attached at the cathode |
weak sulfuric acid (diluted with water) |
|
Table 3. Composition and processes in NiMH and NiCd batteries.
-
NiMH,NiCd
Cathode
Anode
Electrolyte
material composition of the elements
Ni
NiMH
NiCd
potassium hydroxide
Table 4. Composition and processes in alkaline batteries.
Alkaline battery |
Cathode |
Anode |
Electrolyte |
material composition of the elements |
manganese dioxide |
zinc |
an aqueous solution of alkali |
When submerged unpressurized system the design of the battery, a liquid electrolyte flowing between two electrodes. In hermetic designs the electrolyte is usually in the role of impregnation of the separator to provide the movement of ions from anode to cathode and back when charging. Ions are atoms, which electrons have attached or lost. They acquire the ability to move between the electrodes through the separator.
