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24. Describe the designfeatures of an electrochemical cells an example of the construction of any power source.

An electrochemical battery consists of cathode, anode and electrolyte. When charging the battery, the accumulation of electrons at the anode, which creates a voltage potential between the anode and the cathode. In normal operation, as power supply current flows from the cathode to the anode through the load. When charging the battery the current flows in the opposite direction. The electrodes of the battery are connected in two different ways, the first is electric circuit through which electrons flow to feed the load and the second through the electrolyte, where ions move between the electrodes through the dielectric separator (separator). The electrode that releases electrons during a redox reaction is called the anode. The electric potential of the anode of a galvanic cell is negative relative to the cathode. A chemical reaction in the battery is a reversible process, and therefore, the polarity of the electrodes changes depending on the operation mode (charge/discharge), but the terminal marking is always constant. In tables 1, 2 , 3, 4 describes the structure and processes in lithium, lead, Nickel and alkaline batteries.

Тable 1. Composition and processes in Lithium-ion batteries

Li-ion battery

Cathode

Anode

Electrolyte

material composition of the elements

lithium metal oxides

carbon based

lithium salts in an organic solven

composition and processes in charged state

a metal oxide with an intercalation structure

migration of lithium ions to the anode

composition and processes in discharged state

lithium ions return to the positive electrode

mostly carbon based

Тable 2. Composition and processes in lead-acid batteries

Lead-acid battery

Cathode

Anode

Electrolyte

material composition of the elements

lead dioxide

gray spongy lead

hydrochloric acid

composition and processes in charged state

lead dioxide, the electrons join

lead, electrons are detached

strong sulphuric acid

composition and processes in discharged state

lead is converted to lead sulfide at the anode with the release of electrons, and attached at the cathode

weak sulfuric acid (diluted with water)

Table 3. Composition and processes in NiMH and NiCd batteries.

NiMH,NiCd

Cathode

Anode

Electrolyte

material composition of the elements

Ni

NiMH

NiCd

potassium hydroxide

Table 4. Composition and processes in alkaline batteries.

Alkaline battery

Cathode

Anode

Electrolyte

material composition of the elements

manganese dioxide

zinc

an aqueous solution of alkali

When submerged unpressurized system the design of the battery, a liquid electrolyte flowing between two electrodes. In hermetic designs the electrolyte is usually in the role of impregnation of the separator to provide the movement of ions from anode to cathode and back when charging. Ions are atoms, which electrons have attached or lost. They acquire the ability to move between the electrodes through the separator.

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