- •1. Describe current state of processing of mineral resources of Kazakhstan.
- •2. Specify main minerals and ores of rare metals and their methods of enrichment in Kazakhstan.
- •Methods of enrichment
- •3. Give general principles of study of rare metal raw material
- •Describe and give examples of methods of decomposition of rare metal materials.
- •Example. The decomposition tungsten concentrates with sodium hydroxide solution
- •5. Give examples of methods of processing tungsten concentrates
- •6. Give examples of methods of processing molybdenum concentrates
- •7. Describe modern technologies of processing of mineral raw materials containing gallium
- •Preparation of gallium concentrate from aluminate solutions
- •8. Show differences modern technology of processing of mineral raw materials containing molybdenum and tungsten.
- •9. Describe methods of waste-free processing of molybdenum.
- •10. Describe the main problems flotation of minerals and loss of useful components in the flotation mineral processing
- •11. Describe modern technologies of processing of mineral raw materials containing rhenium.
- •12. Describe modern technologies of processing of mineral raw materials containing germanium
- •13. Describe production of high purity germanium compounds
- •Describe modern technological scheme of processing of vanadium
- •Explain differences of purification methods of gallium.
- •Explain technological schemes of rhenium from Zhezkazgan ore, sources loss of rhenium and methods to reduce losses
- •Methods of increasing the extraction of rhenium
- •18.Compare and describe modern technologies of processing of mineral raw materials containing titanium.
- •19. Show the differences in modern technology in the processing of zirconium and hafnium containing rare metal raw materials.
- •20. Explain the differences extraction of selenium and tellurium from waste of industry
- •Roasting with sodium carbonate
- •Roasting
- •21. Compare methods of decomposition of tantalum and niobium containing rare metal raw materials.
- •Decomposition of tantalite-columbite with hydrofluoric acid
- •Decomposition of Tantalite and columbite concentrate with sodium hydroxide
- •Explain production of high purity gallium.
- •23. Explain processing of thallium containing rare metal raw materials.
- •Tl production
- •24. Explain differences of extractions methods of indium from waste of industry.
- •In production from Zinc Circuits
- •24. Critically evaluate production of high purity indium and thallium.
- •Chemical methods
- •Electrolytic refining
- •Thallium refining
- •25. Explain production of lithium metal.
- •26. Create a modern technological scheme of processing of mineral raw materials containing lithium.
- •The sulfuric acid method (пишите любо текс, либо рисуйте схему)
- •27. Create a modern technological scheme of processing of mineral raw materials containing beryllium.
- •Sulfate process, h2so4
- •Sintering
- •Rubidium Alums, Extraction
- •31. Analyze the methods of extraction of rubidium and cesium from radioactive waste.
- •32. Propose technological processes without waste and low-waste processing.
- •Evaluate modern physical and chemical methods of analysis of rare and rare earth metals.
- •Create a modern technological scheme of processing of mineral raw materials containing scandium.
- •43. Analyze contribution of scientists of Kazakhstan in the development of technology of mineral processing, waste-free and low-waste technologies.
- •Critically analyze current non-waste technologies in production of rare metals.
- •Analyze and choose extraction methods of obtaining of rare metals.
- •Evaluate electrochemical methods of extraction of rare metals in Kazakhstan.
- •Critically evaluate of methods of purification to obtain pure rare metals.
Methods of enrichment
The classification of ores and deposits of rare metals
Ores types |
The main methods of primary enrichment |
The main methods of finishing concentrates |
Minerals of titanium, zirconium, tantalum, niobium and other. |
The gravity processes |
Magnetic and electric separation |
Ores of lithium, beryllium and cesium |
Flotation with fatty acid. Pre-enrichment in heavy suspensions |
Selective flotation |
Refractory ores of rare metals (tantalum, niobium, zirconium, hafnium, titanium) |
The gravity processes with magnetic separation and flotation |
Magnetic and electrical separation with gravity and flotation |
Uranium ore |
Hydrometallurgical processes |
The extraction of uranium from pulps using ion-exchange resins |
3. Give general principles of study of rare metal raw material
Rare metals play an important role in the development of major branches of industry, such as vacuum equipment, semiconductor electronics, nuclear power and rocket production, as well as in production of special steels and hard, refractory and corrosion – resistant alloys.
Accordingly, the composition of the ore minerals are sulfide, oxidized, native and others. Industrial used Minerals of rare metals, usually presented non-sulfide compounds: oxides, silicates, aluminum silicates. Simple or complex oxides are titanium minerals ilmenite, rutile, etc .; minerals of tantalum and niobium-tantaoite, colombite; zirconium-mineral baddeleyite.
Sources of rare metals
Rare-metal pegmatites - coarse-grained rock consisting mainly of quartz and feldspar and rich in minerals containing volatile substances (water, fluoride, boron, chlorine). For the rare-metal pegmatites characteristic zonal structure with separate clusters of pollucite, lepidolite, spodumene, beryl. Because of zoning and large crystal size (beryl - up to 2 m, spodumene - up to 10 m in length) pegmatite veins develop manually.
Placers - rare-metal minerals, resistant to chemical and physical weathering accumulate in placers. Group minerals tantalite - columbite are concentrated in placers near the demolition, indigenous source of which can be rare-metal pegmatites and granites. Reserves these placers are usually small.
Carbonatites – products of crystallization of deep carbonate melts (magma). Carbonatite deposits and weathering crust (Nb), and indigenous carbonatite deposits (La, Ce, Pr, Nd) were discovered and explored after the Second World War. Compared with pegmatites and placers it was rich and very large fields, two of which were quickly mastered the industry and have become the main sources of niobium and rare earth raw materials in the world.
Alkaline granites - characterized by a constant a collection of useful components and the relative stability of their content: 0,02-0,04%. Rare-metal alkali granites - is the largest reserves of deposits of tantalum and rare earth elements yttrium and zirconium largest primary deposits.
