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MICROSTRUCTURE OF POLYMERIC NANOMATERIALS / 03. Classification ПНнинг синфланиши ва олиниш Кластерлар турлари..pptx
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ПОЛИМЕР

НАНОМАТЕРИАЛЛАР

МИКРОСТРУКТУРАС

И

3. ПНнинг синфланиши ва олиниш усуллари Кластерлар ва уларнинг турлари Кластер моделлар ва ўлчов эффектлар

Молекуляр ва лигандсиз металлик кластерлар Нанокристаллитлар ва толали структуралар

Тохир Х.Рахимов

ПОЛИМЕР

НАНОМАТЕРИАЛЛАР

МИКРОСТРУКТУРАС

И

3. Синфланиш ва олиниш усуллари

Кластерлар, нанокристаллитлар ва толали структуралар

Тохир Х.Рахимов

Тохир Х.Рахимов

Режа – План - Schedule

 

ПНнинг синфланиши

Олиниш усуллари

Кластерлар

Кластер моделлар ва ўлчов эффектлар Молекуляр ва лигандсиз металлик кластерлар

Бошқа турлари

Нанокристаллитлар ва толали структуралар

Др. Тохир Х.Рахимов

ПНнинг синфланиши

Тохир Х.Рахимов

Олиниш усуллари

materials aspects

• Are important, where efficient insulation or lightweight construction

can

save energy,

polymer membranes are used for drinking water generation

solar cells with new

organic semiconductors are developed for cheap

the progress of mankind

was largely connected with materials development,

ranging from stone, bronze, and iron age

to modern times, where then many other materials became important

Др. Тохир Х.Рахимов

ПНнинг синфланиши

Тохир Х.Рахимов

Олиниш усуллари

One of the developments with many

facets

are “nanomaterials,”

where according to the definition at least one dimension

in the material is

smaller than 1000 nm,

in a more rigorous and commonly accepted

definition smaller than 100 nm

Др. Тохир Х.Рахимов

ПНнинг синфланиши

Тохир Х.Рахимов

Олиниш усуллари

Polymer nanomaterials

• contain at least one polymer as a component

They include for instance

the so-called nanostructured materials.

The preparation of a single material or a blend of materials can be performed in such a way that

crystal domains or phases

are formed at nanoscale

which as a function of their size

can alter materials properties significantly.

Ex

• Domain walls,

• interfaces,

• interphases or defects

just the introduction of nanoholes into a homopolymer can significantly change mechanical properties of this material.

Block-copolymers, where micro-phase segregation occurs at molecular level, should also be considered

here.

If newly formed phases are anisotropic at nano, micro, or macro scale, this again will modify properties in a particular way

Др. Тохир Х.Рахимов

ПНнинг синфланиши

Тохир Х.Рахимов

Олиниш усуллари

Polymer nanomaterials

• contain at least one polymer as a component

They include for instance

the so-called nanostructured materials.

The preparation of a single material or a blend of materials can be performed in such a way that

crystal domains or phases

are formed at nanoscale

which as a function of their size

can alter materials properties significantly.

Ex

• Domain walls,

• interfaces,

• interphases or defects

Masalan, nanoteshiklarni gomopolimerga kiritish mexanik xususiyatlarini sezilarli darajada o'zgartiradi

Sopolimerlarni bloklash, mikro fazali ajratish molekulyar

darajada sodir bo'lgan joyda ham e'tiborga sazovor

Agar yangi hosil bo'lgan fazalar nano, mikro yoki makro miqyosda anizotrop bo'lsa, bu xususiyatlarni ma'lum bir tarzda o'zgartiradi

Др. Тохир Х.Рахимов

ПНнинг синфланиши

Тохир Х.Рахимов

Nanocomposites

The addition or in situ synthesis of nanoparticles,

which often are formed from inorganic components,

can introduce new functionalities

In many cases already at very low concentrations of those particles a significant change of properties is observed.

nanocomposites offer

conductive or magnetic materials to optically active or mechanically reinforced materials for instance.

Some nanocomposites are already

known since a long time,

which includes automotive tires filled with carbon black or colored glasses containing metal nanoparticles.

New multifunctional formulations are now on the way, which include self-repairing composites or materials with sensing properties.

Ko'pincha noorganik tarkibiy qismlardan hosil bo'lgan nanozarrachalar qo'shilishi yoki joyida sintezi yangi funktsiyalarni keltirib chiqarishi mumkin.

Ko'pgina holatlarda zarrachalarning juda past konsentratsiyasida xossalarning sezilarli o'zgarishi kuzatiladi.

Ushbu nanokompozitlar Supero'tkazuvchilar yoki magnit materiallardan tortib optik faol yoki mexanik mustahkamlangan materiallarga qadar ko'plab imkoniyatlarni taklif etadi.

Ba'zi nanokompozitlar uzoq vaqtdan beri ma'lum, ular tarkibida uglerod qora-kuya yoki rangli oynalar.

O'z-o'zidan tuzatuvchi kompozitlar yoki sezgir xususiyatlarga ega materiallar - ko'p funktsional formulalar - hozirda tayyorlanmoqda.

Др. Тохир Х.Рахимов

ПНнинг синфланиши

Тохир Х.Рахимов

Nanocomposites

nano-sized and isolated nanoscale objects

nanoscopicaly thin platelets

Ultra-thin mats

of electro-spun polymer nanofibers used for pollution filters are an example

as well as nanowhiskers of cellulose.

surface properties.

• Those surface properties can be tuned by a thin nanoscopic coating.

Smart surfaces

• then even may change properties in response to an

nanofibers

external trigger

• like temperature,

• pH,

• or light,

• and the properties of the material become responsive or

adaptive to environmental conditions

Др. Тохир Х.Рахимов

ПНнинг синфланиши

Тохир Х.Рахимов

Nanocomposites

nano o'lchamdagi va izolyatsiyalangan nanoskal ob'ektlar

nanoskopik yupqa trombotsitlar

nanotolalar

Ifloslanish filtrlari uchun ishlatiladigan elektro-ipli polimer nanofiberlarning ultra yupqa paspaslari tsellyuloza nanohiskerslariga misoldir.

Ushbu sirt xususiyatlarini nozik nanoskopik qoplama yordamida sozlash mumkin.

Aqlli sirtlar

harorat, pH yoki yorug'lik kabi tashqi qo'zg'atuvchiga qarab xususiyatlarini o'zgartirishi mumkin va materialning xususiyatlari, masalan, atrof-muhit sharoitlariga moslashuvchan yoki moslashuvchan bo'ladi.

Др. Тохир Х.Рахимов

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