- •ПОЛИМЕР
- •ПОЛИМЕР
- •Тохир Х.Рахимов
- •ПНнинг синфланиши
- •ПНнинг синфланиши
- •ПНнинг синфланиши
- •ПНнинг синфланиши
- •ПНнинг синфланиши
- •ПНнинг синфланиши
- •ПНнинг синфланиши
- •ПНнинг синфланиши
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов Систематизация и
- •Тохир Х.Рахимов Систематизация и
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
- •Тохир Х.Рахимов
ПОЛИМЕР
НАНОМАТЕРИАЛЛАР
МИКРОСТРУКТУРАС
И
3. ПНнинг синфланиши ва олиниш усуллари Кластерлар ва уларнинг турлари Кластер моделлар ва ўлчов эффектлар
Молекуляр ва лигандсиз металлик кластерлар Нанокристаллитлар ва толали структуралар
Тохир Х.Рахимов
ПОЛИМЕР
НАНОМАТЕРИАЛЛАР
МИКРОСТРУКТУРАС
И
3. Синфланиш ва олиниш усуллари
Кластерлар, нанокристаллитлар ва толали структуралар
Тохир Х.Рахимов
Тохир Х.Рахимов |
Режа – План - Schedule |
|
ПНнинг синфланиши
Олиниш усуллари
Кластерлар
Кластер моделлар ва ўлчов эффектлар Молекуляр ва лигандсиз металлик кластерлар
Бошқа турлари
Нанокристаллитлар ва толали структуралар
Др. Тохир Х.Рахимов
ПНнинг синфланиши
Тохир Х.Рахимов |
Олиниш усуллари |
materials aspects
• Are important, where efficient insulation or lightweight construction
can
•save energy,
•polymer membranes are used for drinking water generation
•solar cells with new
organic semiconductors are developed for cheap
the progress of mankind
•was largely connected with materials development,
•ranging from stone, bronze, and iron age
•to modern times, where then many other materials became important
Др. Тохир Х.Рахимов
ПНнинг синфланиши
Тохир Х.Рахимов |
Олиниш усуллари |
One of the developments with many
facets
•are “nanomaterials,”
•where according to the definition at least one dimension
in the material is
smaller than 1000 nm,
•in a more rigorous and commonly accepted
definition smaller than 100 nm
Др. Тохир Х.Рахимов
ПНнинг синфланиши
Тохир Х.Рахимов |
Олиниш усуллари |
Polymer nanomaterials |
• contain at least one polymer as a component |
They include for instance
•the so-called nanostructured materials.
•The preparation of a single material or a blend of materials can be performed in such a way that
crystal domains or phases
•are formed at nanoscale
•which as a function of their size
•can alter materials properties significantly.
Ex |
• Domain walls, |
• interfaces, |
• interphases or defects |
just the introduction of nanoholes into a homopolymer can significantly change mechanical properties of this material.
Block-copolymers, where micro-phase segregation occurs at molecular level, should also be considered
here.
If newly formed phases are anisotropic at nano, micro, or macro scale, this again will modify properties in a particular way
Др. Тохир Х.Рахимов
ПНнинг синфланиши
Тохир Х.Рахимов |
Олиниш усуллари |
Polymer nanomaterials |
• contain at least one polymer as a component |
They include for instance
•the so-called nanostructured materials.
•The preparation of a single material or a blend of materials can be performed in such a way that
crystal domains or phases
•are formed at nanoscale
•which as a function of their size
•can alter materials properties significantly.
Ex |
• Domain walls, |
• interfaces, |
• interphases or defects |
Masalan, nanoteshiklarni gomopolimerga kiritish mexanik xususiyatlarini sezilarli darajada o'zgartiradi
Sopolimerlarni bloklash, mikro fazali ajratish molekulyar
darajada sodir bo'lgan joyda ham e'tiborga sazovor
Agar yangi hosil bo'lgan fazalar nano, mikro yoki makro miqyosda anizotrop bo'lsa, bu xususiyatlarni ma'lum bir tarzda o'zgartiradi
Др. Тохир Х.Рахимов
ПНнинг синфланиши
Тохир Х.Рахимов |
Nanocomposites |
The addition or in situ synthesis of nanoparticles,
•which often are formed from inorganic components,
•can introduce new functionalities
•In many cases already at very low concentrations of those particles a significant change of properties is observed.
nanocomposites offer
•conductive or magnetic materials to optically active or mechanically reinforced materials for instance.
•Some nanocomposites are already
known since a long time,
•which includes automotive tires filled with carbon black or colored glasses containing metal nanoparticles.
•New multifunctional formulations are now on the way, which include self-repairing composites or materials with sensing properties.
Ko'pincha noorganik tarkibiy qismlardan hosil bo'lgan nanozarrachalar qo'shilishi yoki joyida sintezi yangi funktsiyalarni keltirib chiqarishi mumkin.
Ko'pgina holatlarda zarrachalarning juda past konsentratsiyasida xossalarning sezilarli o'zgarishi kuzatiladi.
Ushbu nanokompozitlar Supero'tkazuvchilar yoki magnit materiallardan tortib optik faol yoki mexanik mustahkamlangan materiallarga qadar ko'plab imkoniyatlarni taklif etadi.
Ba'zi nanokompozitlar uzoq vaqtdan beri ma'lum, ular tarkibida uglerod qora-kuya yoki rangli oynalar.
O'z-o'zidan tuzatuvchi kompozitlar yoki sezgir xususiyatlarga ega materiallar - ko'p funktsional formulalar - hozirda tayyorlanmoqda.
Др. Тохир Х.Рахимов
ПНнинг синфланиши
Тохир Х.Рахимов |
Nanocomposites |
nano-sized and isolated nanoscale objects
nanoscopicaly thin platelets
Ultra-thin mats
•of electro-spun polymer nanofibers used for pollution filters are an example
•as well as nanowhiskers of cellulose.
surface properties.
• Those surface properties can be tuned by a thin nanoscopic coating.
Smart surfaces
• then even may change properties in response to an
nanofibers
external trigger |
• like temperature, |
• pH, |
• or light, |
• and the properties of the material become responsive or |
adaptive to environmental conditions
Др. Тохир Х.Рахимов
ПНнинг синфланиши
Тохир Х.Рахимов |
Nanocomposites |
nano o'lchamdagi va izolyatsiyalangan nanoskal ob'ektlar
nanoskopik yupqa trombotsitlar
nanotolalar
•Ifloslanish filtrlari uchun ishlatiladigan elektro-ipli polimer nanofiberlarning ultra yupqa paspaslari tsellyuloza nanohiskerslariga misoldir.
•Ushbu sirt xususiyatlarini nozik nanoskopik qoplama yordamida sozlash mumkin.
Aqlli sirtlar
•harorat, pH yoki yorug'lik kabi tashqi qo'zg'atuvchiga qarab xususiyatlarini o'zgartirishi mumkin va materialning xususiyatlari, masalan, atrof-muhit sharoitlariga moslashuvchan yoki moslashuvchan bo'ladi.
Др. Тохир Х.Рахимов